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1-1
Calcule las composiciones del vapor y del lquido en equilibrio a 95C para Benceno-Tolue
kpa
Ecuacion de Antonie
log =/(+)
P= presion de vapor (mmHg)
T= temperatura (C)
calcular T de ebullicin a 1 atm o 760 mmHg donde P=760mmHg
Benceno
log =/(+)
constantes de Antonie
A=
6.89272
B= 1203.531
C=
219.888
=/(log )
Calcular P vapor en rango de temperaturas de ebullicion del mas volatil al menos volati
Temp.
80.1018
83.153836
86.205872
89.257908
92.309944
95.36198
98.414016
101.46605
104.51809
107.57012
110.62216
Pv A
760
834.1014
913.73098
999.16212
1090.6731
1188.547
1293.071
1404.5366
1523.239
1649.4769
1783.5521
Pv B
292.23614
324.3446
359.23284
397.07154
438.0368
482.31
530.07771
581.53158
636.8682
696.28898
760
Xa
1
0.8546338
0.7227565
0.6027805
0.4933271
0.3931966
0.3013425
0.2168497
0.1389168
0.0668399
2.33E-008
Ya
1
0.9379622
0.868954
0.7924677
0.7079719
0.6149114
0.5127069
0.4007545
0.2784257
0.145067
5.48E-008
Xb
1.7013E-015
0.145366175
0.27724345
0.397219499
0.506672875
0.606803357
0.698657507
0.783150257
0.86108319
0.933160057
0.999999977
1.2
1
0.8
0.6
0.4
0.2
0
0.2
0.4
0.6
0.8
1.2
Lineas de Equilibrio B
Linea equilibrio Benceno (A)
1.2
1
0.8
0.6
0.4
0.2
0
0.2
0.4
0.6
Para resolver el Problema usaremos la Ec. De Antonie para calcular las presiones de va
Benceno
log =/(+)
constantes de Antonie
A=
6.89272
B=
1203.531
log =6.892721203.531/(219.888+95)
C=
219.888
P= 1176.5969
calcular Xa,Ya,Xb,Yb
P=
=+
760
=1
=+(1)
=()/()
=()/()
mmHg
Xa=
Xb=
Ya=
Yb=
Ecuacion de Raoult
=
=()/
=()/
120
100
80
Temperatura
60
Xa vs T
Ya vs T
40
20
0
0
0.1
0.2
0.3
0.4
0.5
Axis Title
0.6
0.7
0.8
0.9
de puntos de ebullcin.
log =/(+)
Tolueno
=/(log )
constantes de Antonie
A=
6.95805
B= 1346.773
C=
219.693
calcular Xa,Ya,Xb,Yb
P=
=+
760
mmHg
=1
=+(1)
=()/()
=()/()
Ecuacion de Raoult
=
=()/
=()/
1.2
1
0.8
0.6
0.4
0.2
0
1.2
0.2
0.4
0.6
0.8
0.4
0.6
0.8
1.2
lar las presiones de vapor a 95C para ambos sistemas Benceno y Tolueno con una presion de 76
Antonie
log =/(+)
Tolueno
constantes de Antonie
A=
6.95805
B= 1346.773
log =6.958051346.773/(219.693+95)
C=
219.693
P= 476.88011
1.2
1
0.8
0.6
Linea de equilibr
Fraciones Xa y Ya a 95C
Fraciones Xb y Yb
.9
1.2
1
0.8
0.6
0.4
0.2
0
0.2
0.4
0.6
X
Xa vs T
Ya vs T
0.8
vs Yb
1.2
de Antonie
T=
ibrio Benceno-Tolueno
o (A)
Fraciones Xb y Yb a 95C
95
0.6
X
0.8
1.2
Ejemplo 11.2-1
Un vapor a su punto de rocio y 101.32 kpa, que contiene una fraccion mol de 0.4 de benc
de 100 kg mol, se pone en contacto con 110 kg mol de un liquido a su punto de ebullicion
de benceno y 0.7 de tolueno. Las dos corrientes entran en contacto en una sola etapa, y
equilibrio entre si, suponga un derrame molal constante. calcule la cantidad y las compsi
V1
L= 110 kg mol
Xa= 0.3
=1
Quedando el balance de la
+22=11+11
+22=1+21
Ya
1
0.93796219
0.86895401
0.79246768
0.70797189
0.61491141
0.51270688
0.40075447
0.27842566
0.14506702
5.4794E-008
1.2
1
0.8
0.6
0.4
0.2
0
0.2
0.4
0.6
Linea de 45
0.8
1
Valores tabulados
a vapor-liquido
Ya2= 0.40
V2=
100 kg mol
L1
0.8
0.6
0.4
2=1+21
0.2
0
Xb
1.7013E-015
0.14536618
0.27724345
0.3972195
0.50667288
0.60680336
0.69865751
0.78315026
0.86108319
0.93316006
0.99999998
Yb
6.5419E-016
0.06203781
0.13104599
0.20753232
0.29202811
0.38508859
0.48729312
0.59924553
0.72157434
0.85493298
0.99999995
istema Benceno-Tolueno
0.2
0.4
0.6
(64&(110(0.30)+100(0.40
)110(1))/100 =1)
Ya
0.51
0.3
0.4
0.5
0.6
0.4
0.29
0.18
0.07
0.8
45
1.2
Valores tabulados
Xa
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
Ya
0.51
0.499
0.488
0.477
0.466
0.455
0.444
0.433
0.422
0.411
0.4
0
1
0
1
0.4
0.6
0.8
1.2
Linea de 45
nce de materia global con las condiciones de derrame molal constante tenemos lo siguiente
1)+100(1)
ero como las corrientes saldran en equilibrio usaremos el diagrama que realizamos previamnte e
e tal modo que suponiendo una Xa hayemos una Ya
1)+100(1)
a tabularemos
0.8
0.6
0.4
0.2
0.2
0.4
Curva de equilibrio Benceno
0.6
Linea de 45
Valor
tenemos lo siguiente
ema Benceno-Tolueno
no
0.6
Linea de 45
0.8
Valores tabulados
1.2
Ejemplo 11.3-1
Temp.
80.1017998
83.1538358
86.2058718
89.2579078
92.3099438
95.3619798
98.4140158
101.466052
104.518088
107.570124
110.62216
Pv A
760
834.101395
913.730977
999.162115
1090.67312
1188.54696
1293.07097
1404.53658
1523.23898
1649.47686
1783.55209
Pv B
292.236138
324.344601
359.232839
397.071544
438.036802
482.309998
530.077708
581.531577
636.8682
696.288977
759.999976
Ecuacion de Antonie
log =/(+)
P=
T=
Benceno
log =6.89272120
log =6.89272120
Tolueno
log =/(+)
constantes de Antonie
A=
6.95805
B=
1346.773
log =6.958051346.773/(219.693+85)
C=
219.693
T=
85
T=
105
log =6.958051346.773/(219.693+105)
P1= 345.105386
P2= 645.973896
ceno-Tolueno
acion de Antonie
log =/(+)
presion de vapor (mmHg)
temperatura (C)
log =/(+)
constantes de Antonie
A=
6.89272
B=
1203.531
log =6.892721203.531/(219.888+85)
C=
219.888
T=
85
T=
105
log =6.892721203.531/(219.888+105)
P1= 881.591034
P2= 1542.66307
calculamos lavolatilidad relativa para ambas temperaturas
=/
85C=
105C=
2.554556
2.38811983
Ejemplo 11.4-1
=100/
=+
=0.45
562.16
327.6
0.5827522414
47500000
0.45238
0.0534
=(()+())/()
Tb 366.66
Tr= 0.65223424
2 29939.9055
graficar line
Segn datos de mis tablas
q1=
1.18919019
c4
-0.1181
1 32238.8305688
q2=
1.20371709
libro
32099
Cp libro 159 kj/kg mol k
capacidad calorifica del benceno datos sacados de geankoplis tabla A.3-11
T, K
Kj/kg K
293
1.7
=0.004+0.5353
333
1.859
Cp=
2.00194
156.15132 kj/kg mol K
Mc6h6
78
Cp del benceno
1.9
1.85
1.8
Axis Title
Cp del benceno
1.75
Axis Title
lueno
=0.95
calculamos D y W
=
sustituyendo
=()+
100(0.45)=1000(0.95)(0.95)+(0.1)
=+
100(0.450.95)=(0.10.95)
(100(0.450.95))/((0.10.95))=
=58.82352941/
=10058.82352941
=41.17647059/
=0.1
Y
0.67
0.98
0.21
linea 45
0
1
))/()
+1=0.80+0.190
graficar linea q segn datos del libro
=/(1)/(1)
DONDE R=1
Xn
0
0.1
0.15
0.2
0.3
0.4
0.45
0.5
Yn
0.19
0.27
0.31
0.35
0.43
0.51
0.55
0.59
kj/kg mol k
tabla A.3-11
nceno
del benceno)
x
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.8
y
-0.469292
-0.162892
0.143508
0.449908
0.756308
1.062708
1.369108
1.675508
1.981908
2.288308
2.594708
0.55
0.6
0.65
0.7
0.75
0.8
0.85
0.9
0.95
1
0.63
0.67
0.71
0.75
0.79
0.83
0.87
0.91
0.95
0.99
es liquida y
nceno y 5% mol
dio de la
Datos de equilibrio
Temp.
Pv A
80.1017998
760
83.1538358 834.101395364
86.2058718 913.730976917
89.2579078 999.162115325
92.3099438 1090.67312008
95.3619798 1188.54695895
98.4140158 1293.07097128
101.466052 1404.5365761
104.518088 1523.23897597
107.570124 1649.47685764
110.62216 1783.55209026
Pv B
292.236138
324.344601
359.232839
397.071544
438.036802
482.309998
530.077708
581.531577
636.8682
696.288977
759.999976
Xa
1
0.85463382
0.72275655
0.6027805
0.49332712
0.39319664
0.30134249
0.21684974
0.13891681
0.06683994
2.3349E-008
Ya
1
0.93796219
0.86895401
0.79246768
0.70797189
0.61491141
0.51270688
0.40075447
0.27842566
0.14506702
5.4794E-008
zona de enrequesimiento q
1
linea 45
0
1
0.8
0.6
0.4
0.2
-0.2
-0.4
-0.6
0.1
0.2
0.3
0.4
0.5
0.6
0.
-0.4
-0.6
=0.10
=0.45
zona de enrequesimiento q1
1
0.8
0.6
0.4
0.2
0.1
0.2
0.3
0.4
0.5
0.6
0.7
-0.2
-0.4
-0.6
=0.10
=0.95
=0.45
zona de enrequesimiento
1
0.8
0.6
0.4
0.2
=0.10
0
=0.95
=0.45
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.4
0.2
=0.10
0
=0.95
=0.45
0.1
0.2
0.3
0.4
0.5
0.6
0.7
-0.2
-0.4
-0.6
=0.10
=0.45
=0.95
Xb
1.7013E-015
0.14536618
0.27724345
0.3972195
0.50667288
0.60680336
0.69865751
0.78315026
0.86108319
0.93316006
0.99999998
Yb
6.5419E-016
0.06203781
0.13104599
0.20753232
0.29202811
0.38508859
0.48729312
0.59924553
0.72157434
0.85493298
0.99999995
quesimiento q
0.5
0.6
0.7
0.8
0.9
=0.95
esimiento q1
.5
0.6
0.7
0.8
0.9
0.8
0.9
=0.95
uesimiento
.5
=0.95
0.6
0.7
.5
=0.95
0.6
0.7
=0.95
0.8
0.9
Ejemplo 11.4-2
Calcule lo siguiente para la rectificacion del ejemplo 11.4-1, en el que se destila una alim
destilado de Xd=0.95 y una composicion de residuos de Xw=0.1
Datos de equilibrio
Temp.
Pv A
80.1017998
760
83.1538358 834.101395
86.2058718 913.730977
89.2579078 999.162115
92.3099438 1090.67312
95.3619798 1188.54696
98.4140158 1293.07097
101.466052 1404.53658
104.518088 1523.23898
107.570124 1649.47686
110.62216 1783.55209
2.graficar linea de 45
x
y
0
0
1
1
Pv B
292.236138
324.344601
359.232839
397.071544
438.036802
482.309998
530.077708
581.531577
636.8682
696.288977
759.999976
Xa
1
0.85463382
0.72275655
0.6027805
0.49332712
0.39319664
0.30134249
0.21684974
0.13891681
0.06683994
2.3349E-008
Ya
1
0.93796219
0.86895401
0.79246768
0.70797189
0.61491141
0.51270688
0.40075447
0.27842566
0.14506702
5.4794E-008
3. Graficar Recta q
=/(1)/(1)
=(()+())/()
327.6
129440
-169.5
0.64781
C4=
0
Cp= 143435.909
Cp=
y
-0.55244459
-0.21829639
0.1158518
0.45
0.7841482
1.11829639
1.45244459
1.78659279
2.12074099
2.45488918
2.78903738
/(+1)=()/(
=(()/())/(1(
Yb
6.5419E-016
0.06203781
0.13104599
0.20753232
0.29202811
0.38508859
0.48729312
0.59924553
0.72157434
0.85493298
0.99999995
Resolucion de Problema
1
^=0.70
0.8
0.6
0.4
0.2
^=0.49
0
-0.2
-0.4
-0.6
-0.8
mos delta H y el Cp
e tablas Perry 2-144 y 2-164 2-196
=J/Kg mol
q= 1.17596452
=1+(2)+(3^2)
/()
Temperaturas
143.435909/()
Temperaturas
=0.45
^=0.70
^=0.49
0.15
0.3
0.45
X-Y
/(+1)=()/()
0.54347826
Rmin= 1.19047619
=(()/())/(1()/())
0.
Ecuacion de Fenske
=(log(/(1)
(1)/)/log
=(/)/((1)(1))
mposicion de
esolucion de Problema
=0.95
linea 45
^=0.49
curva de equlibrio
Recta q
))/()
X vs T
Y vs T
=94 .
X vs T
Y vs T
=0.45
0.15
0.3
0.45
acion de Fenske
og(/(1)
)/)/log
=(/)/((1)(1))
0.6
X-Y
0.75
0.9
Ejemplo 11.4-3
En una torre de empobrecimiento que opera a 101.3 Kpa de presion, se introducen 400kg
contiene 70% mol de benceno(A) y 30% mol de tolueno(B). El flujo de producto residual d
resto B. Calcule los kg mol de vapor superior, su composicion y el numero de escalones t
y
0
1
=400/
=0.7
Pv B
292.236138
324.344601
359.232839
397.071544
438.036802
482.309998
530.077708
581.531577
636.8682
696.288977
759.999976
Xa
1
0.85463382
0.72275655
0.6027805
0.49332712
0.39319664
0.30134249
0.21684974
0.13891681
0.06683994
2.3349E-008
Ya
1
0.93796219
0.86895401
0.79246768
0.70797189
0.61491141
0.51270688
0.40075447
0.27842566
0.14506702
5.4794E-008
Y=0.8058
Vd=340/
pobrecimiento
esion, se introducen 400kg mol/h de una alimentacion liquida a punto de ebullicion, que
ujo de producto residual debe ser de 60 kg mol/h, que contiene solamente10% mol de A y el
el numero de escalones teoricos requeridos.
Xb
1.7013E-015
0.14536618
0.27724345
0.3972195
0.50667288
0.60680336
0.69865751
0.78315026
0.86108319
0.93316006
0.99999998
Yb
6.5419E-016
0.06203781
0.13104599
0.20753232
0.29202811
0.38508859
0.48729312
0.59924553
0.72157434
0.85493298
0.99999995
1
0.9
=0.8058
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
=0.1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
+1=/(+1) ()(())/(+
1.-Resolviendo para Xd
()=
400(0.7)60(0.1)=
Donde D=
=
Entonces
400(0.7)60(0.1)=()
=0.1
=60/
V =40060
bullicion, que
e10% mol de A y el
m
= ,
=0.7
0.5
0.6
0.7
0.8
0.9
=/(+1) ()(())/(+1)
Linea de operacin
X
ym+1
0
-0.01759531
0.1
0.09970674
0.15
0.15835777
0.2
0.2170088
0.25
0.27565982
0.3
0.33431085
0.35
0.39296188
0.4
0.4516129
0.45
0.51026393
0.5
0.56891496
0.55
0.62756598
0.6
0.68621701
0.65
0.74486804
0.7
0.80351906
0.75
0.86217009
Lm=
Vm+1=
400
340
W=
Xw=
1
0.9
0.8
=0.8058
0.7
0.6
0.5
0.4
0.3
0.2
0.1
-8.32667268468867E-017
=0.1
0
-0.1
0.1
0.2
0.3
0.4
0.3
0.2
0.1
-8.32667268468867E-017
=0.1
0
-0.1
0.1
0.2
0.3
0.4
0.1
60
0.1
=0.7
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.1
=0.7
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9