Entropa Absoluta del Hierro (Fe)

Mtodo de cubos de DEBYE (0 - 50):

= 3R x

x( )

= 1538 + 273 = 1811

= 55.84
V = 7.10

= 134.4

1.

= 398.22

= 3(

= 0.03078

= 0.2462

= 0.8311

T = 20
= 1943.75(

3.

x( )

T = 10
= 1943.75(

2.

)x

T = 30
= 1943.75(

1943.75( )

 T = 40

4.

= 1943.75(

= 1.9699

= 3.8475

T = 50

5.

= 1943.75(

( ))

1.

=(

)(

) (

2.

=(

)(

) (

)* = 0.24621405

3.

=(

)(

) (

)* = 0.831340286

4.

=(

)(

) (

)* = 1.971699903

5.

=(

)(

) (

)* = 3.854366226

)* = 0.030780109

Mtodo LINDEMAN NERNST:

( )

= R(
(

(
(

)
)

1.

--> T = 30
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.0003028 + 0.05789) = 0.7257

2.

--> T = 40
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.0004704 + 0.173085) = 2.2170

3.

--> T = 50
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.0220 + 0.05789) = 4.1035

4.

--> T = 60
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.057898 + 0.429249) = 6.07472

5.

--> T = 70
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.110244 + 0.530546) = 7.990651

6.

--> T = 80
(

= 12.47 (
(

)
)

(
(

= 12.47 (0.173085 + 0.611457) = 9.78323

)
*

7.

--> T = 90
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.240225 + 0.67542) = 11.418093

8.

--> T = 100
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.307005 + 0.726077) = 12.8825

9.

--> T = 110
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.37052 + 0.766480) = 14.1784

10.

--> T = 120
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.42924 + 0.799010) = 15.3163

11.

--> T = 130
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.482602 + 0.825470) = 16.3116

)
*

12.

--> T = 140
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.530546 + 0.847212) = 17.1806

13.

--> T = 150
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.573356 + 0.865251) = 17.9394

14.

--> T = 160
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.611457 + 0.880358) = 18.6029

15.

--> T = 170
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.645321 + 0.893117) = 19.1843

16.

--> T = 180
(

= 12.47 (
(

(
(

= 12.47 (0.675422 + 0.903981) = 19.6951

17.

--> T = 190
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.702206 + 0.913298) = 20.1453

)
)

18.

--> T = 200
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.726077 + 0.921344) = 20.5433

19.

--> T = 210
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.747396 + 0.928336) = 20.8963

20.

--> T = 220
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.766480 + 0.934448) = 21.2106

21.

--> T = 230
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.783604 + 0.9398199) = 21.4911

22.

--> T = 240
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.79901063 + 0.944564) = 21.7424

23.

--> T = 250
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.812906 + 0.948775) = 21.9682

)
*

24.

--> T = 260
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.825470 + 0.952528) = 22.1716

25.

--> T = 270
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.836860 + 0.955887) = 22.3537

26.

--> T = 280
(

= 12.47 (
(

(
(

= 12.47 (0.847212 + 0.95895) = 22.5220

27.

--> T = 290
(

= 12.47 (
(

)
*

(
(

= 12.47 (0.85664 + 0.961625) = 22.6737

28.

--> T = 295
(

= 12.47 .
(

)
*

(
(

= 12.47 (0.861043 + 0.962886) = 22.7442

29.

--> T = 298
(

= 12.47 (
(

)
)

(
(

= 12.47 (0.863590 + 0.963613) = 22.7852

)
*

( ))

1.

=(

)(

) (

)* = 0.72588

2.

=(

)(

)(

)* = 2.2192

3.

=(

)(

)(

)* = 4.113

4.

=(

5.

=(

6.

=(

7.

=(

8.

=(

)(

)(

)* = 13.0749

9.

=(

)(

)(

)* = 14.4348

10.

=(

)(

)(

)* = 15.6427

11.

=(

)(

) (

)* = 16.7126

12.

=(

)(

) (

)* = 17.6597

13.

=(

)(

) (

)* = 18.4992

14.

=(

)(

) (

)* = 19.2449

15.

=(

)(

) (

)* = 19.9098

16.

=(

)(

) (

)* = 20.5047

17.

=(

)(

) (

)* = 21.0394

18.

=(

)(

) (

)* = 21.5220

19.

=(

)(

) (

)* = 21.9596

)(

)(
)(

)(
(

)(

(
)(

)* = 6.100

)(
(

)* = 8.0424
)* = 9.8720
)(

)* = 11.5542

20.

=(

)(

) (

)* = 22.3583

21.

=(

)(

) (

)* = 22.7229

22.

=(

)(

) (

)* = 23.0580

23.

=(

)(

) (

)* = 23.3672

24.

=(

)(

) (

)* = 23.6536

25.

=(

)(

) (

)* = 23.9182

26.

=(

)(

) (

)* = 24.1689

27.

=(

)(

) (

)* = 24.4024

28.

=(

)(

) (

)* = 24.5137

29.

=(

)(

) (

)* = 24.5792

Valores de
T = 300 K
T = 350 K
T = 400 K
T = 500 K
T = 600 K
T = 700 K

mayores de T = 298 K
= 25.15
= 26.18
= 27.39
= 29.70
= 32.05
= 35.07

 Mtodo mecnica Estadstica :

= Entropa Translacional
= Entropa Rotacional
= Entropa Vibracional
= Entropa Electrnica

Entropa Translacional:

=R,

= 1 atm.

*(

+-

K = 1.38 x

m=
m=
m = 9.27267 x

= (8.31441 J
,

*(

)(

Kg

)x
)(

)(

)(
(

= 272.36J

+-

Entropa Rotacional

R (

DONDE:

Js

R = 8.31441J
e

2.72 :logaritmo neperiano.

MOMENTO DE INERCIA

I = ((55.84 x

)(

) )

I = 2.5066 x

)(

= 1.6068 x

(8.31441) ((

(
)(

)(

512.53 J

Entropa Vibracional:

= R*

)(

)(

)+

1312.92 K

= (8.31441)*

)+

4.2058

Entropa Electrnica

=R (

Degeneracin del estado fundamental del primer estado: 9

Degeneracin del estado fundamental del segundo estado: 5
OPERANDO OBTENEMOS LO SGTE:

11,547

SUMA TOTAL DE LAS ENTROPIAS:

272.36 J
11.547

+ 512.53 J

+ 4.2058

800.64

Cp J/K.mol
0.03078
0.2462
0.8313
1.9717
3.8561
6.1
8.0424
9.872
11.5542
13.0749
14.4348
15.6427
16.7126
17.6597
18.4992
19.2449
19.9098
20.5047
21.0394
21.522
21.9596
22.3583
22.7229
23.058
23.3672
23.6536
23.9182
24.1689
24.4024
24.5137
24.5792
25.15
26.18
27.39
29.7
32.05
35.07

T (K)
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
295
298
300
350
400
500
600
700

Cp/T
0.003078
0.01231
0.02771
0.0492925
0.077122
0.10166667
0.11489143
0.1234
0.12838
0.130749
0.13122545
0.13035583
0.12855846
0.12614071
0.123328
0.12028063
0.11711647
0.113915
0.11073368
0.10761
0.10456952
0.10162864
0.09879522
0.096075
0.0934688
0.09097538
0.08858593
0.0863175
0.08414621
0.08309729
0.08248054
0.08383333
0.0748
0.068475
0.0594
0.05341667
0.0501

ENTROPIA ABSOLUTA

CP/T
0.14
0.12
0.10
0.08

ENTROPIA ABSOLUTA

0.06
0.04
0.02

T (k)

0.00
0

200

400

600

800

Hallando la variacin de entropa de 298K a 398K:

12 4 T 3 T
12 4 T 3
3R (
)( ) (1 0.021 3R(
)( ) )
T2
15
15

T1

3Rx12 4
15x 3

dT

T3
0.021 3Rx12 4 2 T 7
dT

(
)
dT
3
TF
7
15x 3
298
298

398

398

S = 1,0497