Reduciendo terminos

Pt= 620 mmHg

 SOLUCIÓN

(0.63 CO + 0.85 C2H4 + 2.76 H2 + 21.5 C2H6 + 0.58 O2 + 3.84 N2 + 0.23 H2S+ 69.61 CH4) + a O2 + a *3.7

BALANCE MO

C 0.63 + 0.85*2+21.5*2+69.61 = X X= 114.94

O 0.63+0.58*2+2a= 2x+b+ 2y b= 208.41
H 4*0.85+2*2.76+6*21.5+2*0.23+4*69.61= 2b a=218.48
S 0.23=y

(0.63 CO + 0.85 C2H4 + 2.76 H2 + 21.5 C2H6 + 0.58 O2 + 3.84 N2 + 0.23 H2S+ 69.61 CH4) + 218.48 O2 +

(0.63 CO + 0.85 C2H4 + 2.76 H2 + 21.5 C2H6 + 0.58 O2 + 3.84 N2 + 0.23 H2S+ 69.61 CH4) + 0.85* 218.48

BALANCE MONOATOMICO OXIGENO

C 0.63+2*0.85+2*21.5+69.61= X+Y
O 0.63+2*0.85+2*185.708= 2X +Y +208.41+2*0.23

(0.63 CO + 0.85 C2H4 + 2.76 H2 + 21.5 C2H6 + 0.58 O2 + 3.84 N2 + 0.23 H2S+ 69.61 CH4) + 0.85* 218.48

(0.63 CO + 0.85 C2H4 + 2.76 H2 + 21.5 C2H6 + 0.58 O2 + 3.84 N2 + 0.23 H2S+ 69.61 CH4) + 185.708 O2 +

RELACION AIRE COMBUSTIBLE

A/C= (n O2 + n N2) * PM aire / n Combustible * PM Combustible

PM combustible= SUM Yi*PM

PM combustible= 0.63*28+0.85*28+2.76*2+21.5*30+0.58*32+3.84*28+34*0.23+69.61*16
PM combustible= 1939.62

A/C= (185.70+698.23) (28.84)/(1)(1939.62)

A/C= 13.1430 Lb aire/ Lb combustible

DETERMINACIÓN DE LOS GASES HUMEDOS Y SECOS

Wg= Ap + (1-Z)
Wg= 13.1437+(1 -0)

Wg= 14.1437 Lb gas/ Lb combustible

Wg/s= Ap + (1-Z-A)

Wg/s= 13.1437 + (1-0 -1.93) A= n H2O *PM H2O / n Comb * PM Comb

A= 208.41*18/ 1939.62
Wg/s= 12.2137 Lb gas/ Lb comb A= 1.93 Lb agua / Lb comb

VOLUMEN OCUPADO DE AIRE DE COMBUSTIÓN

Va= Wa*Ra*Ta/P P=620/760*(14.7*144)

Va= 13.1430*53.5*68+460/1726.86 P= 1726.86

Va= 215 pie^3 aire / Lb combustible

VOLUMEN DE GASES DE COMBUSTIÓN

Vg= Wg*Rg*Tg/P

PMg= Σ (Yi*PMi) Tg= 480+460

PMg= 0.0487*44+0.0634*28+0.2032*18+0.0002*64+0.6845*28 Tg= 940
PMg= 26.746 Lb / Lb mol

Rg= 1545/26.746 P=620 mmHg /760(14.7*144)

Rg= 57.77 pie/ R P=1726.86 pie^3

Vg= 14.1437*57.765*940/1726.86
 Vg= 444.73 pie^3 gases / Lb combustible

Calculo de PCS y PCI

COMBUSTIBLE MOLES PM W Kcal Kcal *W

CO 0.63 28 17.64 2470 43570.8
C2H4 0.85 28 23.8 11850 282030
H2 2.76 2 5.52 33800 186576
c2h6 21.5 30 645 12300 7933500
O2 0.58 32 18.56 …. …
N2 3.84 28 107.52 …. …
h2s 0.23 34 7.82 3990 31201.8
CH4 69.61 16 1113.76 13050 14534568
TOTAL 1939.62 TOTAL 23011446.6

PCS= 23011446.6 / 1939.62

PCS= 11863.8943 Kcal / Kg combustible *1.8
PCS= 21355.0097 BTU/ Lb combustible

PCI= PCS -ʎ*A

PCI= 11863.8943 -600 * 1.93
PCI= 10705.8944 Kcal/ Kg combustible *1.8
PCI= 19270.61 BTU / Lb combustible

PRESIONES PARCIALES

Pp= Yi *Pt
COMPROBACIÓN
Pp CO2= 0.0481*620= 29.84 mmHg 29.84
Pp CO= 0.0639*620= 39.6 mmHg 39.6
Pp H2O= 0.2031 * 620= 125.9 mmHg 125.9
Pp SO2= 0.0002*620= 0.139 mmHg 0.139
Pp N2= 0.6841*620= 424.2 mmHg 424.2
619.679 mmHg
+ 69.61 CH4) + a O2 + a *3.76 N2 ---------------> X CO2 + b H2O + Y SO2 + (3.84 + a* 3.76) N2

BALANCE MONOATOMICO

+ 69.61 CH4) + 218.48 O2 + 218.48*3.76 N2 ---------------> 114.94 CO2 + 208.41 H2O + 0.23 SO2 + (3.84 + 218.48* 3.76) N2

DEFICIT 15%

+ 69.61 CH4) + 0.85* 218.48 O2 + 0.85* 218.48*3.76 N2 ---------------> X CO2 + Y CO+ 208.41 H2O + 0.23 SO2 + (3.84 + 0.85* 21

X=49.94
Y=65

+ 69.61 CH4) + 0.85* 218.48 O2 + 0.85* 218.48*3.76 N2 ---------------> 49.94 CO2 + 65 CO+ 208.41 H2O + 0.23 SO2 + (3.84 + 0.8

+ 69.61 CH4) + 185.708 O2 + 698.26 N2 ---------------> 49.94 CO2 + 65 CO+ 208.41 H2O + 0.23 SO2 + (3.84 + 0.85* 218.48* 3.76
COS

/ n Comb * PM Comb

0/760*(14.7*144)

0 mmHg /760(14.7*144)
3.84 + 218.48* 3.76) N2

+ 0.23 SO2 + (3.84 + 0.85* 218.48* 3.76) N2

H2O + 0.23 SO2 + (3.84 + 0.85* 218.48* 3.76) N2

+ (3.84 + 0.85* 218.48* 3.76) N2