FACTOR

COMPON MASA TEMPERA ACENTRIC

NO. ENTE MOLAR PRESION C TURA C O
1 METANO 16.043 666.4 -116.67 0.0104
2 ETANO 30.07 706.5 89.92 0.0974
3 PROPANO 44.097 616 206.06 0.1522
4 ISOBUTAN 58.123 527.9 274.46 0.1852
5 N-BUTANO 58.123 550.6 305.62 0.1995
6 ISOPENTAN 72.15 490.4 389.1 0.228
7 N-PENTAN 72.15 488.6 385.8 0.2514
8 NEOPENTA 72.15 464 321.13 0.1963
9 HEXANO 86.177 436.9 453.6 0.2994
10 HEPTANO 100.204 369.8 512.7 0.3494
11
12
Integrantes Núm. Control
Cortez Ángeles Jorge Aldo 20500109
Toribio Mateo Ernesto 20500132
Pérez Coronel Jesús Alberto 20500796
Martínez Bradley Jorge Enrique 20500107
Velázquez Méndez Alan Fernando 20500133

Propiedades de los fluidos petroleros

Ing. Lagos Quiroz Cirilo Alberto
5to semestre
Unidad 4
 Calculo de la densidad de liquido de una mezcla de hidrocarburo
calcular la densidad de un hidrocarburo liquido cuya composicion se proporciona en

Componente Xj Pcj Tcj aj

1 METANO 0.45 666.4 343.33 161365.751387
2 ETANO 0.05 706.5 549.92 494200.9660201
3 PROPANO 0.05 616 666.06 915102.2846552
5 N-BUTANO 0.03 550.6 765.62 1450320.336412
7 N-PENTANO 0.01 488.6 845.8 2096441.308884
9 HEXANO 0.01 436.9 913.6 2842988.819311
HEPTANO+ 0.4 285 825 3377201.5549

Datos RANKINE
Ωa 0.42747
Ωb 0.086664 am
Presión 4000 bm
Constante R 10.732
Temp Farenheit 160 620
z 1.27134
A (am)(p)/RT 4.125531307092

B (bm)(p)/RT 0.87371562887
 mezcla de hidrocarburos con la ecuacion de Redlich- Kwong.
cion se proporciona en la tabla 4.1 y que se encuentra a 4000 lib/pg2 abs y 160 °F.

bj xjaj^0.5 xjbj Mj XjMj

0.479177215216 180.7666027115 0.215629746847 16.043 7.21935
0.723946949973 35.14971429543 0.036197347499 30.07 1.5035
1.00566198807 47.83048935186 0.050283099403 44.097 2.20485
1.293291600272 36.12877388967 0.038798748008 58.123 1.74369
1.610028679898 14.479092889 0.016100286799 72.15 0.7215
1.944882821361 16.86116490433 0.019448828214 86.177 0.86177
2.692331191579 735.0865587018 1.076932476632 215 86
1066.302396744 1.453390533402 100.25466

460

1136999.955204
1.453391

ρ 47.40569248268
 Ejemplo
ecuación d

de las fases

Componente Xj yj TC
1 METANO 0.45 0.86 343.33
2 ETANO 0.05 0.05 549.92
3 PROPANO 0.05 0.05 666.06
5 N-BUTANO 0.03 0.02 765.62
7 N-PENTANO 0.01 0.01 845.8
9 HEXANO 0.01 0.005 913.6
10 HEPTANO+ 0.4 0.005 700

DATOS
Temperatura °F 160 620 zv
Constante R 10.732 zl
Presión 4000
RANKINE 460
Ωa 0.42747
Ωb 0.08664

Fase vapor
at1 1213.0187527179 at2 242.93868722
242.9386872159 48.65481726
336.1647642343 67.325774089
258.04027880351 51.679305403
105.12439649351 21.053906068
124.39969805092 24.914288643
4351.2596300018 871.4533884
6630.9462075178 1328.0201671

Fase liquida
at1 4430.3638000501 at2 582.53646464
464.28282445705 52.685831826
642.44821609222 68.339753271
328.76242929039 33.235756402
200.90440218759 19.488183251
118.87082258199 11.130520609
103.94675782782 10.559078524
6289.5792524872 777.97558852
 Ejemplo 4.7–Cálculo de las densidades de las dos fases de una mezcla de hidrocarbur
ecuación de Soave-Redlich-Kwong, SRK. Una mezcla de hidrocarburos cuya composición
en la tabla inferior existe en equilibrio en dos fases a 4,000 lb/pg2
abs y 160 °F. Calcular las densidades
de las fases vapor y líquido empleando la ecuación de Soave-Redlich-Kwong, SRK. Consid
existe interacción binaria entre los componentes de la mezcla.

Pc TR FA
666.4 1.8058427752
706.5 1.1274367181
616 0.9308470708
550.6 0.8098012069
488.6 0.7330338141
436.9 0.6786339755
285 0.8857142857
M ALFA AC
0.0104 0.49630896384 0.68783932177 8708.74326783
0.0974 0.63124833024 0.92348959054 21074.3327303
0.1522 0.71487698816 1.05095445002 35457.8961002
0.1995 0.786210156 1.16361062667 52415.2065797
0.2514 0.86357445504 1.263835785 72085.6581843
0.2994 0.93428129664 1.35635705672 94058.2959274
0.52 1.2488096 1.15245588012 84648.2899922

1.19303 DATOS H+ Interaccion binaria

0.9265 T H+ 700 0
FACTOR ACÉNTRICO 0.52

at3 336.164764234301 at4 258.040278804

67.3257740890967 51.6793054031
93.1615842372594 71.5108890877
71.5108890877198 54.8918022378
29.1332000295392 22.362662176
34.4749782906543 26.4630144391
1205.8677282312 925.624806341
1837.63891819977 1410.57275849

at3 642.44821609222 at4 328.76242929

67.3257740890967 34.4528702687
93.1615842372594 47.6739260585
47.6739260584799 24.3963565502
29.1332000295392 14.9084414507
17.2374891453271 8.82100481305
15.07334660289 7.71354005284
912.053536254812 466.728568484
na mezcla de hidrocarburos con la
rburos cuya composición se muestra
fases a 4,000 lb/pg2
dades
edlich-Kwong, SRK. Considerar que no
entes de la mezcla.

ATI BI xjbi yjbi xjM yjM

5990.2160628 0.4790445159 0.21557003216 0.41197828368 7.21935 13.79698
19461.9269039 0.72374646619 0.03618732331 0.03618732331 1.5035 1.5035
37264.6336949 1.00538348849 0.05026917442 0.05026917442 2.20485 2.20485
60990.8913754 1.29293344696 0.03878800341 0.02585866894 1.74369 1.16246
91104.4343986 1.60958281208 0.01609582812 0.01609582812 0.7215 0.7215
127576.633424 1.94434422185 0.01944344222 0.00972172111 0.86177 0.430885
97553.4195435 2.2837696 0.91350784 0.011418848 86 1.075
439942.155403 1.28986164364 0.56152984758 100.25466 20.895175

Interaccion binaria
0

at5 105.124396494 at6 124.39969805

21.053906068 24.914288643
29.1332000295 34.474978291
22.362662176 26.463014439
9.11044343986 10.780907675
10.7809076754 12.757663342
377.095194584 446.2382654
574.660710467 680.02881584

at5 200.904402188 at6 118.87082258

21.053906068 12.457144321
29.1332000295 17.237489145
14.9084414507 8.821004813
9.11044343986 5.3904538377
 5.3904538377 3.1894158356
4.7136899323 2.7889891588
285.214536946 168.75531969
Masa molar
16.043
30.07
44.097
58.123
72.15
86.177
215

at7 4351.2596 A 3.2749055

871.45339
1205.8677 ρ 50.517383
925.62481
377.09519 B 0.7754089
446.23827
15608.547
23786.086 36247.954

at7 103.94676
10.893167
15.073347 A 0.8174513
7.7135401
4.7136899 ρ 13.557769
2.7889892
2.4388355 B 0.3375674
147.56833 9047.8751