Curva de equilibrio

P (mmHg) C(gSO2/100gH2O) fraccion molarelacion molax SO2 (fraccionY molar (molSO3/molaire)

0.5 0.02 0.00065789 5.625E-05 5.624684E-05 0.000658328
1.2 0.05 0.00157895 0.00014063 0.0001406052 0.001581444
3.2 0.1 0.00421053 0.00028125 0.0002811709 0.00422833
14.1 0.3 0.01855263 0.00084375 0.0008430387 0.018903338
26 0.5 0.03421053 0.00140625 0.0014042752 0.035422343
39 0.7 0.05131579 0.00196875 0.0019648816 0.05409154
59 1 0.07763158 0.0028125 0.002804612 0.084165478
92 1.5 0.12105263 0.00421875 0.0042010269 0.137724551
161 2.5 0.21184211 0.00703125 0.0069821567 0.268781302
336 5 0.44210526 0.0140625 0.0138674884 0.79245283
517 7.5 0.68026316 0.02109375 0.0206579954 2.127572016

Torre de absorción
Φducto (m) 0.052

Calculo del area

A(m2) 0.002123716633827 𝐴=(𝜋∗∅^2 )/ 4

Condiciones para el calculo de la densidad del aire, sector de Riobamba

P[mmHg] 547.2
T[°C] 25
z 0.96
M_aire (kg/k 29
𝜌_𝑎𝑖𝑟𝑒=(𝑃𝑀_𝑎𝑖𝑟𝑒)
ρ_aire (kg/m30.889632407979287 /𝑅𝑇𝑧

Calculo del gas

v_gas [m/s] 2

G [kgmol/h.m0.469074325113165 𝐺=𝑣_𝑔𝑎𝑠 𝑥 𝐴 𝑥 𝜌_𝑔𝑎𝑠

Concentraciones del gas en porcentaje en peso

asumiendo el contaminante como gas ideal
P[atm] 1
T[K] 298
R[atm.m3/kgm 0.08205
𝑚_𝑐𝑜𝑛𝑡/𝑉_𝑎𝑖𝑟𝑒 =𝑉_𝑐𝑜𝑛𝑡/𝑉_𝑎𝑖𝑟𝑒 ∗𝑀_𝑐𝑜𝑛𝑡/24.5
M_SO2[kg/km 64
Ce[ppm] 160
Cs[ppm] 0.8

C_e[ug/m3] 417959.183673469 % 0.04894136

C_s[ug/m3] 2089.79591836735 % 0.00024471

Cociente molar del gas

y1 𝑦1=((%𝑆𝑂_2)/𝑀_(𝑆𝑂_2 ) )/((100−%𝑆𝑂_2)/𝑀_𝑎𝑖𝑟𝑒 )
0.000221874109395

y2 1.10883031937E-06

Flujo total del Liquido (L)

Q[m3/s] 0.00023
M_agua[kg/k 18
𝐿=(𝜌_𝑎𝑔𝑢𝑎∗𝑄)/𝑀_𝑎𝑔𝑢𝑎
L[kgmol/h.m3 45.91858

Relación L/G
L/G=m 80.546

Recta de Trabajo
x_2 0
b=Y_2 𝑦=(𝐿/𝐺) 𝑥_1+𝑏

𝑦=80.546𝑥_1+8.36𝐸-07

Concentracion del líquido a la salida

𝑥_1=(𝑦_1−𝑦_2)/𝑚
x_1 2.59391721801E-06

X_2 0
X_1 2.59391048962E-06
Y_1 0.000221923348441
Y_2 1.10883154887E-06
molar (molSO3/molaire)
0.000657894736842
0.001578947368421 Curva de equilibrio
0.004210526315789 0.8
0.018552631578947 0.7
0.03421052631579
0.6
0.051315789473684
0.077631578947369 0.5
0.121052631578947 0.4
0.211842105263158
0.3
0.442105263157895
0.680263157894737 0.2

0.1

0
0 0.005 0.01 0.015 0.02 0.02

Torre de absorción para determinar el numero de platos

L
G
𝑥_2=0
y2
 G
y2

G
L
y1
x1

y=80.546x+8.32E-7

Y y x X Curva de equilibrio
8.36E-07 8.359993E-07 0 0 8.36E-07
1.0826E-05 1.082588E-05 1.240271E-07 1.24027E-07 1.0826E-05
2.0816E-05 2.081557E-05 2.480516E-07 2.480516E-07 2.0816E-05
3.0806E-05 3.080505E-05 3.720737E-07 3.720736E-07 3.0806E-05
4.0796E-05 4.079434E-05 4.960934E-07 4.960931E-07 4.0796E-05
5.0786E-05 5.078342E-05 6.201105E-07 6.201101E-07 5.0786E-05
0.000150686 0.0001506633 1.860146E-06 1.860142E-06 0.000150686
0.0002161 0.0002160533 2.593917E-06 2.59391E-06 0.0002161

X Y
2.5939172180115E-06 0.0002161
0 1.108832E-06

L/Gm=A
A 1.2153540406
𝑛=(𝑙𝑜𝑔(((𝑦_(𝑛+1)−𝑚𝑥_0)/(𝑦_1−𝑚𝑥_0 ))((𝐴−1)/𝐴)+1/𝐴)/𝑙𝑜𝑔𝐴)

n 18.413261142

L [kmol/h] 45.91858
L[kg/h] 826.53444
G[kmol/h] 0.4690743251
G[kg/h] 13.603155428

Densidades
ρ_gas [kg/m3] 0.854
ρ_agua [kg/m3] 994.95
 X Y
2.59391E-06 0.0002219233
0 1.108832E-06

0.02 0.025
 Curva de equilibrio y Operación
0.00025

0.0002

0.00015

0.0001

5E-05

0
0 5E-07 1E-06 1.5E-06 2E-06 2.5E-06 3E-06

Curva de equilibrio Curva de operación