TECNOLÓGICO DE ESTUDIOS SUPERIORES DE

ECATEPEC DIVISIÓN DE QUÍMICA Y BIOQUÍMICA.

PROFESOR:
JORGE ANDRES CUEVAS LANDERO

LABORATORIO INTEGRAL

TAREA: COEFICIENTE DE DIFUSION

ALUMNO:

FECHA DE ENTREGA:05/JULIO/2021
Calcular los coeficientes de difusividad de las siguientes sustancias:
Sustancia Diámet Volume Volum Difusi Tiem
ro n en ón del po
interior inicial final tubo min
cm cm cm cm
acetona 1 12. 7.5 5 30
. 5
2
cloroform 1 12. 10 2.8 30
o . 8
2
Etanol 1 12. 5.5 7.7 30
. 2
1
Tetracloru 1 12. 11. 1 30
ro de . 6 6
carbono 0

NOTA: Altitud de la zona metropolitana 2350 m sobre el nivel del mar con una presión
atmosférica de 78 Kp a 20 °C de temperatura. L= 15cm

ACETONA:
3.1416(0.012)
𝐴= 2 = 1.13097𝑥10−4𝑚2
4
𝑘𝑔
(0.05𝑚)(1.13097𝑥10−4𝑚2) (0.79𝑥998.23 ) 𝑘𝑚𝑜𝑙
𝑁𝐴 = 𝑠 𝑘 𝑚 = 4.2279𝑥10−8
3

(30 min∗ 60 )(58.08 ) 𝑠

𝑚𝑖𝑛 𝑘𝑚𝑜𝑙
Análisis dimensional:
𝑘𝑔
𝑚 ∗ 𝑚2 ∗ 𝑘𝑔
𝑚3 ∗
𝑁𝐴 = 𝑚 [ ]
3 = 𝑚3 [=] 𝑘𝑔 [=] 𝑘𝑔 ∗ 𝑘𝑚𝑜𝑙 [=] 𝑘𝑚𝑜𝑙
𝑘𝑔 𝑘𝑔 ∗ 𝑠 𝑘𝑔 ∗ 𝑠 𝑘𝑔 ∗ 𝑠 𝑠
𝑠 ∗ 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝑃𝑣𝑎𝑝𝑜𝑟 40.5 𝐾𝑝𝑎
𝑌𝑣𝑎𝑝𝑜𝑟 = 𝑌𝐴0 =
= = 0.519
𝑃 78 𝐾𝑝𝑎

 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑃 (78 𝐾𝑝𝑎) 𝐾𝑚𝑜𝑙
𝐶= = = 0.032
𝑅𝑇 𝐾𝑝𝑎 ∗ 𝑚 𝑚3
(8.314
𝐾𝑚𝑜𝑙 ∗ 𝐾 3)
(293𝐾)

𝑁𝐴 𝐶𝐷𝐴𝐵 1 − 𝑦𝐴𝐿
𝑗𝐴 = = ∗ 𝐿𝑛 ( )
𝐴 𝐿 1 − 𝑦𝐴0

 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑁𝐴𝐿
1 − 𝑦𝐴 = 𝐷𝐴𝐵
𝐴𝐶 ∗ 𝐿𝑛 ( )
1 − 𝑦𝐴0  SUSTIRUIR LOS VALORES EN LA ECUACION:
𝑘𝑚𝑜𝑙
(4.2279𝑥10−8 )(0.15𝑚)
𝑠
𝐾𝑚𝑜𝑙 1−0
(1.13097𝑥10−4𝑚2) (0.032 ) ∗ 𝐿𝑛 ( ) = 𝐷𝐴𝐵
𝑚 3 1 − 0.519
𝑚2
𝐷𝐴𝐵 = 2.3942𝑥10−3
𝑠
 Análisis dimensional:
𝑘𝑚𝑜𝑙
∗𝑚 𝑘𝑚𝑜𝑙
𝑚2 ∗ 𝑚2
𝑘𝑚𝑜𝑙 ∗ 𝑚
𝑠
𝐷𝐴𝐵[=] [=] [=]
𝑠
[=]
𝐾 𝑘𝑚𝑜𝑙 ∗ 𝑠 𝑠
𝑚𝑚2𝑜𝑙∗
𝐾 𝑚
𝑚3 𝑜𝑙
𝑚

CLOROFORMO:
3.1416(0.0
𝐴 12)2 = 1.13097𝑥10−4𝑚2
=
4
(0.028𝑚)(1.13097𝑥10−4𝑚2) 𝑘𝑚𝑜𝑙
𝑘𝑔 = 2.1855𝑥10 −5
𝑁𝐴 (1483 )
= 𝑚3𝑘 �
𝑠 �
(30 min∗ 60 )(0.11938
)
𝑚𝑖𝑛 𝑘𝑚𝑜𝑙
Análisis
dimensional:
3
𝑚 2 𝑚
𝑘𝑔 ∗
𝑘𝑔∗ 𝑚 ∗

𝑁𝐴 𝑚
= 3 𝑚3 [ ] [=] 𝑘𝑔 ∗ 𝑘𝑚𝑜𝑙 [=] 𝑘𝑚𝑜𝑙
[=] =
𝑘𝑔 𝑙 𝑃 𝑘𝑔 ∗ 𝑠
𝑠∗ 𝑘𝑚𝑜 𝑘𝑚𝑜𝑙
𝐴0

 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑁𝐴𝐿
2 �𝑠 𝑘𝑔 = 𝐷𝐴𝐵
1 �𝑘 ∗𝑠
. ��  SUSTIRUIR LOS VALORES EN LA ECUACION:
2 ��
𝐾 𝑘𝑚𝑜𝑙
(2.1855𝑥10−5 ) (0.15𝑚)
𝑝 ∗𝑜 𝑠
𝐾𝑚𝑜𝑙 1−0
𝑎 𝑙 (1.13097𝑥10−4𝑚2) (0.032 ) ∗ 𝐿𝑛 ( ) = 𝐷𝐴𝐵
𝑌 𝑚 3 1 − 0.2705
=
𝑣 � 78 𝐾𝑝𝑎
0.2705
� 𝑚2
𝑎
𝑝
𝐷𝐴𝐵 = 2.8720 𝑠
=
𝑜𝑟  Análisis dimensional:
=
𝑘𝑚𝑜𝑙
𝑌 ∗𝑚 𝑘𝑚𝑜𝑙
𝑚2 ∗ 𝑚2
𝑘𝑚𝑜𝑙 ∗ 𝑚
𝐴 𝑠
𝐷𝐴𝐵[=] [=] [=]
0 𝑠
= [=]
𝐾𝑚 𝑘𝑚𝑜𝑙 ∗ 𝑠 𝑠
𝑚2 ∗
𝐾𝑚𝑜𝑙 𝑜𝑙
𝑃
� (78 =� 𝑚3 𝑚
� 𝐾𝑝𝑎 � ETANOL:
) �
= 0
(8.3 . � 3.1416(0.
� 011)2
14 0
� = 9.5033𝑥10−5𝑚2
𝐾𝑝𝑎 3 � 𝐴=
� � 4
∗ 2� (0.077𝑚)(9.5033𝑥10−5𝑚2) 𝑘𝑚𝑜𝑙
� 𝑘𝑔 −5
𝑁𝐴 (789 ) = 6.96227𝑥10
�𝑚 �
3) 𝐾𝑚𝑜𝑙
= ∗𝐾 𝑚3 �
� 𝑠 �
=(293 3 (30 min∗ 60 )(0.04607
𝑘
𝐾) )
𝑚𝑖𝑛 𝑘𝑚𝑜𝑙
𝑁 𝐶 1 − 𝑦𝐴𝐿
𝐴 𝐷 Análisis
𝐴𝐵 dimensional:
� ∗ 𝐿𝑛 (
�� 𝐿 ) 𝑘𝑔
1− 𝑚 ∗ 𝑚2 ∗ 𝑚 𝑚3 ∗ 𝑘𝑔
�� 𝑦 𝑁𝐴 𝑚 3 [=] 𝑘𝑔 ∗ 𝑘𝑚𝑜𝑙 [=] 𝑘𝑚𝑜𝑙
� = 3 [=]
= [=
]
= 1 − 𝑦𝐴 𝑘𝑔 𝑃 𝑘 𝑚𝑜𝑙
∗ 𝐿𝑛𝑠(∗ ) 𝑘𝑚𝑜 𝑔
𝐴 1− ∗ 5.846 𝐾𝑝𝑎
𝑦𝐴0 𝑙 𝑠
𝐶
𝐴0 𝑘
 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑁𝐴𝐿
𝑘𝑔 𝑜 𝑘𝑔 𝑠 = 𝐷𝐴𝐵
∗𝑠 𝑠
𝑘𝑚 𝑙  SUSTIRUIR LOS VALORES EN LA ECUACION:
𝑌
= 𝑘𝑚𝑜𝑙
𝑣 � 0.0749
78 𝐾𝑝𝑎 (6.96227𝑥10−5 )(0.15𝑚)
𝑎 � 𝑠
𝐾𝑚𝑜𝑙 1−0
𝑝 (9.5033𝑥10−5𝑚2) (0.032 ) ∗ 𝐿𝑛 ( ) = 𝐷𝐴𝐵
𝑜𝑟
= 𝑚 3 1 − 0. 0749
=
𝑚2
𝑌 𝐷𝐴𝐵 = 44.1102 𝑠
𝐴  Análisis dimensional:
0
= 𝑘𝑚𝑜𝑙
∗𝑚 𝑘𝑚𝑜𝑙
𝑚2 ∗ 𝑚2
𝑃 𝑘𝑚𝑜𝑙 ∗ 𝑚
𝑠
� (78 =�
� 𝐷𝐴𝐵[=]
𝑠
[=] [=]
� 𝐾𝑝𝑎 [=]
) � 𝐾 𝑘𝑚𝑜𝑙 ∗ 𝑠 𝑠
= 0� 𝑚𝑚2𝑜𝑙∗
𝐾 𝑚
(8.3 . � 𝑜𝑙
𝑚3
14 0� 𝑚
�
𝐾𝑝𝑎 3�
� TETRACLORURO DE CARBONO:
∗ 2�
�
3.1416(0.0
�𝑚 � 𝐴 = 7.85398𝑥10−5𝑚2
3) 𝐾𝑚𝑜𝑙 ∗ 𝐾1)2
� =
=(293 3 4
𝐾)
(0.01𝑚)(7.85398𝑥10−5𝑚2) 𝑘𝑚𝑜𝑙
𝑘𝑔 = 4.510267𝑥10 −6
𝑁 𝐶 1 − 𝑦𝐴𝐿 𝑁𝐴 (1590 )
𝐴 𝐷
= 𝑚3𝑘 �
𝐴𝐵 𝑠 �
� (30 min∗ 60 )(0.15382
∗ 𝐿𝑛 ( )
�� 𝐿 ) 1−
�� 𝑦 𝑚𝑖𝑛 𝑘𝑚𝑜𝑙
�
= Análisis
= 𝑦 dimensional:
𝐴
) 𝑘𝑔
𝐴 1− 𝑚 ∗ 𝑚2 ∗ 𝑚 𝑚3 ∗ 𝑘𝑔
𝐶 𝑦𝐴0 𝑁𝐴 𝑚 3 [=] 𝑘𝑔 ∗ 𝑘𝑚𝑜𝑙 [=] 𝑘𝑚𝑜𝑙
= 3 [=]
∗ [=
𝐿𝑛 ]
1 𝑘𝑔 𝑙 𝑘 𝑘𝑚𝑜𝑙
( 𝑠∗ 𝑘𝑚𝑜 𝑔
− 𝑃 ∗
𝐴0 𝑠 11.73 𝐾𝑝𝑎
 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑁𝐴𝐿
𝑘𝑔 𝑜 𝑘𝑔 𝑠
∗𝑠 𝑠
𝑘𝑚 𝑙
𝑌
=
𝑣 � 0.1503
78 𝐾𝑝𝑎
𝑎 �
𝑝
𝑜𝑟
=
=

𝑌
𝐴
0
=

𝑃
� (78 =�
�
� 𝐾𝑝𝑎
) �
= 0�
(8.3 . �
14 0�
�
𝐾𝑝𝑎 3�
�
∗ 2�
�
�𝑚 �
3) 𝐾𝑚𝑜𝑙 ∗ 𝐾
�
=(293 3
𝐾)

𝑁 𝐶 1 − 𝑦𝐴𝐿
𝐴 𝐷

𝐴𝐵
� ∗ 𝐿𝑛 (
�� 𝐿 ) 1−
�� 𝑦
�
=
=

𝐴0

 𝐷𝐸𝑆𝑃𝐸𝐽𝐴𝑅 𝐴 𝐷𝐴𝐵
 𝑁𝐴𝐿
1 − 𝑦𝐴 = 𝐷𝐴𝐵
𝐴𝐶 ∗ 𝐿𝑛 ( )
1 − 𝑦𝐴0  SUSTIRUIR LOS VALORES EN LA ECUACION:
𝑘𝑚𝑜𝑙
(4.51026𝑥10−6 ) (0.15𝑚)
𝑠
𝐾𝑚𝑜𝑙 1−0
(7.85398𝑥10−5𝑚2) (0.032 ) ∗ 𝐿𝑛 ( ) = 𝐷𝐴𝐵
𝑚 3 1 − 0. 1503
𝑚2
𝐷𝐴𝐵 = 1.652748 𝑠
 Análisis dimensional:
𝑘𝑚𝑜𝑙
∗𝑚 𝑘𝑚𝑜𝑙
𝑚2 ∗ 𝑚2
𝑘𝑚𝑜𝑙 ∗ 𝑚
𝑠
𝐷𝐴𝐵[=] [=] [=]
𝑠
[=]
𝐾 𝑘𝑚𝑜𝑙 ∗ 𝑠 𝑠
𝑚𝑚2𝑜𝑙∗
𝐾 𝑚
𝑚3 𝑜𝑙
𝑚