a)Tabla comportamiento real de disolución

X(C2H2)2O P(C2H2)2O PCHCl3 PTotal

0 0 19.33 19.33
0.2 4.6 14.8 19.4
0.4 12.87 9.2 22.07
0.6 26.66 4.6 31.26
0.8 40.93 1.65 42.58
1 53.33 0 53.33

b)Tabla Comportamiento Ley de Raoult

X(C2H2)2O XCHCl3 P(C2H2)2O PCHCl3 PTotal
0 1 0 19.33 19.33
0.2 0.8 10.666 15.464 26.13
0.4 0.6 21.332 11.598 32.93
0.6 0.4 31.998 7.732 39.73
0.8 0.2 42.664 3.866 46.53
1 0 53.33 0 53.33

P°(C2H2)2O= 53.33 P°CHCl3= 19.33

53.33 19.33
53.33 19.33
53.33 19.33
53.33 19.33
53.33 19.33
53.33 19.33
53.33 19.33
d)Tabla comportamiento Ley de Henry

X(C2H2)2O XCHCl3 P(C2H2)2O PCHCl3

0 1 0 5.834
0.2 0.8 3.385 4.6672
0.4 0.6 6.77 3.5004
0.6 0.4 10.155 2.3336
0.8 0.2 13.54 1.1668
1 0 16.925 0
 H(C2H2)2O= 16.925 HCHCl3= 5.834
16.925 5.834
16.925 5.834
16.925 5.834
16.925 5.834
16.925 5.834

Tabla para observar las desviaciones del comportamiento de la disolución

X(C2H2)2O P(C2H2)2O PCHCl3 PTotal P(C2H2)2O PCHCl3 PTotal
0 0 19.33 19.33 0 19.33 19.33
0.2 4.6 14.8 19.4 10.666 15.464 26.13
0.4 12.87 9.2 22.07 21.332 11.598 32.93
0.6 26.66 4.6 31.26 31.998 7.732 39.73
0.8 40.93 1.65 42.58 42.664 3.866 46.53
1 53.33 0 53.33 53.33 0 53.33
f)Convenio II
cloroformo como soluto
XCHCl3 PCHCl3 g II X(C2H2)2O P(C2H2)2O g II
1 19.33 3.31333562 0 0
0.8 14.8 3.17106616 0.2 4.6 0.43127695
0.6 9.2 2.62827105 0.4 12.87 0.60331896
0.4 4.6 1.97120329 0.6 26.66 0.83317707
0.2 1.65 1.4141241 0.8 40.93 0.95935683
0 0 1 53.33 1

HCHCl3= 5.834
5.834
X(C2H2)2O a 5.834
0 0 5.834
0.2 0.08625539 5.834
0.4 0.24132758 5.834
0.6 0.49990624 PTotal
0.8 0.76748547 19.33
1 1 26.13

XCHCl3 a
1 3.31333562
0.8 2.53685293
0.6 1.57696263
0.4 0.78848132
0.2 0.28282482
0 0
f)Convenio II
Dietileter como soluto
X(C2H2)2O P(C2H2)2O g II XCHCl3 PCHCl3 g II
0 0 1 19.33 1
0.2 4.6 1.35893648 0.8 14.8 0.95706156
0.4 12.87 1.90103397 0.6 9.2 0.79324021
0.6 26.66 2.62530773 0.4 4.6 0.59493016
0.8 40.93 3.02289513 0.2 1.65 0.42679772
1 53.33 3.15096012 0 0

H(C2H2)2O= 16.925
16.925
16.925
16.925
16.925
X(C2H2)2O a 16.925
0 0 P(C2H2)2O
0.2 0.2717873 0
0.4 0.76041359 10.666
0.6 1.57518464
0.8 2.4183161
1 3.15096012

XCHCl3 a
1 1
0.8 0.76564925
0.6 0.47594413
0.4 0.23797206
0.2 0.08535954
0 0
 P vs X(C2H2)2O Comportamiento Real
60

50

40

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2

P(C2H2)2O PCHCl3 PTotal

P vs X(C2H2)2O Comportamiento ley de Raoult

60

50

40

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2

P(C2H2)2O PCHCl3 PTotal

P(C2H2)2O PCHCl3
0 5.834
3.385 4.6672
6.77 3.5004
10.155 2.3336
13.54 1.1668
16.925 0
 g vs X(C2H2)2O Convenio I
1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2

gi gi

a vs X(C2H2)2O Convenio I
1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2

a a
 g vs X(C2H2)2O Convenio II Dietileter como soluto
3.5

2.5

1.5

0.5

0
0 0.2 0.4 0.6 0.8 1 1.2

g II g II

a vs X(C2H2)2O Convenio II Dietileter como soluto

3.5
3
2.5
2
1.5
1
0.5
0
0 0.2 0.4 0.6 0.8 1 1.2

a a
 P vs X(C2H2)2O Comportamiento ley de Henry
18
16
14
12
10
8
6
4
2
0
0 0.2 0.4 0.6 0.8 1 1.2

P(C2H2)2O PCHCl3
 P vs X(C2H2)2O Desviaciones del comportamiento real
60

50

40
Presión

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
X(C2H2)20

P(C2H2)2O PCHCl3 P(C2H2)2O PCHCl3

PTotal P(C2H2)2O PCHCl3 PTotal
e)Convenio I

X(C2H2)2O P(C2H2)2O gi XCHCl3 PCHCl3 gi

0 0 1 19.33 1
0.2 4.6 0.43127695 0.8 14.8 0.95706156
0.4 12.87 0.60331896 0.6 9.2 0.79324021
0.6 26.66 0.83317707 0.4 4.6 0.59493016
0.8 40.93 0.95935683 0.2 1.65 0.42679772
1 53.33 1 0 0

P°(C2H2)2O= 53.33 P°CHCl3= 19.33

53.33 19.33
53.33 19.33
X(C2H2)2O a 53.33 19.33
0 0 53.33 19.33
0.2 0.08625539 53.33 19.33
0.4 0.24132758 53.33 19.33
0.6 0.49990624 53.33 19.33
0.8 0.76748547
1 1

XCHCl3 a
1 1
0.8 0.76564925
0.6 0.47594413
0.4 0.23797206
0.2 0.08535954
0 0
 g vs X(C2H2)2O Convenio II Cloroformo como soluto
3.5
3
2.5
2
1.5
1
0.5
0
0 0.2 0.4 0.6 0.8 1 1.2

g II g II

a vs X(C2H2)2O Convenio II Cloroformo como soluto

3.5
3
2.5
2
1.5
1
0.5
0
0 0.2 0.4 0.6 0.8 1 1.2

a a