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P(Kpa) 100

X1 x2 Y1 T(K) ln(y1) Y1 ln(y2)


1 0 1 0 351.45 0.7118678 2.037793888 0
2 0.017 0.983 0.047 350.75 0.68215071 1.9781275373 0.00651358
3 0.047 0.953 0.103 349.95 0.63136482 1.8801749304 0.01823898
4 0.11 0.89 0.206 348.45 0.53389883 1.7055690887 0.04388512
5 0.143 0.857 0.244 347.95 0.48716897 1.6277016248 0.05792408
6 0.178 0.822 0.283 347.35 0.44101016 1.5542764867 0.07326756
7 0.229 0.771 0.332 346.65 0.37920204 1.4611182152 0.09651511
8 0.299 0.701 0.384 346.05 0.30405499 1.3553435813 0.13019085
9 0.384 0.616 0.448 345.55 0.2267229 1.2544822082 0.17385635
10 0.402 0.598 0.458 345.45 0.21216351 1.2363500257 0.18349799
11 0.42 0.58 0.467 345.35 0.19820347 1.2192104414 0.19327939
12 0.516 0.484 0.526 345.15 0.13310948 1.1423750554 0.24776122
13 0.566 0.434 0.556 345.15 0.10511098 1.1108338808 0.2776728
14 0.674 0.326 0.619 345.35 0.05713165 1.0587951904 0.3457991
15 0.719 0.281 0.652 345.55 0.04181009 1.042696442 0.37553677
16 0.743 0.257 0.674 345.65 0.03469964 1.0353086981 0.39173684
17 0.802 0.198 0.731 346.15 0.02019244 1.0203976869 0.43227341
18 0.904 0.096 0.852 347.85 0.00457768 1.0045881747 0.5040958
19 0.944 0.056 0.904 348.55 0.00153609 1.0015372744 0.53301513
20 0.972 0.028 0.944 349.25 0.00037998 1.0003800535 0.55312339
21 1 0 1 350.15 0 1 0.57297996
R(cal/mol.K) 1.987207

Y2 V12 V21 Ps1 Ps2 Pk (P-Pk)^2 V1


1 0.54938797 0.8870826 106.71654 101.332205 101.332205 1.77477092 106.872683
1.00653484 0.5493105 0.88593595 104.295261 98.558264 101.023146 1.04682745 106.750497
1.01840633 0.5492224 0.88462042 101.581676 95.4659125 101.630196 2.65754013 106.61146
1.04486232 0.54905843 0.88213918 96.6449599 89.8858738 101.719155 2.95549245 106.352479
1.05963454 0.54900412 0.88130786 95.042472 88.0875533 102.115119 4.47372768 106.266644
1.07601839 0.54893919 0.88030746 93.1474614 85.9693615 101.809083 3.27278076 106.163964
1.10132623 0.54886374 0.87913646 90.9747507 83.5521347 101.385793 1.92042307 106.044611
1.13904575 0.54879933 0.87812942 89.1447218 81.5257311 101.221634 1.49238936 105.942683
1.18988462 0.54874584 0.87728788 87.6422086 79.8686347 100.760335 0.57810876 105.858006
1.20141255 0.54873517 0.87711931 87.3441428 79.5406227 100.556688 0.30990195 105.841099
1.21322171 0.5487245 0.87695066 87.0468856 79.2137393 100.314179 0.09870824 105.824202
1.28115398 0.54870318 0.8766131 86.4547909 78.5633461 99.677563 0.10396563 105.790435
1.3200542 0.54870318 0.8766131 86.4547909 78.5633461 99.3661093 0.40181746 105.790435
1.4131187 0.5487245 0.87695066 87.0468856 79.2137393 98.6110148 1.92927975 105.824202
1.45577262 0.54874584 0.87728788 87.6422086 79.8686347 98.3772842 2.6332067 105.858006
1.47954831 0.54875653 0.87745636 87.9410846 80.1977783 98.1420213 3.45208478 105.874922
1.54075632 0.54881005 0.87829748 89.4476723 81.8605793 98.1734893 3.33614133 105.959647
1.65548795 0.54899328 0.88114134 94.7245256 87.7315227 99.966755 0.00110523 106.249507
1.70406253 0.54906931 0.88230519 96.9680199 90.249194 100.290785 0.0845557 106.369676
1.7386751 0.54914568 0.88346489 99.2535518 92.8269513 101.030203 1.06131882 106.490326
1.77354428 0.54924438 0.88494981 102.254756 96.2313009 102.254756 5.08392456 106.646159
38.6680707
R(bar.cm^3/mol.K)

e1(expo) V2 e2(expo) A B
0.72749201 58.7145664 0.7196104419 Etil acetato (1) 7.09808 1238.71
0.72833744 58.6391695 0.7204950289 Etanol (2) 8.1122 1592.864
0.72930065 58.553402 0.721502672
0.73109815 58.3937255 0.7233825763
0.73169487 58.3408262 0.7240065051
0.73240933 58.27756 0.7247534498 Metodo de Barker
0.73324067 58.2040413 0.7256224599 a12 (cal/mol)
0.73395137 58.1412735 0.7263652603 a21 (cal/mol)
0.73454232 58.0891408 0.7269828132
0.73466036 58.0787331 0.7271061666 Metodo
0.73477836 58.0683318 0.7272294676
0.73501422 58.0475478 0.727475913
0.73501422 58.0475478 0.727475913
0.73477836 58.0683318 0.7272294676
0.73454232 58.0891408 0.7269828132
0.73442422 58.0995547 0.7268594076
0.73383304 58.1517189 0.7262415921
0.73181407 58.3302657 0.7241311297
0.73097866 58.4043249 0.723257629
0.73014086 58.4787028 0.7223814828
0.72906015 58.5748041 0.7212510911
83.14

C w Zar Tc(K) Pc(bar) Vc(cm^3/mol)


217 0.366 0.2584435 523.3 38.8 286
226.184 0.645 0.23396125 513.9 61.48 167

0
501.990076183662
y1 y2 ln(y1/y2) x1 (delta gE)^2
2.03779389 1 0.7118678 0 0 0.98685309
1.97812754 1.00653484 0.67563712 0.017 0.00017193 0.013112322 2.65084517 0.983663
1.88017493 1.01840633 0.61312584 0.047 0.00017778 0.013333454 2.1573668 0.98594165
1.70556909 1.04486232 0.49001371 0.11 0.00013742 0.011722542 1.9377392 0.99251951
1.62770163 1.05963454 0.4292449 0.143 0.00014188 0.011911465 1.79529601 1.00144344
1.55427649 1.0760184 0.3677426 0.178 6.14E-05 0.007835215 1.70685021 1.01462051
1.46111822 1.10132623 0.28268693 0.229 7.97E-06 0.002823664 1.59360883 1.03696604
1.35534358 1.13904575 0.17386414 0.299 1.40E-07 0.000374048 1.44066963 1.07787399
1.25448221 1.18988462 0.05286656 0.384 1.22E-06 0.00110431 1.33116986 1.12197222
1.23635003 1.20141255 0.02866552 0.402 8.12E-06 0.002850082 1.30438453 1.13948632
1.21921044 1.21322171 0.00492408 0.42 2.47E-05 0.004965441 1.27736306 1.16010875
1.14237506 1.28115398 -0.11465174 0.516 3.33E-05 0.005769835 1.17909006 1.24655949
1.11083388 1.3200542 -0.17256182 0.566 2.89E-05 0.005376253 1.13623796 1.30218674
1.05879519 1.4131187 -0.28866745 0.674 9.28E-06 0.003045981 1.05506087 1.47539009
1.04269644 1.45577262 -0.33372668 0.719 2.91E-06 0.001704559 1.03467842 1.55058888
1.0353087 1.47954831 -0.3570372 0.743 1.09E-05 0.003302575 1.03152383 1.58169281
1.02039769 1.54075632 -0.41208097 0.802 3.87E-06 0.00196773 1.01899949 1.65963382
1.00458818 1.65548795 -0.49951812 0.904 0.0001297 0.011388591 0.99496711 1.75725511
1.00153727 1.70406253 -0.53147903 0.944 0.00016283 0.012760486 0.98757005 1.89950252
1.00038005 1.7386751 -0.55274341 0.972 0.00034317 0.018524956 0.97849739 2.15454668
1 1.77354428 -0.57297996 1 0 0 0.97794962
0 0.7118678 0 0 0
0.017 0.67563712 0.01311232 0.99135044 0.31571331
0.99135044 0.047 0.61312584 0.01333345 0.78304651 0.16992067
0.78304651 0.11 0.49001371 0.01172254 0.66903055 0.17901683
0.66903055 0.143 0.4292449 0.01191147 0.58372752 0.15448262
0.58372752 0.178 0.3677426 0.00783522 0.52013503 0.15239243
0.52013503 0.229 0.28268693 0.00282366 0.42970197 0.14701504
0.42970197 0.299 0.17386414 0.00037405 0.29011746 0.11625332
0.29011746 0.384 0.05286656 0.00110431 0.1709701 0.11810355
0.1709701 0.402 0.02866552 0.00285008 0.13515374 0.10648822
0.13515374 0.42 0.00492408 0.00496544 0.0962841 0.09136002
0.0962841 0.516 -0.11465174 0.00576984 -0.05564434 0.0590074
-0.05564434 0.566 -0.17256182 0.00537625 -0.13632219 0.03623963
-0.13632219 0.674 -0.28866745 0.00304598 -0.33532396 -0.04665651
-0.33532396 0.719 -0.33372668 0.00170456 -0.4045441 -0.07081742
-0.4045441 0.743 -0.3570372 0.00330258 -0.42745851 -0.07042131
-0.42745851 0.802 -0.41208097 0.00196773 -0.48777574 -0.07569476
-0.48777574 0.904 -0.49951812 0.01138859 -0.56879859 -0.06928047
-0.56879859 0.944 -0.53147903 0.01276049 -0.65409987 -0.12262084
-0.65409987 0.972 -0.55274341 0.01852496 -0.7893175 -0.2365741
-0.7893175 1 -0.57297996 0 0 0

0 0
0.017 0.31571331
0.047 0.16992067
0.11 0.17901683
0.143 0.15448262
0.178 0.15239243
0.229 0.14701504
0.299 0.11625332
0.384 0.11810355
0.402 0.10648822
0.42 0.09136002
0.516 0.0590074
0.566 0.03623963
0.674 -0.04665651
0.719 -0.07081742
0.743 -0.07042131
0.802 -0.07569476
0.904 -0.06928047
0.944 -0.12262084
0.972 -0.2365741
1 0

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