Resolución

Reacción
𝟑
𝑪𝟑 𝑯𝟔 (𝒈) + 𝑶𝟐 (𝒈) → 𝑪𝟑 𝑯𝟒 𝑶𝟐 (𝒈) + 𝑯𝟐 𝑶 (𝒈)
𝟐
𝟓
𝑪𝟑 𝑯𝟔 (𝒈) + 𝑶𝟐 (𝒈) → 𝑪𝟐 𝑯𝟒 𝑶𝟐 (𝒈) + 𝑪𝑶𝟐 (𝒈) + 𝑯𝟐 𝑶 (𝒈)
𝟐
𝟗
𝑪𝟑 𝑯𝟔 (𝒈) + 𝑶𝟐 (𝒈) → 𝟑 𝑪𝑶𝟐 (𝒈) + 𝟑 𝑯𝟐 𝑶 (𝒈)
𝟐

𝟑
𝑨 + 𝑩 → 𝑹 + 𝑺
𝟐

Datos
To = 320 °C  593 K
Po = 4.365 atm
FAo = 127 Kmol/h  0.035 Kmol/s
FAire = 1362 Kmol/h  0.378 Kmol/s
yAo = 0.3
yBo = 0.7
k=
Fase “GAS”
n=1
Balance de Materia
𝑬−𝑺+𝑮=𝑨
𝐹𝐴𝑜 − 𝐹𝐴 + 𝑟𝐴 𝑉 = 0
𝐹𝐴𝑜 − (𝐹𝐴𝑜 − 𝐹𝐴𝑜 𝑋𝐴 ) + 𝑟𝐴 𝑉 = 0
𝑉 𝑋𝐴
=
𝐹𝐴𝑜 −𝑟𝐴
𝑋𝐴 𝐹𝐴𝑜
𝑉=
−𝑟𝐴
 𝑏
𝐶𝐴𝑜 (1 − 𝑋𝐴 ) 𝐶𝐵𝑜 − 𝑎 𝐶𝐴𝑜 𝑋𝐴 )
−𝑟𝐴 = 𝑘𝐶𝐴 𝐶𝐵 = 𝑘 ( )( )
1 + 𝜖 𝑋𝐴 1 + 𝜖 𝑋𝐴

𝑋𝐴 𝐹𝐴𝑜 𝑋𝐴 𝐹𝐴𝑜
𝑉= = …………1
𝑘𝐶𝐴 𝐶𝐵 𝑏
𝐶𝐴𝑜 (1 − 𝑋𝐴 ) 𝐶𝐵𝑜 − 𝑎 𝐶𝐴𝑜 𝑋𝐴 )
𝑘(
1 + 𝜖 𝑋𝐴 ) ( 1 + 𝜖 𝑋𝐴 )

𝑃𝑜 𝑦𝐴𝑜 (4.356 𝑎𝑡𝑚)( 0.3) 𝑚𝑜𝑙 𝐾𝑚𝑜𝑙

𝐶𝐴𝑜 = = = 0.026 = 0.026
𝑅 𝑇𝑜 𝑎𝑡𝑚 𝐿 𝐿 𝑚3
(0.082 ) (593 𝐾)
𝑚𝑜𝑙 𝐾
𝑃𝑜 𝑦𝐵𝑜 (4.356 𝑎𝑡𝑚)( 0.7) 𝑚𝑜𝑙 𝐾𝑚𝑜𝑙
𝐶𝐵𝑜 = = = 0.062 = 0.062
𝑅 𝑇𝑜 𝑎𝑡𝑚 𝐿 𝐿 𝑚3
(0.082 ) (593 𝐾)
𝑚𝑜𝑙 𝐾
3
∆𝑛 (1 + 1) − (1 + )
𝜖= (𝑦𝐴𝑜 ) = 2 (0.3) = −0.15
𝑎 1

De la ecuación 1
𝐾𝑚𝑜𝑙
(0.97) (0.035
)
𝑉= 𝑠
𝐾𝑚𝑜𝑙 𝐾𝑚𝑜𝑙 3 𝐾𝑚𝑜𝑙
𝐾𝑚𝑜𝑙 0.026 𝑚3 (1 − 0.97) 0.062
𝑚 3 − 2 (0.026 𝑚 3 ) (0.97)
(0.0446 3 ) ( )( )
𝑚 𝑠 1 + (−0.15)(0.97) 1 + (−0.15)(0.97)

𝑉 = 295 𝑚3
Balance de Energía
Para un tanque CSTR “ISOTÉRMICO NO ADIABÁTICO”
𝑚 𝑇𝑜
𝐹𝐴𝑜 𝑋𝐴
0 = ∑ 𝐹𝑖𝑜 ∫ 𝐶𝑝𝑖 𝑑𝑇 − ∆𝐻𝑅 (𝑇) + 𝑄
𝑇 𝑎
𝑖=1

𝐹𝐴𝑜 𝑋𝐴
𝑄= ∆𝐻𝑅 (𝑇) … … … … … 𝟐
𝑎
𝑇
∆𝐻𝑅 (𝑇) = ∆𝐻𝑅 (𝑇𝑟 ) + ∫ ∆𝐶𝑝
𝑇𝑟
 ∆𝐻𝑅 (𝑇) = ∆𝐻𝑅 (𝑇𝑟 ) + ∆𝐶𝑝(𝑇 − 𝑇𝑟 )

∆𝐶𝑝 = ∑(𝛾 𝐶𝑝𝑖 )𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − ∑(𝛾 𝐶𝑝𝑖 )𝑅𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠

3 𝐾𝐽
∆𝐶𝑝 = [(1)(81.80) + (1)(3.902 )] − [(1)(7.789) + ( ) (3.789 )]
2 𝐾𝑚𝑜𝑙 𝐾
𝐾𝐽
∆𝐶𝑝 = 72.229
𝐾𝑚𝑜𝑙 𝐾
𝐾𝐽
∆𝐻𝑅 (𝑇𝑟 )298 𝐾 = −592,228
𝐾𝑚𝑜𝑙
𝐾𝐽 𝐾𝐽
∆𝐻𝑅 (𝑇) = −592,228 + 72.229 (320 − 298)𝐾
𝐾𝑚𝑜𝑙 𝐾𝑚𝑜𝑙 𝐾
𝐾𝐽
∆𝐻𝑅 (𝑇) = −590639
𝐾𝑚𝑜𝑙
De la ecuación 2
𝐾𝑚𝑜𝑙 𝐾𝐽
𝑄 = (0.035 ) (0.97) (−590639 )
𝑠 𝐾𝑚𝑜𝑙
𝐾𝐽
𝑄 = −20052.2
𝑠

21 % 𝑂2
𝐴𝑖𝑟𝑒 {
79 % 𝑁2
286.02 Kmol/h
𝐾𝑚𝑜𝑙 𝐾𝑚𝑜𝑙
𝐹𝐵𝑜 = 0.21 𝐹𝐴𝑖𝑟𝑒 = 0.21 (0.3783 ) = 0.079
𝑠 𝑠