Procedimiento 1.

pH=3

CH3COOH CH3COO- + H+
0.05M- X X
pH log H
H
10 pH H 103

CH 3COO

H 1x10 3 M 1x10
3 M
Ki 2.04 x105
[CH 3COOH ] [0.05M 1x10 3 M ]

K i 2.04 x105

Procedimiento 2.

pH=5

Para CH3COOH:

0.05n 3
27.5mL 1.375 x10 n
1000mL

Para CH3COONa:

0.05n 4
4.8mL 2.40 x10 n
1000 mL

Volumen total= 27.5mL + 4.8mL=32.3mL

pH log H
H
10 pH H 105

CH3COOH CH3COO- + H+
1.375x10-3n- 2.40x10- X
4
CHX3COONa CH n+X -
3COO + Na
+

Y 2.40x10- 2.40x10-
4
4
n n
 2.40 x104 n 5
0.0323L 1x10 M 1x10 M
5
CH 3COO H
Ki 1.7482 x106
[CH 3COOH ] 1.375 x103 n 5
0.0323L 1x10 M

K i 1.7482 x106

Procedimiento 3.

pH=6

Para CH3COOH:

0.05n 3
27.5mL 1.375 x10 n
1000mL

Para CH3COONa:

0.05n 4
4.8mL 2.40 x10 n
1000mL

Para NaOH:

0.01n 5
6.3mL 6.3 x10 n
1000 mL

Volumen total= 27.5mL + 4.8mL+6.3mL=38.6mL

pH log H
H
10 pH H 106

CH3COOH CH3COO- + H+
1.375x10-3n- 2.40x10- X
4
X-Z
CH3COONa CH n+X+Z
3COO
-
+ Na+
Y 2.40x10- 2.40x10-4n
4
NaOH + CH3COOH n+X+Z
CH3COONa + H2O
Z 1.3375x10 n-X- 6.3x10-5n 6.3x10-5n
-3

Z
 2.40 x104 n 6.3 x10 5 n
1x106 M 1x106 M
CH 3COO H
0.0386 L
Ki 2.3098 x107
[CH 3COOH ] 1.375 x103 n 6.3x105 n
1x106 M
0.0386 L

K i 2.3098 x107

Procedimiento 4.

pH=2

Para CH3COOH:

0.05075n 3
27.5mL 1.3956 x10 n
1000mL

Para CH3COONa:

0.05n 4
4.8mL 2.40 x10 n
1000mL

Para HCl:

0.053n 4
6.3mL 3.339 x10 n
1000 mL

Volumen total= 27.5mL + 4.8mL+6.3mL=38.6mL

pH log H
H
10 pH H 102

CH3COOH CH3COO- + H+
1.3956x10-3n- 2.40x10- 3.339x10-
CH3X
4 4
COONa CH3n+X
COO- + Na+ n+X
-4
Y 2.40x10- 2.40x10 n
4
HCl Cl-n+X + H+
Z 3.339x10- 3.339x10-
4 4
n n+X
 1x102 nH 3
0.0386 L 0.386 x10 nH
1L

0.386 x10 3 nH 3.339 x104 X

X 5.21x105 nH

2.40 x104 n 5.21x105 n

1x102 M
CH 3COO H


0.0386 L
Ki 3.3398 x102
[CH 3COOH ] 1.3956 x10 n 5.21x10 n
4 5

0.0386 L

K i 3.3398 x10 2

Procedimiento 5.

pH=4

CH3COOH CH3COO- + H+
0.025 X X
M-X
pH log H
H
10 pH H 104

CH 3COO
H 1x10 4 M 1x10
4 M
Ki 4
4.016 x107
[CH 3COOH ] [0.025M 1x10 M ]

K i 4.016 x10 7

Procedimiento 6.

pH=5

Para CH3COOH:
 0.025n 4
27.5mL 6.875 x10 n
1000 mL

Para CH3COONa:

0.05n 4
11.5mL 5.75 x10 n
1000mL

Volumen total= 27.5mL + 11.5mL=39mL

pH log H
H
10 pH H 105

CH3COOH CH3COO- + H+
6.875x10-4n- 5.75x10- X
4
CHX3COONa CH n+X -
3COO + Na
+

Y 5.75x10- 5.75x10-
4
4
n n
5.75 x10 n
4
5
0.039 L 1x10 M 1x10 M
5
CH 3COO H
Ki 8.374 x106
[CH 3COOH ] 6.875 x10 n
4

1x10 5 M
0.039 L

K i 8.374 x106

Procedimiento 7.

pH=6

Para CH3COOH:

0.025n 4
27.5mL 6.875 x10 n
1000mL

Para CH3COONa:

0.05n 4
11.5mL 5.75 x10 n
1000mL
Para NaOH:

0.01n 5
6.3mL 6.3 x10 n
1000 mL

Volumen total= 27.5mL + 11.5mL+6.3mL=45.3mL

pH log H
H
10 pH H 105

CH3COOH CH3COO- + H+
6.875x10-4n- 5.75x10- X
4
X-Z
CH3COONa CH n+X+Z
3COO
-
+ Na+
Y 5.75x10 5.75x10-4n -

4
NaOH + CH3COOH n+X+Z
CH3COONa + H2O
Z 6.875x10 n-X- 6.3x10-5n 6.3x10-5n
-4

Z
5.75 x104 n 6.3x105 n
1x105 M 1x105 M
CH 3COO H



0.0453L
Ki 1.0223 x105
[CH 3COOH ] 6.875 x10 n 6.3x10 n
4 5

1x105 M
0.0453L

K i 1.023 x105

Procedimiento 8.

pH=2

Para CH3COOH:

0.025n 4
27.5mL 6.875 x10 n
1000 mL

Para CH3COONa:

0.05n 4
4.8mL 5.75 x10 n
1000mL

Para HCl:
 0.053n 4
6.3mL 3.339 x10 n
1000 mL

Volumen total= 27.5mL + 11.5mL+6.3mL=45.3mL

pH log H
H
10 pH H 102

CH3COOH CH3COO- + H+
6.875x10-4n-X 5.75x10- 3.339x10-
4 4
CH3COONa CH3n+X
COO- + Na+ n+X
-4
Y 5.75x10- 5.75x10 n
4
HCl Cl-n+X + H+
Z 3.339x10- 3.339x10-
4 4
n n+X
1x10 2 nH 4
0.0453L 4.53x10 nH
1 L

4.53 x104 nH 3.339 x104 X

X 1.191x104 nH

5.75 x104 n 1.191x104 n

1x10 M
2
CH 3COO H
0.0453L
Ki 0.0122
[CH 3COOH ] 6.875 x10 n 1.191x104 n
4

0.0453L

K i 0.0122