Clculos

NO. MUESTRA
TESTIGO
No.1
No.2

VOLUMEN GASTADO
14.7
7.5
7.5

Determinacin de amoniaco en fase liquida

M NH 3 =17(V T V M )
M NH 3 =17(14.77.5 ) = 122.4 mg de NH3
M H 2 O=(15000M NH 3)
M H 2 O=( 15000122.4 ) =14877.60 mg de H2O
M NH 3
17
X=
M H 2O
18
122.4
17
Kgmolde NH 3
X=
=0.0087
14877.6
Kgmol de H 2O
18

Clculo de la concentracin de la muestra

C1*V1=C2*V2

C 1=
C 1=

C 2V 2
V1

17.5
=0.5102 N
14.7

Obteniendo la relacin de amoniaco

XNH 3=

MNH 3
122.4
=
=0.0082
MNH 3 + M H 2 O 122.4+14877.6

Calculo de coeficiente de masa

Ecuacin de equilibrio= y=1.3687(x)

YA1=.04359
YA2=.00436
XA1=.0082

yA1=.0434
yA2=.004341
xA1=.008133

yA1*=0.01113
xA2*=0.003172
xA1*=0.0317

Para la fase gaseosa:

y y
( NUT )Gy = A 1 A 2
( y )ml
Media logartmica
( y )1 ( y )2

( y )ml=
( y )1

( y )2

Del mismo modo, para la fase liquida

x x
( NUT )Gx = A 1 A 2
( x )ml

Media logartmica

( x )1 ( x )2
( X ) =
( x )1

( x )2

ml

Siendo para el gas:

( Y )1 = y 1 y 1

( Y )1 =. 043401113=0.03 227
( Y )2 =Y 2Y 2

( Y )2 =.00 43410=0.004341
Y para el lquido:

( X ) 1=x 1 x 1

( X ) 1=0.0317.008133=0.02357

( X ) 2=x 2 x 2
( X ) 2=0.0 031720= 0.003172
Sustituyendo en las ecuaciones de transferencia
Gas
.03227.004341
( Y )ml=
=0.01392
.03227

.004341

( NUT )Gy =

0.04340.004341
=2.8059
0.01392

Liquido

( X )ml =

( NUT )Gx =

0.023570.003172
=0.0 1017
0.02357

0.0 03172

0.0081330
=.7997
0.01 017

Calculo de la altura de la unidad de transferencia para la fase

gaseosa y liquida

( AUT )Gy =

Z
1.8 m
=
=0. 6415
( NUT )Gy 2.8059

( AUT )Gx =

Z
1.8 m
=
=2.2508
( NUT )Gx 0.7997

CALCULO DEL COEFICIENTE VOLUMETRICOS GLOBALES DE

TRANSFERENCIA DE MAS PARA LA FASE GASEOSA Y LIQUIDA.

G1=Gs Y A +Gs=Gs ( 1+Y A 1) =1.1259 ( 1+ 0.0436 )=1.1750

1

kmolA
min

G2=Gs Y A +Gs=Gs ( 1+Y A 2) =1.1259 ( 1+ 0.004359 )=1.1308

2

Gm=

G1 +G2 1.1750+1.1308
kmolA
=
=1.1529
2
2
min

kmolA
h

L1=Ls X A + Ls=Ls ( 1+ X A 1 )=1.4304 ( 1+.00 82 ) =1.442

1

L2=Ls X A + Ls=Ls ( 1+ X A 2 ) =1.4304 ( 1+ 0 )=1.4304

2

Lm=

kmolA
min

kmolA
min

L1 + L2 1.442+1.4304
kmolA
=
=1.4362
2
2
min

S=r 2=(

.15 m 2
) =0.0177
2

( 1 y ) m=

( 1 y 1 ) + ( 1 y 2 ) ( 10.01113 )+ ( 10 )

( 1x )m =

( K y a)=

=0.9944

( 1x 1 ) + ( 1x2 ) ( 1. 0317 ) +( 10.0 03172 )

2

=.9826

Gm
1.1529
kmol
=
=102.108
S ( AUT )G ( 1 y ) m ( 0.0177 )( 0.6415 )( 0.9944 )
h m3 X
y

( K X a )=

Lm
1.4362
kmol
=
=36.6883
S ( AUT )G ( 1 y ) m ( 0.0177 )( 2.2508 )( 0.9 826 )
h m 3 X
x

Tabla de resultados

( NUT )Gy

2.8059

( NUT )Gx

.7997

( AUT )Gy

0.6415

( AUT )GX

2.2508

( K y a)
(KXa)

102.108

kmol
3
h m X

kmol
36.6883 h m 3 X