TERMODINMICA PARA INGENIERA QUMICA 2

PRCTICA CALIFICADA N 1
Se tiene el sistema binario Acetonitrilo (1) / benceno (2) a 45C. Para los datos que se
muestran a continuacin:

P(KPa)

X1

y1

29.819

31.957

0.0455

0.1056

33.553

0.094

0.1818

35.285

0.1829

0.2783

36.457

0.2909

0.3607

36.996

0.398

0.4274

37.068

0.5069

0.4885

36.978

0.5458

0.5098

36.778

0.5946

0.5375

35.792

0.7206

0.6157

34.372

0.8145

0.6913

32.331

0.8972

0.7869

30.038

0.9573

0.8916

27.778

Hallar los coeficientes de actividad:

Ecuacion de Raoult

modificada:

CALCULANDO PRESION DE VAPOR

Constantes de
Antoine

Psat bar

Psat KPa.

4.2 1355.3
0.5723438
57.234384
8
7
37.85
4
3.9 1184.2 217.5 0.5944089 59.440893
BENCENO (C)
9
4
7
3
2
TEMPERATURA (K)
318
TEMPERATURA (C)
45

ACETONITRILO (K)

Utilizando la ecuacin de Raoult modificada se obtiene la siguiente tabla:

P KPa

x1

y1

x2

y2

29.819

31.957

0.0455

0.1056

0.9545

0.8944

33.553

0.094

0.1818

0.906

0.8182

35.285

0.1829

0.2783

0.8171

0.7217

36.457

0.2909

0.3607

0.7091

0.6393

x1
x20.398 Ln 0.4274
1
36.996
0
1
37.068 0.9545
0.50690.25918246
0.4885
0.0455
0.094 0.906 0.12558384
36.978 0.8171
0.5458
0.5098
0.1829
-0.06393678
0.2909 0.7091 -0.23595433
36.778
0.5946
0.5375
0.398 0.602 -0.3650767
0.5069
-0.47137505
35.792 0.4931
0.7206
0.6157
0.5458 0.4542 -0.50506581
0.5946
-0.54321515
34.372 0.4054
0.8145
0.6913
0.7206 0.2794 -0.6267548
32.331 0.1855
0.8972-0.6739131
0.7869
0.8145
0.8972 0.1028 -0.70230594
30.038 0.0427
0.9573
0.8916
0.9573
-0.71579081
1
0
-0.7229105
27.778
1
1

1.2958702
2
1.1338102
2
0.9380643

0.7898167
4
Ln 2
GE / RT0.6941434
0.602
0.5726
-0.68983665 -0.68983665 1
0.4931
0.5115
0.6241434
-0.68562572
-0.64263695
-0.67378865 -0.59864763 5
0.4542
0.4902
0.6034658
-0.64567643
-0.53927625
-0.59247168 -0.48876078 6
0.4054
0.4625
0.5808776
-0.52424268 -0.46089462
4
-0.43559277
-0.45373081
0.2794
0.3843
0.5343229
-0.39838344 -0.45661068 8
-0.34831026
-0.46420071
0.1855
0.3087
0.5097101
-0.18847897 -0.50430053 2
0.1028
0.2131
0.4954415
-0.0384251
-0.55603008
0.12002028 -0.61777081 3
0.0427
0.1084
0.4888054
0.24910999
-0.67458955
1
-0.7229105
0
0
0.4853376
2

Determinar energa de Gibbs residual:

2
0.5016580
1
0.5037749
1
0.5097735
6
0.5243077
7
0.5529588
6
0.5920035
3
0.6468811
0.6714045
3
0.7058798
3
0.8282179
2
0.9623037
8
1.1275197
2
1.2828831
3

Hacer la grfica

G / RT x1
x2

15.5 7.75 4.41

0.04 0.10 0.22
7
3
3

x1/X2
0
-50

3.3
4 3.19 3.68 4.05 4.75 8.96
0.4 0.66 1.02 1.20 1.46 2.57
1
1
7
1
6
9

f(x) = - 16.44x
5 + 15.33
R = 0.93

-100
-150
-200
-250
-300
-350
-400
-450

Determinar el Modelo de Margules

10

15

19.8
3
4.39

65.1 386.4
5
8
8.72 22.41
7
9

20

25

Del grfico anterior:

m= -16.439 = A21
b= 15.334 = A12

NOMBRE: LEVI ZUTA TAFUR

CODIGO: 20110105F