a) Acetona(1)/1,3-butadieno(2)

y
w
Zc
Tc (K)
Pc (bar)
Vc (cc/mol)

Acetona
0.28
0.307
0.233
508.2
47.01
209

Butadieno
0.72
0.19
0.267
425.2
42.77
220.4

ij
11
12
22

Tcij
508.2
464.851202
425.2

Zcij
0.233
0.25
0.267

ij
11
12
22

dB0/dTr
2.0236265323
1.6049316388
1.2728660769

dB1/dTr
6.4891883786
4.0817154855
2.5674091015

T(K)

Vcij
209
214.649548301
220.4

d^Bij/dT
B/T (cc/mol K)
4.0158073645 7.0880794387
2.619237937 4.8378340221
1.7606738062 3.4181095381

b) Acetonitrilo(1)/ter dietlico(2)

y
w
Zc
Tc (K)
Pc (bar)
Vc (cc/mol)

Acetonitrilo
0.37
0.338
0.184
545.5
48.3
173

ter dietlico
0.63
0.281
0.263
466.7
36.4
280

ij
11
12
22

Tcij
545.5
504.56401972
466.7

Zcij
0.184
0.2235
0.263

ij
11
12
22

dB0/dTr
dB1/dTr
2.6334150847 10.9892559805
2.1499842513 7.3248748572
1.7552995377 4.8823861933

wij
0.307
0.2485
0.19

T(K)

Vcij
173
222.22497331
280

wij
0.338
0.3095
0.281

d^Bij/dT
B/T (cc/mol K)
6.3477836061 10.9409652479
4.4170330196 8.7042168706
3.1272500581 7.1339012145

c) Cloruro de metilo (1)/cloruro de etilo (2)

y
w
Zc
Tc (K)
Pc (bar)
Vc (cc/mol)

1
0.45
0.153
0.276
416.3
66.8
143

2
0.55
0.19
0.275
460.4
52.7
200

ij
11
12
22

Tcij
416.3
437.79506621
460.4

Zcij
0.276
0.2755
0.275

ij
11
12
22

dB0/dTr
1.2047499456
1.3732338199
1.5652801073

dB1/dTr
2.2999769449
2.9882617319
3.8825207351

T(K)

Vcij
143
169.909816551
200

d^Bij/dT
B/T (cc/mol K)
1.5566464182 1.9373608584
1.8857207069 2.6564605754
2.302959047 3.6378785988

d) Nitrgeno(1)/Amoniaco(2)

y
w
Zc
Tc (K)
Pc (bar)
Vc (cc/mol)

Nitrgeno
0.83
0.038
0.289
126.2
34
89.2

Amoniaco
0.17
0.253
0.242
405.7
112.8
72.5

ij
11
12
22

Tcij
126.2
226.27271157
405.7

Zcij
0.289
0.2655
0.242

ij
11
12
22

dB0/dTr
0.0585608375
0.2672370245
1.2195117138

dB1/dTr
0.0054343075
0.1131678088
2.3566853619

wij
0.153
0.1715
0.19

T(K)

Vcij
89.2
80.5617445124
72.5

wij
0.038
0.1455
0.253

d^Bij/dT
B/T (cc/mol K)
0.0587673412 0.1437287667
0.2837029407 0.3804486021
1.8157531103 1.3408321959

e) Dixido de azufre(1)/etileno(2)

y
w
Zc
Tc (K)
Pc (bar)
Vc (cc/mol)

1
0.32
0.245
0.269
430.8
78.84
122

2
0.68
0.087
0.281
282.3
50.4
131

ij
11
12
22

Tcij
430.8
348.73319314
282.3

Zcij
0.269
0.275
0.281

ij
11
12
22

dB0/dTr
1.3169129037
0.7601911191
0.4388221392

dB1/dTr
2.7481710358
0.9157464321
0.3051453192

T(K)

Vcij
122
126.446622799
131

wij
0.245
0.166
0.087

d^Bij/dT
B/T (cc/mol K)
1.9902148074 2.0952305084
0.9122050268
1.20274543
0.465369782 0.7685148739

333.15

Pcij
47.1036233684
45.0125905692
42.8255498004

P(bar)

Trij
0.6555489965
0.7166809477
0.7835136406

B0ij
-0.7463621282
-0.6361029594
-0.5405021454

1.7

B1ij
-0.8744137394
-0.5578829477
-0.340217741

HR (cc bar/mol) SR (cc bar/mol K) GR (cc bar/mol)

-3757.4224326828
-8.2243178376 -1017.4909450976

323.15

Pcij
48.2365784971
42.1901396428
36.4456364071

P(bar)

Trij
0.5923923006
0.6404539114
0.6924148275

B0ij
-0.8922981545
-0.7778586332
-0.6768472149

HR (cc bar/mol) SR (cc bar/mol K) GR (cc bar/mol)

-4626.1602873329
-13.1291582975 -1250.8390692527

1.2

B1ij
-1.4118469651
-0.9785818525
-0.6663594102

298.15

Pcij
66.8020016224
59.0179357546
52.631777

P(bar)

Trij
0.8002642325
0.7609724862
0.7236099044

B0ij
-0.5197524721
-0.5703142386
-0.6251173684

B1ij
-0.2994783337
-0.4027249488
-0.5302826022

HR (cc bar/mol) SR (cc bar/mol K) GR (cc bar/mol)

-1206.2464508878
-1.9373608584 -414.2227303292

293.15

Pcij
33.9940073094
61.9980264252
112.5880733241
HR (cc bar/mol)
-181.8286292215

P(bar)

Trij
2.5606180666
1.428143932
0.7965245255

B0ij
-0.0107477304
-0.1556037608
-0.5242867517

SR (cc bar/mol K) GR (cc bar/mol)

-0.4311863
-55.4263653898

B1ij
0.1356850249
0.1004977477
-0.3081899205

298.15

Pcij
78.9729141639
63.0563409679
50.3449510076

P(bar)

Trij
0.7733286908
0.9553148555
1.1801275239

B0ij
-0.5536926761
-0.3710231537
-0.240762204

HR (cc bar/mol) SR (cc bar/mol K) GR (cc bar/mol)

-2166.9674129098
-5.0515308058 -660.8535031501

4.2

B1ij
-0.3672897446
-0.0694073425
0.0532119293

R(cc bar/mol K) 83.14

^Bij
Bij
B (cc/mol)
Z
V cc/mol
-1.0148071462 -910.2776547138 -598.52408535 0.9632649432 15694.4706
-0.7747368719 -665.187678425
-0.6051435162 -499.5267077179

R(cc bar/mol K) 83.14

^Bij
Bij
B (cc/mol)
-1.3695024287 -1287.630000907 -1042.365891
-1.0807297166 -1074.564350877
-0.8640942091 -919.9482074601

Z
V cc/mol
0.9534427567 21346.5433

R(cc bar/mol K) 83.14

^Bij
Bij
B (cc/mol)
Z
V cc/mol
-0.5655726571 -293.0322100262 -414.22273033 0.9832895135 24373.9683
-0.6393815673 -394.3274221649
-0.7258710629 -527.906227528

R(cc bar/mol K) 83.14

^Bij
Bij
B (cc/mol)
-0.0055916995 -1.7258809376
-18.47545513
-0.1409813385 -42.7785407728
-0.6022588016 -180.4287732158

Z
V cc/mol
0.9977258637 8105.68821

R(cc bar/mol K) 83.14

^Bij
Bij
B (cc/mol)
Z
V cc/mol
-0.6436786635 -291.9286132031 -157.34607218 0.9733399866 5744.60417
-0.3825447725 -175.8963438474
-0.2361327661 -110.0832468517