Datos:

Metano
T= 550 K
v= 0.01 m^3/Kg
R= 0.5182 kPa*m^3/Kg*K

a) Ecuación del gas ideal.

𝑃=𝑅𝑇/𝑣

P= 28501 kPa

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟 )
𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟 )

Tcr= 191.1 K
Pcr= 4.64 Mpa
Pcr= 4640 kPa

a= 0.89162452 kPa*m^6/Kg^2
b= 0.00266778 m^3/Kg

P= 29954.6599 kPa

c) La ecuación de Benedict-Webb-Rubin.
𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3
+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )

T= 550 K
Ru= 8.314 kPa*m^3/kmol*K
𝑣 ̅= 0.16043 m^3/kmol
a= 5
Ao= 187.91
 b= 0.00338
Bo= 0.0426
c= 2.58E+05
Co= 2.29E+06
α= 1.24E-04
γ= 6.00E-03

P= 31247.0078 kPa

Datos:
Metano
T= 300 ºC 𝐾=℃+273.15
T= 573.15 K
𝑣 ̅=(𝑃𝑀)(𝑣)
𝑣 ̅= 30.45 m^3/kmol
R= 0.5182 kPa*m^3/kg*K 𝑣=(𝑣 ̅)/𝑃𝑀
v= 1.89802406 m^3/Kg

a) Ecuación del gas ideal.

𝑃=𝑅𝑇/𝑣

P= 156.481857 kPa

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟
) )

Tcr= 191.1 K
Pcr= 4.64 Mpa
Pcr= 4640 kPa

a= 0.89162452 kPa*m^6/Kg^2
b= 0.00266778 m^3/Kg

P= 156.454609 kPa
 c) La ecuación de Benedict-Webb-Rubin.
𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3
+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )

T= 573.15 K
Ru= 8.314 kPa*m^3/kmol*K
𝑣 ̅= 30.45 m^3/kmol
a= 5
Ao= 187.91
b= 0.00338
Bo= 0.0426
c= 2.58E+05
Co= 2.29E+06
α= 1.24E-04
γ= 6.00E-03

P= 156.500783 kPa

Datos:
Monóxido de Carbono 𝐾=℃+273.15
T= 500 ºC
T= 773.15 K 𝑣 ̅=(𝑃𝑀)(𝑣)
𝑣 ̅= 6.4521 m^3/kmol
R= 0.2968 kPa*m^3/kg*K 𝑣=(𝑣 ̅)/𝑃𝑀
v= 0.23034165 m^3/Kg

a) Ecuación del gas ideal.

𝑃=𝑅𝑇/𝑣

P= 996.219826 kPa

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟
) )
𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟
) )

Tcr= 133 K
Pcr= 3.5 Mpa
Pcr= 3500 kPa

a= 0.18782216 kPa*m^6/Kg^2
b= 0.0014098 m^3/Kg

P= 998.814723 kPa

c) La ecuación de Benedict-Webb-Rubin.

𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3

+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )c

T= 773.15 K
Ru= 8.314 kPa*m^3/kmol*K
𝑣 ̅= 6.4521 m^3/kmol
a= 3.71
Ao= 135.87
b= 0.002632
Bo= 0.05454
c= 1.05E+05
Co= 8.67E+05
α= 1.35E-04
γ= 6.00E-03

P= 1001.43264 kPa

"𝑣 ̅=" 𝑉/𝑘𝑚𝑜𝑙 " "

Datos: 1 mol = 0.001 kmol

Dióxido de Carbono 2.50 mol= 0.0025 kmol
T= 160 ºC
v= 0.05271529 m^3/Kg 1 L = 0.001 m^3
R= 0.1889 kPa*m^3/kg*K 5.8 L = 0.0058 m^3
𝑣 ̅= 2.32 m^3/kmol 𝑣=(𝑣 ̅)/𝑃𝑀
 𝑣=(𝑣 ̅)/𝑃𝑀
V= 5.8 L
V= 0.0058 m^3
T= 433.15 K 𝐾=℃+273.15
a) Ecuación del gas ideal.
𝑃=𝑅𝑇/𝑣

P= 1552.1499 kPa

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟
) )

Tcr= 304.2 K
Pcr= 7.39 Mpa
Pcr= 7390 kPa

a= 0.18850448 kPa*m^6/Kg^2
b= 0.00097198 m^3/Kg

P= 1513.47229 kPa

c) Ecuación de Beattie-Bridgeman
𝑃=(𝑅_𝑢 𝑇)/(𝑣 ̅^2 ) ̅ (1−𝑐/(𝑣 ̅𝑇^3 ))(𝑣 ̅+𝐵)−𝐴/(𝑣 ̅^2 ) ̅

𝐴=𝐴_0 (1−𝑎/𝑣 ̅ ) 𝐵=𝐵_0 (1−𝑏/𝑣 ̅ )

T= 433.15 K
Ru= 8.314 kPa*m^3/kmol*K
𝑣 ̅= 2.32 m^3/kmol
Ao= 507.2836
a= 0.07132
Bo= 0.10476
b= 0.07235
c= 6.60E+05

A= 491.689002
B= 0.10149302

P= 1523.12863 kPa
d) Ecuación de Benedict-Webb-Rubin

𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3

+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )
a= 13.86
Ao= 277.3
b= 0.00721
Bo= 0.04991
c= 1.51E+06
Co= 1.40E+07
α= 8.47E-05
γ= 5.39E-03
𝑣 ̅= 2.32 m^3/kmol
Ru= 8.314 kPa*m^3/kmol*K
T= 4.33E+02 K

P= 1521.83001 kPa
 Datos:
Nitrógeno
m= 100 Kg 𝑣=𝑉/𝑚
V= 3.27 m^3
T= 225 K %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐶−𝑉_𝐼)/𝑉_𝐶 ×100
v= 0.0327 m^3/Kg
R= 0.2968 kPa*m^3/Kg*K %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐼−𝑉_𝐶)/𝑉_𝐶 ×100

a) Ecuación del gas ideal.

𝑃=𝑅𝑇/𝑣

P= 2042.201835 kPa %Error= 2.11009174 %

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟 )𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟 )

Tcr= 126.2 K
Pcr= 3.39 Mpa
Pcr= 3390 kPa

a= 0.174594515 kPa*m^6/Kg^2
b= 0.001381127 m^3/Kg

P= 1968.979835 kPa %Error= 1.55100827 %

c) Ecuación de Beattie-Bridgeman.

𝑃=(𝑅_𝑢 𝑇)/(𝑣 ̅^2 ) ̅ (1−𝑐/(𝑣 ̅𝑇^3 ))(𝑣 ̅+𝐵)−𝐴/(𝑣 ̅

𝑣 ^̅=2(𝑃𝑀)(𝑣)
) ̅

𝐴=𝐴_0 (1−𝑎/𝑣 ̅ ) 𝐵=𝐵_0 (1−𝑏/𝑣 ̅ )

T= 225 K
𝑣 ̅= 0.9160251 m^3/kmol
Ru= 8.314 kPa*m^3/kmol*K
Ao= 136.2315
a= 0.02617
Bo= 0.05046
b= -0.00691
c= 4.20E+04

A= 132.3394905
B= 0.050840643

P= 1989.087835 kPa %Error 0.54560827 %

d) Ecuación de Benedict-Webb-Rubin

𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3

+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )

a= 2.54
Ao= 106.73
b= 0.002328
Bo= 0.04074
c= 7.38E+04
Co= 8.16E+05
α= 1.27E-04
γ= 0.0053
T= 225
𝑣 ̅= 9.16E-01
Ru= 8.31E+00

P= 1990.805794 kPa %Error= 0.45971029 %

Datos: Vapor de Agua 𝑣=𝑉/𝑚

T= 473 K
v= 0.351988736 m^3/Kg
R= 0.4615 kPa*m^3/Kg*K %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐶−𝑉_𝐼)/𝑉_𝐶 ×100

a) Ecuación del gas ideal.

𝑃=𝑅𝑇/𝑣 %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐼−𝑉_𝐶)/𝑉_𝐶 ×100

 P= 620.1604695 kPa %Error= 3.36007825 %

b) Ecuación de Van der Waals.

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟 )𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟 )

Tcr= 647.1 K
Pcr= 22.06 MPa
Pcr= 22060 kPa

a= 1.705550144 kPa*m^6/Kg^2
b= 0.001692184 m^3/Kg

P= 609.3903158 kPa %Error= 1.56505263 %

c) Las tablas de vapor

P= 0.6 MPa Nota: Estos datos se obtuvieron de la "TABLA A-6"
P= 600 kPa

Datos: %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐶−𝑉_𝐼)/𝑉_𝐶 ×100

Nitrógeno
T= 150 K
v= 0.041884 m^3/Kg %𝐸𝑟𝑟𝑜𝑟=(𝑉_𝐼−𝑉_𝐶)/𝑉_𝐶 ×100
R= 0.2968 kPa*m^3/Kg*K

a) Ecuación del gas ideal

𝑃=𝑅𝑇/𝑣

P= 1062.935727 kPa %Error= 6.29357272 %

b) Ecuación de Van der Waals

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟 )𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟 )

 Tcr= 126.2 K
Pcr= 3.39 MPa
Pcr= 3390 kPa

a= 0.174594515 kPa*m^6/Kg^2
b= 0.001381127 m^3/Kg

P= 999.6557982 kPa %Error= 0.03442018 %

c) Ecuación de Beattie-Bridgeman

𝑃=(𝑅_𝑢 𝑇)/(𝑣 ̅^2 ) ̅ (1−𝑐/(𝑣 ̅𝑇^3 ))(𝑣 ̅+𝐵)−𝐴/(𝑣 ̅

𝑣^̅=2(𝑃𝑀)(𝑣)
) ̅

𝐴=𝐴_0 (1−𝑎/𝑣 ̅ ) 𝐵=𝐵_0 (1−𝑏/𝑣 ̅ )

T= 150 K
𝑣 ̅= 1.173296492 m^3/Kmol
Ru= 8.314 kPa*m^3/Kmol*K
Ao= 136.2315
a= 0.02617
Bo= 0.05046
b= -0.00691
c= 4.20E+04

A= 133.1929003
B= 0.050757179

P= 1000.369694 kPa %Error= 0.03696944 %

d) Ecuación de Benedict-Webb-Rubin
𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3
+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )

a= 2.54
Ao= 106.73
b= 0.002328
Bo= 0.04074
c= 7.38E+04
Co= 8.16E+05
α= 1.27E-04
γ= 0.0053
𝑣 ̅= 1.173296492 m^3/Kmol
Ru= 8.314 kPa*m^3/Kmol*K
T= 150 K
 P= 998.1772204 kPa %Error= 0.18227796 %

𝑉=𝜋×𝑟^2×ℎ 𝐾=℃+273.15 100 cm = 1 m

20 cm = 0.2 m
V= 0.031416 m^3
π= 3.1416
h= 1m 𝑣=𝑉/𝑚
d= 0.2 m
r= 0.1 m

Datos:
Dióxido de Carbono
T= 25 ºC
T= 298.15 K
v= 0.02618 m^3/Kg
R= 0.1889 kPa*m^3/Kg*K

a) Ecuación del gas ideal

𝑃=𝑅𝑇/𝑣

P= 2151.28094 kPa

b) Ecuación de Van der Waals

𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2

𝑎=(27𝑅^2 𝑇_𝑐𝑟^2)/(64𝑃_𝑐𝑟 )𝑏=(𝑅𝑇_𝑐𝑟)/(8𝑃_𝑐𝑟 )

Tcr= 304.2 K
Pcr= 7.39 MPa
Pcr= 7390 kPa

a= 0.188504485 kPa*m^6/Kg^2
b= 0.000971979 m^3/Kg

P= 1959.199218 kPa
 c) Ecuación de Beattie-Bridgeman
𝑃=(𝑅_𝑢 𝑇)/(𝑣 ̅^2 ) ̅ (1−𝑐/(𝑣 ̅𝑇^3 ))(𝑣 ̅+𝐵)−𝐴/(𝑣 ̅^2 ) ̅

𝐴=𝐴_0 (1−𝑎/𝑣 ̅ ) 𝐵=𝐵_0 (1−𝑏/𝑣 ̅ )

T= 298.15 K
𝑣 ̅= 0.73338034 m^3/kmol
Ru= 8.314 kPa*m^3/Kmol*K
Ao= 136.2315
a= 0.02617
Bo= 0.05046
b= -0.00691
c= 4.20E+04

A= 131.3702048
B= 0.05093544

P= 3362.678747 kPa

d) Ecuación de Benedict-Webb-Rubin
𝑃=(𝑅_𝑢 𝑇)/𝑣 ̅ +(𝐵_0 𝑅_𝑢 𝑇−𝐴_0−𝐶_0/𝑇^2 ) 1/𝑣 ̅^2 +(𝑏𝑅_𝑢 𝑇−𝑎)/𝑣 ̅^3
+𝑎α/𝑣 ̅^6 +𝑐/(𝑣 ̅^3 𝑇^2 ) (1+𝛾/𝑣 ̅^2 ) 𝑒^( 〖−𝛾〗∕𝑣 ̅ ^2 )

a= 2.54
Ao= 106.73
b= 0.002328
Bo= 0.04074
c= 7.38E+04
Co= 8.16E+05
α= 1.27E-04
γ= 0.0053
𝑣 ̅= 0.73338034 m^3/kmol
Ru= 8.314 kPa*m^3/Kmol*K
T= 298.15 K

P= 3362.534934 kPa