PREPARACIÓN DE SOLUCIONES

Cristal Violeta Hidróxido de Sodio

M (mol/L) 1.00E-04 M (mol/L)
V (mL) 100 V (mL)
V (L) 0.1 V (L)
Mw (g/mol) 407.98 Mw (g/mol)
n (moles) 0.00001 n (moles)
masa (g) 0.004 masa (g)
MReal (mol/L) 0.0001 MReal (mol/L)

Solución VNaOH (mL) VCristal Violeta (mL) [Cristal Violeta] (M)

1 20
2 20
3 20
4 20
5 20
6 20
7 20
0.5 0.00000244
1 0.00000476
2 0.00000909
3 0.00001304
4 0.00001667
5 0.00002000
6 0.00002308

Curva de Calibración
1
0.9 f(x) = 42892.3146123515 x
0.8 R² = 0.980709784095665
0.7
A (l = 588nm)

0.6
0.5
0.4
0.3
0.2
0.1
0
0.00000000 0.00000500 0.00001000 0.00001500 0.00002000 0.00002500
[Cristal Violeta] (M)
idróxido de Sodio
0.02
250
0.25
39.997
0.005
0.20
0.02

A (l = 588nm)
0.15
0.295
0.515
0.651
0.757
0.83
0.859

Curva de Calibrac
1
Pendiente 42892 0.9
f(x) = 34499.7035817829
b 0 0.8
0.7
R² = 0.953507156120977
A (l = 588nm)

0.6
0.5
0.4
0.3
0.2
0.1
0
0.00000000 0.00000500 0.00001000 0.000
00 0.00002000 0.00002500
[Cristal Violeta] (
 Curva de Calibración

f(x) = 34499.7035817829 x + 0.140543448438747

R² = 0.953507156120977

0 0.00000500 0.00001000 0.00001500 0.00002000 0.00002500

[Cristal Violeta] (M)
 PREPARACIÓN DE SOLUCIONES

Hidróxido de Sodio Cristal Violeta

M (mol/L) 0.02 M (mol/L)
V (mL) 20 V (mL)
V (L) 0.02 V (L)
Mw (g/mol) 39.997 Mw (g/mol)
n (moles) 0.0004 n (moles)
masa (g) 0.016 masa (g)
MReal (mol/L) MReal (mol/L)

Tiempo (s) A (l = 588nm) [C24H28N3Cl] (M)

0 0.859 2.002704467E-05
30 0.843 1.965401473E-05
60 0.823 1.918772732E-05
90 0.802 1.869812552E-05
120 0.779 1.816189499E-05
150 0.754 1.757903572E-05
180 0.759 1.769560757E-05
210 0.703 1.63900028E-05
240 0.675 1.573720041E-05
270 0.65 1.515434114E-05
300 0.622 1.450153875E-05
330 0.595 1.387205073E-05
360 0.567 1.321924834E-05
390 0.54 1.258976033E-05
420 0.512 1.193695794E-05
450 0.486 1.13307843E-05
480 0.46 1.072461065E-05
510 0.436 1.016506575E-05
540 0.418 9.745407069E-06
570 0.395 9.209176536E-06
600 0.372 8.672946004E-06
630 0.356 8.299916068E-06
660 0.335 7.810314278E-06
690 0.316 7.367341229E-06
720 0.301 7.017625664E-06
750 0.287 6.691224471E-06
780 0.27 6.294880164E-06
810 0.257 5.991793341E-06
840 0.245 5.71202089E-06
870 0.232 5.408934067E-06
900 0.22 5.129161615E-06
930 0.212 4.942646647E-06
960 0.204 4.75613168E-06
990 0.193 4.499673599E-06
1020 0.184 4.28984426E-06
1050 0.177 4.126643663E-06
1080 0.169 3.940128695E-06
1110 0.162 3.776928098E-06
1140 0.157 3.660356244E-06
1170 0.15 3.497155647E-06
1200 0.145 3.380583792E-06
1230 0.141 3.287326308E-06
1260 0.136 3.170754453E-06
1290 0.132 3.077496969E-06
1320 0.127 2.960925114E-06
1350 0.123 2.86766763E-06
1380 0.119 2.774410146E-06
1410 0.115 2.681152663E-06
1440 0.111 2.587895179E-06
1470 0.103 2.401380211E-06
1500 0.105 2.448008953E-06
1530 0.102 2.37806584E-06
1560 0.099 2.308122727E-06
1590 0.097 2.261493985E-06
1620 0.095 2.214865243E-06
1650 0.093 2.168236501E-06
1680 0.091 2.121607759E-06
1710 0.089 2.074979017E-06
1740 0.088 2.051664646E-06
1770 0.086 2.005035904E-06
1800 0.084 1.958407162E-06
1830 0.083 1.935092791E-06
1860 0.081 1.888464049E-06
1890 0.08 1.865149678E-06
1920 0.079 1.841835307E-06
1950 0.077 1.795206565E-06
1980 0.076 1.771892194E-06
2010 0.075 1.748577823E-06
2040 0.074 1.725263452E-06
2070 0.073 1.701949081E-06
2100 0.071 1.655320339E-06
2130 0.07 1.632005968E-06
2160 0.069 1.608691598E-06
2190 0.069 1.608691598E-06
2220 0.068 1.585377227E-06
2250 0.067 1.562062856E-06
2280 0.066 1.538748485E-06
2310 0.066 1.538748485E-06
2340 0.066 1.538748485E-06
2370 0.065 1.515434114E-06
2400 0.064 1.492119743E-06
2430 0.064 1.492119743E-06
2460 0.063 1.468805372E-06
2490 0.062 1.445491001E-06
2520 0.062 1.445491001E-06
2550 0.061 1.42217663E-06
2580 0.061 1.42217663E-06
2610 0.06 1.398862259E-06
2640 0.061 1.42217663E-06
2670 0.06 1.398862259E-06
2700 0.06 1.398862259E-06
CIONES

Cristal Violeta
1.00E-04
6
0.006
407.98
6E-07
0.0002

-LN(Ccv/Ccv0)
0.141749523568308 Absorbancia en función del tiempo
0.160551487550708 1
0.184562244875494 0.9
0.8 f(x) = 2.31298423563292E-10 x³ − 4.11959454311515E-08 x² − 0.00088960162055265 x
0.210409837686049 + 0.880833652135978
0.7 R² = 0.998300029941412
0.239507399681815
A (l = 588nm)

0.6
0.272126077544607 0.5
0.265516668156934 0.4
0.342161553741899 0.3
0.382805754680034 0.2
0.420546082662881 0.1
0.464578352813384 0
0 200 400 600 800 1000 1200 1400
0.508957040006934
t (s)
0.557159141824812
0.605949305994244
0.659193820513056
0.71130982165207 Método Integral
0.766291956069423 3
0.819876202203529 f(x) = 0.00127538929779768 x
0.862037013027807
2.5 R² = 0.979343099550563
0.918632680651442 2
-LN(Ccv/Ccv0)

0.978624591279417
1.5
1.02258771470053
1.0833879137275 1
1.14177623196565
0.5
1.19040818080369
1.23803622979294 0
0 500 1000 1500 2000 2500 3000
1.29909648655419
t (s)
1.34844236065734
1.39626023500784
1.45078107388625 k'exp 0.0013
1.5038908992002 k'teórico
1.54093217088055 % Error #DIV/0!
1.57939845170835
1.63482825664768
1.68258268794358
1.72136871297873
1.76761973062949
1.80992211032018
1.84127264020426
1.88688315145631
1.92078470313199
1.9487585551744
1.98486355981651
2.01471652296619
2.05333135909397
2.08533409018015
2.11839495244103
2.15258631718931
2.18798824424023
2.26278945732293
2.24355809539504
2.27254563226829
2.30239859541797
2.32280746704918
2.34364155395202
2.36491895239931
2.38665893903571
2.40888207582042
2.42018163107436
2.44317114929906
2.46670164670925
2.47867783775597
2.50306929088012
2.51549181087868
2.52807059308554
2.55371302369888
2.56678510526623
2.58003033201625
2.59345335234839
2.60705900440417
2.63483856851125
2.6490232035032
2.6634119409553
2.6634119409553
2.67801074037646
2.6928258261616
2.70786370352614
2.70786370352614
2.70786370352614
2.72313117565693
2.73863536219289
2.73863536219289
2.75438371916103
2.77038406050747
2.77038406050747
2.78664458137925
2.78664458137925
2.80317388333046
2.78664458137925
2.80317388333046
2.80317388333046
62055265 x

200 1400

00 3000
 PREPARACIÓN DE SOLUCIONES

Hidróxido de Sodio Cristal Violeta

M (mol/L) 0.02 M (mol/L) 1.00E-04
V (mL) 14000 V (mL) 5000
V (L) 14 V (L) 5
Mw (g/mol) 39.997 Mw (g/mol) 407.98
n (moles) 0.28 n (moles) 5E-04
masa (g) 11.199 masa (g) 0.2040

Dimensiones del Reactor

Longitud (m) 50 Volumen (m3) 0.002544788224

Diámetro
8.05 Volumen (L) 2.544788224178
interno (mm)
Radio (m) 0.004025 t (s) 590.3680929202
Caudal inicial Caudal inicial
(mL/min) 258.63 (mL/min)
Caudal inicial
4.310511E-06
(m3/s)
Volumen (m3) 0.0025447882

Conversión alcanzada Flujo Conversión alcanzada Flujo

Tapón Laminar

k' (s-1) 0.0013 k' (s-1) 0.0013 t/2

t (s) 590.36809292 t (s) 590.36809292
t 0.3837392604 E (t) 0
X Flujo Tapón X Flujo Laminar
(Teórico) 0.5358 (Teórico) 0.5801
 Caudal NaOH Cristal Violeta
(mL/min) (mL/min)
198.019 51.793

208.93 53.53

206.89 56.73

204.61 54.02

X experimental 0.8254

295.1840464601 %Error X Flujo Tapón 54.04%

% Error X Flujo Laminar 42.27%
 Inicial
Entrada reactor [CV] X X experimental
0.7 1.622.E-05 0.83
Salida reactor [CV] 0.84
0.23 2.594.E-06

5 min
Entrada reactor [CV] X
0.703 1.630.E-05
Salida reactor [CV] 0.82
0.241 2.913.E-06

10 min

Entrada reactor [CV] X

0.71 1.651.E-05

Salida reactor [CV]

0.81

0.246 3.058.E-06