Ejemplo solución de sistemas de ecuaciones diferenciales ordinarias - Problemas de valor inicial

Ejercicio 28.11 Chapra y Canale.

Donde C es la concentración del reactante y T es la temperatura del reactor. Inicialmente, el reactor se encuentra

a. Identifique las variables x y Y del problema. Así como F(x, y).

x t
Y Y1 C
Y2 T
F(x,y)

b. Mediante el Método de Euler y empleando un valor de h = 0.2, encuentre los perfiles de concentración y tem
ambos perfiles en Microsoft Excel®.

h 0.2

Solución numérica Euler

N x=t Y1 = C Y2 = T f1(x,y) f2(x,y)
1 0 1 15 -0.96587368 1015.87368
2 0.2 0.80682526 218.174735 -0.79056491 -1191.18244
3 0.4 0.64871228 -20.0617533 -0.62356559 1024.18312
4 0.6 0.52399916 184.774871 -0.51267663 -1135.07208
5 0.8 0.42146384 -42.2395452 -0.40358979 1025.98525
6 1 0.34074588 162.957504 -0.33301881 -1096.55623
7 1.2 0.27414212 -56.3537428 -0.26177581 1025.31324
8 1.4 0.22178696 148.708905 -0.21658958 -1070.49947
9 1.6 0.17846904 -65.3909893 -0.17007639 1023.98628
10 1.8 0.14445376 139.406267 -0.14099318 -1053.06949
11 2 0.11625513 -71.2076303 -0.11063442 1022.71072
12 2.2 0.09412824 133.334514 -0.09183999 -1041.50515
13 2.4 0.07576024 -74.9665155 -0.0720296 1021.69476
14 2.6 0.06135432 129.372436 -0.0598483 -1033.87606
15 2.8 0.04938466 -77.4027754 -0.0469233 1020.95106
16 3 0.04 126.787436 -0.03901188 -1028.86248
17 3.2 0.03219763 -78.9850602 -0.03058013 1020.43073
18 3.4 0.0260816 125.101085 -0.02543461 -1025.57624
19 3.6 0.02099468 -80.0141632 -0.0199345 1020.07613
20 3.8 0.01700778 124.001063 -0.01658472 -1023.4259
21 4 0.01369083 -80.6841178 -0.01299713 1019.83831
22 4.2 0.01109141 123.283545 -0.01081502 -1022.02042
23 4.4 0.0089284 -81.1205397 -0.00847501 1019.6804
24 4.6 0.0072334 122.815541 -0.00705294 -1021.10247
25 4.8 0.00582281 -81.4049523 -0.0055267 1019.57622
26 5 0.00471747 122.510291 -0.00459969 -1020.50322
s de valor inicial

almente, el reactor se encuentra a 15°C y tiene una concentración de reactante C de 1.0 gmol/L.

perfiles de concentración y temperatura para un intervalo de tiempo de 0 a 5 minutos. Grafique

Concentración vs tiempo
1.2

0.8
C (gmol/L)

0.6 Numèrica - Concentraciòn

0.4

0.2

0
0 1 2 3 4 5 6
t (min)

Temperatura vs tiempo
250

200

150

100
T(°C)

Numèrica - Temperatura
50
 Temperatura vs tiempo
250

200

150

100
T(°C)
Numèrica - Temperatura
50

0
0 1 2 3 4 5 6
-50

-100

t (min)
Donde C es la concentración del reactante y T es la temperatura del reactor. Inicialmente, el reactor se encuentra

a. Identifique las variables x y Y del problema. Así como F (x, y).

x t
Y Y1 C
Y2 T
F(x,y)

c. Repita el literal b empleando un valor de h = 0.02.

h 0.02

Solución numérica Euler

N x=t Y1 = C Y2 = T f1(x,y) f2(x,y)
1 0 1 15 -0.96587368 1015.87368
2 0.02 0.98068253 35.3174735 -0.94938526 796.210528
3 0.04 0.96169482 51.2416841 -0.93248771 620.070872
4 0.06 0.94304507 63.6431015 -0.91544384 479.012829
5 0.08 0.92473619 73.2233581 -0.89840899 366.175407
6 0.1 0.90676801 80.5468663 -0.88147959 276.010927
7 0.12 0.88913842 86.0670848 -0.8647176 204.046749
8 0.14 0.87184407 90.1480198 -0.84816365 146.683456
9 0.16 0.85488079 93.0816889 -0.83184467 101.027781
10 0.18 0.8382439 95.1022445 -0.81577839 64.7559498
11 0.2 0.82192833 96.3973635 -0.79997629 36.0026513
12 0.22 0.80592881 97.1174165 -0.78444539 13.2712229
13 0.24 0.7902399 97.382841 -0.76918959 -4.6388217
14 0.26 0.77485611 97.2900646 -0.75421049 -18.6901596
15 0.28 0.7597719 96.9162614 -0.73950801 -29.654608
16 0.3 0.74498174 96.3231692 -0.72508084 -38.1508559
17 0.32 0.73048012 95.5601521 -0.71092675 -44.6747684
18 0.34 0.71626159 94.6666567 -0.69704285 -49.6237129
19 0.36 0.70232073 93.6741825 -0.68342574 -53.3160807
20 0.38 0.68865221 92.6078608 -0.67007166 -56.0069471
21 0.4 0.67525078 91.4877219 -0.65697659 -57.900632
22 0.42 0.66211125 90.3297093 -0.64413632 -59.1607728
23 0.44 0.64922852 89.1464938 -0.63154654 -59.9183998
24 0.46 0.63659759 87.9481258 -0.61920285 -60.2784118
25 0.48 0.62421353 86.7425576 -0.60710081 -60.324766
26 0.5 0.61207152 85.5360623 -0.59523598 -60.1246388
27 0.52 0.6001668 84.3335695 -0.58360393 -59.7317606
28 0.54 0.58849472 83.1389343 -0.57220025 -59.1890884
29 0.56 0.57705071 81.9551525 -0.56102058 -58.5309484
30 0.58 0.5658303 80.7845335 -0.55006058 -57.784752
31 0.6 0.55482909 79.6288385 -0.53931601 -56.9723721
32 0.62 0.54404277 78.489391 -0.52878267 -56.1112453
33 0.64 0.53346712 77.3671661 -0.51845641 -55.2152554
34 0.66 0.52309799 76.262861 -0.50833317 -54.2954412
35 0.68 0.51293133 75.1769522 -0.49840896 -53.3605637
36 0.7 0.50296315 74.1097409 -0.48867985 -52.4175607
37 0.72 0.49318955 73.0613897 -0.47914199 -51.4719106
38 0.74 0.48360671 72.0319515 -0.46979159 -50.5279246
39 0.76 0.47421088 71.021393 -0.46062495 -49.5889799
40 0.78 0.46499838 70.0296134 -0.45163843 -48.6577073
41 0.8 0.45596561 69.0564593 -0.44282845 -47.736141
42 0.82 0.44710904 68.1017365 -0.43419153 -46.8258387
43 0.84 0.43842521 67.1652197 -0.42572422 -45.9279779
44 0.86 0.42991073 66.2466601 -0.41742317 -45.0434331
45 0.88 0.42156226 65.3457915 -0.40928508 -44.172837
46 0.9 0.41337656 64.4623347 -0.40130672 -43.3166306
47 0.92 0.40535043 63.5960021 -0.39348492 -42.4751023
48 0.94 0.39748073 62.7465001 -0.38581658 -41.6484195
49 0.96 0.3897644 61.9135317 -0.37829866 -40.8366543
50 0.98 0.38219842 61.0967986 -0.37092818 -40.0398035
51 1 0.37477986 60.2960025 -0.36370222 -39.2578049
52 1.02 0.36750582 59.5108464 -0.35661791 -38.4905502
53 1.04 0.36037346 58.7410354 -0.34967246 -37.7378955
54 1.06 0.35338001 57.9862775 -0.34286311 -36.9996694
55 1.08 0.34652275 57.2462841 -0.33618716 -36.2756796
56 1.1 0.339799 56.5207705 -0.32964199 -35.5657183
57 1.12 0.33320616 55.8094562 -0.32322499 -34.8695666
58 1.14 0.32674166 55.1120648 -0.31693365 -34.1869972
59 1.16 0.32040299 54.4283249 -0.31076547 -33.5177775
60 1.18 0.31418768 53.7579693 -0.30471802 -32.8616719
61 1.2 0.30809332 53.1007359 -0.29878892 -32.2184428
62 1.22 0.30211754 52.456367 -0.29297582 -31.5878526
63 1.24 0.29625803 51.82461 -0.28727644 -30.9696644
64 1.26 0.2905125 51.2052167 -0.28168852 -30.3636426
65 1.28 0.28487873 50.5979438 -0.27620988 -29.769554
 66 1.3 0.27935453 50.0025528 -0.27083836 -29.187168
67 1.32 0.27393776 49.4188094 -0.26557184 -28.6162569
68 1.34 0.26862633 48.8464843 -0.26040825 -28.0565965
69 1.36 0.26341816 48.2853523 -0.25534556 -27.5079657
70 1.38 0.25831125 47.735193 -0.25038178 -26.9701474
71 1.4 0.25330361 47.1957901 -0.24551497 -26.4429281
72 1.42 0.24839331 46.6669315 -0.24074322 -25.926098
73 1.44 0.24357845 46.1484096 -0.23606464 -25.4194513
74 1.46 0.23885716 45.6400205 -0.23147742 -24.9227858
75 1.48 0.23422761 45.1415648 -0.22697974 -24.4359034
76 1.5 0.22968801 44.6528467 -0.22256986 -23.9586095
77 1.52 0.22523662 44.1736746 -0.21824603 -23.4907136
78 1.54 0.2208717 43.7038603 -0.21400657 -23.0320286
79 1.56 0.21659156 43.2432197 -0.20984983 -22.5823713
80 1.58 0.21239457 42.7915723 -0.20577416 -22.141562
81 1.6 0.20827909 42.348741 -0.20177799 -21.7094247
82 1.62 0.20424353 41.9145525 -0.19785974 -21.2857868
83 1.64 0.20028633 41.4888368 -0.19401789 -20.8704792
84 1.66 0.19640597 41.0714272 -0.19025094 -20.4633362
85 1.68 0.19260095 40.6621605 -0.18655741 -20.0641954
86 1.7 0.18886981 40.2608766 -0.18293587 -19.6728976
87 1.72 0.18521109 39.8674186 -0.1793849 -19.2892869
88 1.74 0.18162339 39.4816329 -0.17590312 -18.9132106
89 1.76 0.17810533 39.1033687 -0.17248917 -18.5445188
90 1.78 0.17465554 38.7324783 -0.16914172 -18.1830651
91 1.8 0.17127271 38.368817 -0.16585946 -17.8287055
92 1.82 0.16795552 38.0122429 -0.16264113 -17.4812994
93 1.84 0.1647027 37.6626169 -0.15948546 -17.1407086
94 1.86 0.16151299 37.3198027 -0.15639123 -16.806798
95 1.88 0.15838516 36.9836668 -0.15335723 -16.479435
96 1.9 0.15531802 36.6540781 -0.15038229 -16.15849
97 1.92 0.15231037 36.3309083 -0.14746525 -15.8438356
98 1.94 0.14936107 36.0140316 -0.14460497 -15.5353472
99 1.96 0.14646897 35.7033246 -0.14180034 -15.2329027
100 1.98 0.14363296 35.3986666 -0.13905028 -14.9363825
101 2 0.14085196 35.0999389 -0.13635372 -14.6456692
102 2.02 0.13812488 34.8070255 -0.13370961 -14.360648
103 2.04 0.13545069 34.5198126 -0.13111692 -14.0812063
104 2.06 0.13282835 34.2381885 -0.12857465 -13.8072337
105 2.08 0.13025686 33.9620438 -0.12608182 -13.5386221
106 2.1 0.12773522 33.6912713 -0.12363745 -13.2752657
107 2.12 0.12526247 33.425766 -0.1212406 -13.0170604
108 2.14 0.12283766 33.1654248 -0.11889034 -12.7639047
109 2.16 0.12045986 32.9101467 -0.11658577 -12.5156989
110 2.18 0.11812814 32.6598327 -0.11432598 -12.2723452
111 2.2 0.11584162 32.4143858 -0.11211011 -12.0337479
112 2.22 0.11359942 32.1737109 -0.1099373 -11.7998132
113 2.24 0.11140067 31.9377146 -0.1078067 -11.5704491
114 2.26 0.10924454 31.7063056 -0.10571749 -11.3455656
115 2.28 0.10713019 31.4793943 -0.10366887 -11.1250744
116 2.3 0.10505681 31.2568928 -0.10166004 -10.9088888
117 2.32 0.10302361 31.0387151 -0.09969023 -10.6969242
118 2.34 0.10102981 30.8247766 -0.09775867 -10.4890974
119 2.36 0.09907463 30.6149946 -0.09586462 -10.2853269
120 2.38 0.09715734 30.4092881 -0.09400735 -10.085533
121 2.4 0.09527719 30.2075774 -0.09218614 -9.88963735
122 2.42 0.09343347 30.0097847 -0.09040028 -9.69756335
123 2.44 0.09162546 29.8158334 -0.0886491 -9.50923582
124 2.46 0.08985248 29.6256487 -0.08693191 -9.32458114
125 2.48 0.08811384 29.4391571 -0.08524804 -9.14352713
126 2.5 0.08640888 29.2562865 -0.08359686 -8.96600303
127 2.52 0.08473695 29.0769665 -0.08197773 -8.79193952
128 2.54 0.08309739 28.9011277 -0.08039001 -8.62126864
129 2.56 0.08148959 28.7287023 -0.0788331 -8.45392379
130 2.58 0.07991293 28.5596238 -0.0773064 -8.28983969
131 2.6 0.0783668 28.393827 -0.07580932 -8.12895237
132 2.62 0.07685062 28.231248 -0.07434128 -7.9711991
133 2.64 0.07536379 28.071824 -0.07290172 -7.81651842
134 2.66 0.07390576 27.9154936 -0.07149009 -7.66485008
135 2.68 0.07247595 27.7621966 -0.07010583 -7.51613504
136 2.7 0.07107384 27.6118739 -0.06874842 -7.37031541
137 2.72 0.06969887 27.4644676 -0.06741734 -7.22733447
138 2.74 0.06835052 27.3199209 -0.06611207 -7.08713659
139 2.76 0.06702828 27.1781782 -0.06483211 -6.94966728
140 2.78 0.06573164 27.0391849 -0.06357698 -6.8148731
141 2.8 0.0644601 26.9028874 -0.06234617 -6.68270169
142 2.82 0.06321318 26.7692334 -0.06113923 -6.55310171
143 2.84 0.06199039 26.6381713 -0.05995569 -6.42602285
144 2.86 0.06079128 26.5096509 -0.05879509 -6.30141577
145 2.88 0.05961537 26.3836226 -0.05765699 -6.17923213
146 2.9 0.05846224 26.2600379 -0.05654095 -6.05942454
147 2.92 0.05733142 26.1388494 -0.05544655 -5.94194654
148 2.94 0.05622248 26.0200105 -0.05437335 -5.82675258
149 2.96 0.05513502 25.9034754 -0.05332096 -5.71379803
150 2.98 0.0540686 25.7891995 -0.05228896 -5.60303912
151 3 0.05302282 25.6771387 -0.05127695 -5.49443296
152 3.02 0.05199728 25.56725 -0.05028456 -5.3879375
153 3.04 0.05099159 25.4594913 -0.0493114 -5.28351151
154 3.06 0.05000536 25.3538211 -0.0483571 -5.18111458
155 3.08 0.04903822 25.2501988 -0.04742128 -5.0807071
156 3.1 0.04808979 25.1485846 -0.0465036 -4.98225023
157 3.12 0.04715972 25.0489396 -0.04560369 -4.88570591
158 3.14 0.04624765 24.9512255 -0.04472122 -4.79103681
159 3.16 0.04535322 24.8554048 -0.04385584 -4.69820635
160 3.18 0.04447611 24.7614406 -0.04300723 -4.60717866
161 3.2 0.04361596 24.6692971 -0.04217505 -4.51791858
162 3.22 0.04277246 24.5789387 -0.041359 -4.43039165
163 3.24 0.04194528 24.4903309 -0.04055874 -4.34456406
164 3.26 0.04113411 24.4034396 -0.03977399 -4.26040269
165 3.28 0.04033863 24.3182315 -0.03900444 -4.17787506
166 3.3 0.03955854 24.234674 -0.03824979 -4.09694934
167 3.32 0.03879354 24.152735 -0.03750976 -4.0175943
168 3.34 0.03804335 24.0723832 -0.03678405 -3.93977935
169 3.36 0.03730767 23.9935876 -0.0360724 -3.86347448
170 3.38 0.03658622 23.9163181 -0.03537453 -3.78865028
171 3.4 0.03587873 23.8405451 -0.03469017 -3.71527792
172 3.42 0.03518492 23.7662395 -0.03401907 -3.64332912
173 3.44 0.03450454 23.6933729 -0.03336095 -3.57277617
174 3.46 0.03383732 23.6219174 -0.03271558 -3.50359189
175 3.48 0.03318301 23.5518456 -0.03208271 -3.43574964
176 3.5 0.03254136 23.4831306 -0.03146208 -3.3692233
177 3.52 0.03191212 23.4157461 -0.03085347 -3.30398727
178 3.54 0.03129505 23.3496664 -0.03025665 -3.24001644
179 3.56 0.03068991 23.284866 -0.02967137 -3.17728619
180 3.58 0.03009649 23.2213203 -0.02909743 -3.11577239
181 3.6 0.02951454 23.1590049 -0.0285346 -3.05545139
182 3.62 0.02894385 23.0978958 -0.02798266 -2.99629997
183 3.64 0.02838419 23.0379698 -0.0274414 -2.9382954
184 3.66 0.02783536 22.9792039 -0.02691062 -2.88141538
185 3.68 0.02729715 22.9215756 -0.02639012 -2.82563804
186 3.7 0.02676935 22.8650629 -0.02587969 -2.77094195
187 3.72 0.02625176 22.809644 -0.02537913 -2.71730609
188 3.74 0.02574417 22.7552979 -0.02488827 -2.66470986
189 3.76 0.02524641 22.7020037 -0.0244069 -2.61313304
190 3.78 0.02475827 22.649741 -0.02393485 -2.56255584
191 3.8 0.02427957 22.5984899 -0.02347194 -2.51295882
192 3.82 0.02381013 22.5482307 -0.02301798 -2.46432294
193 3.84 0.02334977 22.4989443 -0.02257281 -2.41662954
194 3.86 0.02289832 22.4506117 -0.02213626 -2.3698603
195 3.88 0.02245559 22.4032145 -0.02170815 -2.32399728
196 3.9 0.02202143 22.3567345 -0.02128832 -2.27902287
197 3.92 0.02159566 22.3111541 -0.02087662 -2.23491981
198 3.94 0.02117813 22.2664557 -0.02047289 -2.1916712
199 3.96 0.02076867 22.2226223 -0.02007696 -2.14926044
200 3.98 0.02036713 22.1796371 -0.0196887 -2.10767125
201 4 0.01997336 22.1374836 -0.01930795 -2.0668877
202 4.02 0.0195872 22.0961459 -0.01893456 -2.02689415
203 4.04 0.01920851 22.055608 -0.0185684 -1.98767525
204 4.06 0.01883714 22.0158545 -0.01820933 -1.94921598
205 4.08 0.01847295 21.9768702 -0.0178572 -1.91150159
206 4.1 0.01811581 21.9386401 -0.01751188 -1.87451763
207 4.12 0.01776557 21.9011498 -0.01717325 -1.83824993
208 4.14 0.01742211 21.8643848 -0.01684116 -1.80268458
209 4.16 0.01708528 21.8283311 -0.0165155 -1.76780796
210 4.18 0.01675497 21.7929749 -0.01619614 -1.73360672
211 4.2 0.01643105 21.7583028 -0.01588296 -1.70006774
212 4.22 0.01611339 21.7243015 -0.01557584 -1.66717818
213 4.24 0.01580188 21.6909579 -0.01527465 -1.63492545
214 4.26 0.01549638 21.6582594 -0.0149793 -1.6032972
215 4.28 0.0151968 21.6261934 -0.01468965 -1.5722813
216 4.3 0.014903 21.5947478 -0.01440561 -1.5418659
217 4.32 0.01461489 21.5639105 -0.01412707 -1.51203934
218 4.34 0.01433235 21.5336697 -0.01385391 -1.48279021
219 4.36 0.01405527 21.5040139 -0.01358603 -1.45410731
220 4.38 0.01378355 21.4749318 -0.01332334 -1.42597967
221 4.4 0.01351708 21.4464122 -0.01306573 -1.39839651
222 4.42 0.01325577 21.4184442 -0.0128131 -1.37134728
223 4.44 0.01299951 21.3910173 -0.01256535 -1.34482164
224 4.46 0.0127482 21.3641209 -0.0123224 -1.31880944
225 4.48 0.01250175 21.3377447 -0.01208415 -1.29330072
226 4.5 0.01226007 21.3118786 -0.0118505 -1.26828572
227 4.52 0.01202306 21.2865129 -0.01162137 -1.24375488
228 4.54 0.01179063 21.2616378 -0.01139668 -1.21969881
229 4.56 0.0115627 21.2372439 -0.01117633 -1.19610832
230 4.58 0.01133917 21.2133217 -0.01096024 -1.17297437
231 4.6 0.01111997 21.1898622 -0.01074833 -1.15028814
232 4.62 0.010905 21.1668564 -0.01054052 -1.12804093
233 4.64 0.01069419 21.1442956 -0.01033673 -1.10622425
234 4.66 0.01048746 21.1221711 -0.01013688 -1.08482975
235 4.68 0.01028472 21.1004745 -0.0099409 -1.06384926
236 4.7 0.0100859 21.0791976 -0.0097487 -1.04327475
237 4.72 0.00989093 21.0583321 -0.00956022 -1.02309836
238 4.74 0.00969972 21.0378701 -0.00937539 -1.00331237
239 4.76 0.00951221 21.0178039 -0.00919413 -0.98390924
240 4.78 0.00932833 20.9981257 -0.00901638 -0.96488153
241 4.8 0.009148 20.978828 -0.00884206 -0.94622198
242 4.82 0.00897116 20.9599036 -0.00867111 -0.92792346
243 4.84 0.00879774 20.9413451 -0.00850347 -0.90997898
244 4.86 0.00862767 20.9231455 -0.00833907 -0.89238168
245 4.88 0.00846089 20.9052979 -0.00817785 -0.87512484
246 4.9 0.00829733 20.8877954 -0.00801975 -0.85820185
247 4.92 0.00813694 20.8706314 -0.00786471 -0.84160627
248 4.94 0.00797964 20.8537993 -0.00771266 -0.82533175
249 4.96 0.00782539 20.8372926 -0.00756355 -0.80937207
250 4.98 0.00767412 20.8211052 -0.00741733 -0.79372114
251 5 0.00752577 20.8052308 -0.00727393 -0.77837298
almente, el reactor se encuentra a 15°C y tiene una concentración de reactante C de 1.0 gmol/L.

Concentración vs tiempo
1.2

0.8
C (gmol/L)

0.6 Numèrica - Concentraciòn

0.4

0.2

0
0 1 2 3 4 5 6
t (min)

Temperatura vs tiempo
120

100

80
T(°C)

60 Numèrica - Temperatura

40

20
 100

80

T(°C)
60 Numèrica - Temperatura

40

20

0
0 1 2 3 4 5 6
t (min)
Donde C es la concentración del reactante y T es la temperatura del reactor. Inicialmente, el reactor se encuentra

a. Identifique las variables x y Y del problema. Así como F (x, y).

x t
Y Y1 C
Y2 T
F(x,y)

e. Repita el problema empleando el Método RK4 y un paso de h = 0.2.

h 0.2

Solución numérica RK4

N x=t Y1 = C Y2 = T k1 f1(x,y) k1 f2(x,y) k2 f1(x,y)
1 0 1 15 -0.96587368 1015.87368 -0.88051875
2 0.2 0.82352975 71.7524701 -0.7999853 282.460599 -0.72386216
3 0.4 0.67795823 80.8772647 -0.65906838 50.2957323 -0.59523356
4 0.6 0.55815733 76.0959961 -0.54239551 -18.5644515 -0.48961264
5 0.8 0.45959105 68.1319525 -0.44631408 -35.005449 -0.40284955
6 1 0.37848602 60.2588196 -0.3672976 -35.2905916 -0.33154712
7 1.2 0.3117354 53.3494585 -0.30232807 -31.1665166 -0.27292696
8 1.4 0.25678714 47.5240648 -0.24889935 -26.3413029 -0.22471586
9 1.6 0.21154568 42.6852455 -0.20494955 -21.9029076 -0.18505268
10 1.8 0.17428992 38.6886216 -0.16878688 -18.0993383 -0.15241256
11 2 0.14360576 35.394531 -0.13902388 -14.9214252 -0.12554527
12 2.2 0.11833082 32.6813962 -0.1145224 -12.2915573 -0.10342509
13 2.4 0.09750931 30.447131 -0.09434829 -10.1230178 -0.08520992
14 2.6 0.08035498 28.6071557 -0.07773444 -8.33712076 -0.07020805
15 2.8 0.06622088 27.091741 -0.06405055 -6.86685479 -0.057851
16 3 0.05457452 25.8434988 -0.05277855 -5.65643862 -0.04767136
17 3.2 0.04497753 24.8152188 -0.04349236 -4.65983154 -0.03928467
18 3.4 0.03706894 23.968062 -0.03584147 -3.83914649 -0.0323746
19 3.6 0.03055146 23.2700701 -0.02953747 -3.16323352 -0.02668079
20 3.8 0.02518024 22.6949403 -0.02434292 -2.60648344 -0.02198892
21 4 0.02075357 22.2210198 -0.02006236 -2.14783759 -0.0181225
22 4.2 0.01710527 21.83048 -0.01653483 -1.76997399 -0.01493618
23 4.4 0.01409842 21.5086387 -0.01362775 -1.45863995 -0.01231026
24 4.6 0.01162021 21.2434028 -0.01123192 -1.20210503 -0.01014612
25 4.8 0.00957766 21.0248108 -0.0092574 -0.99071234 -0.00836252
26 5 0.00789418 20.844656 -0.00763005 -0.81651038 -0.00689251
 1
 y1i  h  k11  2k 21  2k
i 1
y1
6
1
y 2  y 2i  h  k12  2k 22  2k
i 1

6
Con :
 i
k11  f1 x1 , y1i , y 2i 
 f x ,y ,y 
i i i
k12 2 1 1 2
almente, el reactor se encuentra a 15°C y tiene una concentración de reactante C de 1.0 gmol/L.
 1 1
k 21  f1  xi  h, y1i  k11 h, y
 2 2
 1 1
k 22  f 2  xi  h, y1i  k11 h, y
 2 2
 1 1
k 31  f1  xi  h, y1i  k 21h, y
 2 2
 1 1
k 32  f 2  xi  h, y1i  k 21h, y
 2 2

k 41  f1 xi  h, y1i  k 31 h, y 2i  k
k 42  f x
2 i  h, y1i  k 31h, y 2i 

érica RK4
k2 f2(x,y) k3 f1(x,y) k3 f2(x,y) k4 f1(x,y) k4 f2(x,y) Concentración vs
-85.3549269 -0.87989307 1015.248 -0.80741028 -1173.08571 1.2
-76.1231354 -0.72919085 287.789286 -0.66105421 -432.049064
1
-63.8348188 -0.6008915 55.9536768 -0.54270849 -177.971506
-52.7828672 -0.49459931 -13.577785 -0.44616884 -87.6355522 0.8
C (gmol/L)

-43.464521 -0.40703888 -30.8161244 -0.36706003 -52.6272452

0.6
-35.7504891 -0.33501395 -31.823756 -0.30209893 -36.8417524
-29.4011119 -0.27578216 -28.311315 -0.24870152 -28.1704392 0.4
-24.1834862 -0.22706416 -23.993 -0.20478434 -22.4703062 0.2
-19.8968686 -0.18698371 -19.9718729 -0.16865038 -18.2583266
-16.374322 -0.15400075 -16.5111387 -0.13891148 -14.9524563 0
0 1 2 3 4 5
-13.4786143 -0.12685186 -13.614832 -0.11442992 -12.2857276
t (min)
-11.0973166 -0.10450031 -11.2163378 -0.0942722 -10.1090877
-9.13837453 -0.08609496 -9.23797573 -0.07767182 -8.32354225
-7.52638811 -0.07093671 -7.60845843 -0.06399901 -6.85562808
-6.19955744 -0.05845102 -6.26682832 -0.05273611 -5.64763864 Temperatura vs
-5.10719297 -0.04816553 -5.16226046 -0.04345741 -4.65305363 90
-4.20768946 -0.03969172 -4.25277501 -0.03581269 -3.83394341 80
-3.46687669 -0.03270993 -3.50381488 -0.02951376 -3.15922846 70
-2.8566753 -0.02695706 -2.88696283 -0.02432339 -2.60338416 60
-2.35400009 -0.02221655 -2.37885376 -0.02004627 -2.14542415 50
T(°C)

40
30
20
 80
70
60
50

T(°C)
-1.93986394 -0.01831006 -1.96027292 -0.01652157 -1.76808242 40
-1.59864486 -0.01509074 -1.6154142 -0.01361682 -1.45714811 30
-1.31748574 -0.01243763 -1.33127167 -0.01122292 -1.20092156 20
-1.08580235 -0.01025108 -1.09714062 -0.00924998 -0.98976849 10
-0.89487974 -0.00844902 -0.90420837 -0.00762394 -0.81575402 0
0 1 2 3 4 5
-0.7375408 -0.0069638 -0.74521835 -0.00628378 -0.67234207
t (min)
 1
 y1i  h  k11  2k 21  2k 31  k 41 
i 1
y1
6
1
y 2  y 2i  h  k12  2k 22  2k 32  k 42 
i 1

6
Con :
11  i
 f1 x1 , y1i , y 2i 
 f x ,y ,y 
i i i
12 2 1 1 2

 1 1 1 
21  f1  xi  h, y1i  k11 h, y 2i  k12 h 
 2 2 2 
 1 1 1 
22  f 2  xi  h, y1i  k11 h, y 2i  k12 h 
 2 2 2 
 1 1 1 
31  f1  xi  h, y1i  k 21h, y 2i  k 22 h 
 2 2 2 
 1 1 1 
32  f 2  xi  h, y1i  k 21h, y 2i  k 22 h 
 2 2 2 
41 
 f1 xi  h, y1i  k 31h, y 2i  k 32 h 
42  f x
2 i  h, y  k 31 h, y  k 32
i
1
i
2 h

Concentración vs tiempo

Numèrica - Concentraciòn

1 2 3 4 5 6
t (min)

Temperatura vs tiempo

Numèrica - Temperatura
 Numèrica - Temperatura

1 2 3 4 5 6
t (min)
Donde C es la concentración del reactante y T es la temperatura del reactor. Inicialmente, el reactor se encuentra

a. Identifique las variables x y Y del problema. Así como F (x, y).

x t
Y Y1 C
Y2 T
F(x,y)

e. Repita el problema empleando el Método RK4 y un paso de h = 0.2.

h 0.02

Solución numérica RK4

N x=t Y1 = C Y2 = T k1 f1(x,y) k1 f2(x,y) k2 f1(x,y)
1 0 1 15 -0.96587368 1015.87368 -0.95767686
2 0.02 0.98084717 33.2601664 -0.94933779 816.736131 -0.94094711
3 0.04 0.96202839 47.907529 -0.93251229 653.437005 -0.92404772
4 0.06 0.94354724 59.5937751 -0.91560013 519.662374 -0.90713482
5 0.08 0.92540412 68.8553421 -0.89872616 410.172743 -0.89030671
6 0.1 0.9075974 76.1332371 -0.88197043 320.638057 -0.87362744
7 0.12 0.89012416 81.7897031 -0.86538565 247.488617 -0.85713964
8 0.14 0.87298059 86.1221023 -0.84900718 187.786158 -0.84087205
9 0.16 0.85616233 89.3744213 -0.83285889 139.114681 -0.82484404
10 0.18 0.8396646 91.746775 -0.81695682 99.4890687 -0.80906852
11 0.2 0.82348235 93.4032408 -0.80131151 67.2791055 -0.79355383
12 0.22 0.80761038 94.4783068 -0.78592962 41.1465513 -0.778305
13 0.24 0.79204338 95.0821756 -0.77081494 19.9931821 -0.76332464
14 0.26 0.77677599 95.3051218 -0.75596918 2.91795819 -0.74861359
15 0.28 0.76180282 95.2210721 -0.74139249 -10.8182356 -0.73417134
16 0.3 0.7471185 94.890544 -0.72708385 -21.8215893 -0.71999637
17 0.32 0.73271769 94.3630583 -0.71304138 -30.5892025 -0.70608643
18 0.34 0.71859509 93.6791184 -0.69926252 -37.5286637 -0.69243867
19 0.36 0.70474545 92.8718346 -0.68574422 -42.9741271 -0.67904984
20 0.38 0.6911636 91.9682567 -0.67248306 -47.1995108 -0.66591636
21 0.4 0.67784444 90.9904664 -0.65947534 -50.4293277 -0.6530344
22 0.42 0.66478293 89.9564737 -0.64671716 -52.8475732 -0.64040001
23 0.44 0.65197412 88.8809521 -0.6342045 -54.6050164 -0.62800909
24 0.46 0.63941314 87.7758412 -0.62193323 -55.8251812 -0.61585746
25 0.48 0.62709521 86.6508409 -0.60989916 -56.6092523 -0.60394094
26 0.5 0.61501562 85.5138167 -0.59809807 -57.0400986 -0.59225528
27 0.52 0.60316976 84.3711319 -0.58652575 -57.1855734 -0.58079629
28 0.54 0.59155309 83.2279198 -0.57517798 -57.1012195 -0.56955975
29 0.56 0.58016117 82.0883072 -0.56405058 -56.832489 -0.55854149
30 0.58 0.56898963 80.9555974 -0.55313941 -56.4165621 -0.5477374
31 0.6 0.55803418 79.83242 -0.54244036 -55.883839 -0.53714339
32 0.62 0.54729062 78.7208541 -0.53194938 -55.2591634 -0.52675543
33 0.64 0.53675484 77.622529 -0.52166246 -54.5628248 -0.51656956
34 0.66 0.52642279 76.5387066 -0.51157569 -53.811381 -0.50658187
35 0.68 0.51629051 75.4703496 -0.50168516 -53.0183318 -0.49678851
36 0.7 0.5063541 74.4181762 -0.49198709 -52.1946723 -0.48718571
37 0.72 0.49660977 73.3827061 -0.48247772 -51.3493448 -0.47776976
38 0.74 0.48705376 72.3642976 -0.47315337 -50.4896112 -0.46853701
39 0.76 0.47768242 71.3631778 -0.46401042 -49.6213566 -0.45948387
40 0.78 0.46849216 70.3794679 -0.45504534 -48.7493393 -0.45060684
41 0.8 0.45947945 69.4132033 -0.44625464 -47.8773949 -0.44190246
42 0.82 0.45064083 68.4643507 -0.4376349 -47.0086045 -0.43336736
43 0.84 0.44197293 67.5328214 -0.42918278 -46.1454314 -0.42499822
44 0.86 0.43347243 66.6184828 -0.42089499 -45.2898342 -0.41679178
45 0.88 0.42513606 65.7211671 -0.41276831 -44.443359 -0.40874485
46 0.9 0.41696064 64.8406794 -0.40479958 -43.6072147 -0.40085431
47 0.92 0.40894304 63.9768033 -0.3969857 -42.7823352 -0.39311709
48 0.94 0.4010802 63.1293061 -0.38932363 -41.9694302 -0.38553017
49 0.96 0.39336911 62.2979427 -0.3818104 -41.1690268 -0.37809062
50 0.98 0.38580681 61.4824591 -0.37444309 -40.3815033 -0.37079555
51 1 0.37839043 60.6825949 -0.36721883 -39.6071172 -0.36364211
52 1.02 0.37111712 59.8980857 -0.36013483 -38.8460284 -0.35662754
53 1.04 0.36398412 59.1286646 -0.35318833 -38.0983173 -0.34974911
54 1.06 0.35698869 58.3740637 -0.34637664 -37.3640006 -0.34300415
55 1.08 0.35012817 57.6340155 -0.33969711 -36.6430435 -0.33639005
56 1.1 0.34339994 56.9082534 -0.33314716 -35.9353703 -0.32990425
57 1.12 0.33680144 56.1965128 -0.32672426 -35.2408724 -0.32354424
58 1.14 0.33033014 55.4985316 -0.3204259 -34.5594152 -0.31730754
59 1.16 0.32398359 54.8140503 -0.31424966 -33.8908441 -0.31119175
60 1.18 0.31775936 54.142813 -0.30819314 -33.2349885 -0.30519451
61 1.2 0.31165508 53.4845672 -0.30225401 -32.5916659 -0.29931348
62 1.22 0.30566843 52.8390641 -0.29642996 -31.9606847 -0.2935464
63 1.24 0.29979713 52.2060589 -0.29071874 -31.3418471 -0.28789105
64 1.26 0.29403894 51.5853107 -0.28511816 -30.7349505 -0.28234523
65 1.28 0.28839168 50.9765827 -0.27962604 -30.1397894 -0.27690681
 66 1.3 0.28285319 50.3796423 -0.27424027 -29.5561569 -0.27157369
67 1.32 0.27742137 49.7942609 -0.26895876 -28.9838455 -0.26634381
68 1.34 0.27209416 49.2202144 -0.2637795 -28.422648 -0.26121515
69 1.36 0.26686953 48.6572823 -0.25870046 -27.8723585 -0.25618574
70 1.38 0.26174549 48.1052487 -0.25371971 -27.3327723 -0.25125365
71 1.4 0.2567201 47.5639014 -0.24883533 -26.803687 -0.24641697
72 1.42 0.25179144 47.0330325 -0.24404542 -26.2849024 -0.24167384
73 1.44 0.24695766 46.512438 -0.23934816 -25.7762209 -0.23702244
74 1.46 0.24221691 46.0019177 -0.23474173 -25.277448 -0.23246098
75 1.48 0.2375674 45.5012753 -0.23022436 -24.7883917 -0.2279877
76 1.5 0.23300736 45.0103185 -0.22579432 -24.3088635 -0.2236009
77 1.52 0.22853505 44.5288585 -0.22144991 -23.8386779 -0.21929887
78 1.54 0.2241488 44.0567103 -0.21718945 -23.3776525 -0.21507998
79 1.56 0.21984693 43.5936925 -0.21301132 -22.9256083 -0.21094261
80 1.58 0.21562781 43.1396273 -0.2089139 -22.4823695 -0.20688516
81 1.6 0.21148984 42.6943402 -0.20489564 -22.0477634 -0.20290608
82 1.62 0.20743147 42.2576603 -0.20095498 -21.6216209 -0.19900384
83 1.64 0.20345114 41.8294201 -0.19709042 -21.2037757 -0.19517696
84 1.66 0.19954735 41.4094551 -0.19330049 -20.7940649 -0.19142396
85 1.68 0.19571863 40.9976043 -0.18958371 -20.3923288 -0.18774342
86 1.7 0.19196352 40.5937098 -0.18593869 -19.9984105 -0.18413391
87 1.72 0.18828061 40.1976168 -0.18236401 -19.6121564 -0.18059407
88 1.74 0.1846685 39.8091735 -0.17885832 -19.233416 -0.17712253
89 1.76 0.18112583 39.4282311 -0.17542027 -18.8620415 -0.17371797
90 1.78 0.17765125 39.0546437 -0.17204855 -18.4978882 -0.17037908
91 1.8 0.17424345 38.6882683 -0.16874187 -18.1408141 -0.16710461
92 1.82 0.17090115 38.3289649 -0.16549897 -17.7906801 -0.16389328
93 1.84 0.16762308 37.9765958 -0.16231861 -17.4473499 -0.16074389
94 1.86 0.164408 37.6310264 -0.15919957 -17.1106899 -0.15765522
95 1.88 0.16125469 37.2921246 -0.15614068 -16.7805691 -0.15462609
96 1.9 0.15816198 36.9597609 -0.15314075 -16.4568591 -0.15165536
97 1.92 0.15512868 36.6338084 -0.15019865 -16.139434 -0.14874189
98 1.94 0.15215365 36.3141425 -0.14731325 -15.8281706 -0.14588457
99 1.96 0.14923578 36.0006413 -0.14448346 -15.5229479 -0.14308231
100 1.98 0.14637395 35.6931851 -0.1417082 -15.2236476 -0.14033405
101 2 0.14356709 35.3916567 -0.13898641 -14.9301534 -0.13763873
102 2.02 0.14081415 35.095941 -0.13631706 -14.6423516 -0.13499534
103 2.04 0.13811407 34.8059254 -0.13369912 -14.3601307 -0.13240286
104 2.06 0.13546584 34.5214993 -0.13113161 -14.0833813 -0.12986032
105 2.08 0.13286847 34.2425544 -0.12861355 -13.8119963 -0.12736673
106 2.1 0.13032098 33.9689844 -0.12614397 -13.5458706 -0.12492117
107 2.12 0.1278224 33.7006852 -0.12372195 -13.2849014 -0.12252269
108 2.14 0.12537179 33.4375546 -0.12134656 -13.0289878 -0.12017038
109 2.16 0.12296823 33.1794926 -0.1190169 -12.7780308 -0.11786336
110 2.18 0.12061082 32.926401 -0.11673208 -12.5319336 -0.11560075
111 2.2 0.11829866 32.6781835 -0.11449123 -12.2906012 -0.11338168
112 2.22 0.11603088 32.4347458 -0.11229352 -12.0539405 -0.11120531
113 2.24 0.11380663 32.1959954 -0.11013809 -11.8218602 -0.10907083
114 2.26 0.11162508 31.9618415 -0.10802414 -11.5942708 -0.10697742
115 2.28 0.1094854 31.7321952 -0.10595087 -11.3710847 -0.10492428
116 2.3 0.10738678 31.5069693 -0.10391748 -11.1522159 -0.10291064
117 2.32 0.10532844 31.2860783 -0.1019232 -10.9375802 -0.10093573
118 2.34 0.10330959 31.0694384 -0.09996729 -10.727095 -0.09899881
119 2.36 0.10132949 30.8569674 -0.09804899 -10.5206794 -0.09709914
120 2.38 0.09938739 30.6485847 -0.09616759 -10.3182541 -0.09523601
121 2.4 0.09748255 30.4442112 -0.09432237 -10.1197412 -0.0934087
122 2.42 0.09561426 30.2437694 -0.09251263 -9.92506456 -0.09161652
123 2.44 0.09378181 30.0471835 -0.09073769 -9.73414941 -0.08985881
124 2.46 0.09198452 29.8543789 -0.08899687 -9.54692251 -0.08813489
125 2.48 0.09022171 29.6652825 -0.08728951 -9.36331206 -0.0864441
126 2.5 0.08849272 29.4798228 -0.08561498 -9.18324765 -0.08478582
127 2.52 0.0867969 29.2979294 -0.08397263 -9.0066603 -0.08315941
128 2.54 0.08513361 29.1195336 -0.08236185 -8.83348235 -0.08156426
129 2.56 0.08350222 28.9445678 -0.08078203 -8.66364749 -0.07999977
130 2.58 0.08190212 28.7729659 -0.07923257 -8.49709073 -0.07846534
131 2.6 0.08033272 28.6046628 -0.07771288 -8.33374833 -0.07696039
132 2.62 0.07879341 28.4395949 -0.07622239 -8.17355784 -0.07548436
133 2.64 0.07728363 28.2776999 -0.07476054 -8.01645799 -0.07403669
134 2.66 0.0758028 28.1189164 -0.07332678 -7.86238877 -0.07261683
135 2.68 0.07435038 27.9631845 -0.07192055 -7.71129131 -0.07122425
136 2.7 0.0729258 27.8104453 -0.07054135 -7.56310791 -0.06985841
137 2.72 0.07152855 27.6606411 -0.06918863 -7.417782 -0.06851881
138 2.74 0.07015808 27.5137154 -0.0678619 -7.27525813 -0.06720495
139 2.76 0.0688139 27.3696125 -0.06656064 -7.13548193 -0.06591631
140 2.78 0.06749549 27.2282781 -0.06528438 -6.9984001 -0.06465242
141 2.8 0.06620236 27.0896589 -0.06403263 -6.86396037 -0.0634128
142 2.82 0.06493403 26.9537024 -0.06280491 -6.73211153 -0.06219699
143 2.84 0.06369001 26.8203575 -0.06160077 -6.60280334 -0.06100452
144 2.86 0.06246984 26.6895737 -0.06041975 -6.47598657 -0.05983495
145 2.88 0.06127307 26.5613017 -0.0592614 -6.35161292 -0.05868783
146 2.9 0.06009924 26.4354932 -0.0581253 -6.22963507 -0.05756274
147 2.92 0.05894791 26.3121007 -0.057011 -6.1100066 -0.05645924
148 2.94 0.05781865 26.1910776 -0.05591809 -5.99268203 -0.05537692
149 2.96 0.05671105 26.0723783 -0.05484617 -5.87761674 -0.05431538
150 2.98 0.05562467 25.9559582 -0.05379481 -5.76476699 -0.05327422
151 3 0.05455912 25.8417732 -0.05276364 -5.65408989 -0.05225304
152 3.02 0.05351399 25.7297804 -0.05175226 -5.54554342 -0.05125146
153 3.04 0.0524889 25.6199375 -0.05076029 -5.43908633 -0.0502691
154 3.06 0.05148345 25.5122032 -0.04978735 -5.33467822 -0.04930559
155 3.08 0.05049728 25.406537 -0.04883309 -5.23227945 -0.04836057
156 3.1 0.04953001 25.3028989 -0.04789714 -5.13185117 -0.04743368
157 3.12 0.04858128 25.2012501 -0.04697915 -5.03335527 -0.04652458
158 3.14 0.04765073 25.1015521 -0.04607877 -4.93675441 -0.04563293
159 3.16 0.04673801 25.0037675 -0.04519566 -4.84201196 -0.04475838
160 3.18 0.04584279 24.9078595 -0.0443295 -4.74909199 -0.04390061
161 3.2 0.04496472 24.8137919 -0.04347996 -4.65795931 -0.04305929
162 3.22 0.04410348 24.7215294 -0.04264671 -4.56857938 -0.04223412
163 3.24 0.04325874 24.6310373 -0.04182945 -4.48091834 -0.04142477
164 3.26 0.0424302 24.5422814 -0.04102787 -4.394943 -0.04063095
165 3.28 0.04161753 24.4552285 -0.04024166 -4.31062082 -0.03985236
166 3.3 0.04082043 24.3698458 -0.03947054 -4.22791987 -0.0390887
167 3.32 0.04003861 24.2861011 -0.0387142 -4.14680885 -0.03833969
168 3.34 0.03927176 24.203963 -0.03797237 -4.06725709 -0.03760504
169 3.36 0.03851962 24.1234007 -0.03724477 -3.98923449 -0.03688448
170 3.38 0.03778188 24.0443837 -0.03653113 -3.91271154 -0.03617775
171 3.4 0.03705828 23.9668824 -0.03583116 -3.83765931 -0.03548456
172 3.42 0.03634854 23.8908677 -0.03514463 -3.76404944 -0.03480467
173 3.44 0.03565241 23.816311 -0.03447126 -3.6918541 -0.03413782
174 3.46 0.03496961 23.7431843 -0.0338108 -3.62104601 -0.03348376
175 3.48 0.03429989 23.6714601 -0.033163 -3.55159842 -0.03284223
176 3.5 0.03364301 23.6011114 -0.03252763 -3.48348511 -0.03221301
177 3.52 0.0329987 23.5321119 -0.03190444 -3.41668035 -0.03159585
178 3.54 0.03236675 23.4644357 -0.0312932 -3.35115892 -0.03099053
179 3.56 0.0317469 23.3980572 -0.03069368 -3.28689609 -0.03039681
180 3.58 0.03113892 23.3329516 -0.03010565 -3.2238676 -0.02981447
181 3.6 0.0305426 23.2690944 -0.02952889 -3.16204967 -0.0292433
182 3.62 0.0299577 23.2064617 -0.0289632 -3.10141898 -0.02868308
183 3.64 0.029384 23.1450299 -0.02840835 -3.04195265 -0.0281336
184 3.66 0.02882129 23.084776 -0.02786413 -2.98362826 -0.02759465
185 3.68 0.02826936 23.0256773 -0.02733035 -2.92642382 -0.02706603
186 3.7 0.02772801 22.9677117 -0.0268068 -2.87031775 -0.02654755
187 3.72 0.02719702 22.9108574 -0.02629329 -2.81528892 -0.02603901
188 3.74 0.02667621 22.8550931 -0.02578961 -2.76131657 -0.02554021
189 3.76 0.02616537 22.8003978 -0.0252956 -2.70838038 -0.02505097
190 3.78 0.02566432 22.7467511 -0.02481105 -2.65646039 -0.02457111
191 3.8 0.02517287 22.6941328 -0.02433579 -2.60553705 -0.02410045
192 3.82 0.02469083 22.6425231 -0.02386964 -2.55559117 -0.02363881
193 3.84 0.02421803 22.5919027 -0.02341242 -2.50660395 -0.02318602
194 3.86 0.02375428 22.5422527 -0.02296397 -2.45855693 -0.02274191
195 3.88 0.02329941 22.4935543 -0.02252411 -2.41143204 -0.0223063
196 3.9 0.02285326 22.4457894 -0.02209268 -2.36521152 -0.02187905
197 3.92 0.02241565 22.3989399 -0.02166952 -2.31987799 -0.02145998
198 3.94 0.02198642 22.3529885 -0.02125447 -2.27541438 -0.02104895
199 3.96 0.02156542 22.3079177 -0.02084737 -2.23180396 -0.02064579
200 3.98 0.02115247 22.2637107 -0.02044808 -2.18903032 -0.02025035
201 4 0.02074744 22.220351 -0.02005643 -2.14707737 -0.0198625
202 4.02 0.02035017 22.1778223 -0.01967229 -2.10592934 -0.01948208
203 4.04 0.0199605 22.1361086 -0.01929551 -2.06557073 -0.01910894
204 4.06 0.0195783 22.0951943 -0.01892596 -2.02598639 -0.01874296
205 4.08 0.01920342 22.055064 -0.01856348 -1.98716142 -0.01838399
206 4.1 0.01883571 22.0157028 -0.01820795 -1.94908122 -0.0180319
207 4.12 0.01847505 21.9770959 -0.01785923 -1.91173149 -0.01768655
208 4.14 0.0181213 21.9392288 -0.01751719 -1.87509818 -0.01734782
209 4.16 0.01777432 21.9020873 -0.01718171 -1.83916752 -0.01701558
210 4.18 0.01743399 21.8656575 -0.01685265 -1.80392602 -0.01668971
211 4.2 0.01710017 21.8299258 -0.0165299 -1.76936043 -0.01637008
212 4.22 0.01677275 21.7948787 -0.01621333 -1.73545776 -0.01605657
213 4.24 0.0164516 21.7605031 -0.01590283 -1.70220527 -0.01574907
214 4.26 0.0161366 21.7267862 -0.01559827 -1.66959048 -0.01544746
215 4.28 0.01582763 21.6937153 -0.01529955 -1.63760114 -0.01515163
216 4.3 0.01552458 21.6612781 -0.01500656 -1.60622523 -0.01486147
217 4.32 0.01522733 21.6294623 -0.01471917 -1.57545096 -0.01457687
218 4.34 0.01493577 21.5982561 -0.01443729 -1.54526679 -0.01429771
219 4.36 0.0146498 21.5676478 -0.01416082 -1.51566138 -0.01402391
220 4.38 0.01436931 21.5376259 -0.01388964 -1.48662362 -0.01375535
221 4.4 0.01409418 21.5081791 -0.01362365 -1.4581426 -0.01349194
222 4.42 0.01382433 21.4792965 -0.01336276 -1.43020764 -0.01323357
223 4.44 0.01355964 21.4509673 -0.01310686 -1.40280824 -0.01298015
224 4.46 0.01330002 21.4231807 -0.01285587 -1.37593414 -0.01273159
225 4.48 0.01304537 21.3959265 -0.01260969 -1.34957524 -0.01248778
226 4.5 0.0127956 21.3691943 -0.01236822 -1.32372164 -0.01224865
227 4.52 0.01255061 21.3429743 -0.01213138 -1.29836367 -0.0120141
228 4.54 0.01231031 21.3172565 -0.01189907 -1.27349178 -0.01178404
229 4.56 0.01207462 21.2920314 -0.01167122 -1.24909667 -0.01155839
230 4.58 0.01184344 21.2672895 -0.01144773 -1.22516918 -0.01133706
231 4.6 0.01161668 21.2430216 -0.01122852 -1.20170032 -0.01111997
232 4.62 0.01139427 21.2192185 -0.0110135 -1.17868131 -0.01090703
233 4.64 0.01117611 21.1958714 -0.01080261 -1.1561035 -0.01069818
234 4.66 0.01096214 21.1729715 -0.01059576 -1.13395843 -0.01049333
235 4.68 0.01075226 21.1505103 -0.01039286 -1.1122378 -0.0102924
236 4.7 0.0105464 21.1284792 -0.01019386 -1.09093346 -0.01009532
237 4.72 0.01034448 21.1068702 -0.00999866 -1.07003743 -0.00990201
238 4.74 0.01014642 21.0856751 -0.00980721 -1.04954187 -0.0097124
239 4.76 0.00995216 21.0648859 -0.00961942 -1.02943909 -0.00952643
240 4.78 0.00976162 21.0444949 -0.00943523 -1.00972157 -0.00934402
241 4.8 0.00957473 21.0244945 -0.00925456 -0.9903819 -0.0091651
242 4.82 0.00939142 21.0048772 -0.00907736 -0.97141285 -0.00898961
243 4.84 0.00921161 20.9856356 -0.00890355 -0.9528073 -0.00881748
244 4.86 0.00903525 20.9667625 -0.00873307 -0.93455829 -0.00864865
245 4.88 0.00886227 20.9482509 -0.00856585 -0.91665896 -0.00848305
246 4.9 0.0086926 20.9300939 -0.00840184 -0.89910262 -0.00832062
247 4.92 0.00852618 20.9122846 -0.00824096 -0.88188268 -0.0081613
248 4.94 0.00836294 20.8948164 -0.00808317 -0.8649927 -0.00800504
249 4.96 0.00820283 20.8776827 -0.0079284 -0.84842634 -0.00785176
250 4.98 0.00804578 20.8608772 -0.00777659 -0.83217741 -0.00770142
251 5 0.00789175 20.8443935 -0.0076277 -0.8162398 -0.00755396
 1
 y1i  h  k11  2k 21  2k
i 1
y1
6
1
y 2  y 2i  h  k12  2k 22  2k
i 1

6
Con :
 i
k11  f1 x1 , y1i , y 2i 
 f x ,y ,y 
i i i
k12 2 1 1 2
almente, el reactor se encuentra a 15°C y tiene una concentración de reactante C de 1.0 gmol/L.
 1 1
k 21  f 1  xi  h, y1i  k11 h, y
 2 2
 1 1
k 22  f 2  xi  h, y1i  k11 h, y
 2 2
 1 1
k 31  f 1  xi  h, y1i  k 21h, y
 2 2
 1 1
k 32  f 2  xi  h, y1i  k 21h, y
 2 2

k 41  f 1 xi  h, y1i  k 31h, y 2i  k
k 42  f x
2 i  h, y1i  k 31h, y 2i 

érica RK4
k2 f2(x,y) k3 f1(x,y) k3 f2(x,y) k4 f1(x,y) k4 f2(x,y) Concentración vs
906.089491 -0.95763742 917.028467 -0.94934601 815.940313 1.2
726.671833 -0.94094242 735.673575 -0.93251822 652.781838
1
579.628732 -0.92406606 587.027901 -0.91560445 519.123582
459.230828 -0.90716887 465.308033 -0.89872935 409.729988 0.8
C (gmol/L)

360.736017 -0.89035168 365.724656 -0.88197277 320.274418

0.6
280.231264 -0.87368007 284.324569 -0.86538736 247.190079
214.49375 -0.85719765 217.851241 -0.84900842 187.541143 0.4
160.872412 -0.8409338 163.625535 -0.83285977 138.913642 0.2
117.18836 -0.82490834 119.44529 -0.81695742 99.3241464
81.6518667 -0.80913448 83.5015475 -0.80131189 67.1438346 0
0 1 2 3 4 5
52.7935135 -0.79362079 54.3090296 -0.78592983 41.0356174
t (min)
29.4072752 -0.77837245 30.6486508 -0.77081502 19.9022189
10.5035673 -0.7633922 11.5200827 -0.75596915 2.84337992
-4.72942439 -0.74868095 -3.8973214 -0.74139238 -10.8793726
-16.9575615 -0.73423828 -16.2766798 -0.72708368 -21.8717013 Temperatura vs
-26.7269104 -0.72006273 -26.1700184 -0.71304116 -30.6302723 120
-34.4852346 -0.70615207 -34.0299933 -0.69926227 -37.5623179
100
-40.5996453 -0.69250349 -40.2277315 -0.68574394 -43.0017004
-45.371093 -0.67911376 -45.0674786 -0.67248275 -47.2220978 80
-49.0462611 -0.66597932 -48.798622 -0.65947502 -50.4478265
T(°C)

60

40

20
 100

80

T(°C)
60
-51.8273266 -0.65309638 -51.6255563 -0.64671683 -52.8627201
-53.8799675 -0.64046096 -53.7157791 -0.63420417 -54.6174154 40
-55.3399328 -0.628069 -55.2065316 -0.62193289 -55.8353276
20
-56.3184304 -0.61591632 -56.2102455 -0.60989881 -56.6175521
-56.9065472 -0.60399874 -56.8190112 -0.59809772 -57.046885 0
0 1 2 3 4 5
-57.1788732 -0.59231204 -57.1082418 -0.5865254 -57.1911193
t (min)
-57.1964743 -0.58085199 -57.1396781 -0.57517763 -57.1057489
-57.0093296 -0.56961441 -56.9638526 -0.56405024 -56.8361854
-56.6583303 -0.55859513 -56.6221101 -0.55313907 -56.419576
-56.1769181 -0.54779002 -56.1482645 -0.54244003 -55.8862938
-55.5924293 -0.537195 -55.5699569 -0.53194905 -55.2611603
-54.927196 -0.52680605 -54.9097696 -0.52166214 -54.5644466
-54.19945 -0.51661921 -54.1861395 -0.51157537 -53.8126957
-53.4240627 -0.50663055 -53.4141058 -0.50168485 -53.0193953
-52.6131524 -0.49683626 -52.6059248 -0.49198678 -52.1955301
-51.776582 -0.48723253 -51.7715723 -0.48247741 -51.3500344
-50.9223669 -0.47781567 -50.9191563 -0.47315307 -50.4901632
-50.0570095 -0.46858202 -50.055255 -0.46401013 -49.6217962
-49.1857732 -0.45952801 -49.1851942 -0.45504505 -48.749687
-48.3129072 -0.45065011 -48.3132739 -0.44625436 -47.8776678
-47.4418307 -0.4419449 -47.4429551 -0.43763463 -47.0088162
-46.5752839 -0.43340897 -46.5770123 -0.42918251 -46.1455933
-45.7154513 -0.42503901 -45.7176582 -0.42089473 -45.2899557
-44.8640638 -0.41683177 -44.8666466 -0.41276805 -44.4434476
-44.0224812 -0.40878407 -44.025356 -0.40479932 -43.6072765
-43.1917605 -0.40089276 -43.1948591 -0.39698545 -42.7823755
-42.3727116 -0.39315478 -42.3759783 -0.38932338 -41.9694531
-41.5659433 -0.38556713 -41.5693327 -0.38181016 -41.1690357
-40.7719001 -0.37812686 -40.7753755 -0.37444285 -40.3815009
-39.9908936 -0.37083108 -39.994425 -0.3672186 -39.6071059
-39.2231272 -0.36367695 -39.2266905 -0.3601346 -38.84601
-38.4687165 -0.35666169 -38.4722921 -0.35318811 -38.0982934
-37.7277066 -0.3497826 -37.7312789 -0.34637642 -37.3639723
-37.0000855 -0.34303699 -37.0036419 -0.3396969 -36.643012
-36.2857956 -0.33642225 -36.289326 -0.33314695 -35.9353363
-35.5847427 -0.32993582 -35.5882391 -0.32672405 -35.2408365
-34.8968037 -0.32357519 -34.9002599 -0.3204257 -34.559378
-34.2218327 -0.31733789 -34.2252439 -0.31424946 -33.8908061
-33.559666 -0.31122151 -33.5630283 -0.30819295 -33.23495
-32.9101262 -0.30522368 -32.9134369 -0.30225382 -32.5916271
-32.2730255 -0.29934209 -32.2762825 -0.29642977 -31.960646
-31.6481688 -0.29357445 -31.6513706 -0.29071856 -31.3418086
-31.0353551 -0.28791855 -31.0385009 -0.28511798 -30.7349123
-30.4343802 -0.2823722 -30.4374694 -0.27962586 -30.1397517
-29.8450377 -0.27693325 -29.8480699 -0.27424009 -29.5561197
-29.2671199 -0.27159962 -29.2700953 -0.26895859 -28.9838089
-28.7004195 -0.26636923 -28.7033383 -0.26377933 -28.4226121
-28.1447296 -0.26124008 -28.1475922 -0.2587003 -27.8723233
-27.5998448 -0.25621019 -27.6026518 -0.25371955 -27.3327378
-27.0655616 -0.25127762 -27.0683135 -0.24883517 -26.8036533
-26.5416784 -0.24644047 -26.5443761 -0.24404527 -26.2848694
-26.0279965 -0.24169688 -26.0306407 -0.23934801 -25.7761888
-25.5243196 -0.23704504 -25.5269111 -0.23474158 -25.2774166
-25.0304545 -0.23248314 -25.0329942 -0.23022422 -24.7883611
-24.5462109 -0.22800943 -24.5486998 -0.22579418 -24.3088336
-24.0714018 -0.2236222 -24.0738407 -0.22144977 -23.8386487
-23.6058433 -0.21931977 -23.608233 -0.21718931 -23.377624
-23.1493545 -0.21510047 -23.1516962 -0.21301118 -22.9255806
-22.7017583 -0.2109627 -22.7040526 -0.20891377 -22.4823424
-22.2628802 -0.20690486 -22.2651283 -0.20489551 -22.0477371
-21.8325494 -0.20292539 -21.8347521 -0.20095486 -21.6215952
-21.4105982 -0.19902279 -21.4127564 -0.1970903 -21.2037507
-20.9968621 -0.19519554 -20.9989766 -0.19330036 -20.7940406
-20.5911796 -0.19144218 -20.5932514 -0.1895836 -20.392305
-20.1933926 -0.18776128 -20.1954225 -0.18593857 -19.9983874
-19.8033458 -0.18415143 -19.8053347 -0.1823639 -19.6121339
-19.4208872 -0.18061124 -19.4228359 -0.17885821 -19.2333941
-19.0458675 -0.17713937 -19.0477769 -0.17542016 -18.8620202
-18.6781406 -0.17373449 -18.6800115 -0.17204844 -18.4978674
-18.3175632 -0.17039528 -18.3193963 -0.16874176 -18.1407938
-17.9639948 -0.16712049 -17.9657909 -0.16549886 -17.7906604
-17.6172976 -0.16390886 -17.6190575 -0.16231851 -17.4473307
-17.2773366 -0.16075916 -17.2790611 -0.15919947 -17.1106712
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 1
 y1i  h  k11  2k 21  2k 31  k 41 
i 1
y1
6
1
y 2  y 2i  h  k12  2k 22  2k 32  k 42 
i 1

6
Con :
11  i
 f1 x1 , y1i , y 2i 
 f x ,y ,y 
i i i
12 2 1 1 2

 1 1 1 
21  f 1  xi  h, y1i  k11 h, y 2i  k12 h 
 2 2 2 
 1 1 1 
22  f 2  xi  h, y1i  k11 h, y 2i  k12 h 
 2 2 2 
 1 1 1 
31  f 1  xi  h, y1i  k 21 h, y 2i  k 22 h 
 2 2 2 
 1 1 1 
32  f 2  xi  h, y1i  k 21h, y 2i  k 22 h 
 2 2 2 
41 
 f 1 xi  h, y1i  k 31h, y 2i  k 32 h 
42  f x
2 i  h, y  k 31 h, y  k 32
i
1
i
2 h

Concentración vs tiempo

Numèrica - Concentraciòn

1 2 3 4 5 6
t (min)

Temperatura vs tiempo

Numèrica - Temperatura
 Numèrica - Temperatura

1 2 3 4 5 6
t (min)