UNIVERSIDAD‌‌NACIONAL‌‌DE‌‌SAN‌‌AGUSTÍN‌‌DE‌ 

‌AREQUIPA‌ ‌
FACULTAD‌‌DE‌‌INGENIERÍA‌‌DE‌‌PROCESOS‌ ‌
ESCUELA‌‌PROFESIONAL‌‌DE‌‌INGENIERÍA‌‌AMBIENTAL‌ ‌

Práctica 3

Asignatura: ‌ Termodinamica y Cinetica

Docente: Monzón Martinez Lalo Jose

Integrantes: ‌ ‌
● Castro Machaca, Maria Gracia
● Castro Cusi, Ilen Nicole Xiomara
● Cornejo Romero, Belén Taywara
● Conde Villanueva, Adrian Ruben
● Palomino Cervantes, Maria Fernanda
● Rodriguez Yancapallo, Dian Alexander

Arequipa - Perú
2021
PROBLEMA 1

0
2𝐶𝑂2 → 2𝐶𝑂(𝑔) + 𝑂2 ∆𝐻 = − 2(− 283, 0) 𝑘𝐽
0
𝐶(𝑠) + 𝑂2(𝑔) → 𝐶𝑂2 ∆𝐻 = − 393, 5 𝑘𝐽
-------------------------------------------------------------------
0
𝐶(𝑠) + 𝐶𝑂2(𝑔) → 2𝐶𝑂(𝑔) ∆𝐻 = 172, 5 𝑘𝐽
PROBLEMA 2
PROBLEMA 3

PROBLEMA 4

0
𝑆(𝑠) + 𝑂2(𝑔) → 𝑆𝑂2 ∆𝐻 =− 296. 4 𝑘𝐽
𝐻2(𝑔) + 1/2𝑂2(𝑔) −−−− 𝐻2𝑂(𝑙) 𝑑𝐻 =− 285. 9 𝑘𝐽
𝑆𝐻2(𝑔) + 3/2𝑂2(𝑙) −−−− 𝑆𝑂2(𝑔) + 𝐻2𝑂(𝑙) ∆𝐻 =− 561. 8 𝑘𝐽

𝑆𝑂2(𝑔) + 𝐻2𝑂(𝑙) ------ 𝑆𝐻2(𝑔) + 3/2𝑂2(𝑙) ∆𝐻 = 561. 8 𝑘𝐽

----------------------------------------------------------------------------------------
𝑆(𝑠)+ 𝐻2(𝑔)----- 𝑆𝐻2(𝑔) ∆𝐻= -20.5 kJ
PROBLEMA 5
PROBLEMA 6

𝐻2(𝑔) + 1/2𝑂2(𝑔) −−−− 𝐻2𝑂(𝑙) 𝑑𝐻 =− 241. 8 𝑘𝐽

0
2(𝐶(𝑠) + 𝑂2(𝑔) )→ 2𝐶𝑂2 ∆𝐻 = (− 393, 13)2 𝑘𝐽
𝐶2𝐻2(𝑔) + 5/2𝑂2(𝑔) → 2𝐶𝑂2 + 𝐻2𝑂(𝑙) 𝑑𝐻 =− 1300 𝑘𝐽
2𝐶𝑂2 + 𝐻2𝑂(𝑙)→𝐶2𝐻2(𝑔) + 5/2𝑂2(𝑔) 𝑑𝐻 = 1300 𝑘𝐽
----------------------------------------------------------------------------------------
2𝐶(𝑠)+ 𝐻2(𝑔)→𝐶2𝐻2(𝑔) 𝑑𝐻 = 271. 94 𝑘𝐽
PROBLEMA 7
a)
𝑜
𝐶8𝐻18(𝑙) → 8𝐶(𝑠) + 9𝐻2(𝑔) ∆𝐻𝑓 =− (− 264, 0) 𝑘𝐽/𝑚𝑜𝑙
𝑜
8(𝐶(𝑠) + 𝑂2(𝑔) → 𝐶𝑂2(𝑔)) ∆𝐻𝑓 = (− 392, 8)8 𝑘𝐽/𝑚𝑜𝑙
𝑜
9(𝐻2(𝑔) + 1/2𝑂2(𝑔) → 𝐻2𝑂(𝑙)) ∆𝐻𝑓 = (− 285, 8)9 𝑘𝐽/𝑚𝑜𝑙
----------------------------------------------------------------------------
𝑜
𝐶8𝐻18(𝑙) + 25/2𝑂(𝑔) → 8𝐶𝑂2(𝑔) + 9𝐻2𝑂(𝑙) ∆𝐻𝑐 =− 5450, 6 𝑘𝐽/𝑚𝑜𝑙

b)
1 𝑚𝑜𝑙 𝐶8𝐻18 −5458,6𝑘𝐽
2000𝑔 𝐶8𝐻18 𝑥 114,23𝑔
𝑥 1 𝑚𝑜𝑙 𝐶8𝐻18
=− 95432, 023𝑘𝐽

PROBLEMA 8

a)
𝐶(𝑠) + 1/2𝑂2(𝑔) → 𝐶𝑂(𝑔) ∆𝐻𝑓 =− 110, 4𝑘𝐽/𝑚𝑜𝑙

𝐻2(𝑔) + 1/2𝑂2(𝑔) → 𝐻2𝑂(𝑙) ∆𝐻𝑓 =− 285, 5𝑘𝐽/𝑚𝑜𝑙

𝐶𝑂(𝑔) + 1/2𝑂2(𝑔) → 𝐶𝑂2(𝑔) ∆𝐻𝑐 =− 283, 0𝑘𝐽/𝑚𝑜𝑙

𝐶𝑂2(𝑔) + 𝐻2𝑂(𝑙) → 𝐻 − 𝐶𝑂𝑂𝐻 + 1/2𝑂2(𝑔) ∆𝐻𝑐 =− (− 259, 6𝑘𝐽/𝑚𝑜𝑙)

---------------------------------------------------------------------------------------
𝐶(𝑠) + 𝑂2(𝑔) + 𝐻2(𝑔) → 𝐻 − 𝐶𝑂𝑂𝐻 ∆𝐻𝑓 = −419,3kJ/mol
b)
1 𝑚𝑜𝑙 𝐻−𝐶𝑂𝑂𝐻 −419,3𝑘𝐽/𝑚𝑜𝑙
1000g H-COOH x 46,03𝑔
x 1𝑚𝑜𝑙 𝐻−𝐶𝑂𝑂𝐻
= − 9109, 28𝑘𝐽/𝑚𝑜𝑙

PROBLEMA 9
PROBLEMA 10

𝐶6𝐻6 + 15/2𝑂2(𝑔) → 6𝐶𝑂2(𝑠) + 3𝐻2𝑂(𝑙)

(𝑙)

0 0 0
𝑎) ∆𝐻 𝑐
= Σ𝐻 𝑓𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠 − Σ𝐻 𝑓𝑟𝑒𝑎𝑐𝑡𝑖𝑣𝑜𝑠
0
∆𝐻 𝑐
= [6(− 376, 2) + 3(− 273, 3)] − [1(46, 9) + 15/2(0)]
0
∆𝐻 𝑐
=− 3077, 1 − 46, 9 = − 3124, 0 𝑘𝐽/𝑚𝑜𝑙

𝑏) 3𝐶2𝐻2 → 𝐶6𝐻6
(𝑔) (𝑙)
0
∆𝐻 𝑟
= (1(46, 9)) − (3(− 226, 7)) = + 727 𝑘𝐽/𝑚𝑜𝑙