Guerrero Aviles Alonso

QU428D Laboratorio de Fisicoquímica II

Fecha: 14/10/2021

Asumir 100 g de solución Masa etanol

Porcentaje en masa de
Masa etanol (g) Masa agua (g) Moles de etanol Moles de agua
etanol
1 0% 0 100 0 5.55093
2 4% 4 96 0.08682 5.32889
3 8% 8 92 0.17365 5.10686
4 12% 12 88 0.26047 4.88482
5 16% 16 84 0.3473 4.66278
6 20% 20 80 0.43412 4.44074
7 24% 24 76 0.52095 4.21871
8 28% 28 72 0.60777 3.99667
9 32% 32 68 0.6946 3.77463
10 36% 36 64 0.78142 3.5526
11 40% 40 60 0.86824 3.33056
12 44% 44 56 0.95507 3.10852
13 48% 48 52 1.04189 2.88648
14 52% 52 48 1.12872 2.66445
15 56% 56 44 1.21554 2.44241
16 60% 60 40 1.30237 2.22037
17 64% 64 36 1.38919 1.99833
18 68% 68 32 1.47601 1.7763
19 72% 72 28 1.56284 1.55426
20 76% 76 24 1.64966 1.33222
21 80% 80 20 1.73649 1.11019
22 84% 84 16 1.82331 0.88815
23 88% 88 12 1.91014 0.66611
24 92% 92 8 1.99696 0.44407
25 96% 96 4 2.08379 0.22204
26 100% 100 0 2.17061 0

Volumen molar de la mezcla vs fracción molar etanol

65
60

f(x)
55 = 4.996744385205 x² + 35.37909963667 x + 17.9280227
cla (mL/mol)

R²50= 0.999887220909214
45
40
 65
60

f(x)
55 = 4.996744385205 x² + 35.37909963667 x + 17.9280227

Volumen molar de la mezcla (mL/mol)

R²50= 0.999887220909214
45
40
35
30
25
20
15
10
5
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Fracción molar del etanol

X y pendiente Vagua Vetanol

0.1 21.515867 36.37834 17.8780359 54.25637

Volumen molar parcial del etanol (mL/mol)

0.2 25.203668 37.37768 17.72813 55.10581
58
0.3 28.991403 38.37702 17.4783 55.85532
0.4 32.879072 39.37636 17.1285357 56.50489
0.5 36.866675 40.3757 16.67883 57.05453
0.6 40.954212 41.37504 16.1291956 57.50423
0.7 45.141683 42.37438 15.4796255 57.854
0.8 49.429088 43.37372 14.73011 58.10383
0.9 53.816427 44.37306 13.8806754 58.25373
1 58.3037 45.3724 12.9313 58.3037
53

52
0 0.1 0.2 0.3 0
Fracción m
 46.07 Masa agua 18.015
g/mol g/mol
Fracción molar del etanol Masa molar promedio de
Moles totales Fracción molar del agua X1
X2 la mezcla, M (g/mol)
5.55093 1 0 18.015
5.41571 0.98397 0.01603 18.46472
5.28051 0.96711 0.03289 18.93773
5.14529 0.94938 0.05062 19.43514
5.01008 0.93068 0.06932 19.95977
4.87486 0.91095 0.08905 20.5133
4.73966 0.89009 0.10991 21.09853
4.60444 0.868 0.132 21.71826
4.46923 0.84458 0.15542 22.37531
4.33402 0.8197 0.1803 23.07332
4.1988 0.79322 0.20678 23.81621
4.06359 0.76497 0.23503 24.60877
3.92837 0.73478 0.26522 25.45575
3.79317 0.70243 0.29757 26.36333
3.65795 0.6677 0.3323 27.33768
3.52274 0.6303 0.3697 28.38693
3.38752 0.58991 0.41009 29.52007
3.25231 0.54617 0.45383 30.7472
3.1171 0.49862 0.50138 32.08122
2.98188 0.44677 0.55323 33.53587
2.84668 0.38999 0.61001 35.12883
2.71146 0.32755 0.67245 36.88058
2.57625 0.25856 0.74144 38.8161
2.44103 0.18192 0.81808 40.96623
2.30583 0.0963 0.9037 43.3683
2.17061 0 1 46.07

39.9097891256065

Derivando la ecuación para calcular la pendiente

anol
y' = 9.9934x + 35.379

En el punto x = 0.4, y' =

+ 17.92802276655 39.37636
+ 17.92802276655
y - 32.879 = 39.37636(x - 0.4)
y = 39.37636x+17.12845 (recta pendiente)

x y
0 17.12845
1 56.50481

Vparcial agua 17.12845

Vparcial etanol 56.50481

0.8 0.9 1

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fracción molar del etanol, Xetanol
 Densidad de la mezcla Volumen molar de la
(g/mL) mezcla (mL/mol)
0.99823 18.04694
0.99103 18.63185
0.98584 19.20974
0.98145 19.80248
0.97583 20.45415
0.97252 21.09293
0.96787 21.79893
0.96268 22.56021
0.95665 23.38923
0.94986 24.29129
0.94238 25.27241
0.93433 26.33841
0.92593 27.49209
0.90936 28.99108
0.8998 30.38195
0.89113 31.85498
0.88183 33.47592
0.88074 34.91064
0.8671 36.99829
0.85747 39.11025
0.84772 41.43919
0.83777 44.02232
0.82754 46.90541
0.81688 50.14963
0.80566 53.82953
0.78934 58.36522

x = 0.5 → y=36.8666
y' = 40.3757
y - 36.8666 = 40.3757*( x - 0.5)
y = 40.3757x + 16.67875

x
0
1
Masa etanol 46.07 g/mol Masa agua

Etanol Agua Datos picnómetro

Masa
Masa Masa
picnómetro
N° V (mL) V (ml) picnómetro picnómetro
+ líquido
(g) + agua (g)
(g)
1 1 45 13.72 39.06 39
2 2 45 19.01 43.92 43.76
3 2 30 21.44 46.4 46.13
4 3 25 22 45.75 45.36
5 5 30 23.79 48.48 47.98
6 10 25 19.37 44.46 43.5
7 10 18 16.69 41.55 40.37
8 15 15 26.11 49.77 47.94
9 20 6 23.88 48.71 45.22
10 25 3 20.77 45.84 41.49
11 30 2 24.51 49.13 44.53
12 2 30 24.29 41.57 41.37

Picnometro Solucion
Masa (g) Volumen (mL) Masa (g)
1 25.34 25.4035 1 25.28
2 24.91 24.9724 2 24.75
3 24.96 25.0226 3 24.69
4 23.75 23.8095 4 23.36
5 24.69 24.7519 5 24.19
6 25.09 25.1529 6 24.13
7 24.86 24.9223 7 23.68
8 23.66 23.7193 8 21.83
9 24.83 24.8922 9 21.34
10 25.07 25.1328 10 20.72
11 24.62 24.6817 11 20.02
12 17.28 17.3233 12 17.08
 18.015 g/mol

Etanol Agua Etanol Agua

Composicion
N° masa (g) masa (g) del etanol moles moles
(%m/m)

1 0.78934 44.92035 1.73 0.0171 2.4935

2 1.57868 44.92035 3.4 0.0343 2.4935
12 1.57868 29.9469 5.01 0.0343 1.6623
3 1.57868 29.9469 5.01 0.0343 1.6623
4 2.36802 24.95575 8.67 0.0514 1.3853
5 3.9467 29.9469 11.64 0.0857 1.6623
6 7.8934 24.95575 24.03 0.1713 1.3853
7 7.8934 17.96814 30.52 0.1713 0.9974
8 11.8401 14.97345 44.16 0.257 0.8312
9 15.7868 5.98938 72.5 0.3427 0.3325
10 19.7335 2.99469 86.82 0.4283 0.1662
11 23.6802 1.99646 92.22 0.514 0.1108

55
50
Volumen molar de la mezcla (mL/mol)

Densidad (g/mL) 45
f(x) = 4.480641166 x² + 36.03091764 x + 18.0545753
0.9951 40
R² = 0.999961296292847
0.9911 35
0.9867 30
0.9811 25
0.9773 20
0.9593 15
0.9502 10
0.9203 5
0.8573 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.8244
0.8111 Fracción molar del etanol
0.986
 Etanol Agua Mezcla Mezcla

Fracción Fracción Volumen

Masa molar
molar molar molar

0.0068 0.9932 18.2058 18.2954

0.0136 0.9864 18.3965 18.5617
0.0202 0.9798 18.5817 18.8455
0.0202 0.9798 18.5817 18.8322
0.0358 0.9642 19.0194 19.3858
0.049 0.951 19.3897 19.8401
0.11 0.89 21.1011 21.9964
0.1466 0.8534 22.1279 23.2876
0.2362 0.7638 24.6416 26.7756
0.5076 0.4924 32.2557 37.6248
0.7204 0.2796 38.2258 46.368
0.8227 0.1773 41.0958 50.6667

3091764 x + 18.0545753

0.6 0.7 0.8 0.9 1

el etanol