MSDS Wya0116

FICHA DE DATOS DE SEGURIDAD
WB EPOXY ZINC RICH PRIMER

Ficha de datos de seguridad según GB / T 16483-2008 y GB / T 17519-2013
Sección 1. Identificación
Código de producto : WYA0116
GHS Identificador
: WB EPOXY ZINC RICH PRIMER
Uso : Aplicaciones industriales.
Material
: Pintura o material relacionado con la pintura.
Detalles del proveedor de la ficha de datos de seguridad

Sherwin Williams Asia Pacífico
Edificio 11, Shibei One Center, No1401 Jiangchang Road
Distrito Jing'an, Shanghai 200436, China
Proveedor Tele. número : +86 21 61937965
dirección de correo : regulatory.asia@sherwin.com

electrónico de la
persona responsable de
esta SDS
Número de teléfono : 0532-83889090 y 400626 7911 (Productos producidos en China) (Disponible las
de emergencia (con 24 horas)
horario de atención)
4001-204937 (Productos enviados a China) (Disponible las 24 horas
)
Horas de operación Disponible las 24 horas
:
Sección 2. Identificación de los peligros.

Clasificación de la sustancia o mezcla según GB 13690-2009 y GB 30000-2013
Visión general de emergencia
Líquido.
Varios
Líquido y vapores altamente inflamables. Causa irritación ocular grave. Causa irritación leve de la piel.
Puede provocar una reacción alérgica en la piel. Puede causar cáncer.
Muy tóxico para los organismos acuáticos, con efectos nocivos duraderos.
SI está expuesto o preocupado: Obtenga atención médica. Si se produce irritación o erupción cutánea: busque
atención médica. Si la irritación ocular persiste: obtenga atención médica.
Vea la Sección 12 para las precauciones ambientales
Fecha de emisión / Fecha de revisión : 2020/01/07. Fecha de emisión anterior : Versión : 1.06 1/19
2019/11/21.
SHW-A4-AP-GH432-CN
WYA01 WB EPOXY ZINC RICH PRIMER
16
.
Clasificación de la : LÍQUIDOS INFLAMABLES - Categoría 2
sustancia o mezcla CORROSIÓN / IRRITACIÓN DE LA PIEL - Categoría 3
LESIONES OCULARES GRAVES / IRRITACIÓN OCULAR - Categoría 2A
SENSIBILIZACIÓN DE LA PIEL - Categoría 1
CARCINOGENICIDAD - Categoría 1A PELIGRO ACUÁTICO (AGUDO) - Categoría 1
PELIGRO ACUÁTICO (LARGO PLAZO) - Categoría 1
Elementos de etiqueta de GHS
Pictogramas de peligro :
Palabra clave : Peligro

Declaraciones de peligro : Highly flammable liquid and vapor.
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16
d sk Contaminated work clothing should not be
irritation. allowed out of the workplace.
May Response : Collect spillage. IF exposed or concerned: Get
an allerg medical attention. IF ON SKIN
skin (or hair): Take off immediately all contaminated
reaction. clothing. Rinse skin with water or shower. IF ON
May SKIN: Wash with plenty of soap and water.
cancer. Take off contaminated clothing and wash it
Very before reuse. If skin irritation or rash occurs: Get
aquatic medical attention. IF IN EYES: Rinse cautiously
with with water for several minutes. Remove contact
lasting lenses, if present and easy to do. Continue
effect rinsing. If eye irritation persists: Get medical
Precautionary attention.
statements Storage : Store locked up. Store in a well-ventilated place.
: Obtain special Keep cool.
instructions Disposal : Dispose of contents and container in
before use. Do accordance with all local, regional, national and
not handle until international regulations.
all safety
precautions have
been read and Physical and : Highly flammable liquid and vapor.
understood. chemical
Wear protective hazards
gloves. Wear
eye or face Health hazards : Causes serious eye irritation. Causes mild
protection. Wear skin irritation. May cause an allergic skin
protective reaction. May cause cancer.
clothing. Keep
away from heat,
hot surfaces, Symptoms related to the physical, chemical and toxicological characteristics
sparks, open
flames and other
ignition sources.
No smoking.
Use explosion-
proof electrical,
ventilating,
lighting and all
material-
handling
equipment. Use
only non-
sparking tools.
Take
precautionary
measures
against static
discharge. Keep
container tightly
closed. Avoid
release to the
environment.
Avoid breathing
vapor. Wash
hands thoroughly
after handling.
Eye contact : Adverse symptoms may include the
following: pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the
following: irritation
redness
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential : Not available.
immediate effects
Potential delayed effects : Not available.
Long term exposure
immediate effects
Environmental hazards : Very toxic to aquatic life with long lasting effects.
Other hazards which do : Please refer to the SDS for additional information.
not result in
classification
Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Hazardous ingredients
Ingredient name % CAS number EC number Hazard
classificati
on
Zinc ≥50 - ≤75 7440-66-6 231-175-3 H316, H410
Ethanol ≤7.7 64-17-5 200-578-6 H225, H319,
H315, H350,
H401, H412
1-Methoxy-2-propanol ≤5 107-98-2 203-539-1 H226, H316,
H320, H336
Zinc Oxide ≤5 1314-13-2 215-222-5 H316, H320,
H410
Polyethylene Polyamine Adduct ≤2.2 99377-78-3 H319, H315,
H317, H411
2-Propoxyethanol ≤3 2807-30-9 220-548-6 H226, H312,
H303, H319,
H316
Alkylamine <1 61791-26-2 500-153-8 H302, H318,
H315, H410
(Z)-N-9-octadecenylpropane-1,3-diamine <1 7173-62-8 230-528-9 H302, H314,
H372, H410
Isophorone Diamine ≤0.3 2855-13-2 220-666-8 H302 + H312,
H314, H317,
Classification of the substance or mixture according to GB 13690-2009 and GB 30000-
2013
Section 3. Composition/information on ingredients

H412
Triethyoxysilyl Propylamine ≤0.3 919-30-2 213-048-4 H227, H302,
H313, H314,
H317
(Z)-octadec-9-enylamine ≤0.3 112-90-3 204-015-5 H312, H314,
H304, H335,
H373, H410
Sodium Nitrite ≤0.3 7632-00-0 231-555-9 H272, H301,
H320, H400,
H411
See Section 16 for
the full text of the
H statements
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment and hence
require reporting in this section.
Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and
lower eyelids. Check for and remove any contact lenses. Continue to rinse for at
least 10 minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical
attention. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin : Wash with plenty of soap and water. Remove contaminated clothing and shoes.
contact Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. In
the event of any complaints or symptoms, avoid further exposure. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh
: air and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water
to drink. Stop if the exposed person feels sick as vomiting may be dangerous.
Do not induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not enter the
lungs. Get medical attention. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Most important symptoms/effects, acute and

delayed Potential acute health effects
Eye : Causes serious eye irritation.
contact
2013
Inhalation : No known significant effects or critical hazards.
2013
WYA0116 WB EPOXY ZINC RICH
PRIMER
Section 4. First aid measures
Skin contact : Causes mild skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the
following: pain or irritation
watering
redness
Skin : Adverse symptoms may include the
contact following: irritation
redness
: No specific data.
Ingestion
Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be
delayed. The exposed person may need to be kept under medical surveillance
for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If
it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures

Extinguishing media
Suitable : Recommended: alcohol-resistant foam, carbon dioxide, powders.
extinguishing media
Unsuitable : Do not use water jet.
extinguishing media
Specific hazards : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion
arising from the hazard. In a fire or if heated, a pressure increase will occur and the container may
chemical burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air
and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. This
material is very toxic to aquatic life with long lasting effects. Fire water
contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
: Decomposition products may include the following
Hazardous thermal materials: carbon dioxide
decomposition carbon monoxide
products nitrogen oxides
metal
oxide/oxides
2013
Advice for firefighters PRIMER
Section 5. Fire-fighting measures
Special protective : Promptly isolate the scene by removing all persons from the vicinity of the
actions for fire-fighters incident if there is a fire. No action shall be taken involving any personal risk or
without suitable training. Move containers from fire area if this can be done
without risk. Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire- breathing apparatus (SCBA) with a full face-piece operated in positive
fighters pressure mode.
Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non- : No action shall be taken involving any personal risk or without suitable training.
emergency Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
personnel entering. Do not touch or walk through spilled material. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation
is inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
precautions drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities. Collect
spillage.
Methods and materials for containment and cleaning up

Spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with
non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations (see
Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Reference to other sections See Section 7 of the safety data sheet (technical measures).
See Section 8 for information on appropriate personal protective equipment.
:
Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do
not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or
mist. Avoid release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container
or an approved alternative made from a compatible material, kept tightly closed
when not in use. Store and use away from heat, sparks, open flame or any other
ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Take precautionary measures
against
Section 7. Handling and storage
electrostatic discharges. Empty containers retain product residue and can
be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material
occupational is handled, stored and processed. Workers should wash hands and face before
hygiene eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure
limits
Ingredient name Exposure limits
alcohol [Dry] ACGIH TLV (United States, 3/2019).
STEL: 1000 ppm 15 minutes.
1-Methoxy-2-propanol ACGIH TLV (United States,
3/2019). TWA: 50 ppm 8 hours.
TWA: 184 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 369 mg/m³ 15 minutes.
Zinc Oxide GBZ 2.1 (China, 4/2007).
PC-TWA: 3 mg/m³ 8 hours.
PC-STEL: 5 mg/m³ 15 minutes.
Appropriate : Use only with adequate ventilation. Use process enclosures, local exhaust
engineering controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any
lower explosive limits. Use explosion-proof ventilation equipment.
Environmental : Emissions from ventilation or work process equipment should be checked to
exposure controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the
process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection
measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products,
: before eating, smoking and using the lavatory and at the end of the working
period.
Appropriate techniques should be used to remove potentially contaminated
clothing. Contaminated work clothing should not be allowed out of the workplace.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Date of issue/Date of revision : 2020/01/07. Date of previous issue : 2019/11/21. Version : 1.06 7/19
SHW-A4-AP-GH432-CN
Eye/face : Use safety eyewear designed to protect against splash of liquids.
protection Skin
protection
SHW-A4-AP-GH432-CN
Section 8. Exposure controls/personal protection
Hand : Wear suitable gloves tested to EN374.
protection : Short Term Exposure less than 10 minutes Continuous use Nitrile gloves.
Gloves Hazardous ingredients Section 3 For more than 4 hours of protection in the
presence of Ethyl methyl ketone or Methyl ethyl ketone Acetone or Methyl
isobutyl ketone Butyl gloves 0.7mm For more than 4 hours of protection in the
presence of Aromatic solvent use polyvinyl alcohol (PVA) gloves.
Long Term Exposure Spill / For prolonged or repeated handling, use PE /
PE Laminate gloves > 8 hours (breakthrough time) .
There is no one glove material or combination of materials that will give
unlimited resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the
product. The instructions and information provided by the glove
manufacturer on use, storage, maintenance and replacement must be
followed.
Gloves should be replaced regularly and if there is any sign of damage to the
glove material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by
physical/ chemical damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not
be applied once exposure has occurred.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Body : Personnel should wear antistatic clothing made of natural fibers or of
protection high- temperature-resistant synthetic fibers.
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static
electricity, wear anti-static protective clothing. For the greatest protection from
static discharges, clothing should include anti-static overalls, boots and gloves.
Refer to European Standard EN 1149 for further information on material and
design requirements and test methods.
Other skin : Appropriate footwear and any additional skin protection measures should be
protection selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product.
: If workers are exposed to concentrations above the exposure limit, they must
Respiratory use appropriate, certified respirators.
protection
Section 9. Physical and chemical properties

Appearance
Physical : Liquid.
state Color : Various
Odor : Solvent.
Odor : Not available.
threshold pH : Testing not technically possible.
Melting point : Not available.
Boiling point : 77°C (170.6°F)
Flash point Evaporation rate
SHW-A4-AP-GH432-CN
: Closed cup:
16°C (60.8°F)
[Pensky-Martens
Closed Cup]
: 1.6 (butyl
acetate = 1)
SHW-A4-AP-GH432-CN
Section 9. Physical and chemical properties
Lower and upper : Lower: 1.26%
explosive (flammable) Upper: 19%
limits
Vapor pressure : 5.9 kPa (44 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative : 2.92
density : Not available.
Solubility : Not available.
Partition coefficient: n-
octanol/water : Not available.
Auto-ignition
temperature
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
VOC content : 416 g/L
Aerosol product
Heat of combustion : 4.03 kJ/g
Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical : The product is stable.

stability
Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
Conditions to : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut,
avoid weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Do
not allow vapor to accumulate in low or confined areas.
: Avoid high temperature. Avoid static electricity.
Incompatible materials Reactive or incompatible with the following

materials: oxidizing materials
:
Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and protection of
employees.
Section 11. Toxicological information

Acute toxicity
Product/ingredient name Result Species Dose Exposure
alcohol [Dry] LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
1-Methoxy-2-propanol LD50 Dermal Rabbit 13 g/kg -
LD50 Oral Rat 6600 mg/kg -
2-Propoxyethanol LD50 Oral Rat 3089 mg/kg -
Alkylamine LD50 Dermal Rat >10 g/kg -
LD50 Oral Rat 500 mg/kg -
Triethyoxysilyl Propylamine LD50 Dermal Rabbit 4.29 g/kg -
2013

LD50 Oral Rat 1.57 g/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Zinc Skin - Mild irritant Human - 72 hours 300 -
ug I
alcohol [Dry] Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
mg
Eyes - Moderate irritant Rabbit - 100 Ul -
Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 400 mg -
Skin - Moderate irritant Rabbit - 24 hours 20 -
mg
1-Methoxy-2-propanol Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Skin - Mild irritant Rabbit - 500 mg -
Zinc Oxide Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
2-Propoxyethanol Eyes - Severe irritant Rabbit - 24 hours 750 -
ug
Eyes - Severe irritant Rabbit - 100 mg -
Skin - Mild irritant Guinea pig - 500 mg -
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
Alkylamine Eyes - Moderate irritant Rabbit - 100 mg -
Eyes - Severe irritant Rabbit - 24 hours 100 -
Ul
Triethyoxysilyl Propylamine Eyes - Mild irritant Rabbit - 100 mg -
Eyes - Severe irritant Rabbit - 24 hours 750 -
ug
Skin - Severe irritant Rabbit - 24 hours 5 -
mg
sodium nitrite Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Date of issue/Date of : 2020/01/07. Date of previous : Version : 1.06 10/19

revision issue 2019/11/21.
SHW-A4-AP-GH432-CN

Name Category Route of Target organs
exposure
1-Methoxy-2-propanol Category 3 Not Narcotic effects
(Z)-octadec-9-enylamine Category 3 applicable. Respiratory
Not tract irritation
applicable.
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
(Z)-N-9-octadecenylpropane-1,3-diamine Category 1 Not Not determined
(Z)-octadec-9-enylamine Category 2 determined gastrointestinal
Not tract, immune
determined system and
liver
Information on the : Not available.

likely routes of
exposure
Potential acute health
effects
Eye : Causes serious eye irritation.
contact
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes mild skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological

characteristics Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Skin : Adverse symptoms may include the
contact following: irritation
redness
: No specific data.
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
immediate effects
Long term exposure
immediate effects
Potential chronic health effects
SHW-A4-AP-GH432-CN
Not available.
General Once sensitized, a severe allergic reaction may occur when subsequently exposed
: to very low levels.
May cause cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity
:

Mutagenicity No known significant effects or critical
:
hazards. No known significant effects or
Teratogenicity
: critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 47472.18 mg/kg
Dermal 11766.47 mg/kg
Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Zinc Acute EC50 106 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata - Exponential
growth phase
Acute EC50 10000 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute IC50 65 µg/l Marine water Algae - Nitzschia closterium - 4 days
Exponential growth phase
Acute LC50 65 µg/l Fresh water Crustaceans - Ceriodaphnia 48 hours
dubia - Neonate
Acute LC50 68 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 12.21 µg/l Marine water Fish - Periophthalmus waltoni - 96 hours
Adult
Chronic EC10 27.3 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
growth phase
Chronic EC10 59.2 µg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 9 mg/l Fresh water Aquatic plants - Ceratophyllum 3 days
demersum
Chronic NOEC 178 µg/l Marine water Crustaceans - Palaemon 21 days
elegans
Chronic NOEC 2.6 µg/l Fresh water Fish - Cyprinus carpio 4 weeks
alcohol [Dry] Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - 21 days
SHW-A4-AP-GH432-CN
Neonate
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
Zinc Oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours
Acute IC50 46 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
growth phase
Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
SHW-A4-AP-GH432-CN
Section 12. Ecological information

Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Alkylamine Acute LC50 2350 µg/l Fresh water Daphnia - Daphnia pulex 48 hours
Acute LC50 650 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
5-amino-1,3,3-trimethyl- Acute EC50 17.4 mg/l Fresh water Daphnia - Daphnia magna 48 hours
cyclohexanemethanamine
sodium nitrite Acute EC50 159000 µg/l Marine water Algae - Tetraselmis chuii 72 hours
Acute EC50 1600000 µg/l Marine water Algae - Tetraselmis chuii 96 hours
Acute LC50 1100 µg/l Fresh water Crustaceans - Cherax 48 hours
quadricarinatus
Acute LC50 0.16 µg/l Fresh water Fish - Ictalurus punctatus - 96 hours
Fingerling
Chronic NOEC 0.912 mg/l Marine water Fish - Hippocampus 35 days
abdominalis - Juvenile
(Fledgling, Hatchling, Weanling)
Persistence/degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
alcohol [Dry] - - Readily
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Zinc Oxide - 28960 high
(Z)-N-9-octadecenylpropane- - 0.5 low
1,3-diamine
Triethyoxysilyl Propylamine - 3.4 low
Mobility in soil
Soil/water : Not available.
partition
coefficient (KOC)
Other adverse effects : No known significant effects or critical hazards.

Do not allow to enter drains or watercourses.
Section 13. Disposal considerations

Disposal : The generation of waste should be avoided or minimized wherever possible.
methods Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care
should be taken when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product residues. Vapor
from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have
been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
WYA0116
WB EPOXY ZINC RICH PRIMER
Section 13. Disposal considerations
Do not incinerate closed container. Incinerate in a licensed, high-
temperature, hazardous-waste incinerator.
Section 14. Transport information

China ADR IMDG IATA
UN number UN1263 UN1263 UN1263 UN1263
UN proper PAINT. Marine PAINT PAINT. Marine PAINT

shipping pollutant (Zinc, pollutant (Zinc,
name Zinc Oxide) Zinc Oxide)
Transport Hazard 3 3 3 3
Class(es)/Label(s)
Packing group II II II II
Environmental Yes. Yes. Yes. Yes. The
hazards/Marine environmentally
pollutant hazardous
substance mark is
not required.
Additional information
China : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5
kg.
Emergency schedules F-E, S-E
ADR : The environmentally hazardous substance mark is not required when transported
in sizes of ≤5 L or ≤5 kg.
Special provisions 640 (C)
Tunnel code D/E
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5
kg.
Emergency schedules F-E, S-E
IATA : The environmentally hazardous substance mark may appear if required by
other transportation regulations.
Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do
in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL and the IBC Code

Multi-modal shipping descriptions are provided for informational purposes and do not consider container
sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not
indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for
suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the
person offering the product for transport. People loading and unloading dangerous goods must be trained
on all of the risks deriving from the substances and on all actions in case of emergency situations.
Section 15. Regulatory information

National inventory : Australia inventory (AICS): Not determined.
Canada inventory: Not determined.
China inventory (IECSC): Not determined.
Europe inventory: Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory: Not determined.
Mexico inventory: Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
United States inventory (TSCA 8b): Not determined.
Vietnam inventory: Not determined.
List of Goods banned for Importing
None of the components are listed.
Inventory of Hazardous Chemicals
Ingredient name CAS number Status Reference
number
Ethanol 64-17-5 Listed 107 / 2568
Zinc 7440-66-6 Listed 2358
Sodium nitrite 7632-00-0 Listed 2492
Isophoronediamine 2855-13-2 Listed 3
Methanol 67-56-1 Listed 1022
List of Goods banned for Exporting
List of Toxic Chemicals Severely Restricted for Importing & Exporting by China
Inventory of Highly Toxic Chemicals

Catalogue of Hazardous Chemicals of Priority Management
Methanol; Wood alcohol Listed
Section 16. Other information

History
Date of printing : 2020/01/07.
Date of issue/Date : 2020/01/07.
of revision
Date of previous : 2019/11/21.
issue Version : 1.06
2013
PRIMER
Key to : ATE = Acute Toxicity Estimate
abbreviations BCF = Bioconcentration
Factor
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation
Group UN = United
Nations
Manufa : 威士伯工业涂料（广东）有限公司
cturer Valspar industrial coating (Guangdong) Co., Ltd
地址：佛山市顺德区容桂街道高黎工业区宝业路 2 号
No. 2 Baoye Road, Gaoli, Ronggui Street
Shunde District, Foshan City
Guangdong Province
China
威士伯涂
料（上
海）有限
公司
Valspar
coating(S
hanghai)
Co., Ltd 地
址：上海
市嘉定区
嘉新公路
838 号
No. 838
Jiaxin
Road,
Jiading
Dsitrict
Shanghai,
China
威
士
伯
制
漆
(中
国)
有
限
公
司
Val
spa
r
Pai
nts
(Ch
ina)
Co.
,
Ltd.
中国广东省佛山市顺德区
容桂兴华工业区华盛路 3
2013
PRIMER
号 nggui
邮 : FLAMMABLE RIOUS EYE DAMAGE/ EYE
政 Xinghu LIQUIDS - IRRITATION - Category 2A SKIN
编 a Category 2 SENSITIZATION - Category 1
码 Industri SKIN CARCINOGENICI
52
83 al CORROSION/IR TY - Category 1A
05 Estate, RITATION - AQUATIC
3 Shunde Category 3 HAZARD
H District S (ACUTE) -
Foshan, E Category 1
ua
Guangd AQUATIC HAZARD (LONG-TERM) - Category 1
sh
ong Full text of
en : H225 - Highly
Provinc abbreviated H
g flammable liquid
e statements
Ro and vapor. H319 -
528305,
ad Causes serious
China eye irritation.
Ro
H316 - Causes
mild skin
Procedure used to derive irritation.
H317 - May cause
an allergic skin
FLAMMABLE reaction. H350 -
LIQUIDS - Category 2 May cause cancer.
On basis of test data H410 - Very toxic to aquatic life with long lasting effects.
SKIN Precautionary statements : P201 - Obtain special instructions before use.
CORROSION/IRRITA P202 - Do not handle until all safety precautions
TION - Category 3 have been read and understood. P280 - Wear
Calculation method
protective gloves. Wear eye or face protection.
SERIOUS EYE
Wear protective clothing.
DAMAGE/ EYE
P210 - Keep away from heat, hot surfaces, sparks,
IRRITATION -
open flames and other ignition sources. No
Category 2A
smoking.
Calculation method
P241 - Use explosion-proof electrical, ventilating,
SKIN
lighting and all material-handling equipment.
SENSITIZATION -
P242 - Use only non-sparking tools.
Category 1
P243 - Take precautionary
Calculation method
measures against static
CARCINOGENICITY
discharge. P233 - Keep
- Category 1A
container tightly closed.
Calculation method
P273 - Avoid
AQUATIC HAZARD
release to the
(ACUTE) - Category 1
environment.
Calculation method
P261 - Avoid
AQUATIC HAZARD
breathing
(LONG-TERM) -
vapor.
Category 1
P264 - Wash hands thoroughly after handling.
Calculation method
P272 - Contaminated work clothing should not
Classification be allowed out of the workplace. P391 -
according to Collect spillage.
Regulation (EC) No. P308 + P313 - IF exposed or concerned: Get medical
1272/2008 attention.
[CLP/GHS] P303 + P361 + P353 - IF ON SKIN (or hair): Take off
Fu classification immediately all contaminated clothing. Rinse skin
ll s [CLP/GHS] with water or shower.
P302 + P352 + P362 + P364 - IF ON SKIN:
te
Wash with plenty of soap and water. Take off
xt
contaminated clothing and wash it before reuse.
of
2013
PRIMER
P333 ates information that has changed from
P313 previously issued version. Notice to reader
skin
irritation It is recommended that each customer or recipient of this Safety Data Sheet (SDS)
rash study it carefully and
Get consult resources, as necessary or appropriate, to become aware of and
attenti understand the data contained in this SDS and any hazards associated with
P305 the product. This information is provided in good faith and believed to be
P351 accurate as of the effective date herein. However, no warranty, express or
P338 implied, is given. The information presented here applies only to the product
EYES: as shipped. The addition of any material can change the composition, hazards
Rinse and risks of the product. Products shall not be repackaged, modified, or tinted
cautiouslyexcept as specifically instructed by the manufacturer, including but not
with limited to the incorporation of
for severalproducts not specified by the manufacturer, or the use or addition of products
minut in proportions not specified by the manufacturer. Regulatory requirements are
Rem subject to change and may differ between various locations and jurisdictions.
contact The customer/buyer/user is responsible to ensure that his activities comply
lense with all country, federal, state, provincial or local laws. The conditions for use
present of the product are not under the control of the manufacturer; the
easy customer/buyer/user is responsible to determine the conditions necessary for
Cont the safe use of this product. The customer/buyer/user should not use the
rinsin product for any purpose other than the purpose shown in the applicable
P337 section of this SDS without first referring to the supplier and obtaining written
P313 handling instructions. Due to the proliferation of sources for information such
eye as manufacturer-specific SDS, the manufacturer cannot be responsible for
persist SDSs obtained from any other source.
Get
attenti
P405
Store
lock
P403
Store
well
vent
place.
- Ke
P501
Dispose
contents
and
contai
accordance
with
local,
regiona
natio
internation
regu
I
n
d
i
c
2013
PRIMER

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FICHA DE DATOS DE SEGURIDAD

WB EPOXY ZINC RICH PRIMER

Detalles del proveedor de la ficha de datos de seguridad

Proveedor Tele. número : +86 21 61937965

dirección de correo : regulatory.asia@sherwin.com

Sección 2. Identificación de los peligros.

Palabra clave : Peligro

Section 3. Composition/information on ingredients

Section 3. Composition/information on ingredients

Section 4. First aid measures

Most important symptoms/effects, acute and

Indication of immediate medical attention and special treatment needed, if necessary

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Section 6. Accidental release measures

Methods and materials for containment and cleaning up

Section 7. Handling and storage

Conditions for safe storage, including any incompatibilities

Section 8. Exposure controls/personal protection

Section 9. Physical and chemical properties

Section 10. Stability and reactivity

Chemical : The product is stable.

Incompatible materials Reactive or incompatible with the following

Section 11. Toxicological information

Section 11. Toxicological information

Date of issue/Date of : 2020/01/07. Date of previous : Version : 1.06 10/19

Section 11. Toxicological information

Information on the : Not available.

Symptoms related to the physical, chemical and toxicological

Section 11. Toxicological information

Numerical measures of toxicity

Section 12. Ecological information

Section 12. Ecological information

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Section 14. Transport information

UN proper PAINT. Marine PAINT PAINT. Marine PAINT

Transport in bulk according to Annex II of MARPOL and the IBC Code

Section 15. Regulatory information

Inventory of Highly Toxic Chemicals

Section 16. Other information

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