Donde: T=

P= Presión atm P=
T= temperatura k T=
v= volumen molar l/g-mol
R= 0.082054 atm.l/g-molK
a= constantes dependientes de Tc y Pc del gas
b= constantes dependientes de Tc y Pc del gas

a= 17.167305893 R 2TC2.5
a  0.4278
3 b= 0.0221008899 PC

RTC
b  0.0867
PC

Gas Pc Tc
Helio 2.26 5.26 limite inferior
Hidrogeno 12.8 33.3 limite superior
Oxigeno 49.7 154.4

a b m f(a) f(b)
0.5978 0.6489 0.606969103 -0.4402773151 2.0134164470
0.5978 0.606969103 0.6069933384 -0.4402773151 -0.0011606564
0.6069933384 0.606969103 0.6069933235 0.0000007154 -0.0011606564
 TOLERANCIA 0.0000001
100 °C
50 atm
373 K

Ecuación de un gas real

Ecuación de Redlich- Kwong
R 2TC2.5
0.4278
PC  a 
P   (v  b)  RT
RTC  v ( v  b ) T 
0.0867
PC

0.5978
0.6489

-3.5 -3 -2.5 -2 -1.5 -1

f(m) error iter
-0.0011606564 0.04193090 1
0.0000007154 0.00003993 2 CONTINUA
0.0000000000 0.00000002 3 FIN
 Despeje de la ecuacion de redlich kwong

V f(V)
-3 -182.01188 [𝑃+𝑎/(𝑣(𝑣+𝑏) √𝑇)](𝑣−𝑏)−𝑅𝑇=0
-2 -132.16556
-1 -82.640254
-0.06 -66.804557
-0.057 -69.907155
-0.055 -72.336853
0.456 -7.1420877
0.5978 -0.4402773
0.6489 2.01341645
1 19.139262

f(V)
50

0
5 -2 -1.5 -1 -0.5 0 0.5 1 1.5

-50 f(V)

-100

-150

-200
 R 2TC2.5
a  0.4278
PC
Gas Pc Tc
Helio 2.26 5.26
Hidrogeno 12.8 33.3 RTC
b  0.0867
Oxigeno 49.7 154.4 PC

a b
helio a= 0.08087163 0.01655755

hidrogeno a= 1.43992844 0.01850773

oxigeno a= 17.1673059 0.02210089

 R 2TC2.5 R= 0.0821
a  0.4278
PC

RTC
b  0.0867
PC