Calcular el ø ECUACIÓN VIRIAL

Calculamos la Presión de Saturacón

Acetato de Etilo
A
Datos T(°C)= 220 39 Acetado de Etilo C4H8O2 4.13361
T(K)= 493.15
R 83.14472
Tr 0.942565 Tc(K) Pc w
B0 -0.380889 Acetado de Etilo 523.2 38.3 0.363
B1 -0.081506
B -466.22065

P ln (cf) cf(ø) f
0 0 1 0.00000
2.60537 -0.02962 0.97081 2.52932
5.21074 -0.05925 0.94247 4.91098
7.81611 -0.08887 0.91496 7.15144
10.42148 -0.11850 0.88825 9.25693
13.02685 -0.14812 0.86233 11.23340
15.63222 -0.17775 0.83716 13.08660
18.23759 -0.20737 0.81272 14.82204
20.84296 -0.23699 0.78900 16.44501
Psat 23.44833 -0.26662 0.76597 17.96061
26.05400 0.69621 18.13898
28.65900 0.63921 18.31907
31.26400 0.59177 18.50095
33.87000 0.55166 18.68471
36.47500 0.51735 18.87022
39.08100 0.48764 19.05764
41.68600 0.46171 19.24685
44.29100 0.43887 19.43795
2*Psat 46.89700 0.41860 19.63101
de Saturacón

B C Psat
1195.130 212.470 23.4483

Vc(cm3/mol) Zc Vl (ml/mol)
286 0.252 155.50332
EE: Redlich Kwong Soave
T(K)= 493.15

Acetato de Etilo

Tc 523.2
Pc 38.3

w 0.363 sigma= 1
Tr 0.942565 e 0
alfa 1.060824 omega 0.08664
q 5.553022 psi 0.42748

P Pr beta Z0 Z1 I
1 0.026110 0.002400 0.988990 0.000000 0.002424
5 0.130548 0.012000 0.943121 0.000000 0.012643
10 0.261097 0.024000 0.880705 0.000000 0.026886
20 0.522193 0.048000 0.726644 0.000000 0.063967
Psat 24.7228413 0.645505 0.059334 0.621715 0.000000 0.091153
Psat 24.7228413 0.645505 0.059334 0.123341 0.000000 0.392759
25 0.652742 0.060000 0.124477 0.000000 0.393403
30 0.783290 0.072000 0.144805 0.000000 0.403609
35 0.913838 0.083999 0.164797 0.000000 0.411920
40 1.044386 0.095999 0.184458 0.000001 0.419000
45 1.174935 0.107999 0.203823 -0.000002 0.425181
2Psta 49.4456827 1.291010 0.118669 0.203823 0.006100 0.458825
 ln(cf) cf
-0.010968 0.989091
-0.055722 0.945802
-0.113932 0.892318
-0.240905 0.785916
-0.308884 0.734266 VAPOR
-0.308884 0.734266 -2.4233E-08 LIQUIDO
-0.318651 0.727130
-0.476476 0.620968
-0.606799 0.545093
-0.717037 0.488196
-0.811974 0.443981
-0.880755 0.414470
 Fugacidad Vs Presión Colum
nF

1.2

0.8
Coefug

0.6

0.4

0.2

0
0 5 10 15 20 25 30 35 40 45 50

Presión