Grupo Yi Vi Hi Mi ni Yi*ni

̵̵̵̶ CH2- 2700 15.85 0.000033 14 3 8100

̵̵̵̶ C0- 27000 13.4 0.11 28 0 0
̵̵̵̶ COO- 8000 23 0.075 44 0 0
̵̵̵̶ O- 4000 10 0.02 16 0 0
̵̵̵̶ CONH- 12000 24.9 0.75 43 0 0
̵̵̵̶ CHOH- 13000 19.15 0.75 30 0 0
̵̵̵̶ CHCl- 20000 29.35 0.015 48.5 6 120000
Sumatoria 128100

tg 384.684685 k
denisdad 1.4889336 g/cm3
Absorcion 0.00487022 g agua/g polimero

Especificaciones

tg 383 k
D 1.5 g/cm3
A 0.005 g agua/g polimero

Funcion Objetivo
0.00074753

Restricciones
Primera restriccion

3 <= 7
0 <= 7
0 <= 7
0 <= 7
0 <= 7
0 <= 7
6 <= 7

3 >= 0
0 >= 0
0 >= 0
0 >= 0
0 >= 0
0 >= 0
6 >= 0
Segunda restriccion(temperatura de transicin vitrea)

384.684685 >= 298

384.684685 <= 673

Tercera restriccion(densidad)

1.4889336 >= 1
1.4889336 <= 1.5

Caurta restriccion(absorcion de agua)

0.00487022 >= 0
0.00487022 <= 0.18
Hi*ni Mi*ni Vi*ni
0.000099 42 47.55
0 0 0
0 0 0
0 0 0
0 0 0
0 0 0
0.09 291 176.1
0.090099 333 223.65
 Grupo Yi Vi Hi Mi ni Yi*ni
̵̵̵̶ CH2- 2700 15.85 0.000033 14 3 8100
̵̵̵̶ C0- 27000 13.4 0.11 28 0 0
̵̵̵̶ COO- 8000 23 0.075 44 0 0
̵̵̵̶ O- 4000 10 0.02 16 0 0
̵̵̵̶ CONH- 12000 24.9 0.75 43 0 0
̵̵̵̶ CHOH- 13000 19.15 0.75 30 0 0
̵̵̵̶ CHCl- 20000 29.35 0.015 48.5 6 120000
128100
tg 384.684685
d 1.4889336
Ab 0.00487022

Especificaciones

tg 383 k
D 1.5 g/cm3
A 0.005 g agua/g polimero

Funcion Objetivo

0.00074753

Restricciones

primera restriccion

1 <= 7
2 <= 7
3 <= 7
4 <= 7
5 <= 7
6 <= 7
7 <= 7

1 >= 0
2 >= 0
3 >= 0
4 >= 0
5 >= 0
 6 >= 0
7 >= 0

segunda restriccion

1.4889336 >= 1
1.4889336 <= 1.5

Tercera restriccion

384.684685 >= 298

384.684685 <= 673

Cuarta restriccion

0.005 >= 0
0.00487022 <= 0.18
Hi*ni Mi*ni Vi*ni
0.000099 42 47.55
0 0 0
0 0 0
0 0 0
0 0 0
0 0 0
0.09 291 176.1
0.090099 333 223.65
 Grupo Valencia Tc(K) Pc(bar) Vc(cm3/mol) Tb(K)
̶̶ CH3 1 0.0141 -0.0012 65 23.58
̶̶ CH2 2 0.0189 0 56 22.88
̶̶ CH̶ 3 0.0164 0.002 41 21.74
̶̶=C= 4 0.0067 0.0043 27 18.25
̶̶ OH 1 0.0741 0.0112 28 92.88
̶̶ O 2 0.0168 0.0015 18 22.42
̶̶ NH2 1 0.0243 0.0109 38 73.23
̶̶ NH̶ 2 0.0295 0.0077 35 50.17
̶̶ N= 3 0.0169 0.0074 9 11.74
̶̶ S̶ 2 0.0119 0.0049 54 68.78
̶̶ SH 1 0.0031 0.0084 63 63.56
̶̶ F 1 0.0111 -0.0057 27 -0.03
̶̶ Cl 1 0.0105 -0.0049 58 38.13
Sumatoria

Datos
T inf -1.1 C 272.05 K
Tsup 43.3 C 316.45 K

P inf > 1.4 bar

Psup < 14 bar

Cpl < 32.2 cal/molK

Hv > 18400 j/mol

Tb 244.2
Tc 387.8262022148
Pc 46.9774475368

Tbr 0.62966349
h 6.5453853467
G 3.4976499521
Tr inf 0.7014740068
Tr sup 0.8159582777
k 0.4855375706
 Pr inf 0.0625972333
Pr sup 0.2271539227
P inf 2.9406582423 bar
P sup 10.6711114886 bar
Cpl 27.09304 cal/mol k
Svb 83.2194482266
ΔHb^v 20322.1892569 J/mol
n 0.3719153631
ΔH^v 18756.5891818 J/mol

Fun.Objet 1.2931027931

Restriccion duvenie e achenie (1996)

ni Cp(J/molK) M(Kg/kmol) n n*Tc(K) n*Pc(bar) n*Vc(cm3/mol) n*Tb(K)
4 36.8 15.04 0 0 0 0 0
3 30.4 14.03 0 0 0 0 0
2 21 13.02 0 0 0 0 0
1 7.36 12.01 1 0.0067 0.0043 27 18.25
2 44.8 17.01 0 0 0 0 0
1 35 16 0 0 0 0 0
3 58.6 16.03 0 0 0 0 0
2 43.9 15.02 0 0 0 0 0
1 31 14.01 0 0 0 0 0
1 33 32.07 0 0 0 0 0
2 44.8 33.08 0 0 0 0 0
1 17 19 2 0.0222 -0.0114 54 -0.06
1 36 35.45 2 0.021 -0.0098 116 76.26
0.0499 -0.0169 197 94.45
n*ni n*Cp(J/molK)n*M(Kg/kmol)(2-Vj)*ni nj(vj-2) nj(vj-1)+2
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
1 7.36 12.01 -2 4 5
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
0 0 0 0 2 2
2 34 38 2 0 2
2 72 70.9 2 0 2
5 113.36 120.91 2 24 29
1-Buteno 5000 P T
50.6625 -23.35994
4500
107.252513 -5.1757041
4000 291.542558 24.2083453
792.494838 61.4599746
3500 2154.22432 109.476172
3551.71545 138.596982
3000
3900.7963 144.48721
2500 3969.97119 145.607332
4022.6001 146.450006
2000

1500
1,3-Butadieno P T
1000 50.6625 -21.059347
107.252513 -2.9643926
500 291.542558 26.2196425
792.494838 63.1384918
0
-10 102154.22432
30 110.640808
50 70 90 110 130 150 170 190 210 2
3551.71545 139.42927
4284.18662 151.215531
4326.56006 151.85

i-buteno P T
50.6625 -23.992245
107.252513 -5.8801541
291.542558 23.3835201
792.494838 60.4758021
2154.22432 108.274503
3551.71545 137.255683
3900.7963 143.116852
4002.33008 144.74801

MTBE P T
50.6625 35.3163822
107.252513 57.045436
291.542558 92.066351
792.494838 136.287617
2154.22432 192.929405
2766.07878 209.454265
3336.52789 222.534533
3370 223.24801
170 190 210 230 250