MEMORIA DE CLCULO DEL REACTOR DE PIRLISIS

2ClCH2CH2Cl

Reaccin
Temp.
P
K
Conversin
R
Prod. MCV
RA

MCV

F EDC
CEDC

Vol. Reactor

final
P.M.P final
Q prom.
reaccin
vel. Lineal
dimetro

2CH2 = CHCl + 2HCl

530 C
16 atm
0.04503 S-1
0.6
82.05 cm3-atm/gmol-K
413000 Ton/ao
KCA

826.000 Kgmol/h
1376.667 Kgmol/h
382.407 gmol/s
0.000 gmol/cm3
1.000
43.112 m3

Volmen calculado bajo el uso de la Useful In

24.0272695 Kg/m3
18.7061131 Kg/m3
77.044 g/gmol
6376.04256 m3/h
24.3414554 seg.
12 m/s
20 cm.

n tubos

Clculo de el requerimiento de combustible y aire para la combustin

Gas natural es usado como combustible de combustin con la siguiente composicin:

Vol.
CH4 =
83.4 %
C2H6 =
15.8 %
N2 =
0.8 %

Component

% volmen

P.M.

% Peso

fraccin peso

72.89
25.89
1.22

0.7289
0.2589
0.0122

CH4
C2H6
N2

83.4
16
15.8
30
0.8
28
Ecuacin emprica

Astoi =

2.47*CO + 34.34*H2 + 17.265*CH4 + 13.3*C2H2 + 14.81*C2H4 + 16.12*C2H6 + 15.69*C3H8 + 15.44

Hrxn

51424067.7 Btu/h
Eficiencia trmica
0.9
Astoi =
16.76 lb/lb fuel
HHV =
23181.0 Btu/lb
Combustible requerido
2464.85 lb/h
Aire requerido
41304.4 lb/h
Exceso de aire =
Humeda absoluta =
Aire total requerido =

<---- Referente a la cantidad d

<--- Cantidad estequiometric

15 %
0.02 lb H2O/lb aire seco
48450.0069 lb/h

Donde
Astoi = Dry stoichiometric air required for combustion, lb/lb of fuel
CO = weight fraction of Carbon Monoxide Gaseous fuel
H2 = weight fraction of Hydrogen in Gaseous fuel
CH4 = weight fraction of Methane in Gaseous Fuel
C2H2 = weight fraction of acetylene in Gaseous Fuel
C2H4 = weight fraction of ethylene in Gaseous Fuel
C2H6 = weight fraction of ethane in Gaseous Fuel
C3H8 = weight fraction of propane in Gaseous Fuel
O2 = weight fraction of Oxygen in Gaseous fuel
Aire atmosfrico total requerio para combustin en el horno:
Atot =
where
Atot =
Astoi =
HHV =
H=
Aexc =

Astoi*(1000000/HHV of fuel)*(1+ H)*(1 + Aexc)

total atmospheric air, lb/MM Btu

Dry stoichiometric or theoretical air required, lb/lb fuel
Higher Heating Value, Btu/lb
absolute
humidityfrom
of atmospheric
air expressed
a fraction
- lb of wate
(to
be calculated
% Relative Humidity
(RH) as
& Dry
Bulb Temperature
100% RH, H = 0.0507 from Humid Air chart)
excess air expressed as a fraction (10% excess air will be entered as 0.1

R DE PIRLISIS

2CH2 = CHCl + 2HCl

ajo el uso de la Useful Integral

ire para la combustin

a siguiente composicin:

Cte.
combustin
HHV,
Btu/lb
23876
22320
16.12*C2H6 + 15.69*C3H8 + 15.44*C4H10 - 4.32*O2

Referente a la cantidad de calor transferido con respecto al generado

Cantidad estequiometrica

Se obtiene de carta psicromtrica

d) as
a fraction
- lb of waterusing
vaporpsychrometric
per 1 lb of drychart,
air
& Dry
Bulb Temperature
example: at 105F &

air will be entered as 0.1, 15% = 0.15 etc.)