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ELV NO IDEAL

SISTEMA CLOROFORMO (1) - METANOL (2)


COEFICIENTE ACTIVIDAD GAMMA POR
A) ECUACION DE VAN LAAR
B) ECUACION DE MARGULES
Prof. Eva Lpez Merida
Laboratorio de Termodinmica Qumica 1-

METANOL (2)
D GAMMA POR
AN LAAR
ARGULES
Qumica 1- ESIQIE

INTRODUCE EN LA TABLA VERDE LOS DATOS EXPERIMENTALES


TEMPERATURA, INDICE DE REFRACCION DE LIQUIDO, INDICE DE REFRACCION DE CONDENSADOS
a=
12.922
b=
-28.704
c=
15.511
TEMP
fraccion mol
Indice de
Indice de
fraccion mol
EBULL
CLOROFORMO
Refraccion
Refraccion
CLOROFORMO
T(C)

X1

n(liquido)

n(condensado)

Y1 (exp)

61
60
59
58
55
53
48
48
46
46
45

0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

1.324
1.3276
1.3286
1.331
1.3356
1.3845
1.3982
1.4083
1.4176
1.4311
1.4407

1.3255
1.3278
1.3314
1.3369
1.3382
1.4004
1.4146
1.4155
1.4171
1.4183
1.4364

0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000

N DE CONDENSADOS

CORRELACION DE DATOS PARA EL CLCULO DE FRACCION MOL DE FASE VAPOR


CORRELACION CUADRATICA - MINIMOS CUADRADOS

39.587

28.697

20.824

15.127

10.821

7.712

5.500

3.073
3.106
3.116
3.138
3.182
3.674
3.822
3.934
4.038
4.194
4.308

2.321
2.340
2.345
2.358
2.382
2.654
2.733
2.793
2.849
2.931
2.990

1.753
1.763
1.765
1.772
1.784
1.917
1.955
1.983
2.010
2.048
2.076

1.324
1.328
1.329
1.331
1.336
1.385
1.398
1.408
1.418
1.431
1.441

0.000
0.176
0.353
0.531
0.714
0.958
1.173
1.388
1.608
1.843
2.076

0.000
0.133
0.266
0.399
0.534
0.692
0.839
0.986
1.134
1.288
1.441

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

Curva de Calibracin
Fraccin mol versus Indice de refraccin
1.00
y = 12.922x2 - 28.704x + 15.511
R = 0.9302

0.90
fraccin mol (cloroformo)

0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
1.3

1.32

1.34

1.36

1.38

1.4

1.42

indice de refraccin /(liq)

1.44

1.46

1.3

1.32

1.34

1.36

1.38

1.4

1.42

indice de refraccin /(liq)

1.44

1.46

DE FASE VAPOR

39.587
28.697
20.824

28.697
20.824
15.127

20.824
15.127
11

10.821
7.712
5.500

74210.2743 -204416.577
-204416.577 563124.021
140623.981
-387421

140623.981
-387421
266561.973

12.922
-28.704
15.511

TEMPERATURA DE EBULLICION (PUROS)=


Constantes de
A=
P(mmHg)
Antoine
T(C)
Log base 10

53.8671
6.9371

58.0042
8.0724

1171.2
227

1574.99
238.87

B=
C=

Cloroformo

Metanol

X2

X1

n(liq)

n(cond)

Y1

T(C)

T(C)

Psat(1)

Psat(2)

1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00

0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

1.324
1.3276
1.3286
1.331
1.3356
1.3845
1.3982
1.4083
1.4176
1.4311
1.4407

1.3255
1.3278
1.3314
1.3369
1.3382
1.4004
1.4146
1.4155
1.4171
1.4183
1.4364

0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000

61
60
59
58
55
53
48
48
46
46
45

61.0000
60.00
59.00
58.00
55.00
53.00
48.00
48.00
46.00
46.00
45.0000

742.1
718.2
695.0
672.4
608.0
567.9
476.6
476.6
443.6
443.6
427.8

660.9
634.7
609.4
584.9
516.3
474.5
382.1
382.1
349.6
349.6
334.3

Resultados Experimentales
60
58
56

Temperatura C

54
52
50
48
46
44
42
40
0.0

0.1

0.2

0.3

0.4

0.5
X,Y

0.6

Parametros A(12), A(21)


A12=
A21=

0.08820
1.35904

Determinacion del Parmetro A12 por mi


2.5333
3.0250
3.8500

gamma(1)

gamma(2)

Ln(gamma1)

Ln(gamma2)

1.464
0.842
0.672
0.576
1.350
1.563
1.352
1.292
1.163

0.840
0.960
1.098
1.436
0.850
0.903
1.168
1.808
3.457

0.38107
-0.17187
-0.39690
-0.55157
0.30010
0.44669
0.30176
0.25633
0.15062

-0.17433
-0.04095
0.09307
0.36195
-0.16227
-0.10228
0.15493
0.59232
1.24041

X1^4

X1^3

0.0001
0.0016
0.0081
0.0256
0.0625
0.1296
0.2401
0.4096
0.6561
1.0000

X1^2

0.001
0.008
0.027
0.064
0.125
0.216
0.343
0.512
0.729
1.000

0.01
0.04
0.09
0.16
0.25
0.36
0.49
0.64
0.81
1.00

Resultados Experimentales

perimentales
1.0

0.9
fraccin mol cloroformo Y1

0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.6

0.7

0.8

0.9

1.0

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

fraccin mol cloroformo X1

0.8

0.9

1.0

del Parmetro A12 por minimos cuadrados


5.5000
0.5427
X1

X1^2*LnG1

0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

0.0038
-0.0069
-0.0357
-0.0883
0.0750
0.1608
0.1479
0.1640
0.1220
0.0000

0.6339
X1*LnG1

0.0381
-0.0344
-0.1191
-0.2206
0.1501
0.2680
0.2112
0.2051
0.1356
0.0000

0.7162
LnG1

0.3811
-0.1719
-0.3969
-0.5516
0.3001
0.4467
0.3018
0.2563
0.1506
0.0000

2.533
3.025
3.850

3.025
3.850
5.500

18.939
-20.833
4.167

-20.833
24.129
-5.250

Determinacion de A12
Dilucin Infinita
3.0

y = 1.3009x2 - 0.8412x + 0.0882


R = 0.1706

Ln(gamma 1)

2.5
2.0
1.5
1.0
0.5
0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

fraccin mol X1
0.9

1.0

0.7

0.8

0.9

1.0

Determinacion del Parmetro A21 por minimos cuadrados


2.5333
3.0250
3.8500
5.5000
X2^4

3.850
5.500
10.000

X2^3

1.0000
0.6561
0.4096
0.2401
0.1296
0.0625
0.0256
0.0081
0.0016
0.0001

0.5427
0.6339
0.7162

4.167 0.05559022
-5.250 0.22978757
1.383 -0.07616304

X2^2

1.00
0.73
0.51
0.34
0.22
0.13
0.06
0.03
0.01
0.00

X2

1.00
0.81
0.64
0.49
0.36
0.25
0.16
0.09
0.04
0.01

Determinacin de A21
Dilucin Infinita
3
y = 3.307x2 - 4.5101x + 1.4259
R = 0.7115

2.5
Ln(gamma 2)

2
1.5
1
0.5
0
-0.5
0.0

0.1

0.2

0.3

0.4

0.5

0.6

fraccin mol X2

0.7

0.8

0.9

1.0

1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10

A21 por minimos cuadrados


0.0016
X2^2*LnG2

0.2596
X2*LnG2

1.9629
LnG2

0
0
0
-0.1412059 -0.15689545 -0.17432828
-0.02621032 -0.0327629 -0.04095363
0.04560297 0.06514709 0.09306728
0.13030302 0.21717171 0.36195285
-0.0405667 -0.0811334 -0.1622668
-0.01636433 -0.04091082 -0.10227706
0.01394343 0.04647808 0.15492695
0.02369276 0.11846379 0.59231894
0.0124041 0.12404101 1.24041007

2.533
3.025
3.850

3.025
3.850
5.500

3.850
5.500
10.000

18.939
-20.833
4.167

-20.833
24.129
-5.250

4.167
-5.250
1.383

0.0016
0.2596
1.9629

2.800513
-4.074465
1.359044

Mtodo de Newton-Raphson para ELV con ecuacin de van Laar con treinta iteracione
MetanolCloroformo
A= 8.0724 6.9371
B=
1575 1171.2
C= 238.87
227

T(m)
58.0
57.6
57.2
56.8
56.3
55.9
55.5
55.1
54.7
54.3
53.9

T(m)
58.0
57.5
57.0
56.5
56.0
55.5
55.1
54.6
54.2
53.8
53.9

T(m)
58.0
57.5
56.9
56.4
55.8
55.3
54.8
54.3
53.9
53.5

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100

Van Laar
A12=
0.0882
A21= 1.359044

Teb1=
Teb2=
P=

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
663
654
645
636
628
619
610
602
593
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
661
650
640
629
619
610
600
592
584
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20

672
660
648
637
625
614
604
594
585
578

53.9 Cloroformo
58.0 Metanol
585 mmHg

Psat(2)
585
575
565
556
546
537
528
519
510
501
492

Psat(2)
585
573
561
550
539
528
518
508
499
492
492

Psat(2)
585
572
559
546
534
523
512
501
492
485

Pcalc
585.0
590.0
595.0
599.8
604.6
609.0
612.9
615.9
616.9
613.3
585.0

Pcalc
585.0
587.9
590.9
594.1
597.2
600.2
603.0
605.2
606.1
604.0
585.0

Pcalc
585.0
586.7
588.5
590.5
592.5
594.6
596.5
598.1
598.9
597.6

8.0724
1574.99
238.87

F(T)
0.00
4.99
9.96
14.84
19.56
23.98
27.89
30.86
31.91
28.35
0.00

F(T)
0.00
2.90
5.93
9.05
12.17
15.21
17.98
20.18
21.13
18.98
0.00

F(T)
0.00
1.68
3.53
5.50
7.54
9.59
11.52
13.12
13.92
12.64

F(T)
55.24
56.63
57.96
59.25
60.47
61.62
62.67
63.57
64.22
64.32
61.99

F(T)
55.24
56.37
57.46
58.51
59.52
60.47
61.36
62.14
62.76
63.03
61.99

F(T)
55.24
56.22
57.16
58.06
58.93
59.75
60.51
61.20
61.79
62.17

53.9

T(m)
58.0
57.4
56.8
56.3
55.7
55.1
54.6
54.1
53.6
53.3
53.9

T(m)
58.0
57.4
56.8
56.2
55.6
55.0
54.5
53.9
53.5
53.2
53.9

T(m)
58.0
57.4
56.8
56.2
55.6
55.0
54.4
53.9
53.4
53.1
53.9

T(m)
58.0
57.4

1.000

0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100

1.000
0.900

1.00

3.89

585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
660
647
634
622
611
600
589
580
574
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
646
633
621
609
597
587
577
572
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
646
633
620
607
596
585
575
570
585

gamma(1) gamma(2) Psat(1)


1.09
1.09

1.00
1.00

672
659

492

Psat(2)
585
571
558
544
532
519
508
497
487
481
492

Psat(2)
585
571
557
543
530
517
505
494
484
478
492

Psat(2)
585
570
556
542
529
516
503
492
482
477
492

Psat(2)
585
570

585.0

Pcalc
585.0
586.0
587.1
588.3
589.7
591.0
592.4
593.5
594.1
593.4
585.0

Pcalc
585.0
585.6
586.2
587.0
587.9
588.8
589.7
590.5
591.0
590.6
585.0

Pcalc
585.0
585.3
585.7
586.2
586.8
587.4
588.0
588.5
588.9
588.7
585.0

Pcalc
585.0
585.2

0.00

F(T)
0.00
0.97
2.09
3.33
4.66
6.03
7.36
8.50
9.13
8.39
0.00

F(T)
0.00
0.56
1.24
2.02
2.87
3.78
4.69
5.49
5.97
5.56
0.00

F(T)
0.00
0.33
0.73
1.22
1.77
2.37
2.98
3.54
3.90
3.68
0.00

F(T)
0.00
0.19

61.99

F(T)
55.24
56.13
56.98
57.79
58.56
59.28
59.96
60.59
61.15
61.59
61.99

F(T)
55.24
56.08
56.87
57.62
58.33
58.99
59.61
60.19
60.72
61.21
61.99

F(T)
55.24
56.05
56.81
57.52
58.19
58.81
59.39
59.94
60.45
60.95
61.99

F(T)
55.24
56.03

56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.3
53.0
53.9

10

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2

0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200

1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

645
632
619
607
595
584
574
569
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
632
619
606
594
583
573
568
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
632
618
606
594
582
573
568
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06

672
659
645
632
618
605
593
582
572

556
542
528
515
502
491
481
475
492

Psat(2)
585
570
556
541
528
514
502
490
480
475
492

Psat(2)
585
570
556
541
527
514
501
489
480
474
492

Psat(2)
585
570
556
541
527
514
501
489
479

585.4
585.7
586.1
586.5
586.9
587.3
587.5
587.4
585.0

Pcalc
585.0
585.1
585.3
585.4
585.7
585.9
586.2
586.5
586.7
586.6
585.0

Pcalc
585.0
585.1
585.2
585.3
585.4
585.6
585.8
585.9
586.1
586.1
585.0

Pcalc
585.0
585.0
585.1
585.2
585.3
585.4
585.5
585.6
585.7

0.44
0.74
1.09
1.48
1.89
2.28
2.55
2.43
0.00

F(T)
0.00
0.11
0.26
0.45
0.67
0.93
1.20
1.47
1.66
1.60
0.00

F(T)
0.00
0.06
0.15
0.27
0.41
0.58
0.76
0.94
1.08
1.06
0.00

F(T)
0.00
0.04
0.09
0.16
0.25
0.36
0.48
0.61
0.70

56.77
57.46
58.10
58.70
59.25
59.77
60.27
60.79
61.99

F(T)
55.24
56.02
56.75
57.42
58.05
58.62
59.16
59.66
60.15
60.67
61.99

F(T)
55.24
56.02
56.74
57.40
58.01
58.58
59.10
59.59
60.07
60.60
61.99

F(T)
55.24
56.01
56.73
57.39
57.99
58.55
59.07
59.55
60.02

53.0
53.9

11

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
53.0
53.9

12

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

13

T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

14

T(m)
58.0

0.900
1.000

0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000

1.000

1.04
1.00

1.20
3.89

567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
582
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
582
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
582
572
567
585

gamma(1) gamma(2) Psat(1)


1.09

1.00

672

474
492

Psat(2)
585
570
556
541
527
514
501
489
479
474
492

Psat(2)
585
570
555
541
527
513
501
489
479
473
492

Psat(2)
585
570
555
541
527
513
500
489
479
473
492

Psat(2)
585

585.7
585.0

Pcalc
585.0
585.0
585.1
585.1
585.2
585.2
585.3
585.4
585.5
585.5
585.0

Pcalc
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.3
585.3
585.3
585.0

Pcalc
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.2
585.2
585.0

Pcalc
585.0

0.70
0.00

F(T)
0.00
0.02
0.05
0.10
0.16
0.23
0.31
0.39
0.46
0.46
0.00

F(T)
0.00
0.01
0.03
0.06
0.10
0.14
0.19
0.25
0.30
0.30
0.00

F(T)
0.00
0.01
0.02
0.04
0.06
0.09
0.12
0.16
0.19
0.20
0.00

F(T)
0.00

60.55
61.99

F(T)
55.24
56.01
56.73
57.38
57.98
58.53
59.04
59.52
59.99
60.52
61.99

F(T)
55.24
56.01
56.72
57.38
57.97
58.52
59.03
59.50
59.97
60.50
61.99

F(T)
55.24
56.01
56.72
57.37
57.97
58.52
59.02
59.49
59.95
60.49
61.99

F(T)
55.24

57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

15

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

16

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

17

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7

0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300

1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02

672
659
645
631
618
605
593
581

570
555
541
527
513
500
489
479
473
492

Psat(2)
585
570
555
541
527
513
500
489
479
473
492

Psat(2)
585
570
555
541
527
513
500
489
479
473
492

Psat(2)
585
570
555
541
527
513
500
489

585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.1
585.1
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

0.00
0.01
0.02
0.04
0.06
0.08
0.10
0.13
0.13
0.00

F(T)
0.00
0.00
0.01
0.01
0.02
0.03
0.05
0.07
0.08
0.09
0.00

F(T)
0.00
0.00
0.00
0.01
0.01
0.02
0.03
0.04
0.05
0.06
0.00

F(T)
0.00
0.00
0.00
0.00
0.01
0.01
0.02
0.03

56.01
56.72
57.37
57.97
58.51
59.01
59.48
59.94
60.48
61.99

F(T)
55.24
56.01
56.72
57.37
57.97
58.51
59.01
59.48
59.94
60.47
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.01
59.47
59.94
60.47
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.01
59.47

53.2
52.9
53.9

18

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

19

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

20

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

21

T(m)

0.800
0.900
1.000

0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

1.06
1.04
1.00

1.06
1.20
3.89

572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)

479
473
492

Psat(2)
585
570
555
541
527
513
500
489
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)

585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc

0.03
0.04
0.00

F(T)
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.02
0.02
0.02
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.02
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.00

F(T)

59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)

58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

22

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

23

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

24

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600

1.000
0.900
0.800
0.700
0.600
0.500
0.400

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08

1.00
1.00
1.00
1.00
1.00
1.01
1.01

672
659
645
631
618
605
593

585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500

585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0

0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00

55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00

53.7
53.2
52.9
53.9

25

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

26

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

27

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

28

T(m)

0.700
0.800
0.900
1.000

0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

1.07
1.06
1.04
1.00

1.02
1.06
1.20
3.89

581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)

488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)

585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc

0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)

59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

F(T)

58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

29

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

30

T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

gamma(1) gamma(2) Psat(1)


1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00

1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89

672
659
645
631
618
605
593
581
572
567
585

585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

Psat(2)
585
570
555
541
527
513
500
488
479
473
492

585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99

ar con treinta iteraciones


H

T(m+1)
58.0
57.5
57.0
56.5
56.0
55.5
55.1
54.6
54.2
53.8
53.9

T(m+1)
58.0
57.5
56.9
56.4
55.8
55.3
54.8
54.3
53.9
53.5
53.9

T(m+1)
58.0
57.4
56.8
56.3
55.7
55.1
54.6
54.1
53.6
53.3

Y1 teorica

Y1 (EXP)

T(C) EXP

0.000
0.124
0.244
0.360
0.472
0.580
0.683
0.780
0.870
0.945
1.000

0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000

61
60
59
58
55
53
48
48
46
46
45

Y1
0.000
0.123
0.242
0.357
0.467
0.572
0.673
0.768
0.855
0.931
1.000

Y1
0.000
0.123
0.241
0.355
0.464
0.567
0.666
0.759
0.846
0.922

53.9

T(m+1)
58.0
57.4
56.8
56.2
55.6
55.0
54.5
53.9
53.5
53.2
53.9

T(m+1)
58.0
57.4
56.8
56.2
55.6
55.0
54.4
53.9
53.4
53.1
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9

T(m+1)
58.0
57.4

1.000

Y1
0.000
0.123
0.241
0.354
0.462
0.564
0.662
0.754
0.839
0.915
1.000

Y1
0.000
0.123
0.241
0.353
0.460
0.562
0.659
0.750
0.835
0.911
1.000

Y1
0.000
0.123
0.240
0.353
0.460
0.561
0.657
0.748
0.832
0.908
1.000

Y1
0.000
0.123

56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.3
53.0
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
53.0
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2

0.240
0.352
0.459
0.560
0.656
0.746
0.830
0.906
1.000

Y1
0.000
0.123
0.240
0.352
0.459
0.560
0.655
0.745
0.829
0.905
1.000

Y1
0.000
0.123
0.240
0.352
0.459
0.560
0.655
0.745
0.828
0.904
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.655
0.744
0.828

53.0
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0

0.904
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.655
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000

57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7

0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744

53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)

0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1

58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3

0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654

53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)

0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1

58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000

Mtodo de Newton-Raphson para ELV con ecuacin de Margules con treinta iteracion
Metanol Cloroformo
A= 8.0724 6.9371
B=
1575 1171.2
C= 238.87
227

T(m)
58.0
57.6
57.2
56.8
56.3
55.9
55.5
55.1
54.7
54.3
53.9

T(m)
58.0
57.3
56.4
55.5
54.8
54.2
53.7
53.4
53.1
53.1
53.9

T(m)
58.0
57.2
55.9
54.7
53.6
52.9
52.4
52.1
52.0
52.2

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100

Margules
A12=
0.0882
A21= 1.359044

Teb1=
Teb2=
P=

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
663
654
645
636
628
619
610
602
593
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
657
638
619
603
591
582
575
570
569
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45

672
654
628
602
581
566
556
550
548
553

53.9 Cloroformo
58.0 Metanol
585 mmHg

Psat(2)
585
575
565
556
546
537
528
519
510
501
492

Psat(2)
585
569
548
528
511
498
489
482
476
476
492

Psat(2)
585
565
537
510
488
472
462
457
454
459

Pcalc
585.0
600.3
631.9
668.3
698.0
715.2
719.4
713.8
699.7
669.4
585.0

Pcalc
585.0
594.0
613.6
637.3
657.5
669.6
672.9
669.5
660.5
640.9
585.0

Pcalc
585.0
590.2
602.2
617.3
630.6
638.8
641.3
639.3
633.8
621.5

8.0724
1574.99
238.87

F(T)
0.00
15.35
46.93
83.27
113.05
130.18
134.44
128.78
114.74
84.41
0.00

F(T)
0.00
8.99
28.59
52.33
72.53
84.56
87.91
84.49
75.50
55.91
0.00

F(T)
0.00
5.24
17.21
32.33
45.60
53.76
56.26
54.32
48.77
36.52

F(T)
55.24
57.85
62.22
66.97
70.80
73.05
73.75
73.30
71.99
69.28
61.99

F(T)
55.24
57.06
59.91
63.00
65.54
67.09
67.64
67.46
66.80
65.47
61.99

F(T)
55.24
56.60
58.49
60.47
62.11
63.14
63.57
63.56
63.33
62.91

53.9

T(m)
58.0
57.1
55.7
54.2
52.9
52.0
51.5
51.2
51.2
51.6
53.9

T(m)
58.0
57.0
55.5
53.8
52.4
51.5
50.9
50.7
50.7
51.2
53.9

T(m)
58.0
57.0
55.4
53.6
52.1
51.1
50.6
50.3
50.4
51.0
53.9

T(m)
58.0
57.0

1.000

0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100

1.000
0.900

1.00

3.89

585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
652
622
591
566
549
539
534
534
542
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
651
618
584
557
539
529
524
524
534
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
650
616
580
551
532
522
517
518
530
585

gamma(1) gamma(2) Psat(1)


1.09
1.32

1.00
0.99

672
650

492

Psat(2)
585
563
531
498
473
455
445
440
439
447
492

Psat(2)
585
562
527
491
463
445
434
430
430
440
492

Psat(2)
585
561
524
487
457
438
427
423
424
435
492

Psat(2)
585
561

585.0

Pcalc
585.0
588.0
595.3
604.7
613.2
618.6
620.4
619.4
616.1
608.6
585.0

Pcalc
585.0
586.8
591.1
596.9
602.3
605.8
607.0
606.5
604.6
600.2
585.0

Pcalc
585.0
586.0
588.6
592.2
595.5
597.7
598.6
598.4
597.3
594.7
585.0

Pcalc
585.0
585.6

0.00

F(T)
0.00
3.05
10.29
19.73
28.25
33.63
35.42
34.37
31.07
23.61
0.00

F(T)
0.00
1.77
6.12
11.95
17.32
20.79
22.04
21.51
19.60
15.16
0.00

F(T)
0.00
1.02
3.63
7.20
10.54
12.75
13.60
13.36
12.28
9.69
0.00

F(T)
0.00
0.59

61.99

F(T)
55.24
56.33
57.62
58.90
59.92
60.60
60.93
61.03
61.06
61.23
61.99

F(T)
55.24
56.17
57.11
57.93
58.56
58.99
59.25
59.41
59.60
60.13
61.99

F(T)
55.24
56.08
56.80
57.34
57.72
57.99
58.19
58.38
58.67
59.43
61.99

F(T)
55.24
56.03

55.3
53.5
52.0
50.9
50.3
50.1
50.2
50.8
53.9

T(m)
58.0
57.0
55.3
53.4
51.9
50.8
50.2
49.9
50.0
50.7
53.9

T(m)
58.0
57.0
55.2
53.4
51.8
50.7
50.1
49.9
49.9
50.7
53.9

10

T(m)
58.0
57.0
55.2
53.3
51.7
50.6
50.0
49.8
49.9

0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200

1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

614
577
548
528
518
513
514
527
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
650
613
576
546
526
515
511
512
525
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
613
575
544
524
513
509
511
524
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72

672
649
613
575
544
523
512
508
510

523
484
454
434
423
419
420
432
492

Psat(2)
585
560
522
483
452
431
420
416
417
430
492

Psat(2)
585
560
522
482
450
430
419
414
416
429
492

Psat(2)
585
560
521
481
450
429
418
413
415

587.1
589.3
591.4
592.8
593.3
593.3
592.7
591.2
585.0

Pcalc
585.0
585.3
586.3
587.6
588.9
589.7
590.1
590.1
589.8
588.9
585.0

Pcalc
585.0
585.2
585.8
586.6
587.3
587.9
588.1
588.1
588.0
587.5
585.0

Pcalc
585.0
585.1
585.4
585.9
586.4
586.7
586.9
586.9
586.8

2.15
4.32
6.39
7.78
8.35
8.25
7.66
6.17
0.00

F(T)
0.00
0.34
1.27
2.59
3.86
4.73
5.11
5.08
4.76
3.92
0.00

F(T)
0.00
0.20
0.75
1.55
2.33
2.87
3.12
3.12
2.96
2.49
0.00

F(T)
0.00
0.12
0.44
0.93
1.40
1.74
1.90
1.92
1.83

56.62
56.98
57.20
57.37
57.54
57.75
58.09
58.97
61.99

F(T)
55.24
55.99
56.51
56.77
56.89
57.00
57.14
57.35
57.73
58.68
61.99

F(T)
55.24
55.98
56.44
56.64
56.70
56.77
56.89
57.11
57.50
58.50
61.99

F(T)
55.24
55.97
56.41
56.56
56.59
56.63
56.74
56.96
57.36

50.6
53.9

11

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.8
49.9
50.6
53.9

12

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

13

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

14

T(m)
58.0

0.900
1.000

0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000

1.000

1.02
1.00

2.45
3.89

523
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
613
574
543
523
512
507
509
522
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
509
522
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
522
585

gamma(1) gamma(2) Psat(1)


1.09

1.00

672

428
492

Psat(2)
585
560
521
481
449
428
417
413
414
428
492

Psat(2)
585
560
521
481
449
428
417
413
414
427
492

Psat(2)
585
560
521
481
449
428
417
412
414
427
492

Psat(2)
585

586.6
585.0

Pcalc
585.0
585.1
585.3
585.6
585.8
586.1
586.2
586.2
586.1
586.0
585.0

Pcalc
585.0
585.0
585.2
585.3
585.5
585.6
585.7
585.7
585.7
585.6
585.0

Pcalc
585.0
585.0
585.1
585.2
585.3
585.4
585.4
585.4
585.4
585.4
585.0

Pcalc
585.0

1.58
0.00

F(T)
0.00
0.07
0.26
0.55
0.85
1.05
1.16
1.18
1.14
1.00
0.00

F(T)
0.00
0.04
0.15
0.33
0.51
0.64
0.70
0.72
0.70
0.63
0.00

F(T)
0.00
0.02
0.09
0.20
0.31
0.39
0.43
0.44
0.44
0.40
0.00

F(T)
0.00

58.38
61.99

F(T)
55.24
55.96
56.38
56.52
56.52
56.54
56.65
56.87
57.27
58.31
61.99

F(T)
55.24
55.96
56.37
56.49
56.48
56.49
56.60
56.81
57.22
58.26
61.99

F(T)
55.24
55.96
56.36
56.47
56.45
56.46
56.56
56.78
57.19
58.23
61.99

F(T)
55.24

56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

15

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

16

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

17

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7

0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300

1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

649
612
574
543
522
511
507
508
522
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
522
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34

672
649
612
574
543
522
511
507

560
521
481
449
428
416
412
414
427
492

Psat(2)
585
560
521
481
448
428
416
412
414
427
492

Psat(2)
585
560
521
481
448
427
416
412
414
427
492

Psat(2)
585
560
521
481
448
427
416
412

585.0
585.1
585.1
585.2
585.2
585.3
585.3
585.3
585.3
585.0

Pcalc
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.2
585.2
585.2
585.0

Pcalc
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.1
585.1
585.1
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.1

0.01
0.05
0.12
0.18
0.23
0.26
0.27
0.27
0.25
0.00

F(T)
0.00
0.01
0.03
0.07
0.11
0.14
0.16
0.17
0.17
0.16
0.00

F(T)
0.00
0.00
0.02
0.04
0.07
0.09
0.10
0.10
0.10
0.10
0.00

F(T)
0.00
0.00
0.01
0.03
0.04
0.05
0.06
0.06

55.95
56.36
56.46
56.44
56.44
56.54
56.75
57.17
58.21
61.99

F(T)
55.24
55.95
56.35
56.46
56.43
56.43
56.53
56.74
57.15
58.20
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.43
56.52
56.73
57.14
58.19
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.52
56.73

49.8
50.5
53.9

18

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

19

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

20

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

21

T(m)

0.800
0.900
1.000

0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

1.09
1.02
1.00

1.72
2.45
3.89

508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)

414
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)

585.1
585.1
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc

0.06
0.06
0.00

F(T)
0.00
0.00
0.01
0.02
0.02
0.03
0.04
0.04
0.04
0.04
0.00

F(T)
0.00
0.00
0.00
0.01
0.01
0.02
0.02
0.02
0.02
0.03
0.00

F(T)
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.02
0.02
0.00

F(T)

57.14
58.19
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.73
57.14
58.19
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99

F(T)

58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

22

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

23

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

24

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600

1.000
0.900
0.800
0.700
0.600
0.500
0.400

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29

1.00
0.99
0.97
0.96
0.97
1.02
1.13

672
649
612
574
543
522
511

585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416

585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0

0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00

55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51

49.7
49.8
50.5
53.9

25

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

26

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

27

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

28

T(m)

0.700
0.800
0.900
1.000

0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

1.18
1.09
1.02
1.00

1.34
1.72
2.45
3.89

507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)

412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)

585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc

0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)

56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

F(T)

58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

29

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

30

T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

X1

X2

0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

gamma(1) gamma(2) Psat(1)


1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00

1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89

672
649
612
574
543
522
511
507
508
521
585

585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

Psat(2)
585
560
521
481
448
427
416
412
413
427
492

585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0

0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99

es con treinta iteraciones

T(m+1)
58.0
57.3
56.4
55.5
54.8
54.2
53.7
53.4
53.1
53.1
53.9

T(m+1)
58.0
57.2
55.9
54.7
53.6
52.9
52.4
52.1
52.0
52.2
53.9

T(m+1)
58.0
57.1
55.7
54.2
52.9
52.0
51.5
51.2
51.2
51.6

Y1 teorica

Y1 (EXP)

T(C) EXP

0.000
0.150
0.328
0.502
0.648
0.753
0.822
0.864
0.896
0.935
1.000

0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000

61
60
59
58
55
53
48
48
46
46
45

Y1
0.000
0.148
0.319
0.481
0.614
0.709
0.772
0.814
0.848
0.897
1.000

Y1
0.000
0.148
0.314
0.468
0.591
0.679
0.738
0.779
0.816
0.871

53.9

T(m+1)
58.0
57.0
55.5
53.8
52.4
51.5
50.9
50.7
50.7
51.2
53.9

T(m+1)
58.0
57.0
55.4
53.6
52.1
51.1
50.6
50.3
50.4
51.0
53.9

T(m+1)
58.0
57.0
55.3
53.5
52.0
50.9
50.3
50.1
50.2
50.8
53.9

T(m+1)
58.0
57.0

1.000

Y1
0.000
0.147
0.311
0.460
0.576
0.660
0.716
0.756
0.794
0.853
1.000

Y1
0.000
0.147
0.309
0.454
0.567
0.647
0.702
0.742
0.780
0.842
1.000

Y1
0.000
0.147
0.308
0.451
0.561
0.639
0.693
0.732
0.771
0.834
1.000

Y1
0.000
0.147

55.3
53.4
51.9
50.8
50.2
49.9
50.0
50.7
53.9

T(m+1)
58.0
57.0
55.2
53.4
51.8
50.7
50.1
49.9
49.9
50.7
53.9

T(m+1)
58.0
57.0
55.2
53.3
51.7
50.6
50.0
49.8
49.9
50.6
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.8
49.9

0.308
0.449
0.558
0.634
0.687
0.727
0.766
0.830
1.000

Y1
0.000
0.147
0.307
0.448
0.555
0.631
0.684
0.723
0.762
0.827
1.000

Y1
0.000
0.146
0.307
0.447
0.554
0.629
0.681
0.721
0.760
0.825
1.000

Y1
0.000
0.146
0.307
0.447
0.553
0.628
0.680
0.719
0.759

50.6
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9

T(m+1)
58.0

0.824
1.000

Y1
0.000
0.146
0.307
0.447
0.553
0.628
0.679
0.718
0.758
0.823
1.000

Y1
0.000
0.146
0.307
0.447
0.553
0.627
0.679
0.718
0.757
0.822
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.679
0.718
0.757
0.822
1.000

Y1
0.000

56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7

0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.757
0.822
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.757
0.822
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.822
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717

49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)

0.756
0.822
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1

58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0

0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678

49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)

0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1

58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000

Resultados ELV NO IDEAL cloroformo - metanol


ecuacion de VAN LAAR

X1

T(C) Exp

A12=
A21=
T (C) Teorica

0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0

61.0
60.0
59.0
58.0
55.0
53.0
48.0
48.0
46.0
46.0
45.0

58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9

0.0882
1.3590
Y exp
0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000

Y teorica
0.0000
0.1228
0.2402
0.3520
0.4583
0.5591
0.6542
0.7435
0.8267
0.9027
1.0000

ELV cloroformo - metanol X versus Y


Ecuacin de van Laar
1.0
0.9
0.8
0.7

Y1

0.6
0.5
0.4
0.3
0.2
0.1
0.0

0.0

0.1

0.2

0.3

0.4

0.5
X1

0.6

0.7

0.8

0.9

X1
Experimental

Teorico Van Laar

T (C)

T versus x,y ELV cloroformo-metanol


Ecuacin de van Laar
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
40
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

x,y

0.9

1.0

Liquido Experimental

Liquido Teorico

Vapor Experimental

Vapor Teorico

0.9

1.0

Resultados ELV NO IDEAL cloroformo - metanol


ecuacion de Margules

X1

T(C) Exp

A12=
A21=
T (C) Teorica

0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0

61.0
60.0
59.0
58.0
55.0
53.0
48.0
48.0
46.0
46.0
45.0

58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9

0.0882
1.3590
Y exp
0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000

Y teorica
0.0000
0.1464
0.3067
0.4464
0.5522
0.6265
0.6781
0.7170
0.7564
0.8214
1.0000

ELV cloroformo - metanol X versus Y


Ecuacin de Margules
1.0
0.9
0.8
0.7

Y1

0.6
0.5
0.4
0.3
0.2
0.1
0.0

0.0

0.1

0.2

0.3

0.4

0.5
X1

0.6

0.7

0.8

0.9

X1
Experimental

Teorico Margules

T (C)

T versus x,y ELV cloroformo-metanol


Ecuacin de Margules
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
40
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

x,y

0.9

1.0

Liquido Experimental

Liquido Teorico

Vapor Experimental

Vapor Teorico

0.9

1.0