macla nº 16.
junio ‘12
174
Influencia del Co2> en el Polimorfismo del
CaCO3
/ JORGE GONZÁLEZ-LÓPEZ, A. FERNÁNDEZ-GONZÁLEZ (5), A. JIM9NEZ
Departamento de Geología, Facultad de Geología, Universidad de Oviedo, C/ Jesús Arias de Velasco s/n, OO00Q Oviedo (Asturias).
INTRODUCCIÓN
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EXPERIMENTAL
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resumen SEM/SEA 2012
revista de la sociedad española de mineralogía
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&/$5/> fig 1. Imagen de SEM del experimento E1 tras Q
minutos de envejecimiento. La flecha negra indica
Exp. Q0 mL Q0 mL la fase amorfa y la blanca el CaCOO.
Na2COO CaCl2 CoCl2
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RESULTADOS Y DISCUSIÓN
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fig 2. Diagrama de DRX (polvo) para el experimento E1 transcurridos 60 días. Junto a cada reflexión se
indica la fase identificada: aragonito (A) y Co2(OH)2COO (N).
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hasta g) 60 días. Aragonito (A), Monohidrocalcita (M) y Co2(OH)2COO (N).
macla nº 16. junio ‘12
revista de la sociedad española de mineralogía
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CONCLUSIONES
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REFERENCIAS
Barber, D.M, Malone, P.G, Larson R.J. (1cdQ):
The effect of cobalt ion on nucleation of
calcium-carbonate polymorphs. Chemical
Geology, 16: 2Oc-2W1.
Fernández-Díaz L., Fernández-González A. y
Prieto M. (2010): The role of sulfate groups
in controlling CaCOO polymorphism.
Geochimica et Cosmochimica Acta, dW:
606W-60d6.
Fernández-González A., Fernández-Díaz L.,
Prieto M. (2011): Cristalización de CaCOO
en Gel de Sílice en presencia de Se(VI).
Macla, 1Q:iQ-i6.
jatsikopoulos D., Fernandez-Gonzalez A,
Prieto A.C, Prieto M (200i): Co-
crystallization of Co(II) with calcite:
Implications for the mobility of cobalt in
aqueous environments. Chemical Geology,
2QW: id-100.
Lippmann F. (1cdO): Sedimentary Carbonate
Minerals. Springer-Verlag. Berlin, Springer,
22i p.
Reddy M. l Wang j. (1ci0): Crystallization of
calcium carbonate in the presence of
metalions. Inhibition by magnesium ion at
pH i.i and 2QºC. Jounal of Crystal Growth,
Q0, Wd0pWi0.
Sánchez-Pastor N., Gigler A., Cruz J., Park S.,
Jordan G., Fernández-Díaz L. (2011):
Growth of calcium carbonate in the
presence of Cr(VI). Crystal Growth and
Design, 11: O0i1pO0ic.