Datos:

P (Psia)= 800 R 8.3144598

P (Kpa)= 5515.808
T (F)= -25
T (K)= 241.483333

Nº componentes Componentes Peso Molecular % molar zi w Tc(K) Pc(Kpa)

1 C1 16.04 86.698 0.89391 0.01150 190.699 4640.842
2 C2 30.07 7.399 0.07629 0.09860 305.428 4884.021
3 C3 44.1 2.346 0.02419 0.15240 369.898 4256.809
4 n-C4 58.12 0.544 0.00561 0.20100 425.199 3796.753
96.987 1

Ⴔ vap* = 0.9417 Ⴔ liq* = 0.0583

am vap = 249.8867 am liq = 735.4677
bm vap = 0.0277 bm liq = 0.0437
A vap= 0.3419 A liq = 1.0063
B vap= 0.0760 B liq = 0.1199
Z vap = 0.0000 Z liq = 0.0000
V vap (m3/Kmol) 0.0000 V liq (m3/Kmol) 0.0000
Resolución del Algoritmo
Primera Iteración
Componente zi Pvap (Kpa) Ki f(Ⴔ) yi* xi* Yi* Normalizado
C1 0.89391 17268.342 3.13070 0.63354 0.9309 0.2973 0.9309
C2 0.07629 1014.737 0.18397 -0.26883 0.0606 0.3294 0.0606
C3 0.02419 157.392 0.02853 -0.27577 0.0081 0.2839 0.0081
n-C4 0.00561 26.071 0.00473 -0.08890 0.0004 0.0893 0.0004
0.00004 1.00000 0.99996 1.00000

Metodo Newton Rapson:

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−(𝐴𝐵−𝐵^2−
=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
Nº de
iteraciones Z sup f f'
 Constantes para mi w<0,49 Constantes para aci y bi
C1 C2 C3 Ωa Ωb
0.37464 1.54226 0.26992 0.45724 0.0778
Constantes para mi w>0,49
C1 C2 C3 C4
0.37964 1.485 0.1644 0.01667

Tri Pri mi αi aci ai bi

1.2663 1.1885 0.39234 0.90409 247.6922 223.9372 0.02658
0.7906 1.1294 0.52408 1.11953 603.7436 675.9103 0.04045
0.6528 1.2958 0.60341 1.24515 1015.9963 1265.0722 0.05621
0.5679 1.4528 0.67373 1.35955 1505.1662 2046.3549 0.07244

Xi* Normalizado am vap am liq φ vap φ liq Ki P-R f(Ⴔ) yi

0.2973 236.5469 404.262497 Err:502
0.3294 410.2850 704.900341 Err:502
0.2839 558.9765 964.177273 Err:502
0.0893 707.2664 1223.85387 Err:502
1.00000 1913.07469 3297.19398 Err:502 0.00000 0.00000 0.00000 0.00000

on Rapson:
𝐴−2𝐵−3𝐵^2 )𝑍−(𝐴𝐵−𝐵^2−𝐵^3 )
𝐴−2𝐵−3𝐵^2 )=0
Zcal Diferencia
PROPIEDADES DEL GAS NATURAL <empty> 0.00224137 0.00682878 0.0123046
0.00224137 <empty> 0.00125796 0.00409639
0.00682878 0.00125796 <empty> 0.00081897
0.0123046 0.00409639 0.00081897 <empty>

Interaccion Binaria
bi*yi Kij C1 C2 C3 n-C4 aij C1
0.02376079 Methane 0.00000 0.00224 0.00683 0.01230 Methane 223.937234
0.00308606 Ethane 0.00224 0.00000 0.00126 0.00410 Ethane 388.180012
0.00135965 Propane 0.00683 0.00126 0.00000 0.00082 Propane 528.621634
0.00040633 n-Butane 0.01230 0.00410 0.00082 0.00000 n-Butane 668.615842

xi Yi Normalizado Xi Normalizado

0.00000 0.00000 0.00000

 Constantes de Antoine Extendida
C2 C3 n-C4 A B C
388.180012 528.621634 668.615842 Methane 31.35 -1307.52 0
675.910272 923.539574 1171.25729 Ethane 44.0103 -2568.82 0
923.539574 1265.07219 1607.65299 Propane 52.3785 -3490.55 0
1171.25729 1607.65299 2046.3549 n-Butane 66.945 -4604.09 0
de Antoine Extendida
D E F
-3.26134 2.94E-05 2
-4.97635 1.46E-05 2
-6.10875 1.12E-05 2
-8.25491 1.16E-05 2
 Constantes de Antoine Extendida
A B C
Nitrogen 35.4113 -966.243 0
CO2 133.62 -4735 0
H2S 78.6762 -3839.89 0
Methane 31.35 -1307.52 0
Ethane 44.0103 -2568.82 0
Propane 52.3785 -3490.55 0
i-Butane 58.7845 -4136.68 0
n-Butane 66.945 -4604.09 0
i-Pentane 66.7563 -5059.18 0
n-Pentane 63.3315 -5117.78 0
n-Hexane 70.4265 -6055.6 0
n-Heptane 78.3285 -6947 0
de Antoine Extendida
D E F
-4.31849 7.93E-05 2
-21.267 0.040908 1
-11.199 0.018848 1
-3.26134 2.94E-05 2
-4.97635 1.46E-05 2
-6.10875 1.12E-05 2
-7.01666 1.04E-05 2
-8.25491 1.16E-05 2
-8.08935 9.25E-06 2
-7.48305 7.77E-06 2
-8.37865 6.62E-06 2
-9.44866 6.47E-06 2