Balance de Masa

Contaminante endosulfan sulfate

C acuosa mg/m3
Solubilidad mg/L
Kow 3.66
K Henry 0.0000464 atm*m3/mol
Área 100 m2
Temperatura 301.15 k
Koc 3.37 cm3/g
K`H 0.001879 Adimensional
C aire 93,561 mg/m3
R 0.000082 atm*m3/mol*k

Precipitación mm
kd 0.04718 horizonte Ap
Bw 0.2490 Adimensional
Ksw 4,979.355 kg/m3
Concentración 49793545.3914195 mg/m3
Concentración 49,793.545 mg/l
L2 (profundida total del 130.000 cm
perfil final)
L1 (profundida 20.000 cm
horizonte Ap inicial)
Concentración total del
10000
contaminante mg/Kg
Perfil AS-81

Real Da
Horizonte Profundidad (cm)
(g/cm3) (g/cm3)

Ap 0 20 2.46 1.24
Bg1 20 45 2.58 1.38
Bg2 45 100 2.64 1.38
Cg 100 130 2.64 1.38

Distribución de masa
Horizonte % Masa % Vol
% M aire
Ap 16.33%
Bg1 19.16%
Bg2 41.74%
Cg 22.77%
 Da % Porosidad
% microporosidad
(Kg/m3) total

1240 49.59 37.99

1380 46.51 35.57
1380 47.73 38.54
1380 47.73 38.54

Distribución de masa Distribución por horizontes

% M ac % M adsor % M aire
43.25% 74.84% 0.23092184%
22.50% 15.87% 0.603020%
24.13% 6.54% 1.305903%
10.12% 2.75% 1.691048%
 Foc
% 50 % 50
% %C %M (fraccion de
microporosꝊ microporosꝊ
macroporosidad Organico Organica carbono
ws as
orgánico)
11.61 19.00 19.00 1.4 2.66 0.014
10.94 17.785 17.78500 0.48 0.91 0.0048
9.18 19.27 19.2700 0.2 0.38 0.002
9.18 19.27 19.2700 0.2 0.38 0.002

bución por horizontes

% M ac % M adsor Distribuc
76.276% 23.493%
88.312% 11.085% % M adsor
94.150% 4.544%
93.782% 4.527% % M ac

% M aire

0.00% 10.00% 20.00% 30.00% 40.00% 50

Distribución por h

Cg

Bg2

Bg1

Ap

0% 20% 40%

Distribución
100.00000000%

80.00000000%
Distribución (%)

60.00000000%

40.00000000%

20.00000000%
 80.00000000%

Distribución (%)
60.00000000%

40.00000000%

20.00000000%

0.00000000%
Ap Bg1
 Concentración agua (Cw)
profundidad Kd (mg/m3) V Suelo M Suelo V Agua
(m) (cm3/g) (m3) (Kg) (m3)

0.2 0.04718 49793545.39 20 24800 3.799

0.25 0.016176 22130464.62 25 34500 4.44625
0.55 0.00674 9958709.08 55 75900 10.5985
0.3 0.00674 7660545.44 30 41400 5.781

Distribución de Masa
Ap
Bg1
Bg2
Cg

.00% 40.00% 50.00% 60.00% 70.00% 80.00% 90.00% 100.00%

tribución por horizontes

% M aire
% M ac
% M adsor

60% 80% 100%

Distribución por horizontes

% M aire
% M ac
% M adsor
 % M aire
% M ac
% M adsor

Bg1 Bg2 Cg
 C Adsorbida V Aire
Kd (cm3/g) M fase ac (mg)
(mg/Kg) (m3)

0.047180 2,349.26 6.121 189,165,678.94

0.016176 357.98 7.181 98,397,578.31
0.006740 67.12 15.648 105,547,378.17
0.006740 51.63 8.535 44,285,613.22
2,825.996 437,396,248.63

Distribución de Masa
100.00%
90.00%
80.00%
70.00%
60.00%
50.00%
40.00%
30.00%
20.00%
10.00%
0.00%
% M aire % M ac % M adsor
 M fase volatilizada
M fase Adsorbida (mg) Masa Total (mg)
(mg)

58,261,634.89 572,686.16 248,000,000.00

12,350,392.65 671,884.09 111,419,855
5,094,536.97 1,463,993.91 112,105,909
2,137,567.96 798,542.13 47,221,723
77,844,132.47 3,507,106.30 518,747,487.41

e Masa

Cg
Bg2
Bg1
Ap

% M adsor
 M fase
M fase ac (mg) M fase Adsorbida (mg) volatilizada
(mg)

189,165,678.94 58,261,634.89 572,686.16

98,397,578.31 12,350,392.65 671,884.09
105,547,378.17 5,094,536.97 1,463,993.91
44,285,613.22 2,137,567.96 798,542.13
437,396,248.63 77,844,132.47 3,507,106.30

200,000,000.00

180,000,000.00

160,000,000.00

140,000,000.00

120,000,000.00

100,000,000.00

80,000,000.00

60,000,000.00

40,000,000.00

20,000,000.00

0.00
0.5 1 1.5 2 2.5 3

M fase ac (mg) M fase Adsorbida (mg) M fase volatilizada (mg)

 3 3.5 4 4.5

M fase volatilizada (mg)

 Parámetro valor
Koc (según el
3.45 4,570.881896
contaminnate) 1logkow-0.21
Koc Montgomery 3.37