TAREA AUTÓNOMA #16

IGUALACIÓN DE ECUACIONES QUÍMICAS

MÉTODO DEL IÓN ELECTRÓN
MEDIO BÁSICO
RESOLVER LOS SIGUIENTES EJERCICIOS:
1. ZN + NANO3 + NAOH → NA2ZNO2 + NH3 + H2O

ZN + NANO3 + NAOH → NA2ZNO2 + NH3 + H2O

ZN0 + NA+1N+5O-23 + NA+1O-2H+1 → NA+12ZN+2O-22 + N-3H+13 + H+12º
O: ZN0 → NA+12ZN+2O-22 (ZN)
R: NA+1N+5O-23 → N-3H+13 (N)

O: ZN0 → NA+12ZN+2O-22
R: NA+1N+5O-23 → N-3H+13

O: ZN + 2NAOH → NA2ZNO2
R: 2NANO3 + ZN → 2NH3 + NA2ZNO2

O: ZN + 2NAOH → NA2ZNO2
R: 2NANO3 + ZN → 2NH3 + NA2ZNO2 + 4H2O

O: ZN + 2NAOH → NA2ZNO2 + 2H+
R: 2NANO3 + ZN + 14H+ → 2NH3 + NA2ZNO2 + 4H2O

O: ZN + 2NAOH + 2OH- → NA2ZNO2 + 2H2O

R: 2NANO3 + ZN + 14H2O → 2NH3 + NA2ZNO2 + 4H2O + 14OH-

O: ZN + 2NAOH + 2OH- → NA2ZNO2 + 2H2O + 2E-

R: 2NANO3 + ZN + 14H2O + 14E- → 2NH3 + NA2ZNO2 + 4H2O + 14OH-

O: ZN + 2NAOH + 2OH- → NA2ZNO2 + 2H2O + 2E- | *7

R: 2NANO3 + ZN + 14H2O + 14E- → 2NH3 + NA2ZNO2 + 4H2O + 14OH- | *1
O: 7ZN + 14NAOH + 14OH- → 7NA2ZNO2 + 14H2O + 14E-
R: 2NANO3 + ZN + 14H2O + 14E- → 2NH3 + NA2ZNO2 + 4H2O + 14OH-

2NANO3 + 14NAOH + 8ZN + 14OH- + 14H2O + 14E- → 2NH3 + 8NA2ZNO2 +

14E- + 18H2O + 14OH-
NANO3 + 7NAOH + 4ZN → NH3 + 4NA2ZNO2 + 2H2O
 1*0 + 7*0 + 4*0 = 1*0 + 4*0 + 2*0

0=0
4ZN + NANO3 + 7NAOH → 4NA2ZNO2 + NH3 + 2H2O

2. MNO2 + KCLO3 + KOH → K2MNO4 + KCL + H2O

MNO2 + KOH + O2 → K2MNO4 + H2O

MN+4O-22 + K+1O-2H+1 + O02 → K+12MN+6O-24 + H+12º

O: MN +4 O2-2→ K2MN+6O-24 (Mn)
R: O 2 → H2+1 O-2 (O)

O: MN +4 O- -22 → K+12MN+6O-24
R: O2 → H+12 O-2

O: MNO2 + 2KOH → K2MNO4
R: O2 → 2H2O

O: MNO2 + 2KOH + 2OH- → K2MNO4 + 2H2O + 2E-

R: O2 + 4H2O + 4E- → 2H2O + 4OH-

SE IGUALAN LOS ELECTRONES

O: MNO2 + 2KOH + 2OH- → K2MNO4 + 2H2O + 2E- (2)
R: O2 + 4H2O + 4E- → 2H2O + 4OH- (1)

O: 2MNO2 + 4KOH + 4OH- → 2K2MNO4 + 4H2O + 4E-

R: O2 + 4H2O + 4E- → 2H2O + 4OH-

2MNO2 + O2 + 4KOH + 4H2O + 4OH- + 4E- → 2K2MNO4 + 6H2O + 4OH- + 4E-

 2MNO2 + O2 + 4KOH → 2K2MNO4 + 2H2O

2*0 + 1*0 + 4*0 = 2*0 + 2*0

0=0
2MNO2 + 4KOH + O2 → 2K2MNO4 + 2H2O

3 Br2 + KOH → KBr + KBrO3 + H2O

Br02 + K+1O-2H+1 → K+1Br-1 + K+1Br+5O-23 + H+12O-2

Oxidación Br02 → 2K+1Br+5O-23 + 10e-

Br02 + 2KOH → 2K+1Br+5O-23 + 10e-
Br02 + 2KOH + 10OH- → 2K+1Br+5O-23 + 10e-
Br02 + 2KOH + 10OH- → 2K+1Br+5O-23 + 10e- + 6H2O

Reducción
Br02 + 2e- → 2K+1Br
Br02 + 2KOH + 2e- → 2K+1Br
Br02 + 2KOH + 2e- → 2K+1Br-1 + 2OH-

X1 (Br02 + 2KOH + 10OH- → 2K+1Br+5O-23 + 10e- + 6H2O)

X5 (Br02 + 2KOH + 2e- → 2K+1Br-1 + 2OH-)

Br02 + 2KOH + 10OH- → 2K+1Br+5O-23 + 10e- + 6H2O

 
 5Br02 + 10KOH + 10e- → 10K+1Br-1 + 10OH-
6Br02 + 12KOH + 10OH- + 10e- → 2K+1Br+5O-23 + 10K+1Br-1 + 10e- + 10OH- + 6H2O

3Br02 + 6KOH → K+1Br+5O-23 + 5K+1Br-1 + 3H2O

ELEMENTO IZQUIERDA DERECHO DIFERENCIA

Br 3*2 1*1 + 5*1 0
K 6*1 1*1 + 5*1 0
O 6*1 1*3 + 3*1 0
H 6*1 3*2 0

3Br2 + 6KOH → 5KBr + KBrO3 + 3H2O

4 KMnO4 + NH3 → KNO3 + MnO2 + KOH + H2O

K+1Mn+7O-24 + N-3H+13 → K+1N+5O-23 + Mn+4O-22 + K+1O-2H+1 + H+12º
Oxidación
N-3H+13 → K+1N+5O-23 + 8e-
N-3H+13 + KMnO4 → K+1N+5O-23 + MnO2 + 8e-
N-3H+13 + KMnO4 + 8OH- → K+1N+5O-23 + MnO2 + 8e- + 7H2O
Reducción
K+1Mn+7O-24 + 3e- → Mn+4O2-2
K+1Mn+7O-24 + 3e- → Mn+4O-22 + KOH
K+1Mn+7O-24 + 3e- → Mn+4O-22 + KOH + 3OH-

x3 N-3H+13 + KMnO4 + 8OH- → K+1N+5O-23 + MnO2 + 8e- + 7H2O

 
x8 K+1Mn+7O-24 + 3e- + 2H2O → Mn+4O-22 + KOH + 3OH-

3N-3H+13 + 3KMnO4 + 24OH- → 3K+1N+5O-23 + 3MnO2 + 24e- + 21H2O

 
8K+1Mn+7O-24 + 24e- + 16H2O → 8Mn+4O-22 + 8KOH + 24OH-

3N-3H+13 + 11K+1Mn+7O-24 + 24e- + 24OH- + 16H2O → 3K+1N+5O-23 + 11Mn+4O-

22 + 8KOH + 24e- + 24OH- + 21H2O

3N-3H+13 + 11K+1Mn+7O-24 → 3K+1N+5O-23 + 11Mn+4O-22 + 8KOH + 5H2O

ELEMENTO IZQUIERDA DERECHO DIFERENCIA
N 3*1 3*1 0
H 3*3 8*1 + 5*2 -9
K 11*1 3*1 + 8*1 0
Mn 11*1 11*1 0
O 11*4 3*3 + 11*2 + 8*1 + 5*1 0

3N-3H+13 + 11K+1Mn+7O-24 → 3K+1N+5O-23 + 11Mn+4O-22 + 8KOH + 5H2O