R=8.

314 ∆ U C 2 H 6 O 2=−3227000 J /mol

C 7 H 6 O 2=122.12 g /mol T =° C+273.15=K
C 10 H 8=128.17 g /mol

Reacción 1:
15
C 7 H 6 O2 (s )+ O →7 CO 2(g )+ 3 H 2 O(l )
2 2 (g)

l alam= 2.3( cal

cm )( 4.184 ) =9.6232
J
mol
1 cal=4.184 J
Reacción 2:
C 10 H 3(s )+ 12O2 (g) →10 CO2 (g) + 4 H 2 O(l)

Caso 1:
a)
∆ UcomB=∆ HcomB−∆ ngRTin

∆ UcomB=(−3227000 ) −( 7− ( 15
2 )
( 8.314 )( 301.729 ) )

∆ UcomB=−3,225,745.713 J /mol
b)
n carb ∆ Ucomb+l alam(l ∈−l fn)
CBcal=
(Tfn−Tin )

(mcarb g 0.8429)(1mol ) −3
=6.90 × 10
(122.12 g)

( ( 6.90 ×10−3 ) (−3,225,745.713 ) ) +( ( 9.6232 ) ( 10−2.6 ))

CBcal=
(303.932−301−729)
CBcal=−10 , 079.271 J /k
c)
( ( CBcal ) ( Tfn−Tin ) −( latam )( l∈−l fn ) )
∆ U comb Nafta=
(0.007522)
 ((−10,074.271 ) (305.748−301.959 )−( 9.6232 )( 10−2.7 ) )
∆ U comb Nafta=
(0.007522)
0.9641 −3
=7.52× 10
128.17
∆ Ucomb=−5,090,643.941 J /mol
d) Entalpia de nafta
∆ Hrxn=qp=qv +∆ ngRTin
−5,090,643.941+(10−12)(8.314)(301.954)
J
∆ Hrxn=−5,089,378.2 =qv
mol
e) Porcentaje de desviación