UNIVERSIDAD NACIONAL JOSE MARIA ARGUEDAS

FACULTAD DE INGENIERIA

ESCUELA PROFESIONAL DE INGENIERÍA AMBIENTAL

TALLER DE FISICOQUÍMICA

DOCENTE:

Barazorda Carrillo, José Gabriel

ALUMNO:

Céspedes Rodas, Marcial Edgar

ANDAHUAYLAS – PERÚ

2022
 LEYES DE GASES
LEY DE BOILE
La presión y el volumen de un gas son inversamente proporcionales si se mantiene
constante su temperatura. Esto quiere decir a mayor presión menor volumen y

viceversa.
 𝑉1 𝑃1 = 𝑉2 𝑃2 = 𝑉3 𝑃3 = 𝑉4 𝑃4 = 𝑉5 𝑃5 = 𝑉6 𝑃6 = 𝑉7 𝑃7 = 𝑉8 𝑃8 = 𝑉9 𝑃9 = 𝑉10 𝑃10 …
𝑇 = 36° 𝐶 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑛 = 150 𝑚𝑜𝑙 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑉1 = 3.9 𝐿
𝑃1 = 108 𝑎𝑡𝑚
𝑉2 = 𝑖𝑛𝑐𝑜𝑔.
𝑉𝑛 𝑃𝑛
𝑉𝑛+1 =
𝑃𝑛+1
Condición: 𝑃2 = 103 𝑎𝑡𝑚
𝑉1 = 3.9 𝐿
𝑃1 = 108 𝑎𝑡𝑚
𝑉1 𝑃1 (3.9 𝐿)(108 𝑎𝑡𝑚)
𝑉2 = = = 4.089 𝐿
𝑃2 103 𝑎𝑡𝑚
Condición: 𝑃3 = 100 𝑎𝑡𝑚
𝑉2 = 4.089 𝐿
𝑃2 = 103 𝑎𝑡𝑚
𝑉2 𝑃2 (4.089 𝐿)(103 𝑎𝑡𝑚)
𝑉3 = = = 4.212 𝐿
𝑃3 100 𝑎𝑡𝑚
Condición: 𝑃4 = 96 𝑎𝑡𝑚
𝑉3 = 4.212 𝐿
𝑃3 = 100 𝑎𝑡𝑚
𝑉3 𝑃3 (4.212 𝐿)(100 𝑎𝑡𝑚)
𝑉4 = = = 4.388 𝐿
𝑃4 96𝑎𝑡𝑚
Condición: 𝑃5 = 94 𝑎𝑡𝑚
𝑉4 = 4.388 𝐿
𝑃4 = 96 𝑎𝑡𝑚
𝑉4 𝑃4 (4.388 𝐿)(96 𝑎𝑡𝑚)
𝑉5 = = = 4.481 𝐿
𝑃5 94𝑎𝑡𝑚
Condición: 𝑃6 = 92 𝑎𝑡𝑚
𝑉5 = 4.481 𝐿
𝑃5 = 94 𝑎𝑡𝑚
 𝑉5 𝑃5 (4.481 𝐿)(94 𝑎𝑡𝑚)
𝑉6 = = = 4.578 𝐿
𝑃6 92 𝑎𝑡𝑚
Condición: 𝑃7 = 90 𝑎𝑡𝑚
𝑉6 = 4.578 𝐿
𝑃6 = 92 𝑎𝑡𝑚
𝑉6 𝑃6 (4.578 𝐿)(92 𝑎𝑡𝑚)
𝑉7 = = = 4.680 𝐿
𝑃7 90 𝑎𝑡𝑚
Condición: 𝑃8 = 84 𝑎𝑡𝑚
𝑉7 = 4.680 𝐿
𝑃7 = 90 𝑎𝑡𝑚
𝑉7 𝑃7 (4.680 𝐿)(90 𝑎𝑡𝑚)
𝑉8 = = = 5.014 𝐿
𝑃8 84 𝑎𝑡𝑚
Condición: 𝑃9 = 81 𝑎𝑡𝑚
𝑉8 = 5.014 𝐿
𝑃8 = 84 𝑎𝑡𝑚
𝑉8 𝑃8 (5.014 𝐿)(84 𝑎𝑡𝑚)
𝑉9 = = = 5.200 𝐿
𝑃9 81 𝑎𝑡𝑚
Condición: 𝑃10 = 75 𝑎𝑡𝑚
𝑉9 = 5.200 𝐿
𝑃9 = 81 𝑎𝑡𝑚
𝑉9 𝑃9 (5.200 𝐿)(81 𝑎𝑡𝑚)
𝑉10 = = = 5.616 𝐿
𝑃10 75 𝑎𝑡𝑚
Condición: 𝑃11 = 72 𝑎𝑡𝑚
𝑉10 = 5.616 𝐿
𝑃10 = 75 𝑎𝑡𝑚
𝑉10 𝑃10 (5.616 𝐿)(75 𝑎𝑡𝑚)
𝑉11 = = = 5.850 𝐿
𝑃11 72 𝑎𝑡𝑚
Condición: 𝑃12 = 66 𝑎𝑡𝑚
𝑉11 = 5.850 𝐿
𝑃11 = 72 𝑎𝑡𝑚
𝑉11 𝑃11 (5.850 𝐿)(72 𝑎𝑡𝑚)
𝑉12 = = = 6.382 𝐿
𝑃12 66 𝑎𝑡𝑚
Condición: 𝑃13 = 62 𝑎𝑡𝑚
𝑉12 = 6.382 𝐿
𝑃12 = 66 𝑎𝑡𝑚
𝑉12 𝑃12 (6.382 𝐿)(66 𝑎𝑡𝑚)
𝑉13 = = = 6.794 𝐿
𝑃13 62 𝑎𝑡𝑚
Condición: 𝑃14 = 59 𝑎𝑡𝑚
𝑉13 = 6.794 𝐿
𝑃13 = 62 𝑎𝑡𝑚
𝑉13 𝑃13 (6.794 𝐿)(62 𝑎𝑡𝑚)
𝑉14 = = = 7.139 𝐿
𝑃14 59 𝑎𝑡𝑚
Condición: 𝑃15 = 54 𝑎𝑡𝑚
𝑉14 = 7.139 𝐿
𝑃14 = 59 𝑎𝑡𝑚
𝑉14 𝑃14 (7.139 𝐿)(59 𝑎𝑡𝑚)
𝑉15 = = = 7.800 𝐿
𝑃15 54 𝑎𝑡𝑚
Condición: 𝑃16 = 50 𝑎𝑡𝑚
𝑉15 = 7.800 𝐿
𝑃15 = 54 𝑎𝑡𝑚
𝑉15 𝑃15 (7.800 𝐿)(54 𝑎𝑡𝑚)
𝑉16 = = = 8.424 𝐿
𝑃16 50 𝑎𝑡𝑚
Condición: 𝑃17 = 48 𝑎𝑡𝑚
𝑉16 = 8.424 𝐿
𝑃16 = 50 𝑎𝑡𝑚
𝑉16 𝑃16 (8.424 𝐿)(50 𝑎𝑡𝑚)
𝑉17 = = = 8.775 𝐿
𝑃17 48 𝑎𝑡𝑚
Condición: 𝑃18 = 45 𝑎𝑡𝑚
𝑉17 = 8.775 𝐿
𝑃17 = 48 𝑎𝑡𝑚
𝑉17 𝑃17 (8.775 𝐿)(48 𝑎𝑡𝑚)
𝑉18 = = = 9.360 𝐿
𝑃18 45 𝑎𝑡𝑚
Condición: 𝑃19 = 39 𝑎𝑡𝑚
𝑉18 = 9.360 𝐿
𝑃18 = 45 𝑎𝑡𝑚
𝑉18 𝑃18 (9.360 𝐿)(45 𝑎𝑡𝑚)
𝑉19 = = = 10.800 𝐿
𝑃19 39 𝑎𝑡𝑚
Condición: 𝑃20 = 36 𝑎𝑡𝑚
𝑉19 = 10.800 𝐿
𝑃19 = 39 𝑎𝑡𝑚
𝑉19 𝑃19 (10.800 𝐿)(39 𝑎𝑡𝑚)
𝑉20 = = = 11.700 𝐿
𝑃20 36 𝑎𝑡𝑚
Condición: 𝑃21 = 30 𝑎𝑡𝑚
𝑉20 = 11.700 𝐿
𝑃20 = 36 𝑎𝑡𝑚
𝑉20 𝑃20 (11.700 𝐿)(36 𝑎𝑡𝑚)
𝑉21 = = = 14.040 𝐿
𝑃21 30 𝑎𝑡𝑚
Condición: 𝑃22 = 27 𝑎𝑡𝑚
𝑉21 = 14.040 𝐿
𝑃21 = 30 𝑎𝑡𝑚
𝑉21 𝑃21 (14.040 𝐿)(30 𝑎𝑡𝑚)
𝑉22 = = = 15.600 𝐿
𝑃22 27 𝑎𝑡𝑚
Condición: 𝑃23 = 21 𝑎𝑡𝑚
𝑉22 = 15.600 𝐿
𝑃22 = 27 𝑎𝑡𝑚
𝑉22 𝑃22 (15.600 𝐿)(27 𝑎𝑡𝑚)
𝑉23 = = = 20.057 𝐿
𝑃23 21 𝑎𝑡𝑚
Condición: 𝑃24 = 18 𝑎𝑡𝑚
𝑉23 = 20.057 𝐿
𝑃23 = 21 𝑎𝑡𝑚
𝑉23 𝑃23 (20.057 𝐿)(21 𝑎𝑡𝑚)
𝑉24 = = = 23.400 𝐿
𝑃24 18 𝑎𝑡𝑚
Condición: 𝑃25 = 9 𝑎𝑡𝑚
𝑉24 = 23.400 𝐿
𝑃24 = 18 𝑎𝑡𝑚
 𝑉24 𝑃24 (23.400𝐿)(18 𝑎𝑡𝑚)
𝑉25 = = = 46.800 𝐿
𝑃25 9 𝑎𝑡𝑚

Demostración de la ecuación de línea de tendencia

421.2
𝑉=
𝑃
Condición: 𝑃25 = 9 𝑎𝑡𝑚
421.2 421.2
𝑉25 = = = 46.800 𝐿
𝑃25 9
Condición: 𝑃21 = 30 𝑎𝑡𝑚
421.2 421.2
𝑉21 = = = 14.040 𝐿
𝑃21 30
Condición: 𝑃20 = 36 𝑎𝑡𝑚
421.2 421.2
𝑉20 = = = 11.700 𝐿
𝑃20 36
Condición: 𝑃15 = 54 𝑎𝑡𝑚
421.2 421.2
𝑉15 = = = 7.800 𝐿
𝑃15 54
Condición: 𝑃12 = 66 𝑎𝑡𝑚

Ley de Boile
50.000

45.000 y = 421.2x-1
R² = 1
40.000

35.000

30.000
V (L)

25.000
Series1
20.000 Potencial (Series1)
15.000

10.000

5.000

0.000
0 20 40 60 80 100 120
P (atm)
 Ley de Boile (Inversa)
0.12
y = 0.0024x + 2E-17
R² = 1
0.1

0.08
1/P (1/atm)

0.06
Series1
Lineal (Series1)
0.04

0.02

0
0.000 5.000 10.000 15.000 20.000 25.000 30.000 35.000 40.000 45.000 50.000
V (L)

421.2 421.2
𝑉12 = = ̂ 𝐿 ≅ 6.382 𝐿
= 6. 38181
𝑃12 66
Condición: 𝑃10 = 75 𝑎𝑡𝑚
421.2 421.2
𝑉10 = = = 5.616 𝐿
𝑃10 75
Condición: 𝑃9 = 81 𝑎𝑡𝑚
421.2 421.2
𝑉9 = = = 5.200 𝐿
𝑃9 81
Condición: 𝑃6 = 92 𝑎𝑡𝑚
421.2 421.2
𝑉6 = = = 4.57826 … 𝐿 ≅ 4.578 𝐿
𝑃6 92
Condición: 𝑃4 = 96 𝑎𝑡𝑚
421.2 421.2
𝑉4 = = = 4.3875 𝐿 ≅ 4.388 𝐿
𝑃4 96
Condición: 𝑃1 = 108 𝑎𝑡𝑚
421.2 421.2
𝑉1 = = = 3.900 𝐿
𝑃1 108

Ejemplo de la Ley de Boyle en la vida real

A presión de 12 atm, 28 L de un gas a temperatura constante experimenta un cambio
ocupando un volumen de 15 L. Calcular la presión que ejercerá el gas.

V1 = 28 L
P1 = 12 atm
V2 = 15 L
P2 = ¿?

𝑉1 𝑃1 28 𝐿 ∗ 12 𝑎𝑡𝑚
𝑃2 = = = 22.4 𝑎𝑡𝑚
𝑉2 15 𝐿
Condición
P (atm) V (L) 1/P (1/atm)
1 108 3.900 0.00925926
2 103 4.089 0.00970874
3 100 4.212 0.01
4 96 4.388 0.01041667
5 94 4.481 0.0106383
6 92 4.578 0.01086957
7 90 4.680 0.01111111
8 84 5.014 0.01190476
9 81 5.200 0.01234568
10 75 5.616 0.01333333
11 72 5.850 0.01388889
12 66 6.382 0.01515152
13 62 6.794 0.01612903
14 59 7.139 0.01694915
15 54 7.800 0.01851852
16 50 8.424 0.02
17 48 8.775 0.02083333
18 45 9.360 0.02222222
19 39 10.800 0.02564103
20 36 11.700 0.02777778
21 30 14.040 0.03333333
22 27 15.600 0.03703704
23 21 20.057 0.04761905
24 18 23.400 0.05555556
25 9 46.800 0.11111111
LEY DE CHARLES
𝑉1 𝑉2 𝑉3 𝑉4 𝑉5 𝑉6 𝑉7 𝑉8 𝑉9 𝑉10
= = = = = = = = = …
𝑇1 𝑇2 𝑇3 𝑇4 𝑇5 𝑇6 𝑇7 𝑇8 𝑇9 𝑇10
𝑃 = 100 𝑎𝑡𝑚 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑛 = 100 𝑚𝑜𝑙 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑉1 = 12 𝐿
𝑇1 = 20° 𝐶
𝑉2 = 𝑖𝑛𝑐𝑜𝑔.
𝑉𝑛 𝑇𝑛+1
𝑉𝑛+1 =
𝑇𝑛
Condición: 𝑇2 = 25° 𝐶
𝑉1 = 12 𝐿
𝑇1 = 20° 𝐶
𝑉1 𝑇2 (12 𝐿)(25° 𝐶)
𝑉2 = = = 15 𝐿
𝑇1 20° 𝐶
Condición: 𝑇3 = 27° 𝐶
𝑉2 = 15 𝐿
𝑇2 = 25° 𝐶
𝑉2 𝑇3 (15 𝐿)(27° 𝐶)
𝑉3 = = = 16.2 𝐿
𝑇2 25° 𝐶
Condición: 𝑇4 = 31° 𝐶
𝑉3 = 16.2 𝐿
𝑇3 = 27° 𝐶
𝑉3 𝑇4 (16.2 𝐿)(31° 𝐶)
𝑉4 = = = 18.6 𝐿
𝑇3 27° 𝐶
Condición: 𝑇5 = 36° 𝐶
𝑉4 = 18.6 𝐿
𝑇4 = 31° 𝐶
𝑉4 𝑇5 (18.6 𝐿)(36° 𝐶)
𝑉5 = = = 21.6 𝐿
𝑇4 31° 𝐶
Condición: 𝑇6 = 40° 𝐶
𝑉5 = 21.6 𝐿
𝑇5 = 36° 𝐶
𝑉5 𝑇6 (21.6 𝐿)(40° 𝐶)
𝑉6 = = = 24 𝐿
𝑇5 36° 𝐶
Condición: 𝑇7 = 45° 𝐶
𝑉6 = 24 𝐿
𝑇6 = 40° 𝐶
𝑉6 𝑇7 (24 𝐿)(45° 𝐶)
𝑉7 = = = 27 𝐿
𝑇6 40° 𝐶
Condición: 𝑇8 = 48° 𝐶
𝑉7 = 27 𝐿
𝑇7 = 45° 𝐶
𝑉7 𝑇8 (27 𝐿)(48° 𝐶)
𝑉8 = = = 28.8 𝐿
𝑇7 45° 𝐶
Condición: 𝑇9 = 54° 𝐶
𝑉8 = 28.8 𝐿
𝑇8 = 48° 𝐶
𝑉8 𝑇9 (28.8 𝐿)(54° 𝐶)
𝑉9 = = = 32.4 𝐿
𝑇8 48° 𝐶
Condición: 𝑇10 = 60° 𝐶
𝑉9 = 32.4 𝐿
𝑇9 = 54° 𝐶
𝑉9 𝑇10 (32.4 𝐿)(60° 𝐶)
𝑉10 = = = 36 𝐿
𝑇9 54° 𝐶
Condición: 𝑇11 = 63° 𝐶
𝑉10 = 36 𝐿
𝑇10 = 60° 𝐶
𝑉10 𝑇11 (36 𝐿)(63° 𝐶)
𝑉11 = = = 37.8 𝐿
𝑇10 60° 𝐶
Condición: 𝑇12 = 69° 𝐶
𝑉11 = 37.8 𝐿
𝑇11 = 63° 𝐶
 𝑉11 𝑇12 (37.8 𝐿)(69° 𝐶)
𝑉12 = = = 41.4 𝐿
𝑇11 63° 𝐶
Condición: 𝑇13 = 72° 𝐶
𝑉12 = 41.4 𝐿
𝑇12 = 69° 𝐶
𝑉12 𝑇13 (41.4 𝐿)(72° 𝐶)
𝑉13 = = = 43.2 𝐿
𝑇12 69° 𝐶
Condición: 𝑇14 = 75° 𝐶
𝑉13 = 43.2 𝐿
𝑇13 = 72° 𝐶
𝑉13 𝑇14 (43.2 𝐿)(75° 𝐶)
𝑉14 = = = 45 𝐿
𝑇13 72° 𝐶
Condición: 𝑇15 = 79° 𝐶
𝑉14 = 45 𝐿
𝑇14 = 75° 𝐶
𝑉14 𝑇15 (45 𝐿)(79° 𝐶)
𝑉15 = = = 47.4 𝐿
𝑇14 75° 𝐶
Condición: 𝑇16 = 81° 𝐶
𝑉15 = 47.4 𝐿
𝑇15 = 79° 𝐶
𝑉15 𝑇16 (47.4 𝐿)(81° 𝐶)
𝑉16 = = = 48.6 𝐿
𝑇15 79° 𝐶
Condición: 𝑇17 = 84° 𝐶
𝑉16 = 48.6 𝐿
𝑇16 = 81° 𝐶
𝑉16 𝑇17 (48.6 𝐿)(84° 𝐶)
𝑉17 = = = 50.4 𝐿
𝑇16 81° 𝐶
Condición: 𝑇18 = 89° 𝐶
𝑉17 = 50.4 𝐿
𝑇17 = 84° 𝐶
𝑉17 𝑇18 (50.4 𝐿)(89° 𝐶)
𝑉18 = = = 53.4 𝐿
𝑇17 84° 𝐶
Condición: 𝑇19 = 92° 𝐶
𝑉18 = 53.4 𝐿
𝑇18 = 89° 𝐶
𝑉18 𝑇19 (53.4 𝐿)(92° 𝐶)
𝑉19 = = = 55.2 𝐿
𝑇18 89° 𝐶
Condición: 𝑇20 = 95° 𝐶
𝑉19 = 55.2 𝐿
𝑇19 = 92° 𝐶
𝑉19 𝑇20 (55.2 𝐿)(95° 𝐶)
𝑉20 = = = 57 𝐿
𝑇19 92° 𝐶
Condición: 𝑇21 = 96° 𝐶
𝑉20 = 57 𝐿
𝑇20 = 96° 𝐶
𝑉20 𝑇21 (57 𝐿)(96° 𝐶)
𝑉21 = = = 57.6 𝐿
𝑇20 96° 𝐶
Condición: 𝑇22 = 100° 𝐶
𝑉21 = 57.6 𝐿
𝑇21 = 96° 𝐶
𝑉21 𝑇22 (57.6 𝐿)(100° 𝐶)
𝑉22 = = = 60 𝐿
𝑇21 96° 𝐶
Condición: 𝑇23 = 108° 𝐶
𝑉22 = 60 𝐿
𝑇22 = 100° 𝐶
𝑉22 𝑇23 (60 𝐿)(108° 𝐶)
𝑉23 = = = 64.8 𝐿
𝑇22 100° 𝐶
Condición: 𝑇24 = 114° 𝐶
𝑉23 = 64.8 𝐿
𝑇23 = 108° 𝐶
𝑉23 𝑇24 (64.8 𝐿)(114° 𝐶)
𝑉24 = = = 68.4 𝐿
𝑇23 108° 𝐶
Condición: 𝑇25 = 120° 𝐶
𝑉24 = 68.4 𝐿
 𝑇24 = 114° 𝐶
𝑉24 𝑇25 (68.4 𝐿)(120° 𝐶)
𝑉25 = = = 72 𝐿
𝑇24 114° 𝐶

Ley de Charles
80
y = 0.6x1
R² = 1
70

60

50
V (L)

40
Series1
30 Potencial (Series1)

20

10

0
0 20 40 60 80 100 120 140
T (° C)

Demostración de la ecuación de línea de tendencia

𝑉 = 0.6 ∗ 𝑇
Condición: 𝑇25 = 120° 𝐶
𝑉25 = 0.6 ∗ 120 = 72 𝐿
Condición: 𝑇21 = 96° 𝐶
𝑉21 = 0.6 ∗ 96 = 57.6 𝐿
Condición: 𝑇20 = 95° 𝐶
𝑉20 = 0.6 ∗ 95 = 57 𝐿
Condición: 𝑇15 = 79° 𝐶
𝑉15 = 0.6 ∗ 79 = 47.4 𝐿
Condición: 𝑇12 = 69° 𝐶
𝑉12 = 0.6 ∗ 69 = 41.4 𝐿
Condición: 𝑇10 = 60° 𝐶
𝑉10 = 0.6 ∗ 60 = 36 𝐿
 Condición: 𝑇9 = 54° 𝐶
𝑉9 = 0.6 ∗ 54 = 32.4 𝐿
Condición: 𝑇6 = 40° 𝐶
𝑉6 = 0.6 ∗ 40 = 24 𝐿
Condición: 𝑇4 = 31° 𝐶
𝑉4 = 0.6 ∗ 31 = 18.6 𝐿
Condición: 𝑇1 = 20° 𝐶
𝑉1 = 0.6 ∗ 20 = 12 𝐿

Ley de Charles (Inversa)

0.06

0.05
y = 0.6x-1
R² = 1
0.04
1/T (1/° C)

0.03
Series1
Potencial (Series1)
0.02

0.01

0
0 10 20 30 40 50 60 70 80
V (L)

Ejemplo de la Ley de Charles en la vida real

Un gas tiene una temperatura de 400 K y tiene un volumen 100 cm3. ¿Qué volumen
ocupará este gas a una temperatura de 310 K?

𝑉1 = 100 𝑐𝑚3
𝑇1 = 400 𝐾
𝑉2 =¿ ?
𝑇2 = 310 𝐾
𝑉1 𝑇2 (100 𝑐𝑚3 )(310 𝐾)
𝑉2 = = = 77.5 𝑐𝑚3
𝑇1 400 𝐾
Condición
T (° C) V (L) 1/T (1/° C)
1 20 12 0.05
2 25 15 0.04
3 27 16.2 0.03703704
4 31 18.6 0.03225806
5 36 21.6 0.02777778
6 40 24 0.025
7 45 27 0.02222222
8 48 28.8 0.02083333
9 54 32.4 0.01851852
10 60 36 0.01666667
11 63 37.8 0.01587302
12 69 41.4 0.01449275
13 72 43.2 0.01388889
14 75 45 0.01333333
15 79 47.4 0.01265823
16 81 48.6 0.01234568
17 84 50.4 0.01190476
18 89 53.4 0.01123596
19 92 55.2 0.01086957
20 95 57 0.01052632
21 96 57.6 0.01041667
22 100 60 0.01
23 108 64.8 0.00925926
24 114 68.4 0.00877193
25 120 72 0.00833333
LEY DE AVOGADRO
𝑉1 𝑉2 𝑉3 𝑉4 𝑉5 𝑉6 𝑉7 𝑉8 𝑉9 𝑉10
= = = = = = = = = …
𝑛1 𝑛2 𝑛3 𝑛4 𝑛5 𝑛6 𝑛7 𝑛8 𝑛9 𝑛10
𝑃 = 100 𝑎𝑡𝑚 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑇 = 36° 𝐶 (𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑒)
𝑉1 = 7 𝐿
𝑛1 = 2 𝑚𝑜𝑙𝑒𝑠
𝑉2 = 𝑖𝑛𝑐𝑜𝑔.
𝑉𝑎 𝑛𝑎+1
𝑉𝑎+1 =
𝑛𝑎
Condición: 𝑛2 = 5 𝑚𝑜𝑙𝑒𝑠
𝑉1 = 7 𝐿
𝑛1 = 2 𝑚𝑜𝑙𝑒𝑠
𝑉1 𝑛2 (7 𝐿)(5 𝑚𝑜𝑙)
𝑉2 = = = 17.5 𝐿
𝑛1 2 𝑚𝑜𝑙
Condición: 𝑛3 = 6 𝑚𝑜𝑙𝑒𝑠
𝑉2 = 17.5 𝐿
𝑛2 = 5 𝑚𝑜𝑙𝑒𝑠
𝑉2 𝑛3 (17.5 𝐿)(6 𝑚𝑜𝑙)
𝑉3 = = = 21 𝐿
𝑛2 5 𝑚𝑜𝑙
Condición: 𝑛4 = 10 𝑚𝑜𝑙𝑒𝑠
𝑉3 = 21 𝐿
𝑛3 = 6 𝑚𝑜𝑙𝑒𝑠
𝑉3 𝑛4 (21 𝐿)(10 𝑚𝑜𝑙)
𝑉4 = = = 35 𝐿
𝑛3 6 𝑚𝑜𝑙
Condición: 𝑛5 = 15 𝑚𝑜𝑙𝑒𝑠
𝑉4 = 35 𝐿
𝑛4 = 10 𝑚𝑜𝑙𝑒𝑠
𝑉4 𝑛5 (35 𝐿)(10 𝑚𝑜𝑙)
𝑉5 = = = 52.5 𝐿
𝑛4 15 𝑚𝑜𝑙
Condición: 𝑛6 = 18 𝑚𝑜𝑙𝑒𝑠
𝑉5 = 52.5 𝐿
𝑛5 = 15 𝑚𝑜𝑙𝑒𝑠
𝑉5 𝑛6 (52.5 𝐿)(18 𝑚𝑜𝑙)
𝑉6 = = = 63 𝐿
𝑛5 15 𝑚𝑜𝑙
Condición: 𝑛7 = 21 𝑚𝑜𝑙𝑒𝑠
𝑉6 = 63 𝐿
𝑛6 = 18 𝑚𝑜𝑙𝑒𝑠
𝑉6 𝑛7 (63 𝐿)(21 𝑚𝑜𝑙)
𝑉7 = = = 73.5 𝐿
𝑛6 18 𝑚𝑜𝑙
Condición: 𝑛8 = 25 𝑚𝑜𝑙𝑒𝑠
𝑉7 = 73.5 𝐿
𝑛7 = 21 𝑚𝑜𝑙𝑒𝑠
𝑉7 𝑛8 (73.5 𝐿)(25 𝑚𝑜𝑙)
𝑉8 = = = 87.5 𝐿
𝑛7 21 𝑚𝑜𝑙
Condición: 𝑛9 = 30 𝑚𝑜𝑙𝑒𝑠
𝑉8 = 87.5 𝐿
𝑛8 = 25 𝑚𝑜𝑙𝑒𝑠
𝑉1 𝑛2 (87.5 𝐿)(30 𝑚𝑜𝑙)
𝑉9 = = = 105 𝐿
𝑛1 25 𝑚𝑜𝑙
Condición: 𝑛10 = 36 𝑚𝑜𝑙𝑒𝑠
𝑉9 = 105 𝐿
𝑛9 = 30 𝑚𝑜𝑙𝑒𝑠
𝑉9 𝑛10 (105 𝐿)(36 𝑚𝑜𝑙)
𝑉10 = = = 126 𝐿
𝑛9 30 𝑚𝑜𝑙
Condición: 𝑛11 = 42 𝑚𝑜𝑙𝑒𝑠
𝑉10 = 126 𝐿
𝑛10 = 36 𝑚𝑜𝑙𝑒𝑠
𝑉10 𝑛11 (126 𝐿)(42 𝑚𝑜𝑙)
𝑉11 = = = 147 𝐿
𝑛10 36 𝑚𝑜𝑙
Condición: 𝑛12 = 45 𝑚𝑜𝑙𝑒𝑠
𝑉11 = 147 𝐿
𝑛11 = 42 𝑚𝑜𝑙𝑒𝑠
 𝑉11 𝑛12 (147 𝐿)(45 𝑚𝑜𝑙)
𝑉12 = = = 157.5 𝐿
𝑛11 42 𝑚𝑜𝑙
Condición: 𝑛13 = 50 𝑚𝑜𝑙𝑒𝑠
𝑉12 = 157.5 𝐿
𝑛12 = 45 𝑚𝑜𝑙𝑒𝑠
𝑉12 𝑛13 (157.5 𝐿)(50 𝑚𝑜𝑙)
𝑉13 = = = 175 𝐿
𝑛12 45 𝑚𝑜𝑙
Condición: 𝑛14 = 54 𝑚𝑜𝑙𝑒𝑠
𝑉13 = 175 𝐿
𝑛13 = 50 𝑚𝑜𝑙𝑒𝑠
𝑉13 𝑛14 (175 𝐿)(54 𝑚𝑜𝑙)
𝑉14 = = = 189 𝐿
𝑛13 50 𝑚𝑜𝑙
Condición: 𝑛15 = 60 𝑚𝑜𝑙𝑒𝑠
𝑉14 = 189 𝐿
𝑛14 = 54 𝑚𝑜𝑙𝑒𝑠
𝑉14 𝑛15 (189 𝐿)(60 𝑚𝑜𝑙)
𝑉15 = = = 210 𝐿
𝑛14 54 𝑚𝑜𝑙
Condición: 𝑛16 = 69 𝑚𝑜𝑙𝑒𝑠
𝑉15 = 210 𝐿
𝑛15 = 60 𝑚𝑜𝑙𝑒𝑠
𝑉15 𝑛16 (210 𝐿)(69 𝑚𝑜𝑙)
𝑉16 = = = 241.5 𝐿
𝑛15 60 𝑚𝑜𝑙
Condición: 𝑛17 = 72 𝑚𝑜𝑙𝑒𝑠
𝑉16 = 241.5 𝐿
𝑛16 = 69 𝑚𝑜𝑙𝑒𝑠
𝑉16 𝑛17 (241.5 𝐿)(72 𝑚𝑜𝑙)
𝑉17 = = = 252 𝐿
𝑛16 69 𝑚𝑜𝑙
Condición: 𝑛18 = 78 𝑚𝑜𝑙𝑒𝑠
𝑉17 = 252 𝐿
𝑛17 = 72 𝑚𝑜𝑙𝑒𝑠
𝑉17 𝑛18 (252 𝐿)(78 𝑚𝑜𝑙)
𝑉18 = = = 273 𝐿
𝑛17 72 𝑚𝑜𝑙
Condición: 𝑛19 = 81 𝑚𝑜𝑙𝑒𝑠
𝑉18 = 273 𝐿
𝑛18 = 78 𝑚𝑜𝑙𝑒𝑠
𝑉18 𝑛19 (273 𝐿)(81 𝑚𝑜𝑙)
𝑉19 = = = 283.5 𝐿
𝑛18 78 𝑚𝑜𝑙
Condición: 𝑛20 = 90 𝑚𝑜𝑙𝑒𝑠
𝑉19 = 283.5 𝐿
𝑛19 = 81 𝑚𝑜𝑙𝑒𝑠
𝑉19 𝑛20 (283.5 𝐿)(90 𝑚𝑜𝑙)
𝑉20 = = = 315 𝐿
𝑛19 81 𝑚𝑜𝑙
Condición: 𝑛21 = 96 𝑚𝑜𝑙𝑒𝑠
𝑉20 = 315 𝐿
𝑛20 = 90 𝑚𝑜𝑙𝑒𝑠
𝑉20 𝑛21 (315 𝐿)(96 𝑚𝑜𝑙)
𝑉21 = = = 336 𝐿
𝑛20 90 𝑚𝑜𝑙
Condición: 𝑛22 = 102 𝑚𝑜𝑙𝑒𝑠
𝑉21 = 336 𝐿
𝑛21 = 96 𝑚𝑜𝑙𝑒𝑠
𝑉21 𝑛22 (336 𝐿)(102 𝑚𝑜𝑙)
𝑉22 = = = 357 𝐿
𝑛21 96 𝑚𝑜𝑙
Condición: 𝑛23 = 108 𝑚𝑜𝑙𝑒𝑠
𝑉22 = 357 𝐿
𝑛22 = 102 𝑚𝑜𝑙𝑒𝑠
𝑉22 𝑛23 (357 𝐿)(108 𝑚𝑜𝑙)
𝑉23 = = = 378 𝐿
𝑛22 102 𝑚𝑜𝑙
Condición: 𝑛24 = 117 𝑚𝑜𝑙𝑒𝑠
𝑉23 = 378 𝐿
𝑛23 = 108 𝑚𝑜𝑙𝑒𝑠
𝑉23 𝑛24 (378 𝐿)(117 𝑚𝑜𝑙)
𝑉24 = = = 409.5 𝐿
𝑛23 108 𝑚𝑜𝑙
Condición: 𝑛25 = 126 𝑚𝑜𝑙𝑒𝑠
𝑉24 = 409.5 𝐿
𝑛24 = 117 𝑚𝑜𝑙𝑒𝑠
𝑉24 𝑛25 (409.5 𝐿)(126 𝑚𝑜𝑙)
𝑉25 = = = 441 𝐿
𝑛24 117 𝑚𝑜𝑙

Ley de Avogadro
500
y = 3.5x
450
R² = 1
400

350

300
V (L)

250
Series1
200
Lineal (Series1)
150

100

50

0
0 20 40 60 80 100 120 140
n (mol)

Demostración de la ecuación de línea de tendencia

𝑉 = 3.5 ∗ 𝑛
Condición: 𝑛25 = 126 𝑚𝑜𝑙
𝑉25 = 3.5 ∗ 126 = 441 𝐿
Condición: 𝑛21 = 96 𝑚𝑜𝑙
𝑉21 = 3.5 ∗ 96 = 336 𝐿
Condición: 𝑛20 = 90 𝑚𝑜𝑙
𝑉20 = 3.5 ∗ 90 = 315 𝐿
Condición: 𝑛15 = 60 𝑚𝑜𝑙
𝑉15 = 3.5 ∗ 60 = 210 𝐿
Condición: 𝑛12 = 45 𝑚𝑜𝑙
𝑉12 = 3.5 ∗ 45 = 157.5 𝐿
Condición: 𝑛10 = 36 𝑚𝑜𝑙
𝑉10 = 3.5 ∗ 36 = 126 𝐿
Condición: 𝑛9 = 30 𝑚𝑜𝑙
𝑉9 = 3.5 ∗ 30 = 105 𝐿
Condición: 𝑛6 = 18 𝑚𝑜𝑙
𝑉6 = 3.5 ∗ 18 = 63 𝐿
Condición: 𝑛4 = 10 𝑚𝑜𝑙
𝑉4 = 3.5 ∗ 10 = 35 𝐿
Condición: 𝑛1 = 2 𝑚𝑜𝑙
𝑉1 = 3.5 ∗ 2 = 7 𝐿

Ley de Avogadro (Inversa)

0.6

0.5
y = 3.5x-1
R² = 1
0.4
1/n (1/mol)

0.3
Series1
Potencial (Series1)
0.2

0.1

0
0 100 200 300 400 500
V (L)
Condición n (mol) V (L) 1/n (1/mol)
1 2 7 0.5
2 5 17.5 0.2
3 6 21 0.16666667
4 10 35 0.1
5 15 52.5 0.06666667
6 18 63 0.05555556
7 21 73.5 0.04761905
8 25 87.5 0.04
9 30 105 0.03333333
10 36 126 0.02777778
11 42 147 0.02380952
12 45 157.5 0.02222222
13 50 175 0.02
14 54 189 0.01851852
15 60 210 0.01666667
16 69 241.5 0.01449275
17 72 252 0.01388889
18 78 273 0.01282051
19 81 283.5 0.01234568
20 90 315 0.01111111
21 96 336 0.01041667
22 102 357 0.00980392
23 108 378 0.00925926
24 117 409.5 0.00854701
25 126 441 0.00793651