DIAGRAMA DE DISTRIBUCIÓN DE ESPEC

CT= H3PO4 +H2PO4 + HPO4˭ + PO4Ξ

K1 = 7.50E-03
K2 = 6.20E-08
K3 = 3.60E-13

pH H3O⁺ n α H3PO4 α H2PO4 α HPO4 α PO4≡ sumatoria

0.5 0.31622777 0.03237278 0.97683238 0.02316761 1.4364E-09 5.1710115E-21 0.9999999969
1 0.1 0.001075 0.93023252 0.06976744 4.3256E-08 1.5572092E-19 1
1.5 0.03162278 3.9123E-05 0.80829551 0.19170411 3.7586E-07 4.2788358E-18 1
2 0.01 1.75E-06 0.57142705 0.42857029 2.6571E-06 9.5656889E-17 1
2.5 0.00316228 1.0662E-07 0.29658148 0.70340473 1.3791E-05 1.5699994E-15 1
3 0.001 8.5005E-09 0.11764062 0.88230467 5.4703E-05 1.969304E-14 1
3.5 0.00031623 7.8177E-10 0.04045024 0.95936167 0.00018809 2.1412952E-13 1
4 0.0001 7.6047E-11 0.01314985 0.98623868 0.00061147 2.2012847E-12 1
4.5 3.1623E-05 7.5463E-12 0.00419049 0.99386094 0.00194858 2.2182976E-11 1
5 0.00001 7.5565E-13 0.00132336 0.99252299 0.00615364 2.2153113E-10 1
5.5 3.1623E-06 7.6502E-14 0.00041336 0.98036547 0.01922116 2.1881757E-09 1
6 0.000001 7.966E-15 0.00012553 0.94150136 0.05837308 2.101431E-08 1
6.5 3.1623E-07 8.9708E-16 3.5251E-05 0.83604798 0.16391658 1.8660591E-07 1
7 0.0000001 1.215E-16 8.2304E-06 0.61727802 0.38271237 1.3777645E-06 1
7.5 3.1623E-08 2.2205E-17 1.4241E-06 0.33776496 0.66222608 7.5389139E-06 1
8 0.00000001 5.4002E-18 1.8518E-07 0.13888456 0.86108426 3.0999033E-05 1
8.5 3.1623E-09 1.5456E-18 2.046E-08 0.04852401 0.95136766 0.0001083056 1
9 1E-09 4.7267E-19 2.1157E-09 0.01586739 0.98377844 0.0003541602 1
9.5 3.1623E-10 1.4796E-19 2.1372E-10 0.00506882 0.99379981 0.0011313615 1
10 1E-10 4.6742E-20 2.1394E-11 0.00160454 0.99481413 0.0035813309 1
10.5 3.1623E-11 1.4879E-20 2.1253E-12 0.00050405 0.98824557 0.0112503848 1
11 1E-11 4.8182E-21 2.0755E-13 0.00015566 0.96510071 0.0347436257 1
11.5 3.1623E-12 1.6379E-21 1.9307E-14 4.5789E-05 0.8977523 0.1022019132 1
12 1E-12 6.3241E-22 1.5813E-15 1.1859E-05 0.7352854 0.2647027431 1
12.5 3.1623E-13 3.1445E-22 1.0057E-16 2.3851E-06 0.46763388 0.5323637381 1
13 1E-13 2.139E-22 4.6751E-18 3.5063E-07 0.21739123 0.7826084212 1
13.5 3.1623E-14 1.821E-22 1.7365E-19 4.1185E-08 0.08074805 0.9192519094 1
14 1E-14 1.7205E-22 5.8123E-21 4.3592E-09 0.02702703 0.9729729687 1

α H3PO4 (H₃O⁺)³/ n ácido sin desprotonar - alfa 0

α H2PO4 k1(H₃O⁺)² /n ácido monobásico - alfa 1

α HPO4 (k1)(k2) (H₃O⁺)/n ácido dibásico - alfa 2

α PO4≡ (k1)(k2(k3) /n fracción del fosfato - alfa 3

DIAGRAMA DE DISTRIBUCIÓN D

CT= H4Y +H3Y + H2Y + HY

K1 = 1.02E-02
K2 = 2.14E-03
K3 = 6.92E-07
K4 = 5.50E-11

pH H⁺ n α H4Y α H3 Y α H2Y α HY αY
0.5 0.31622777 0.01032474 0.96854785 0.03124074 0.00021141 4.6263781E-10 8.0464406E-20
1 0.1 0.00011042 0.90564713 0.09237601 0.00197685 1.3679778E-08 7.523878E-18
1.5 0.03162278 1.3444E-06 0.74383687 0.23992631 0.01623647 3.5530207E-07 6.1796009E-16
2 0.01 2.2383E-08 0.44676861 0.45570399 0.09752065 6.7484292E-06 3.711636E-14
2.5 0.00316228 6.4088E-10 0.15603543 0.5032959 0.34059414 7.4532083E-05 1.2963013E-12
3 0.001 3.3043E-11 0.0302635 0.3086877 0.66059167 0.0004571294 2.5142119E-11
3.5 0.00031623 2.5201E-12 0.00396805 0.1279904 0.86614616 0.0018953843 3.2965523E-10
4 0.0001 2.3009E-13 0.00043461 0.04433038 0.9486702 0.0065647978 3.6106388E-09
4.5 3.1623E-05 2.2629E-14 4.4191E-05 0.0142538 0.9645938 0.021108169 3.671244E-08
5 0.00001 2.3441E-15 4.2661E-06 0.00435142 0.9312046 0.0644393582 3.5441647E-07
5.5 3.1623E-06 2.6637E-16 3.7542E-07 0.00121092 0.81946285 0.1793227386 3.1188756E-06
6 0.000001 3.6944E-17 2.7068E-08 0.00027609 0.59084007 0.4088613258 2.2487373E-05
6.5 3.1623E-07 6.9606E-18 1.4367E-09 4.634E-05 0.31359518 0.6862391236 0.0001193543
7 0.0000001 1.7296E-18 5.7816E-11 5.8973E-06 0.12620123 0.8733125458 0.0004803219
7.5 3.1623E-08 5.0032E-19 1.9987E-12 6.4469E-07 0.04362805 0.9547108268 0.0016604834
8 0.00000001 1.5406E-19 6.4908E-14 6.6207E-08 0.0141682 0.9804393193 0.0053924163
8.5 3.1623E-09 4.8815E-20 2.0485E-15 6.6076E-09 0.00447156 0.9785096776 0.0170187561
9 1E-09 1.5958E-20 6.2666E-17 6.3919E-10 0.00136788 0.9465707323 0.0520613903
9.5 3.1623E-10 5.6096E-21 1.7827E-18 5.75E-11 0.00038912 0.8515115089 0.1480993702
10 1E-10 2.3415E-21 4.2708E-20 4.3562E-12 9.3223E-05 0.6451011466 0.3548056307
10.5 3.1623E-11 1.3085E-21 7.6426E-22 2.4651E-13 1.6682E-05 0.3650569781 0.6349263396
 11 1E-11 9.8183E-22 1.0185E-23 1.0389E-14 2.2232E-06 0.1538458118 0.846151965
11.5 3.1623E-12 8.7854E-22 1.1383E-25 3.6715E-16 2.4846E-07 0.0543698941 0.9456298575
12 1E-12 8.4588E-22 1.1822E-27 1.2058E-17 2.5805E-08 0.0178571424 0.9821428318
12.5 3.1623E-13 8.3555E-22 1.1968E-29 3.8604E-19 2.6124E-09 0.0057167269 0.9942832705
13 1E-13 8.3228E-22 1.2015E-31 1.2255E-20 2.6227E-10 0.001814882 0.9981851177
13.5 3.1623E-14 8.3125E-22 1.203E-33 3.8803E-22 2.6259E-11 0.0005746292 0.9994253708
14 1E-14 8.3092E-22 1.2035E-35 1.2275E-23 2.627E-12 0.0001817851 0.9998182149

α H 4Y (H⁺)⁴/ n alfa 0

α H 3Y k1(H⁺)³/n alfa 1

α H 2Y (k1)(k2) (H⁺)²/n alfa 2

α HY (k1)(k2(k3) (H⁺)/n alfa 3

αY (k1)(k2(k3)(k4) /n alfa 4
DE DISTRIBUCIÓN DE ESPECIES DE ÁCIDO TETRAPROTICO

pH Valor que oscila entre 0,5 y 14

H₃O⁺ concentración de hidronios en función del pH, 10 elevado al valor del pH

k1;k2;k3 constantes de acidez

n (H₃O⁺)³ + k1 (H₃O⁺)²+(k1) (k2) (H₃O⁺)+(k1)(k2)(k3)

(H 3O  )3
 0  H 3 PO 4 =
n

B1 (H 3O  ) 2
1  H 2 PO 4 =
n
B2 (H 3O  )
 2  HPO4 =
n
 B3
 3  PO 4 =
n

n  (H 3O  ) 3  ( H 3O  ) 2 B1  ( H 3O  ) B2  B3

Gráfica de especies de fosfato

1.2

0.8
α Fosfatos

0.6

0.4

0.2

0
0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13
pH

α H3PO4 α H2PO4 α HPO4 α PO4≡

 α
0.4

0.2

0
0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13
pH

α H3PO4 α H2PO4 α HPO4 α PO4≡

GRAMA DE DISTRIBUCIÓN DE ESPECIES DEL EDTA

pH Valor que oscila entre 0,5 y 14

H₃O⁺ concentración de hidronios en función del pH, 10 elevado al valor del pH

k1;k2;k3;K4 constantes de acidez

n (H⁺)⁴ + k1 (H⁺)³+(k1)(k2) (H⁺)²+(k1)(k2)(K3) (H⁺)+(k1)(k2)(k3)(K4)

Sumatoria
1
1
1
1 [H  ]4
1 0 
1
n
1
K1[ H  ]3
1 1 
n
1
1 K1K 2 [H  ]2
1 2 =
n
1
1 K1K 2 K 3 [H  ]
1 3 
n
1
1 K 1K 2 K 3 K 4
1 4 
n
1
1
n  [H  ]4  K1[H  ]3  K1 K 2 [H  ]2  K1 K 2 K 3 [H  ]  K1 K 2 K 3 K 4
1
1
1
1
1 Gráfica de especies de EDT
1 1.2
1
1 1
1
0.8

0.6

α
0.4

0.2

0
0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 1
pH

α H4Y α H3Y α H2Y α HY

osfato

.5 10 10.5 11 11.5 12 12.5 13 13.5 14

PO4≡
.5 10 10.5 11 11.5 12 12.5 13 13.5 14

PO4≡

vado al valor del pH

2)(k3)(K4)

 K1 K 2 K 3 K 4
fica de especies de EDTA

6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13 13.5 14

pH

α H2Y α HY αY