Masa Volumen Concentraciones

Masas molares Dilución

Compuesto experiment de solución experimental
(g/mol) (mol/l) (mol/l)
al (ml)

tiosulfato de sodio 158.1000 4.3074

250 0.1089802498992
tiosulfato de sodio
248.1000 6.7595
pentahidratado
persulfato de
270.3200 7.1646 0.106016572951 0.04240663
potasio 250

Yoduro de potasio 166.0028 8.3478 0.201148414364 0.08045937

250
Temperatura
30.0000
ambiente (°C)

V persulfato (ml) 50 0.05

V Yoduro (ml) 50 0.05
V Alicuota (ml) 10 0.01
V mezcla 100 0.1
 Para 30 °C
V
Moles 0
LnK vs 1/T
N° de Tiempo tiosianato V tiosianato
iniciales de KI moles 0.0032
0.0031 KI (mol) 0.0033
tiempo (seg)
0.0034 0.0035
muestras (min) en real(ml)
(mol) -1
bureta(ml) -2
1 0 0.5 0.5 0.0010057421
-3 5.449012495E-05 0
-4
2 5.15 1.2 0.7 0.0010057421
-5 7.6286174929E-05 309
-6
3 10.15 2.3 1.1 0.0010057421
-7 0.00011987827489 609
f(x) = − 4885.15247664974 x + 9.0193166654
-8 R² = 0.94898496714474
4 15.15 3.6 1.3 0.0010057421
-9 0.00014167432487 909
5 20.15 5.2 1.6 -10 0.00017436839984
0.0010057421 1209
6 25.15 7 1.8 0.0010057421 0.00019616444982 1509

Para 4°C
V
Moles
N° de Tiempo tiosianato V tiosianato
iniciales de KI moles KI (mol) tiempo (seg)
muestras (min) en real(ml)
(mol)
bureta(ml)
1 0 0.1 0.1 0.0004022968 1.089802499E-05 0
2 10 0.3 0.3 0.0004022968 3.269407497E-05 600
3 20 0.5 0.2 0.0004022968 2.179604998E-05 1200
4 30 1.1 0.6 0.0004022968 6.538814994E-05 1800
5 40 2.1 1 0.0004022968 0.0001089802499 2400
6 50 2.4 0.3 0.0004022968 3.269407497E-05 3000
7 60 3 0.6 0.0004022968 6.538814994E-05 3600
8 70 3.7 0.7 0.0004022968 7.6286174929E-05 4200
9 80 4.8 1.1 0.0004022968 0.00011987827489 4800

Para 40°C
V
Moles
N° de Tiempo tiosianato V tiosianato
iniciales de KI moles KI (mol) tiempo (seg)
muestras (min) en real(ml)
(mol)
bureta(ml)
1 0 0.3 0.1 0.0004022968 1.089802499E-05 0
2 5 1.1 0.8 0.0004022968 8.7184199919E-05 300
3 10 2.2 1.1 0.0004022968 0.00011987827489 600
4 15 3.6 1.4 0.0004022968 0.00015257234986 900
5 20 5.2 1.6 0.0004022968 0.00017436839984 1200
6 25 7.2 2 0.0004022968 0.0002179604998 1500
 V
Moles
N° de Tiempo tiosianato V tiosianato
iniciales de KI moles KI (mol) tiempo (seg)
muestras (min) en real(ml)
(mol)
bureta(ml)
1 0 0.2 0.2 0.0004022968 2.179604998E-05 0
2 10 0.8 0.3 0.0004022968 3.269407497E-05 600
3 20 1.7 0.9 0.0004022968 9.8082224909E-05 1200
4 30 2.9 1.2 0.0004022968 0.00013077629988 1800
5 40 4.4 1.5 0.0004022968 0.00016347037485 2400
6 50 6 1.6 0.0004022968 0.00017436839984 3000
7 60 7.7 1.7 0.0004022968 0.00018526642483 3600
8 70 9.6 1.9 0.0004022968 0.00020706247481 4200
LnK vs 1/T
3 0.0034 (a-nI)
0.0035 (a-nI)mmol
0.0036 0.00371/(a-nI) K (1/M.S)

0.0009512519 0.9512519469 1.0512462059

m 0.00012601 1.04643579

0.0009294559 0.9294558969 1.0758982791

7.98E-05 5.27307E-06 0.00482872

5247664974 x0.0008858638 0.8858637969 1.1288417062

+ 9.01931666541861 1.76E-04 0.99304455 0.00664609
96714474
0.0008640677 0.864067747 1.1573166613
9.49E-05
0.0008313737 0.831373672 1.202828564 1.52E-04 40615.1577
0.0008095776 0.809577622 1.2352120079 1.08E-04 40.6151577
prom. 1.22E-04

(a-nI) (a-nI)mmol 1/(a-nI) K (1/M.S) Y X

0.0003913988 0.3913988037 2.5549388257 1 2.55493883 0

0.0003696028 0.3696027538 2.7056075471 2.51E-04 2 2.70560755 600
0.0003805008 0.3805007787 2.6281155147 -1.29E-04 34 2.62811551 1200
0.0003369087 0.3369086788 2.9681633717 5.67E-04 4 2.96816337 1800
0.0002933166 0.2933165788 3.4092856394 7.35E-04 6 2.70560755 3000
0.0003696028 0.3696027538 2.7056075471 -1.17E-03 7 2.96816337 3600
0.0003369087 0.3369086788 2.9681633717 4.38E-04 8 3.06738442 4200
0.0003260107 0.3260106538 3.0673844193 1.65E-04 9 3.54084385 4800
0.0002824186 0.2824185538 3.5408438518 7.89E-04
prom. 2.05E-04

(a-nI) (a-nI)mmol 1/(a-nI) K (1/M.S)

0.0003913988 0.3913988037 2.5549388257 m 0.0017576

0.0003151126 0.3151126288 3.1734684953 2.06E-03 0.00015825
0.0002824186 0.2824185538 3.5408438518 1.22E-03 0.96859206
0.0002497245 0.2497244789 4.0044132018 1.55E-03
0.0002279284 0.2279284289 4.3873421357 1.28E-03
0.0001843363 0.1843363289 5.4248666327 3.46E-03
 prom. 1.91E-03

(a-nI) (a-nI)mmol 1/(a-nI) K (1/M.S)

0.0003805008 0.3805007787 2.6281155147 0.00061057 2.54381546

0.0003696028 0.3696027538 2.7056075471 1.29E-04 3.33143E-05 0.08361822
0.0003042146 0.3042146038 3.2871531723 9.69E-04 0.98245073 0.12954079
0.0002715205 0.2715205288 3.6829627735 6.60E-04
0.0002388265 0.2388264539 4.1871408454 8.40E-04
0.0002279284 0.2279284289 4.3873421357 3.34E-04
0.0002170304 0.2170304039 4.6076493525 3.67E-04
0.0001952344 0.1952343539 5.1220493726 8.57E-04
prom. 5.94E-04
 1.25
f(x) = 0.00012601
1.2 R² = 0.993044550
LnK T 1/T Y X

1.15
-6.34380445 313.15 0.00319336 -6.34380445 0.00319336

1.1
-7.40112531 303.15 0.0032987 -8.97912615 0.0032987

1.05
-8.79630274 273.15 0.00366099 -8.79630274 0.00366099

-4885.15248 9.01931667
0.95
1132.65473 3.84000576 0 200
0.94898497 0.39292724

m 0.00015129 2.58669064 40 -6.34380445 4

5.51101E-05 0.1574258 30 -8.97912615
3.5
0.51845191 0.25612838 0 -8.79630274
3 f(x) = 0.0001512914058
R² = 0.51845190948848
0.00015129 2.52925368 -3762.06029 4.6923805 2.5
4.13585E-05 0.12029562 4672.82199 15.8421299 2
0.69042369 0.19221688 0.39326873 1.62104038
1.5
1
31277.7693
31.2777693 0.5
0
0 1000 2

Para 40 °C
6
2.52944343
5 f(x) = 0.00175760279106517 x + 2.52944343054245
0.14373646
R² = 0.968592064251111
0.19860046 4

0
0 200 400 600 800 1000 1200 1400 1600
 4

0
0 200 400 600 800 1000 1200 1400 1600

para 30 tiempo 10min

6

5
f(x) = 0.000610565297500968 x + 2.54381546448357
R² = 0.982450729220116
4

0
0 500 1000 1500 2000 2500 3000 3500 4000 4500
 Ki vs t
1.25
f(x) = 0.00012601291553463 x + 1.04643578720799
1.2 R² = 0.993044550503048
-6.34380445

1.15
-8.97912615

1.1

1.05

0.95
0 200 400 600 800 1000 1200 1400 1600

-4.6
Para 4°C 0.0031
-4.8
0.0032

4 -5

3.5 -5.2
f(x) = 0.000151291405848654 x + 2.58669063581552 -5.4 f(x)
3
R² = 0.51845190948848 R² =
-5.6
2.5
-5.8
2
-6
0
1.5 -6.2
1 -6.4
0.5
0
0 1000 2000 3000 4000 5000 6000

1200 1400 1600

1200 1400 1600

4000 4500
 0.00319336 K T log K/T 1/T

0.0032987 0.0017576 313.15 -5.2508316825 0.00319336 m

0.00061057 303.15 -5.6959254558 0.0032987

0.00015129 273.15 -6.2565869463 0.00366099

Log K/T vs 1/T

-4.6
0.0031 0.0032 0.0033 0.0034 0.0035 0.0036 0.0037
-4.8
-5
-5.2
-5.4 f(x) = − 1995.19304781726 x + 1.0179815409206
-5.6 R² = 0.943055382265574

-5.8
-6
-6.2
-6.4
 (Kj/mol)

-1995.19305 1.01798154 DH 16588.035 16.588035

490.278292 1.66217597 DS -77.3277648 -0.07732776

0.94305538 0.17008157
 V
V Moles
N° de Tiempo tiosianato moles KI tiempo
tiosianato iniciales de (a-nI)
muestras (min) en (mol) (seg)
real(ml) KI (mol)
bureta(ml)
1 0 0.1 0.1 0.0004023 8.045937E-06 0 0.00039425
2 10 0.3 0.3 0.0004023 1.20689E-07 600 0.00040218
3 20 0.5 0.2 0.0004023 8.045937E-08 1200 0.00040222
4 30 1.1 0.6 0.0004023 2.413781E-07 1800 0.00040206
5 40 2.1 1 0.0004023 4.022968E-07 2400 0.00040189
6 50 2.4 0.3 0.0004023 1.20689E-07 3000 0.00040218
7 60 3 0.6 0.0004023 2.413781E-07 3600 0.00040206
8 70 3.7 0.7 0.0004023 2.816078E-07 4200 0.00040202
9 80 4.8 1.1 0.0004023 4.425265E-07 4800 0.00040185

0.08045937 para 4
2.489
2.4885
2.488
f(x) = 3.65421063331258E-07 x + 2.4862327094998
2.4875 R² = 0.428838176549967
2.487
2.4865
2.486
2.4855
2.485
0 1000 2000 3000 4000 5000 60
 (a-nI)mmol 1/(a-nI) K (1/M.S)

0.39425089 2.5364559
0.40217614 2.48647272 -8.33E-05
0.40221637 2.48622402 -4.14E-07
0.40205545 2.48721911 1.66E-06
0.40189453 2.48821499 1.66E-06
0.40217614 2.48647272 -2.90E-06
0.40205545 2.48721911 1.24E-06
0.40201522 2.48746801 4.15E-07
0.4018543 2.48846409 1.66E-06 3.6542106E-07 2.486232709
prom. -1.00E-05 1.7216736E-07 0.000521642
0.4288381766 0.000669463

-14.8222156

2.4862327094998

4000 5000 6000