A

NOMBRE BENCENO
FORMULA C6H6
TEMPERATURA 65.82 °C
TEMPERATURA 338.97 K
PM 78.113 [kg/kmol]
A 155.6259
B -0.2710512
C 0.000675
Cp 141.3056 J/mol . K kJ/kmol . K
Cp 1808.9895 J/mol . K
CP 1.809 KJ/kg.k

T DE VAPOR 96.6288 °C
T DE VAPOR 369.7788 K
λb 30.761 [kJ/mol]
Tb 353.3 [K]
Tc 562 [K]
λ 29.8144 KJ/kmol
λ 381.6829 KJ/Kg

Cpv a

Peso CALOR ESPECÍFICO

Fórmula
NOMBRE DEL COMPUESTO Molecular Constantes para el C
global
[kg/kmol] A
TETRACLORURO DE CARBONO CCL4 153.823 139.7338
TETRAFLUORURO DE CARBONO CF4 88.005 86.44433
MONOXIDO DE CARBONO CO 28.01 61.53487
DIOXIDO DE CARBONO CO2 44.01 98.63061
SULFURO DE CARBONILO COS 60.07 71.81666
DISULFURO DE CARBONO CS2 76.131 68.39258
CLOROFORMO CHCL3 119.377 110.5378
DICLOROFLUOROMETANO CHCL2F 102.923 98.07049
TRIFLUOROMETANO CHF3 70.014 79.87337
TRIYODOMETANO CHI3 393.732 194.6557
 DICLOROMETANO CH2CL2 84.933 117.1086
CLOROFLUOROMETANO CH2CLF 68.478 86.91451
DIFLUOROMETANO CH2F2 52.024 70.30925
FORMALDEHIDO CH2O 30.026 77.73247
BROMOMETANO CH3BR 94.939 101.7486
CLOROMETANO CH3CL 50.488 72.76645
FLUOROMETANO CH3F 34.033 64.32159
NITROMETANO CH3NO2 61.04 114.6402
METANO CH4 16.043 54.87106
METANOL CH4O 32.042 74.86274
TETRACLOROETENO C2CL4 165.834 145.6195
CLOROETENO C2H3CL 62.499 69.85845
ETILENO C2H4 28.054 62.89727
BROMOETANO C2H5BR 108.966 89.6772
CLOROETANO C2H5CL 64.514 95.86747
ETANO C2H6 30.069 66.3402
PROPANO C3H6 42.08 82.1637
CICLOPROPANO C3H6 42.08 76.03351
ACETONA C3H6O 58.08 117.8108
PROPANO C3H8 44.096 87.31411
BUTANO C4H10 58.123 120.0291
CICLOPENTANO C5H8 68.118 103.1864
CICLOPENTANO C5H10 70.134 116.2369
PENTANO C5H12 72.15 143.6066
HEXACLOROBENZENO C6CL6 284.784
HEXAFLUOROBENZENO C6F6 186.056
BROMOBENZENO C6H5BR 157.01 158.5244
CLOROBENZENO C6H5CL 112.558 150.4141
FLUOROBENZENO C6H5F 96.104 151.1213
IODOBENZENO C6H5I 204.01 160.6757
BENCENO C6H6 78.113 155.6259
FENOL C6H6O 94.113 207.4793
ANILINA C6H7N 93.128 206.272
1-HEXENO C6H12 84.161 157.713
CICLOHEXANO C6H12 84.161 178.9841
HEXANO C6H14 86.177 181.7722
TOLUENO C7H8 92.14 147.0419
HEPTANO C7H16 100.203 211.9577
OCTANO C8H18 114.23 256.3503
ETANOL C2H6O 46.069 100.922
AGUA H2O 18.02 103.08
ACIDO ACETICO C2H4O2 60.052 155.4802
 B
NOMBRE TOLUENO
FORMULA C7H8
TEMPERATURA 65.82 °C
TEMPERATURA 338.97 K
PM 92.14 [kg/kmol]
A 147.0419
B -0.1140537
C 0.00049
Cp 164.6824 J/mol . K kJ/kmol . K
Cp 1787.3063 J/mol . K
CP 1.7873 KJ/kg.k

T DE VAPOR 96.6288 °C
T DE VAPOR 369.7788 K
λb 33.179 [kJ/mol]
Tb 383.7 [K]
Tc 593.1 [K]
λ 34.0005 KJ/kmol
λ 369.0091 KJ/Kg

CALOR LATENTE
CALOR ESPECÍFICO DEL LÍQUIDO: CpL
VAPORIZACION Hvap = λ
Constantes para el CPL λb a Tb
Tmín [K] Tmáx [K] Tb [K]
B C [kJ/mol]
-0.2045003 5.87E-04 250 379.84 29.999 349.8
-0.0761166 8.45E-0.4 86.4 175.15 11.966 145.2
-0.1769687 2.05E-03 68.1 111.61 6.042 81.6
-0.2941525 9.33E-04 216.56 258.57 15.326 216.6
-0.0295 2.38E-04 134.3 252.91 20.887 222.9
-0.0457 2.43E-04 161.3 349 26.736 319
-0.1215667 4.41E-04 209.6 364.33 29.706 334.3
-0.0261 2.22E-04 138 312.07 24.937 282.1
-0.0537 4.71E-04 110 221 16.694 191
-0.0915083 1.86E-04 396.16 521.16 42.359 491.2
-0.1496366 6.16E-04 178.1 343.15 27.991 313.2
-0.036 2.66E-04 140.16 294.06 22.744 264.1
-0.0251 2.87E-04 101.71 251.49 20.476 221.5
-0.0567 3.24E-04 156 279.55 23.012 249.6
-0.046 2.50E-04 179.5 307.5 23.912 277.5
-0.044 2.29E-04 175.4 279.15 21.422 249.2
-0.0529 3.65E-04 131.4 224.79 16.677 194.8
-0.1749068 4.96E-04 244.6 403.99 34.413 374
-0.0947 8.59E-04 90.7 141.62 8.18 111.6
-0.102315 4.07E-04 175.5 367.77 35.254 337.8
-0.1795366 5.12E-04 251 424.22 34.727 394.2
-0.0162 1.77E-04 119.4 289.4 22.263 259.4
-0.038 3.79E-04 104 199.39 13.544 169.4
-0.0596 3.32E-04 154.6 341.73 26.485 311.7
-0.0227 2.03E-04 136.8 315.5 24.686 285.5
-0.0209 3.04E-04 89.9 214.63 14.707 184.6
-0.0128 2.50E-04 87.9 255.65 18.41 225.7
-0.033698 2.38E-04 145.7 270.29 20.041 240.3
-0.1592447 6.34E-04 178.2 359.35 29.121 329.4
-0.0124 2.59E-04 85.5 261.14 18.774 231.1
-0.0378 3.09E-04 134.8 302.98 22.393 273
-0.0742 4.39E-04 138.1 347.38 26.987 317.4
-0.1220498 5.20E-04 179.3 352.41 27.296 322.4
-0.1447664 7.62E-04 143.4 339.22 25.773 309.2
63.593 582.6
31.677 353.4
-0.144351 4.40E-04 242.3 459.1 42.501 429.1
-0.142546 4.64E-04 227.6 435.06 36.547 405.1
-0.2053858 6.31E-04 234 388.05 33.388 358.1
-0.119998 3.73E-04 241.8 491.57 39.497 461.6
-0.2710512 6.75E-04 278.7 383.31 30.761 353.3
-0.1037491 2.74E-04 314 484.89 45.606 454.9
-0.2115065 5.64E-04 267 487.2 41.84 457.2
-0.1157768 6.79E-04 133.3 367.91 28.284 337.9
-0.3215673 7.97E-04 279.6 383.9 29.957 353.9
-0.2155013 8.76E-04 177.8 371.93 28.853 341.9
-0.1140537 4.90E-04 178 413.73 33.179 383.7
-0.2299336 9.03E-04 182.6 401.56 31.698 371.6
-0.3221647 1.04E-03 216.4 428.77 34.413 398.8
-0.1118386 4.99E-04 159.1 381.45 38.744 351.5
-0.1748 2.75E-04 273.15 423.15 40.669 373.15
-0.3265951 7.44E-04 289.8 421.29 23.681 391.3
J/kmol . K

OR LATENTE
HALLAR ENTALPIAS
CION Hvap = λ
X (FRACCCION) 0.98 a) constantes para determinar elcalor espe
Tc [K]
Ec. Cuadrática
TEMPERATURA 1 para el calor T: Temperatura [K]
56.2644 com
556.5 especifico
TEMP REF / OTRAde líquidos: CpL0: calor especifico del líquido [J/mol.K]
227.5 + CT 2
CPL = A + BTcp/λ A, B, C: constantes del Cp
133.4 A 127.3812 Rango: Tmin a Tmax [K]
304.2 Ec. Bde Watson para el 112.5617
calor latente T:Temperatura [K]
378 de vaporización:
SOLUCION 7150.3506 Tc: Temperatura critica [K]
552 Tc−T 0.38
Tb: Temperatura de ebullición normal [K]
λ = λ𝑏 ቂ ቃ
535.5 Tc−Tb
λb: Calor latente de vaporización normal [kJ/mol]
451.6 HALLA ENTALPIA DE VAPOR λ: Calor latente de vaporización [kJ/mol]
299.1 X FRACCION Rango: Tf a Tc [K]
0.98
794.6 Ec. De Riedel (ER), es usado para el Tc: Temperatura critica [K]
TEMPERATURA 1 56.3646
cálculo de λb en casos que no se Tb: Temperatura de ebullición normal [K]
disponga el valor del calor latente de Pc: Presión critica [bar]
vaporización normal: R= 0.008314 kJ/mol.K
 λb: Calor latente de vaporización normal [kJ/mol]
λ: Calor latente de vaporización [kJ/mol]
Rango: Tf a Tc [K]
Ec. De Riedel (ER), es usado para el Tc: Temperatura critica [K]
508.3 cálculo
TEMP REFde/λOTRA
b en casos que no se Tb:0 Temperatura de ebullición normal [K]
424.9 disponga el valor del calor
cp latenteλ de Pc: Presión critica [bar]
351.5 A vaporización normal: R= 0.008314 kJ/mol.K
127.3937 29113.9139
4022.7 Ln(Pc )−1.013
B λ = 1.093RTb ቈ 112.5312቉ 40637.7948 (En la tabla, el uso de esta alternativa se
b Tb
464 SOLUCION 0.930−
36508.1321
Tc identifica con ER)
416.2
317.9
588
190.7
513
620.2
425
282.8
505.7
460.4
305.4
365
398
508.4
369.7
425.6
506
511.8
470
825.8
516.6
670.1
632.6
559.8
721.1
562
692.9
698.9
508.5
553.5
507.9
593.1
540.1
569.1
515.8
647.3
594.4
 ANEXO 12

terminar elcalor especifico de liquidos y el calor latente de vaporizacion de

compuestos puros
do [J/mol.K]

ón normal [K]
ción normal [kJ/mol]
ión [kJ/mol]

ón normal [K]
ción normal [kJ/mol]
ión [kJ/mol]

ón normal [K]

ternativa se
 DESTILACIÓN DIFERENCIAL

BALANCE DE MATERIA

llenar llenar
F 20 kmol To 0 °C
Xf 0.5 mol Tv 96.6288 °C
Dt 16.5273 kmol TD 35 °C
Xd = Yav 0.5735 mol Tw 104.1034 °C
W 3.4727 kmol Tf 24 °C
Xw 0.15 mol

MA 78.113 kg/kmol
MB 92.14 kg/kmol

Hf Hw
CpA = 1.809 KJ/kg.k CpA = 1.809
CpB = 1.7873 KJ/kg.k CpB = 1.7873
hf = 3671.8589 hw = 16778.9187
hf = 3451.0064 KJ/kmol hw = 16483.0963
primero escribir primero escribir

Qr = 746767.10188

Hd
CpA = 1.809 KJ/kg.k
CpB = 1.7873 KJ/kg.k
Hd = 5294.661
Hd = 5005.1018 KJ/kmol Qc = 675825.56
tercero escribir
ACIÓN DIFERENCIAL DESTILACIÓN BATCH CON REC
BALANCE DE ENERGÍA

F= 2.8892
Tmv 48.3144 °C Xf =
TmD 17.5 °C Dt = 0.7943
Tmw 52.0517 °C Yav = 0.8692
Tmf 12 °C W= 0.1
Xw = 0.8

MA 78.113
MB 92.14

hw
CpA = 1.809
CpB = 1.7873
hw = 10348.6284
hw =

Hv qc
KJ/kg.k CpA = 1.809 KJ/kg.k λA= 381.6829
KJ/kg.k CpB = 1.7873 KJ/kg.k λB= 369.0091
λA= 381.6829 KJ/kmol λC= 30361.9385
KJ/kmol λB= 369.0091 KJ/kmol qc = 80307.9043
Hv 46217.3899
SEgundo escribir 45896.57 KJ/kmol qc =

Kj

Kj
ILACIÓN BATCH CON RECTIFICACIÓN con reflujo constante
LANCE DE ENERGÍA F(m) = 250 kg
Xf (m) = 0.4 mol

Rv = 0.7
kmol Tr = 0 RD = 2.33
Tv = 50.81
kmol TD = 35
Tw = 70.89
kmol Tf = 20

kg/kmol
kg/kmol

hf HL
KJ/kg.k CpA = 1.809 KJ/kg.k CpA = 1.809
KJ/kg.k CpB = 1.7873 KJ/kg.k CpB = 1.7873
hf = 3293.6364 hL = 5052.7372
KJ/kmol hf = KJ/kmol hL =

qr
KJ/kg T vapor = qr = 0 KJ
KJ/kg

KJ
KJ/kg.k
KJ/kg.k

KJ/kmol
 ANEXO 16
DATOS DE EQUILIBRIO LIQUIDO VAPOR : ELV PARA
ALGUNOS SITEMAS BINARIOS

ETANOL - AGUA ETANOL - AGUA

P = 1 atm P = 548mmHg
X Y X Y
T(°C) T(°C)
f.molar f.molar f.molar f.molar
100.00 0.0000 0.0000 91.09 0.000 0.0000
95.50 0.0190 0.1700 81.95 0.050 0.3280
89.00 0.0721 0.3891 78.19 0.100 0.4416
86.70 0.0966 0.4375 76.18 0.150 0.5000
85.30 0.1238 0.4704 74.92 0.200 0.5374
84.10 0.1661 0.5089 74.03 0.250 0.5651
82.70 0.2337 0.5445 73.34 0.300 0.5880
82.30 0.2608 0.5580 72.77 0.350 0.6084
81.50 0.3273 0.5826 72.28 0.400 0.6277
80.70 0.3965 0.6122 71.86 0.450 0.6468
79.80 0.5079 0.6564 71.48 0.500 0.6663
79.70 0.5198 0.6599 71.14 0.550 0.6866
79.30 0.5732 0.6841 70.83 0.600 0.7083
78.74 0.6763 0.7385 70.57 0.650 0.7317
78.41 0.7472 0.7815 70.34 0.700 0.7573
78.15 0.8943 0.8943 70.16 0.750 0.7857
70.04 0.800 0.8176
69.97 0.850 0.8538
69.98 0.900 0.8953
70.09 0.950 0.9434
70.30 1.000 1.0000

METANOL - AGUA ACETONA - ETANOL

P = 1 atm P = 1 atm
X Y X Y
T(°C) T(°C)
f.molar f.molar f.molar f.molar
100.00 0.000 0.0000 78.30 0.000 0.0000
96.40 0.020 0.1340 75.40 0.050 0.1550
93.50 0.040 0.2300 73.00 0.100 0.2620
91.20 0.060 0.3040 71.00 0.150 0.3480
89.30 0.080 0.3650 69.00 0.200 0.4170
87.70 0.100 0.4180 67.30 0.250 0.4780
84.40 0.150 0.5170 65.90 0.300 0.5240
81.70 0.200 0.5790 64.70 0.350 0.5660
78.00 0.300 0.6650 63.60 0.400 0.6050
75.30 0.400 0.7290 61.80 0.500 0.6740
73.10 0.500 0.7790 60.40 0.600 0.7390
71.20 0.600 0.8250 59.10 0.700 0.8020
69.30 0.700 0.8700 58.00 0.800 0.8650
67.60 0.800 0.9150 57.00 0.900 0.9290
66.00 0.900 0.9580 56.10 1.000 1.0000
65.00 0.950 0.9790
64.50 1.000 1.0000

ACETONA - ÁCIDO ACÉTICO ACETONA - METANOL

P = 1 atm P = 1 atm
X Y X Y
T(°C) T(°C)
f.molar f.molar f.molar f.molar
118.10 0.000 0.0000 64.50 0.000 0.0000
110.00 0.050 0.1620 63.60 0.050 0.1020
103.80 0.100 0.3060 62.50 0.100 0.1860
93.10 0.200 0.5570 60.20 0.200 0.3220
85.80 0.300 0.7250 58.65 0.300 0.4280
79.70 0.400 0.8400 57.55 0.400 0.5130
74.60 0.500 0.9120 56.70 0.500 0.5860
70.20 0.600 0.9470 56.00 0.600 0.6560
66.10 0.700 0.9690 55.30 0.700 0.7250
62.60 0.800 0.9840 55.05 0.800 0.8000
59.20 0.900 0.9930 56.10 1.000 1.0000
56.10 1.000 1.0000

CLOROFORMO - BENZENO n - HEXANO - BENCENO

P = 1 atm P = 1 atm
X Y X Y
T(°C) T(°C)
f.molar f.molar f.molar f.molar
80.60 0.0000 0.0000 80.10 0.000 0.0000
79.80 0.0800 0.1000 78.50 0.050 0.1110
79.00 0.1500 0.2000 77.10 0.100 0.1910
78.20 0.2200 0.3000 76.00 0.150 0.2580
77.30 0.2900 0.4000 75.10 0.200 0.3170
76.40 0.3600 0.5000 74.40 0.250 0.3710
75.30 0.4400 0.6000 73.70 0.300 0.4220
74.00 0.5400 0.7000 72.70 0.350 0.4700
71.90 0.6600 0.8000 72.20 0.400 0.5180
68.90 0.7900 0.9000 71.50 0.450 0.5630
61.40 1.0000 1.0000 71.00 0.500 0.6020
70.60 0.550 0.6400
70.30 0.600 0.6760
69.90 0.650 0.7100
69.50 0.700 0.7440
69.30 0.750 0.7820
69.10 0.800 0.8220
68.90 0.850 0.8620
68.80 0.900 0.9060
68.70 0.950 0.9521
68.70 0.970 0.9712
68.70 1.000 1.0000
 ACETONA - AGUA
P = 1 atm
X Y
T(°C)
f.molar f.molar
100.0 0.000 0.000
77.1 0.050 0.630
67.4 0.100 0.754
64.0 0.150 0.794
62.5 0.200 0.831
61.7 0.250 0.826
61.0 0.300 0.834
60.7 0.350 0.838
60.1 0.400 0.842
59.9 0.450 0.846
59.6 0.500 0.850
59.5 0.550 0.855
58.7 0.600 0.863
58.4 0.650 0.869
58.2 0.700 0.875
58.0 0.750 0.882
57.6 0.800 0.898
57.5 0.850 0.915
57.1 0.900 0.935
56.8 0.950 0.962
56.5 1.000 1.000

BENCENO - TOLUENO
P = 1 atm
X Y
T(°C)
f.molar f.molar
110.40 0.000 0.0000
109.60 0.020 0.0455
107.90 0.060 0.1320
106.20 0.100 0.2090
104.60 0.140 0.2800
102.95 0.180 0.3440
101.40 0.220 0.4040
 99.90 0.260 0.4585
98.50 0.300 0.5075
97.20 0.340 0.5555
94.60 0.420 0.6400
93.35 0.460 0.6790
92.20 0.500 0.7140
91.10 0.540 0.7470
90.05 0.580 0.7765
89.00 0.620 0.8054
88.00 0.660 0.8305
86.95 0.700 0.8545
86.00 0.740 0.8785
85.00 0.780 0.9005
84.10 0.820 0.9215
83.20 0.860 0.9405
81.45 0.940 0.9765
80.30 1.000 1.0000

CLOROFORMO - ACETONA
P = 1 atm
X Y
T(°C)
f.molar f.molar
56.20 0.0000 0.0000
57.50 0.0855 0.0478
58.30 0.1410 0.0835
59.40 0.2045 0.1312
60.40 0.2612 0.1765
61.60 0.3367 0.2495
62.80 0.4250 0.3520
63.90 0.5229 0.4830
64.40 0.7340 0.7630
63.80 0.7892 0.8240
63.10 0.8625 0.9000
62.80 0.8892 0.9350
61.30 1.0000 1.0000

SULFURO DE CARBONO -
TETRACLORURO DE CARBONO

P = 1 atm
X Y
T(°C)
f.molar f.molar
76.70 0.0000 0.0000
74.90 0.0296 0.0823
73.10 0.0615 0.1555
70.30 0.1106 0.2660
68.60 0.1435 0.3325
63.80 0.2585 0.4950
59.30 0.3908 0.6340
55.30 0.5318 0.7470
52.30 0.6630 0.8290
50.40 0.7574 0.8780
48.50 0.8604 0.9320
46.30 1.0000 1.0000
Wf 0.35 en peso
Ma 78.113
Mb 92.14
xf 0.3884 mol

verificar sistema

Fm 800 kg
Xf 0.35 mol
Ma 78.113
Mb 92.14
F 9.1711 Kmol