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〖𝑃𝑂〗 _4 〗 ^(3−)]′= 〖 [𝑃𝑂 〗 _4^(3−)]∗1+10^(1

Conc. Total o condicional

〖 [ 〖𝑃𝑂〗 _4 〗 ^(3−)]′=0.1𝑀
¿Cuánto fosfato libre tendre a un pH =13?

−)]=( 〖 [ 〖𝑃𝑂〗 _4 〗 ^(3−)]′)/(1+10^(12.34−𝑝

PO43- HPO42- H2PO4- PO43-


alfa PO43-
pH 1 10^12.34-pH 10^19.53-2pH 10^21.67-3pH
0 1 2.1878E+12 3.3884E+19 4.6774E+21
0.5 1 6.9183E+11 3.3884E+18 1.4791E+20
1 1 2.1878E+11 3.3884E+17 4.6774E+18
1.5 1 6.9183E+10 3.3884E+16 1.4791E+17
2 1 2.1878E+10 3.3884E+15 4.6774E+15
2.14 1 1.5849E+10 1.7783E+15 1.7783E+15
3 1 2.1878E+09 3.3884E+13 4.6774E+12
3.5 1 6.9183E+08 3.3884E+12 1.4791E+11
4 1 2.1878E+08 3.3884E+11 4.6774E+09
4.5 1 6.9183E+07 3.3884E+10 1.4791E+08
5 1 2.1878E+07 3.3884E+09 4.6774E+06
5.5 1 6.9183E+06 3.3884E+08 1.4791E+05
6 1 2.1878E+06 3.3884E+07 4.6774E+03
6.5 1 6.9183E+05 3.3884E+06 1.4791E+02
7 1 2.1878E+05 3.3884E+05 4.6774E+00
7.19 1 1.4125E+05 1.4125E+05 1.2589E+00
8 1 2.1878E+04 3.3884E+03 4.6774E-03
8.5 1 6.9183E+03 3.3884E+02 1.4791E-04
9 1 2.1878E+03 3.3884E+01 4.6774E-06
9.5 1 6.9183E+02 3.3884E+00 1.4791E-07
10 1 2.1878E+02 3.3884E-01 4.6774E-09
10.5 1 6.9183E+01 3.3884E-02 1.4791E-10
11 1 2.1878E+01 3.3884E-03 4.6774E-12
11.5 1 6.9183E+00 3.3884E-04 1.4791E-13
12 1 2.1878E+00 3.3884E-05 4.6774E-15
12.34 1 1.0000E+00 7.0795E-06 4.4668E-16
13 1 2.1878E-01 3.3884E-07 4.6774E-18
13.5 1 6.9183E-02 3.3884E-08 1.4791E-19
14 1 2.1878E-02 3.3884E-09 4.6774E-21
∗1+10^(12.34−𝑝𝐻)+10^(19.53−2𝑝𝐻)+10^(21.67

^(12.34−𝑝𝐻)+10^(19.53−2𝑝𝐻)+10^(21.67−3𝑝𝐻)

alfa PO43- [PO43-] %


4.7112E+21 2.1226E-23 0.0000
Abundancia re
1.5130E+20 6.6094E-22 0.0000
5.0162E+18 1.9935E-20 0.0000 120.0000

1.8180E+17 5.5007E-19 0.0000


100.0000
8.0658E+15 1.2398E-17 0.0000
3.5566E+15 2.8117E-17 0.0000
80.0000
3.8564E+13 2.5931E-15 0.0000
3.5370E+12 2.8272E-14 0.0000 60.0000
3.4374E+11 2.9092E-13 0.0000
3.4102E+10 2.9324E-12 0.0000 40.0000
3.4150E+09 2.9283E-11 0.0000
3.4591E+08 2.8909E-10 0.0000 20.0000
3.6077E+07 2.7719E-09 0.0000
4.0804E+06 2.4507E-08 0.0000 0.0000
0 2 4 6
5.5763E+05 1.7933E-07 0.0002
2.8251E+05 3.5397E-07 0.0004
2.5267E+04 3.9577E-06 0.0040
7.2582E+03 1.3778E-05 0.0138
2.2226E+03 4.4991E-05 0.0450
6.9622E+02 0.00014363 0.1436
2.2012E+02 0.00045431 0.4543
7.0217E+01 0.00142416 1.4242
2.2881E+01 0.00437044 4.3704
7.9186E+00 0.01262842 12.6284
3.1878E+00 0.03136964 31.3696
2.0000E+00 0.04999982 49.9998
1.2188E+00 0.0820495 82.0495
1.0692E+00 0.09352935 93.5293
1.0219E+00 0.09785908 97.8591
+10^(21.67−3𝑝𝐻)

21.67−3𝑝𝐻) )

Abundancia relativa en f(pH)


0

0
0 2 4 6 8 10 12 14 16

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