kmol

Masa inicial [kg] 1 Peso Atomico [kg/kmol] 1

C 12
Combustible O2 32 CO2
C 100%
N2 28

Tipo combustion C + O2
CO2 100% Entra 0.08333333 0.1875
Rx 0.08333333 0.08333333
Produce 0 0
Comburente Sale 0 0.10416667
O2 21%
N2 79%
H2O 0%
Exceso 125%
 Balance masa
nm3/kmol Entrada
22.4 kmol/kg comb kg/kg comb Nm3/kg comb
C 0.0833 1.00 1.86666666667
44 H2 0.0000 0.00 0
N2 0.6875 19.25 15.4
O2 0.1875 6.00 4.2
Total 0.9583 26.25 21.4666666667

Balance de energia
--> CO2 [kg/kg comb]
0 C 0.08333333333
0 O2 0.08333333333
0.08333333 CO2 0.08333333333
0.08333333

Compusto
O2
CO2
N2

F.O 0
 Balance masa
Salida
kmol/kg comb kg/kg comb Nm3/kg comb
CO2 0.08 3.67 1.86666666667
N2 0.6875 19.25 15.4
O2 0.10416666667 3.33333333 2.33333333333
Total 0.88 26.25 19.6

Balance de energia
△Hf 298K QRX1 [kJ/kg comb]
0 0
0 0
394000 32833.3333333
Total 32833.3333333

[kg/kg comb]Tº [K] △HT -△H298 Qsalida [kJ/kg comb]

0.10416667 1403.65019992 37312.1372 3886.68096221
0.08 1403.65019992 56253.9017 4687.82514296
0.6875 1403.65019992 35285.5669 24258.8272282
Masa inicial [kg] 1 CH4 +
Entra 0.05625 +
Combustible Rx 0.05625 +
CH4 90% Produce 0 +
C2H6 10% Sale 0 +

Comburente
O2 20% C2H6 +
N2 70% Entra 0.003 +
H2O 10% Rx 0.003 +
Exceso 10% Produce 0 +
Sale 0.000 +
Peso Molecular [kmol]
CH4 16 BALAN
O2 32 Entrada [kmol/kg comb] [kg/kg comb]
CO2 44 CH4 0.0563 0.90
H2O 18 O2 0.1366 4.37
C2H6 30 H2O 0.0683 1.23
N2 28 C2H6 0.0033 0.10
N2 0.4780 13.39
kmol Nm3/kmol Total 19.99
1 22.4
BALANCE ENERGIA
[kg/kg comb]
CH4 0.0563
O2 0.1125
REACCION 1
CO2 0.0563
H2O 0.1125

[kg/kg comb]
C2H6 0.003
O2 0.012
REACCION 2
CO2 0.007
H2O 0.01

INCREMENTO DE ENTALPIA
Compusto [kg/kg comb] Tº [K]
CH4 0.000 2099.24
C2H6 0.000 2099.24
CO2 0.063 2099.24
O2 0.012 2099.24
N2 0.478 2099.24
H2O 0.191 2099.24

Funcion Objetivo 0.00

 2O2 = CO2 + 2H2O
0.12375 = 0 + 0
0.1125 = 0 + 0
0 = 0.05625 + 0.1125
0.01125 = 0.05625 + 0.1125

7/2O2 = 2CO2 + 3H2O

0.013 = 0 + 0
0.012 = 0 + 0
0 = 0.007 + 0.01
0.001 = 0.007 + 0.010

BALANCE MASA
Nm3/kg comb Salida [kmol/kg comb] [kg/kg comb] Nm3/kg comb
1.260 CO2 0.06 2.77 1.409
3.059 O2 0.01 0.40 0.278
1.530 N2 0.48 13.39 10.708
0.075 H2O 0.19 3.43 4.274
10.708 Total 19.99

ANCE ENERGIA
△Hf 298K QRX1 [kJ/kg comb]
75000 4218.75
0 0
394000 22162.5
242000 27225
Total 45168.75

△Hf 298K QRX2 [kJ/kg comb]

84000.00 280.00
0.00 0.00
394000.00 2626.67
242000.00 2420.00
Total 4766.67

ENTO DE ENTALPIA
△HT -△H298K Qsalida [kJ/kg comb]
0.00 0.00
0.00 0.00
97015.34 6103.88
62492.41 775.95
59213.78 28306.66
77303.88 14748.94
Masa inicial [kg] 1 CH4 +
Entra 0.03375 +
Combustible Rx 0.03375 +
CH4 60% Produce 0 +
C2H6 10% Sale 0 +

Tipo combustion
CO2 90% C2H6 +
CO 10% Entra 0.003 +
Rx 0.003 +
Comburente Produce 0 +
O2 20% Sale 0.000 +
N2 70%
H2O 10% BA
Exceso 10% Entrada [kmol/kg comb] [kg/kg comb]
CH4 0.0375 0.60
Peso Molecular [kmol] O2 0.0929 2.97
CH4 16 H2O 0.0465 0.84
O2 32 C2H6 0.0033 0.10
CO2 44 N2 0.3252 9.10
H2O 18 Total 13.61
C2H6 30
N2 28
CO 28 [kmol/kg comb]
CH4 0.0338
O2 0.0675
REACCION 1
kmol Nm3/kmol CO2 0.0338
1 22.4 H2O 0.0675

Perdidas 15% [kmol/kg comb]

REACCION 2 C2H6 0.003
O2 0.011
CO2 0.006
H2O 0.009

Entrada
Compuesto [kmol/kg comb] Tº [K]
CH4 0.0375 303
C2H6 0.0033 303
O2 0.0929 303
N2 0.3252 303
H2O 0.0465 303
 2O2 = CO2 + 2H2O
0.07425 = 0 + 0
0.0675 = 0 + 0
0 = 0.03375 + 0.0675
0.00675 = 0.03375 + 0.0675

7/2O2 = 2CO2 + 3H2O

0.012 = 0 + 0
0.011 = 0 + 0
0 = 0.006 + 0.009
0.001 = 0.006 + 0.009

BALANCE MASA
Nm3/kg comb Salida [kmol/kg comb] [kg/kg comb] Nm3/kg comb
0.840 CO2 0.0398 1.75 0.890
2.081 O2 0.0084 0.27 0.189
1.041 N2 0.3252 9.10 7.284
0.075 H2O 0.1315 2.37 2.945
7.284 CO 0.0044 0.12 0.099
Total 13.61

BALANCE ENERGIA
△Hf 298K QRX1 [kJ/kg comb] [kmol/kg comb]
75000 2531.25 CH4 0.0038
0 0 O2 0.0056
REACCION 3
394000 13297.5 CO 0.0038
242000 16335 H2O 0.0075
Total 27101.25
△Hf 298K QRX2 [kJ/kg comb] [kmol/kg comb]
84000 252.00 C2H6 0.00033
0 0.00 O2 0.00083
REACCION 4
394000 2364.00 CO 0.00067
242000 2178.00 H2O 0.00100
Total 4290.00

INCREMENTO DE ENTALPIA
Entrada Salida
△H Qentrada [kJ/kg comb] Compuesto [kmol/kg comb] Tº [K]
-283.2 -10.62 CO2 0.040 1803.95
-283.2 -0.943999999999996 O2 0.008 1803.95
-25.2 -2.3411849999999 N2 0.325 1803.95
 90 29.2648125 H2O 0.131 1803.95
-10798.3370154 -501.605250901553 CO 0.0044 1803.95
Total -486.245623401553

F.O. 0.00
 CH4 + 3/2 O2 = CO + 2H2O
Entra 0.00375 + 0.0061875 = 0+ 0
Rx 0.00375 + 0.005625 = 0+ 0
Produce 0 + 0 = 0.00375 + 0.0075
Sale 0 + 0.0005625 = 0.00375 + 0.0075

C 2H 6 + 5/2O2 = 2CO + 3H2O

Entra 0.00033 + 0.00092 = 0.00000 + 0.00000
Rx 0.00033 + 0.00083 = 0.00000 + 0.00000
Produce 0.00000 + 0.00000 = 0.00067 + 0.00100
Sale 0.00000 + 0.00008 = 0.00067 + 0.00100

△Hf 298K QRX3 [kJ/kg comb]

75000 281.25
0 0
111000 416.25
242000 1815
Total 1950.0
△Hf 298K QRX4 [kJ/kg comb]
84000 28.00
0 0.00 Total 33629.25
111000 74.00 Perdida 5044.3875
242000 242.00
Total 288.00

Salida
△HT -△H298K Qsalida [kJ/kg comb]
79711.61 3168.54
51803.07 437.52
49055.96 15951.26
 63307.34 8321.88
49679.5170456 219.42
Total 28098.62