SISTEMA BINARIO n-HEXANO / n-HEPTANO

〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟

P 1.013 bar

Constante Cpa
Constante Teb (°C)
A B C (cal/mol°C)
n-Hexano 68.73 4.00139 1170.875 224.317 46.71
n-Heptano 98.42 4.02023 1263.909 216.432 53.77

N T(°C) P°a(bar) P°b(bar) Xa Ya αAB

1 68.73 1.0136 0.3872 1.0 1 2.6175
2 71.699 1.1116 0.4302 0.8553 0.9386 2.5840
3 74.668 1.2168 0.4769 0.7246 0.8703 2.5517
4 77.637 1.3296 0.5275 0.6053 0.7944 2.5206
5 80.606 1.4504 0.5824 0.4961 0.7103 2.4906
6 83.575 1.5795 0.6417 0.3960 0.6174 2.4616
7 86.544 1.7173 0.7056 0.3038 0.5151 2.4336
8 89.513 1.8641 0.7746 0.2188 0.4027 2.4066
9 92.482 2.0204 0.8487 0.1402 0.2796 2.3805
10 95.451 2.1865 0.9284 0.0673 0.1452 2.3552
11 98.42 2.3628 1.0138 0 0 2.3308

x vs y
P=1.013 bar
1 100

0.9 95
0.8
90
0.7

0.6 85
T (°C)

0.5
Y

80
0.4

0.3 75

0.2
70
0.1
65
0 0.0 0.1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Linea de Referencia Linea de Equilibrio

0.1
65
0 0.0 0.1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Linea de Referencia Linea de Equilibrio

 x,y vs entalpia
P=1.013 bar
13000.0000

λ (cal/mol) t0(°C) Rango 29.69 12000.0000

11000.0000
6895
0 Intervalo 2.969
7593 10000.0000

9000.0000
hL Hv Datos para linea de ref.

Entalpia
8000.0000
3210.8502 10105.818 1 1
3422.3001 10318.05 0.9 0.9 7000.0000

3632.9424 10541.598 0.8 0.8 6000.0000

3842.7869 10777.57 0.7 0.7 5000.0000
4051.8582 11027.149 0.6 0.6
4000.0000
4260.1916 11291.597 0.5 0.5
4467.8299 11572.257 0.4 0.4 3000.0000
0.0 0.1 0.2 0.3 0.4 0.5 0
4674.8211 11870.555 0.3 0.3
4881.2165 12188 0.2 0.2 x,y

5087.0695 12526.21 0.1 0.1

x vs hL y vs Hv
5292.4339 12886.869 0 0

x,y vs T
P=1.013 bar
100

95

90

85
T (°C)

80

75

70

65
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x, y

Punto de Burbuja Punto de Rocio

65
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x, y

Punto de Burbuja Punto de Rocio

 x,y vs entalpia
P=1.013 bar

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

x vs hL y vs Hv
 SISTEMA BINARIO n-PENTANO / n-HEXANO
〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟
P 1.013 bar

Constante Cpa
Constante Teb (°C) λ (cal/mol)
A B C (cal/mol°C)
n-Pentano 36.055 3.97786 1064.84 232.014 39.96 6164
n-Hexano 68.7 4.00139 1170.875 224.317 46.71 6895

N T(°C) P°a(bar) P°b(bar) Xa Ya αAB hL

1 36.055 1.0130 0.3195 ### ### 3.1706 1440.7494
2 39.3195 1.1308 0.3632 ### ### 3.1135 1611.9415
3 42.584 1.2591 0.4116 ### ### 3.0590 1785.1140
4 45.8485 1.3983 0.4650 ### ### 3.0070 1959.8752
5 49.113 1.5492 0.5239 ### ### 2.9573 2135.9186
6 52.3775 1.7123 0.5885 ### ### 2.9097 2313.0051
7 55.642 1.8883 0.6593 ### ### 2.8642 2490.9486
8 58.9065 2.0779 0.7367 ### ### 2.8205 2669.6055
9 62.171 2.2816 0.8211 ### ### 2.7787 2848.8659
10 65.4355 2.5001 0.9129 ### ### 2.7385 3028.6461
11 68.7 2.7341 1.0127 ### ### 2.7000 3208.8840

x vs y
P=1.013 bar
1

0.9

0.8

0.7

0.6

0.5
Y

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Linea de referencia Curva de Equilibrio

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Linea de referencia Curva de Equilibrio

 x,y vs Entalpia
p=1.013 bar
11000.0000
t0(°C) Rango 32.645
10000.0000

0 Intervalo 3.2645 9000.0000

8000.0000

Hv Datos para linea de ref. 7000.0000

Entalpia
7604.7471 1 1 6000.0000
7790.0371 0.9 0.9 5000.0000
7985.8014 0.8 0.8 4000.0000
8193.2996 0.7 0.7
3000.0000
8413.8959 0.6 0.6
8649.0637 0.5 0.5 2000.0000

8900.3911 0.4 0.4 1000.0000

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
9169.5852 0.3 0.3
x, y
9458.4772 0.2 0.2
9769.0276 0.1 0.1
X vs hL Y vs Hv
10103.33 0 0

x,y vs T
P=1.013 bar
75

70

65

60
T (°C)

55

50

45

40

35
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x, y

Punto de burbuja Punto de rocio

35
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x, y

Punto de burbuja Punto de rocio

y vs Entalpia
=1.013 bar

3 0.4 0.5 0.6 0.7 0.8 0.9 1

x, y

X vs hL Y vs Hv

8 0.9 1
8 0.9 1
 SISTEMA BINARIO n-HEPTANO / n-OCTANO
〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟
P 1.013 bar

Constante Cpa
Constante Teb (°C) λ (cal/mol)
A B C (cal/mol°C)
n-Heptano 98.42 4.02023 1263.909 216.432 53.77 7593
n-Heptano 125.67 4.05075 1356.36 209.635 60.74 8224

N T(°C) P°a(bar) P°b(bar) Xa Ya αAB hL

1 98.42 1.0138 0.4444 1.0 1 2.2812 5292.9569
2 101.145 1.0974 0.4857 0.8620 0.9338 2.2595 5535.8750
3 103.87 1.1864 0.5300 0.7358 0.8618 2.2383 5776.3697
4 106.595 1.2809 0.5776 0.6191 0.7828 2.2179 6014.6260
5 109.32 1.3812 0.6284 0.5109 0.6966 2.1980 6250.8186
6 112.045 1.4875 0.6827 0.4104 0.6026 2.1786 6485.1118
7 114.77 1.5999 0.7408 0.3169 0.5004 2.1598 6717.6600
8 117.495 1.7189 0.8026 0.2296 0.3896 2.1416 6948.6085
9 120.22 1.8445 0.8685 0.1481 0.2696 2.1238 7178.0931
10 122.945 1.9771 0.9385 0.0717 0.1399 2.1066 7406.2414
11 125.67 2.1169 1.0130 0 0 2.0898 7633.1729

x vs y
P=1.013
1 130
0.9
125
0.8
0.7 120
0.6
115
0.5
T (°C)
y

0.4 110
0.3
105
0.2
0.1 100
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
95
0.0
x

Linea de Referencia Linea de equilibrio

95
0.0
 x,y vs Entalpia
t0(°C) Rango 27.25 P=1.013
16000.0000
0 Intervalo 2.725
14000.0000

Hv Datos para linea de ref. 12000.0000

12885.813 1 1

Entalpia
10000.0000
13119.985 0.9 0.9
13365.408 0.8 0.8 8000.0000
13623.012 0.7 0.7
13893.779 0.6 0.6 6000.0000

14178.749 0.5 0.5

4000.0000
14479.016 0.4 0.4 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
14795.738 0.3 0.3 x,y
15130.131 0.2 0.2
15483.474 0.1 0.1 x vs hL y vs Hv
15857.114 0 0

x,y vs T
130
P=1.013
125

120

115
T (°C)

110

105

100

95
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

Punto de Burbuja Punto de Rocio

95
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

Punto de Burbuja Punto de Rocio

s Entalpia
013

0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

hL y vs Hv
 SISTEMA BINARIO BENCENO/TOLUENO

〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟

P 1.013 bar

Constante Cpa
Constante Teb (°C) λ (cal/mol)
A B C (cal/mol°C)
Benceno 80.09 3.98523 1184.24 217.572 32.49 7342
Tolueno 110.64 4.05043 1327.62 217.625 37.59 7930

N T(°C) P°a(bar) P°b(bar) Xa Ya αAB hL

1 80.09 1.0157 0.3900 1.0 1 2.6043 2603.8750
2 83.145 1.1147 0.4329 0.8508 0.9362 2.5752 2764.6533
3 86.2 1.2212 0.4795 0.7193 0.8672 2.5470 2924.0256
4 89.255 1.3354 0.5300 0.5998 0.7906 2.5197 3082.0857
5 92.31 1.4576 0.5846 0.4907 0.7061 2.4932 3238.9278
6 95.365 1.5884 0.6437 0.3909 0.6130 2.4675 3394.6449
7 98.42 1.7280 0.7075 0.2994 0.5107 2.4425 3549.3275
8 101.475 1.8768 0.7761 0.2152 0.3988 2.4183 3703.0629
9 104.53 2.0353 0.8499 0.1376 0.2764 2.3948 3855.9352
10 107.585 2.2038 0.9291 0.0658 0.1431 2.3719 4008.0242
11 110.64 2.3827 1.0141 0 0 2.3496 4159.4061

x vs y
P=1.013 bar
1
115
0.9
110
0.8

0.7 105

0.6 100

0.5
Y

95
T°C

0.4
90
0.3
85
0.2

0.1 80

0 75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0.0
x

Linea de Referencia Linea de Equilibrio

0 75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0.0
x

Linea de Referencia Linea de Equilibrio

 x,y vs Entalpia
t0(°C) Rango 30.55
P=1.013 bar
0 Intervalo 3.055 12000.0000

10000.0000
Hv Datos para linea de ref.
9945.7686 1 1
Axis Title 8000.0000
10107.91 0.9 0.9
10279.147 0.8 0.8 6000.0000
10460.332 0.7 0.7
10652.374 0.6 0.6 4000.0000
10856.24 0.5 0.5
11072.957 0.4 0.4 2000.0000
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
11303.615 0.3 0.3
11549.369 0.2 0.2 Axis Title
11811.438 0.1 0.1
12091.112 0 0 x vs hL y vs Hv

x,y vs T
P=1.013 bar
115

110

105

100

95
T°C

90

85

80

75
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

Puntos de Burbuja Puntos de Rocio

75
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x,y

Puntos de Burbuja Puntos de Rocio

talpia
bar

0.5 0.6 0.7 0.8 0.9 1.0

Title

y vs Hv
 SISTEMA BINARIO METANOL/AGUA

〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟

P 1.013 bar

Constante Cte de
Constante Teb (°C) t0(°C)
A B C Van Laar
Metanol 64.54 5.20277 1580.08 239.5 0.9014
0
Agua 100 5.11564 1687.537 230.17 0.5559

N T(°C) P°a(bar) P°b(bar) xA xB δ1 δ2

1 64.54 1.0135 0.2452 1 0 #DIV/0! 1.7435
2 68.086 1.1634 0.2868 0.7684 0.2316 1.0224 1.4848
3 71.632 1.3313 0.3343 0.5636 0.4364 1.0987 1.2900
4 75.178 1.5188 0.3882 0.3934 0.6066 1.2388 1.1573
5 78.724 1.7277 0.4492 0.2657 0.7343 1.4305 1.0790
6 82.27 1.9597 0.5182 0.1774 0.8226 1.6402 1.0380
7 85.816 2.2167 0.5958 0.1169 0.8831 1.8422 1.0175
8 89.362 2.5008 0.6829 0.0741 0.9259 2.0263 1.0074
9 92.908 2.8141 0.7804 0.0428 0.9572 2.1894 1.0025
10 96.454 3.1587 0.8893 0.019 0.981 2.3334 1.0005
11 100 3.5370 1.0105 0 1 2.4630 #DIV/0!

x vs y
P=1.013 bar
1 105
0.9 100
0.8 95
0.7 90
0.6 T°C 85
0.5
80
y

0.4
75
0.3
70
0.2
65
0.1
60
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Linea de Referencia Linea de Equilibrio

 Cpa
λ (cal/mol) Rango Intervalo
(cal/mol°C)
19.38 8415 12000
35.46 3.546
18 9718
10000
xA yA αAB hL Hv Datos para linea de ref.
1 1 #DIV/0! 2412.5052 9665.7852 1 1 8000
0.7689 0.90284 2.0256703 1956.8735 9851.9809 0.9 0.9

Entalpia
0.5640 0.81440 1.626873 1510.1556 10026.716 0.8 0.8 6000
0.3936 0.73109 1.2140424 1106.0909 10194.447 0.7 0.7
0.2659 0.64874 0.8565984 782.48061 10360.208 0.6 0.6 4000
0.1775 0.56328 0.5935377 545.92473 10528.86 0.5 0.5
0.1170 0.47156 0.4145109 375.23481 10704.095 0.4 0.4
2000
0.0742 0.37130 0.2943643 247.93582 10888.503 0.3 0.3
0.0429 0.26075 0.2128725 148.88599 11084.022 0.2 0.2
0
0.0190 0.13839 0.1564792 68.57646 11292.269 0.1 0.1 0 0.1 0.2
0 0 #DIV/0! 0 11518 0 0

x,y vs T
P=1.013 bar
105

100

95

90

85
T°C

80

75

70

65

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x,y

Puntos de Burbuja Puntos de Rocio

 x,y vs Entalpia
12000

10000

8000
Entalpia

6000

4000

2000

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x,y

x vs hL y vs Hv
 SISTEMA BINARIO ETANOL/AGUA

〖𝑙𝑜𝑔〗 _10 𝑃_𝑣𝑎𝑝=𝐴 𝐵/(𝑇 °𝐶+𝐶) 𝑏𝑎𝑟

P 1.013 bar

Constante Cte de
Constante Teb (°C) t0(°C)
A B C Van Laar
Etanol 78.3 5.33675 1648.22 230.918 1.6383
0
Agua 100 5.11564 1687.537 230.17 0.9414

N T(°C) P°a(bar) P°b(bar) xA xB δ1 δ2

1 78.3 1.0150 0.4415 1 0 #DIV/0! 2.5636
2 79.385 1.0595 0.4615 0.5608 0.4392 1.1709 1.5648
3 80.47 1.1056 0.4822 0.4146 0.5854 1.3892 1.3323
4 81.555 1.1534 0.5036 0.3041 0.6959 1.6966 1.1920
5 82.64 1.2029 0.5259 0.2277 0.7723 2.0454 1.1143
6 83.725 1.2542 0.5489 0.1767 0.8233 2.3832 1.0721
7 84.81 1.3073 0.5728 0.1414 0.8586 2.6904 1.0478
8 85.895 1.3622 0.5976 0.1154 0.8846 2.9687 1.0328
9 86.98 1.4191 0.6233 0.0954 0.9046 3.2207 1.0229
10 88.065 1.4779 0.6499 0.0793 0.9207 3.4522 1.0161
11 89.15 1.5387 0.6774 0.0661 0.9339 3.6644 1.0114
12 90.235 1.6016 0.7059 0.055 0.945 3.8605 1.0080
13 91.32 1.6666 0.7354 0.0456 0.9544 4.0407 1.0056
14 92.405 1.7338 0.7659 0.0373 0.9627 4.2117 1.0038
15 93.49 1.8032 0.7975 0.0301 0.9699 4.3698 1.0025
16 94.575 1.8749 0.8301 0.0237 0.9763 4.5185 1.0015
17 95.66 1.9490 0.8639 0.018 0.982 4.6580 1.0009
18 96.745 2.0254 0.8987 0.0129 0.9871 4.7886 1.0005
19 97.83 2.1044 0.9348 0.0083 0.9917 4.9116 1.0002
20 98.915 2.1858 0.9720 0.004 0.996 5.0311 1.0000
21 100 2.2699 1.0105 0 1 5.1464 #DIV/0!

x vs y
P=1.013 bar 105
1

0.9 100

0.8
95
0.7

0.6
90
T°C

0.5
y

0.4
85
0.3
 0.8
95
0.7

0.6
90

T°C
y 0.5

0.4
85
0.3

0.2 80
0.1

0 75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1

Linea de Referencia Linea de Equilibrio

 Cpa
λ (cal/mol) Rango Intervalo
(cal/mol°C)
26.83 9216
21.7 1.085
18 9718

xA yA αAB hL Hv Datos para linea de ref.

1 1 #DIV/0! 3510.189 11316.789 1 1
0.5610298 0.6870878 1.1454766 1996.6096 11283.64 0.9 0.9
0.4147783 0.6288838 1.0400546 1496.3004 11297.614 0.8 0.8 12000

0.3042119 0.5876609 0.8735181 1112.2325 11314.177 0.7 0.7

0.2278042 0.5533119 0.7117293 843.95805 11331.515 0.6 0.6 10000
0.1768370 0.5217767 0.5833694 663.73868 11348.863 0.5 0.5
0.1415040 0.4913070 0.4860694 538.00274 11365.87 0.4 0.4
0.1154973 0.4610890 0.4111206 444.74242 11382.358 0.3 0.3 8000
0.0954609 0.4306928 0.3521587 372.23183 11398.219 0.2 0.2
0.0793921 0.3998624 0.3045723 313.43622 11413.378 0.1 0.1

Entalpia
6000
0.0661913 0.3684289 0.2656335 264.53972 11427.774 0 0
0.0550931 0.3362712 0.2332414 222.86445 11441.354
0.0456229 0.3032966 0.2060568 186.7743 11454.07 4000
0.0373767 0.2694296 0.1827888 154.83344 11465.874
0.0301608 0.2346064 0.162899 126.40879 11476.719
2000
0.0237675 0.1987708 0.145689 100.76922 11486.56
0.0180625 0.1618718 0.1307312 77.459771 11495.35
0.0129364 0.1238622 0.1176654 56.106344 11503.041 0
0 0.1
0.0083011 0.0846972 0.106189 36.406119 11509.587
0.0040839 0.0443341 0.095995 18.109265 11514.937
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

x,y vs T
105

100

95

90
T°C

85
 95

90
T°C

85

80

75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x,y

Punto de Burbuja Punto de rocio

 x,y vs Entalpia
12000

10000

8000
Entalpia

6000

4000

2000

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Axis Title

x vs hL y vs Hv