Como parte de las estrategias de recuperación ambiental, para el post conflicto, se están proponiendo tecnologías de r

se desarrollan experimentos en reactores de 0,5 m3, usando procesos de remoción catalítica, oxidación química, bior
que la eficiencia en la remoción de mercurio, depende del pH, del oxígeno disuelto - OD, de la cantidad de iones sulfa
concentración de mercurio. Según la resolución 2115/2007, del Ministerio de Protección Social - Ministerio del Amb
en los cuerpos de agua en niveles inferiores a 0,001 mg/L (± 0,0003 mg/L). El espectrofotómetro para análisis de me
estándar, en cuanto los instrumentos volumétricos y gravimétricos, tienen tolerancia del 1,2 % unidades desviación es
01. Realizar e interpretar los gráficos suficientes y necesarios, que permitan describir la tendencia de los datos y su
02. Desarrollar el tratamiento estadístico, suficiente y necesario, que permita inferir las condiciones y mejor méto
eficiencia, con el menor costo;
03. Realizar las pruebas estadísticas suficientes y necesarias, que permitan discriminar la calidad analítica de los re
el mejor método de remoción;
04. Con base en tratamiento estadístico y su pertinente interpretación, indicar sí el método para cuantificar el mercu
05. ¿Los métodos propuestos para la remoción de mercurio, cumplen con los requisitos de la norma?, ¿Por qué?, ¿Es
con base en criterios ambientales, costo / beneficio y eficiencia? Justificas cada respuesta, con argumentos estadístico
OBSERVACIONES: El presente ejercicio, implica la aplicación de TODAS las herramientas estadísticas presentadas
dadas como apoyo didáctico. Es importante que en quimiometría, el factor relevante es la INTERPRETACIÓN conte
y normativas.
iendo tecnologías de remoción de mercurio total, en cuerpos de aguas superficiales. Para ello,
idación química, biorremediación e intercambio iónico. Por estudios experimentales, se sabe
cantidad de iones sulfato - SO 4=, de los sólidos totales del agua - ST, lo cual se refleja en la
- Ministerio del Ambiente, Vivienda y Desarrollo territorial, el mercurio debe estar contenido
ro para análisis de mercurio, presenta una relación S/N de 0,009 unidades de desviación
unidades desviación estándar.
encia de los datos y su posible tratamiento estadístico;
diciones y mejor método a usar en la remoción y cuantificación de mercurio y, que garantice su

dad analítica de los resultados, la correlación de parámetros, el cumplimiento de las normas y

a cuantificar el mercurio en analíticamente válido.

orma?, ¿Por qué?, ¿Es posoble optimizarlos?, ¿Cómo?, ¿Cuál es la tecnología más apropiada,
argumentos estadísticos, químicos, analíticos, científicos y normativos.
stadísticas presentadas durante las clases, además de las lecturas y consultas especializadas,
RPRETACIÓN contextual, fundamentada en bases estadísticas, analíticas, químicas, científicas
 se van haran un grafico total
para los 4 metodos para
determinar las varibles
directamente proporcionales
punto o inversamente proporcionales, interpretacion
se observara ccual es el metodo
con mas remosion de Hg ,
tambien se determianra cual
metodo es mas eficienteteniendo
en cuenta el costo beneficio y
teniendo en cuenta el impacto
ambiental . se hara un grafico
para el para las curvas de
calibracion para determinar
tendencias , y se hara un grafico
para los parametro de calidad
analitica para
se realizara la determinar
estadistica si hay
dsitribucion
descriptiva normal( se haran
dos
congraficos paradeelcalidad
la raw data para este
teniendo en cuenta que
analitica despues , se haranse tienen
que pasar a concentracion.
graficos de posicion ,
dispersion ,error,
incertidumbre,boxplot y cartas
de control,
se hara las pruebas de pearson para determinar la ortogonalidad , el anova para elegir el mejor metodo, y s
a elegir el mejor metodo, y se hara RLM para dterminar cual es el mejor metodo.
 % REMOSION DE hg

10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0

0.0
Remoción Hg
(%)
pH

CHg
OD
(mg/L)
SO4=
(mg/L)
ST
(mg/L)
Remoción Hg
(%)
pH

CHg
OD
(mg/L)
SO4=
(mg/L)
ST
(mg/L)
Remoción Hg

concentracion
(%)
pH

CHg
OD
(mg/L)
REMOSION DE MERCURIO TOTAL

SO4=
(mg/L)
ST
(mg/L)
Remoción Hg
(%)
pH

CHg
OD
(mg/L)
SO4=
(mg/L)
ST
(mg/L)
 remosion de mercurio
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
% de remosion

1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
-0.1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
-0.2
-0.3

parametro
 remosion de mercurio (Concentracion del blanco)
0.0

0.0

0.0

0.0
001 002 003 004 005 006 007 008 009 010 011 012 013 014 015 016 017 018 019
concentracion

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

-0.1

-0.1

-0.1

lectura
 REMOSION DE Mercurio(Concentracion)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
0.9
0.9
0.9
0.9
0.9
concentracion

0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.9
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19

lectura
 REMOCIÓN CATALÍTICA
Remoción Hg OD SO4= ST
pH AHg
(%) (mg/L) (mg/L) (mg/L)
30.26 7.2486 0.8287 22.5428 8.8549 66.1804
41.13 7.2288 0.8226 23.3010 9.0812 65.0561
42.93 7.2251 0.7960 23.5538 9.1092 63.4757
45.52 7.1935 0.6636 23.9026 9.5394 62.6217
48.68 7.1883 0.6564 24.1955 9.5997 57.4137
54.21 7.0892 0.6494 24.9708 9.8643 56.9064
54.36 6.9459 0.6431 25.0600 10.1123 56.2696
54.61 6.9320 0.6348 25.5301 10.1125 55.1633
56.97 6.8884 0.6180 26.1650 11.0277 55.0036
57.68 6.8590 0.5768 26.9138 11.4278 54.1177
61.80 6.7769 0.5697 26.9916 11.4684 53.3026
63.48 6.7713 0.5461 27.0399 11.6677 51.6866
64.31 6.7405 0.5436 27.2326 11.6873 44.7652
64.94 6.5733 0.5421 27.7480 11.7104 37.8030
65.64 6.5538 0.4868 27.9372 12.1207 34.8420
66.36 6.4775 0.4552 28.4543 12.1640 34.3896
79.60 6.4079 0.4292 29.0855 12.3564 34.1117
82.27 6.3388 0.4113 29.1130 12.3625 30.2032
82.87 6.2305 0.3026 30.1287 12.3686 18.9015

REMOCIÓN CATALÍTICA
Remoción Hg OD SO4= ST
pH
(%) CHg
(mg/L) (mg/L) (mg/L)
30.26 7.2486 0.6090 22.5428 8.8549 66.1804
41.13 7.2288 0.6029 23.3010 9.0812 65.0561
42.93 7.2251 0.5763 23.5538 9.1092 63.4757
45.52 7.1935 0.4439 23.9026 9.5394 62.6217
48.68 7.1883 0.4367 24.1955 9.5997 57.4137
54.21 7.0892 0.4297 24.9708 9.8643 56.9064
54.36 6.9459 0.4234 25.0600 10.1123 56.2696
54.61 6.9320 0.4151 25.5301 10.1125 55.1633
56.97 6.8884 0.3983 26.1650 11.0277 55.0036
57.68 6.8590 0.3571 26.9138 11.4278 54.1177
61.80 6.7769 0.3500 26.9916 11.4684 53.3026
63.48 6.7713 0.3264 27.0399 11.6677 51.6866
64.31 6.7405 0.3239 27.2326 11.6873 44.7652
64.94 6.5733 0.3224 27.7480 11.7104 37.8030
65.64 6.5538 0.2671 27.9372 12.1207 34.8420
 66.36 6.4775 0.2355 28.4543 12.1640 34.3896
79.60 6.4079 0.2096 29.0855 12.3564 34.1117
82.27 6.3388 0.1916 29.1130 12.3625 30.2032
82.87 6.2305 0.0829 30.1287 12.3686 18.9015

Remoción Hg OD SO4=
(%) pH CHg (mg/L) (mg/L)

Remoción Hg
(%) 1
pH -0.9544232416 1
CHg -0.9630385675 0.9520512222 1
OD
(mg/L) 0.97187984007 -0.9827329315 -0.9703701137 1
SO4=
(mg/L) 0.93026427636 -0.9520705718 -0.9335354882 0.9790208399 1
ST
(mg/L) -0.9231470461 0.9687817243 0.9429711667 -0.9425396842 -0.886812089
 OXIDACIÓN QUÍMICA
Remoción Hg OD SO4= ST
pH AHg
(%) (mg/L) (mg/L) (mg/L)
22.26 6.1159 0.7342 30.0967 12.1595 67.7125
25.59 6.2357 0.7289 30.0734 12.1527 62.1703
28.39 6.2460 0.7073 29.8820 12.0774 61.4350
34.00 6.2595 0.6331 29.8453 11.9286 60.6389
35.60 6.2882 0.5691 29.4142 11.9265 57.9759
36.28 6.3234 0.5452 29.1338 11.8764 52.5238
39.26 6.4399 0.5226 28.9447 11.7290 51.4259
40.57 6.5055 0.5162 28.7435 11.6312 51.3680
41.70 6.5118 0.4909 28.5009 11.2610 50.1660
44.46 6.5430 0.4446 28.4122 10.7136 44.6357
49.10 6.7577 0.4170 28.1791 10.6399 39.4875
51.62 6.7630 0.4057 26.8122 10.5849 37.4816
52.26 6.7668 0.3926 26.1100 10.5360 32.8953
54.52 6.8902 0.3628 26.0922 10.2966 27.5671
56.91 7.1187 0.3560 26.0573 10.0320 27.3800
63.31 7.1920 0.3400 24.7792 9.5844 26.0283
70.74 7.2245 0.2839 24.7259 9.1509 25.6639
72.89 7.2314 0.2559 23.6118 9.0106 25.6294
73.42 7.2672 0.2226 23.5967 8.8607 24.8066

OXIDACIÓN QUÍMICA
Remoción Hg OD SO4= ST
pH
(%) CHg
(mg/L) (mg/L) (mg/L)
22.26 6.1159 0.5145 30.0967 12.1595 67.7125
25.59 6.2357 0.5092 30.0734 12.1527 62.1703
28.39 6.2460 0.4876 29.8820 12.0774 61.4350
34.00 6.2595 0.4134 29.8453 11.9286 60.6389
35.60 6.2882 0.3494 29.4142 11.9265 57.9759
36.28 6.3234 0.3255 29.1338 11.8764 52.5238
39.26 6.4399 0.3029 28.9447 11.7290 51.4259
40.57 6.5055 0.2965 28.7435 11.6312 51.3680
41.70 6.5118 0.2713 28.5009 11.2610 50.1660
44.46 6.5430 0.2249 28.4122 10.7136 44.6357
49.10 6.7577 0.1973 28.1791 10.6399 39.4875
51.62 6.7630 0.1860 26.8122 10.5849 37.4816
52.26 6.7668 0.1729 26.1100 10.5360 32.8953
54.52 6.8902 0.1431 26.0922 10.2966 27.5671
56.91 7.1187 0.1363 26.0573 10.0320 27.3800
63.31 7.1920 0.1203 24.7792 9.5844 26.0283
70.74 7.2245 0.0642 24.7259 9.1509 25.6639
72.89 7.2314 0.0362 23.6118 9.0106 25.6294
73.42 7.2672 0.0029 23.5967 8.8607 24.8066

ST Remoción Hg OD
(mg/L) (%) pH CHg (mg/L)

Remoción Hg
(%) 1
pH 0.97903733011 1
CHg -0.9759623809 -0.948862065 1
OD
(mg/L) -0.9766609655 -0.9720461834 0.9382640353 1
SO4=
(mg/L) -0.9826584308 -0.9800144606 0.9486330759 0.9761836248
ST
1 (mg/L) -0.9594830281 -0.9734450812 0.9656684113 0.9531653459
 BIORREMEDIACIÓN
Remoción Hg OD SO4= ST Remoción Hg
pH AHg
(%) (mg/L) (mg/L) (mg/L) (%)
31.01 6.1032 0.7959 34.1662 12.3251 82.7507 24.20
33.38 6.1382 0.7901 34.0549 11.9933 80.5480 28.65
34.96 6.2013 0.7852 33.5305 11.6963 77.3957 32.98
35.04 6.2167 0.7307 33.4984 11.6261 73.2257 33.53
35.72 6.2294 0.6568 33.4148 11.2634 62.4671 37.40
36.92 6.3267 0.6396 32.9124 11.2230 54.4069 44.43
42.19 6.3804 0.6393 32.4998 11.2077 51.0563 46.24
51.55 6.3858 0.6129 29.3697 11.1968 41.2925 46.87
56.68 6.4992 0.6080 29.1974 10.9914 38.9179 47.98
59.53 6.7109 0.5953 28.6818 10.8834 34.5278 59.45
60.80 6.7370 0.5668 28.6679 10.8705 33.8947 60.12
61.29 6.7471 0.5155 28.4707 10.2055 27.2405 66.58
63.93 6.7543 0.4219 27.8066 10.1288 25.8055 74.57
63.96 6.7720 0.3692 27.4746 10.1094 22.9970 75.31
65.68 7.0274 0.3572 24.6427 9.8753 22.0235 80.55
73.08 7.0968 0.3504 24.1437 9.7883 21.0593 86.21
78.52 7.1198 0.3496 23.7480 9.7549 19.3736 86.42
79.01 7.1513 0.3338 22.7506 9.4303 16.7868 86.93
79.59 7.2737 0.3100 22.5994 9.2910 16.7061 90.67

DATOS EN TERMINOS DE CONCENTRACION

BIORREMEDIACIÓN
Remoción Hg OD SO4= ST Remoción Hg
pH
(%) CHg
(mg/L) (mg/L) (mg/L) (%)
31.01 6.1032 0.5762 34.1662 12.3251 82.7507 24.20
33.38 6.1382 0.5704 34.0549 11.9933 80.5480 28.65
34.96 6.2013 0.5655 33.5305 11.6963 77.3957 32.98
35.04 6.2167 0.5111 33.4984 11.6261 73.2257 33.53
35.72 6.2294 0.4371 33.4148 11.2634 62.4671 37.40
36.92 6.3267 0.4199 32.9124 11.2230 54.4069 44.43
42.19 6.3804 0.4196 32.4998 11.2077 51.0563 46.24
51.55 6.3858 0.3932 29.3697 11.1968 41.2925 46.87
56.68 6.4992 0.3883 29.1974 10.9914 38.9179 47.98
59.53 6.7109 0.3756 28.6818 10.8834 34.5278 59.45
60.80 6.7370 0.3471 28.6679 10.8705 33.8947 60.12
61.29 6.7471 0.2958 28.4707 10.2055 27.2405 66.58
63.93 6.7543 0.2022 27.8066 10.1288 25.8055 74.57
63.96 6.7720 0.1495 27.4746 10.1094 22.9970 75.31
65.68 7.0274 0.1375 24.6427 9.8753 22.0235 80.55
 73.08 7.0968 0.1307 24.1437 9.7883 21.0593 86.21
78.52 7.1198 0.1299 23.7480 9.7549 19.3736 86.42
79.01 7.1513 0.1141 22.7506 9.4303 16.7868 86.93
79.59 7.2737 0.0904 22.5994 9.2910 16.7061 90.67

SO4= ST Remoción Hg OD
(mg/L) (mg/L) (%) pH CHg (mg/L)

Remoción Hg
(%) 1
pH 0.97697447371 1
CHg -0.941996581 -0.9562824374 1
OD
(mg/L) -0.9837535093 -0.9831075535 0.9505838207 1
SO4=
1 (mg/L) -0.949338505 -0.9665071208 0.9813821747 0.9519141422
ST
0.9517980535 1 (mg/L) -0.9546192797 -0.9310713228 0.9482949742 0.9287210038
 INTERCAMBIO IÓNICO CURVAS CAL
OD SO4=
ST CHg
pH AHg AHg01
(mg/L) (mg/L) (mg/L) (mg/L)
7.2907 0.9067 21.9700 8.8003 66.1759 0.0000 0.0891
7.2802 0.8693 22.1521 9.0731 61.0800 0.1000 0.1598
7.2503 0.8642 22.2591 9.1444 60.2600 0.2000 0.2231
7.2464 0.8621 23.4327 9.1552 55.9101 0.3000 0.2617
6.9378 0.8055 23.8491 9.2391 53.1392 0.4000 0.2889
6.8874 0.7531 24.2026 9.2869 51.5023 0.5000 0.3567
6.8644 0.7456 24.8393 9.3566 50.0551 0.6000 0.4153
6.7108 0.6658 25.5309 9.4492 47.5514 0.7000 0.4547
6.6069 0.6011 25.6462 9.4570 41.2137 0.8000 0.5017
6.6000 0.5945 25.7646 9.8810 40.3146 0.9000 0.5881
6.5530 0.4798 26.9531 10.1347 36.9001 1.0000 0.6292
6.5122 0.4686 27.3534 10.2999 34.0229 1.1000 0.7008
6.5080 0.4624 27.4562 11.4004 33.5581 1.2000 0.7127
6.4956 0.4443 27.8267 11.7081 32.8477 1.3000 0.7797
6.4576 0.3739 28.9525 11.7542 30.3223 1.4000 0.8008
6.3937 0.3353 29.7518 11.8112 25.7972 1.5000 0.8572
6.3881 0.3298 30.0154 11.8168 24.2798 1.6000 0.9110
6.2656 0.2865 30.1603 11.9720 23.1628 1.7000 0.9464
6.2440 0.2420 30.1839 12.1246 21.3162 1.8000 0.9954

ION
INTERCAMBIO IÓNICO CURVAS CAL
OD SO4=
ST CHg
pH CHg
(mg/L) (mg/L) (mg/L) (mg/L) CHg01

7.2907 0.6870 21.9700 8.8003 66.1759 0.0000 -0.1306

7.2802 0.6496 22.1521 9.0731 61.0800 0.1000 -0.0599
7.2503 0.6445 22.2591 9.1444 60.2600 0.2000 0.0034
7.2464 0.6424 23.4327 9.1552 55.9101 0.3000 0.0420
6.9378 0.5858 23.8491 9.2391 53.1392 0.4000 0.0692
6.8874 0.5334 24.2026 9.2869 51.5023 0.5000 0.1370
6.8644 0.5260 24.8393 9.3566 50.0551 0.6000 0.1956
6.7108 0.4461 25.5309 9.4492 47.5514 0.7000 0.2350
6.6069 0.3815 25.6462 9.4570 41.2137 0.8000 0.2820
6.6000 0.3748 25.7646 9.8810 40.3146 0.9000 0.3685
6.5530 0.2601 26.9531 10.1347 36.9001 1.0000 0.4095
6.5122 0.2490 27.3534 10.2999 34.0229 1.1000 0.4811
6.5080 0.2427 27.4562 11.4004 33.5581 1.2000 0.4930
6.4956 0.2246 27.8267 11.7081 32.8477 1.3000 0.5600
6.4576 0.1543 28.9525 11.7542 30.3223 1.4000 0.5811
 6.3937 0.1156 29.7518 11.8112 25.7972 1.5000 0.6375
6.3881 0.1101 30.0154 11.8168 24.2798 1.6000 0.6914
6.2656 0.0668 30.1603 11.9720 23.1628 1.7000 0.7267
6.2440 0.0223 30.1839 12.1246 21.3162 1.8000 0.7758

SO4= ST Remoción Hg OD
(mg/L) (mg/L) (%) pH CHg (mg/L)

Remoción Hg
(%) 1
pH -0.94401379 1
CHg -0.9846890484 0.9669497433 1
OD
(mg/L) 0.98645238042 -0.9593662312 -0.9888855845 1
SO4=
1 (mg/L) 0.97176080086 -0.8628331372 -0.9435161429 0.9447956293
ST
0.9459820182 1 (mg/L) -0.9842130185 0.9734602061 0.9916964152 -0.9904404
CURVAS CALIBRACIÓN Fe PARÁMETROS CALIDAD ANALÍTICA Hg

AHg02 AHg03 AHg04 AHg05 AHg06 AHg07 Lectura AHgB01 AHgB02 AHgB03 AHgPat01

0.0949 0.0878 0.0934 0.0706 0.0694 0.0841 001 0.0994 0.0966 0.0857 0.5951
0.1408 0.1571 0.1366 0.1194 0.1196 0.1666 002 0.1091 0.0883 0.0849 0.5725
0.2427 0.2010 0.2068 0.2173 0.2029 0.2273 003 0.1138 0.1018 0.0828 0.5980
0.2725 0.2848 0.2736 0.2657 0.2487 0.2849 004 0.1097 0.0924 0.0864 0.5870
0.3259 0.3142 0.2928 0.3097 0.3298 0.3126 005 0.0824 0.0837 0.0875 0.5846
0.3621 0.3694 0.3455 0.3575 0.3449 0.3545 006 0.0841 0.1079 0.1016 0.5910
0.3905 0.4007 0.3839 0.4004 0.4227 0.4056 007 0.1122 0.1085 0.1103 0.5661
0.4600 0.4289 0.4628 0.4569 0.4590 0.4377 008 0.1096 0.1094 0.0960 0.5808
0.5154 0.5565 0.5291 0.5256 0.5156 0.5254 009 0.0911 0.0911 0.1026 0.5869
0.5812 0.5777 0.5746 0.5654 0.5618 0.5834 010 0.0955 0.1001 0.1058 0.5665
0.6298 0.6164 0.6170 0.6318 0.6065 0.6244 011 0.1036 0.0875 0.1130 0.5796
0.6777 0.6975 0.6957 0.6854 0.6546 0.6896 012 0.0974 0.1022 0.1117 0.5971
0.7244 0.7511 0.7457 0.7194 0.7167 0.7055 013 0.1125 0.0881 0.1118 0.5952
0.7599 0.7781 0.7932 0.7679 0.7750 0.7576 014 0.0949 0.0931 0.0914 0.5650
0.8127 0.8276 0.8075 0.8160 0.8213 0.8059 015 0.1136 0.1007 0.1096 0.5671
0.8567 0.8682 0.8617 0.8757 0.8467 0.8604 016 0.0940 0.0858 0.0889 0.5934
0.9116 0.8988 0.9087 0.9027 0.8989 0.9129 017 0.1149 0.0971 0.1098 0.5655
0.9326 0.9518 0.9418 0.9368 0.9426 0.9311 018 0.0991 0.0979 0.0924 0.5792
0.9803 0.9943 0.9931 0.9729 0.9852 0.9592 019 0.0846 0.0962 0.1058 0.5907

CURVAS CALIBRACIÓN Fe PARÁMETROS CALIDAD ANALÍTICA Hg

CHg02 CHg03 CHg04 CHg05 CHg06 CHg07 Lectura CHgB01 CHgB02 CHgB03 CHgPat01

-0.1248 -0.1319 -0.1263 -0.1490 -0.1503 -0.1356 001 -0.0212 -0.0270 -0.0486 0.9666
-0.0789 -0.0626 -0.0831 -0.1003 -0.1001 -0.0531 002 -0.0020 -0.0435 -0.0503 0.9215
0.0231 -0.0187 -0.0129 -0.0024 -0.0168 0.0076 003 0.0075 -0.0165 -0.0543 0.9723
0.0528 0.0651 0.0539 0.0460 0.0290 0.0652 004 -0.0008 -0.0353 -0.0473 0.9504
0.1062 0.0945 0.0731 0.0900 0.1102 0.0929 005 -0.0552 -0.0526 -0.0450 0.9457
0.1424 0.1497 0.1258 0.1378 0.1252 0.1348 006 -0.0518 -0.0044 -0.0169 0.9584
0.1708 0.1810 0.1643 0.1807 0.2030 0.1859 007 0.0043 -0.0031 0.0004 0.9087
0.2403 0.2092 0.2431 0.2373 0.2393 0.2180 008 -0.0009 -0.0014 -0.0282 0.9380
0.2957 0.3368 0.3094 0.3059 0.2959 0.3057 009 -0.0378 -0.0379 -0.0150 0.9502
0.3615 0.3580 0.3549 0.3457 0.3421 0.3637 010 -0.0290 -0.0200 -0.0086 0.9096
0.4102 0.3968 0.3973 0.4121 0.3868 0.4047 011 -0.0129 -0.0450 0.0057 0.9357
0.4581 0.4779 0.4760 0.4658 0.4349 0.4700 012 -0.0252 -0.0158 0.0032 0.9705
0.5047 0.5315 0.5260 0.4997 0.4970 0.4858 013 0.0047 -0.0439 0.0034 0.9667
0.5403 0.5584 0.5735 0.5482 0.5554 0.5379 014 -0.0303 -0.0339 -0.0372 0.9065
0.5930 0.6080 0.5878 0.5963 0.6016 0.5862 015 0.0069 -0.0187 -0.0010 0.9107
 0.6370 0.6485 0.6420 0.6560 0.6270 0.6407 016 -0.0320 -0.0483 -0.0423 0.9632
0.6919 0.6791 0.6890 0.6830 0.6792 0.6932 017 0.0095 -0.0258 -0.0006 0.9075
0.7129 0.7321 0.7222 0.7171 0.7229 0.7114 018 -0.0219 -0.0243 -0.0353 0.9348
0.7606 0.7746 0.7734 0.7532 0.7655 0.7396 019 -0.0508 -0.0277 -0.0086 0.9578

SO4= ST
(mg/L) (mg/L)

-0.9316141259 1
AD ANALÍTICA Hg

AHgPat02 AHgPat03 VR C Max Min

0.5822 0.5814 AHgPat01 1 19 0.9723 0.906475788

0.5844 0.5823 AHgPat02 1 19 0.9707 0.895123643
0.5593 0.5695 AHgPat03 1 19 0.971652364 0.896179691
0.5817 0.5621
0.5595 0.5889
0.5731 0.5846 Caja inf Caja cen Caja sup Bigote inf
0.5755 0.5842 AHgPat01 0.024712059 0.916071854 0.020033785 0.009596066
0.5727 0.5850 AHgPat02 0.016965423 0.910074414 0.013300805 0.014950771
0.5662 0.5613 AHgPat03 0.012225703 0.922698941 0.010495809 0.026519249
0.5791 0.5598
0.5694 0.5790
0.5784 0.5816
0.5963 0.5712
0.5767 0.5794
0.5852 0.5977
0.5673 0.5946
0.5644 0.5750
0.5617 0.5844
0.5972 0.5834

AD ANALÍTICA Hg

CHgPat02 CHgPat03

0.9409 0.9393
0.9452 0.9411
0.8951 0.9156
0.9398 0.9009
0.8956 0.9541
0.9227 0.9456
0.9274 0.9448
0.9220 0.9464
0.9091 0.8992
0.9346 0.8962
0.9152 0.9344
0.9333 0.9396
0.9689 0.9189
0.9300 0.9353
0.9468 0.9717
0.9111 0.9656
0.9054 0.9265
0.8999 0.9453
0.9707 0.9432
 Rango M Me Mo MG H Q1

0.065809134 0.940783913 0.945696729 ### 0.940498278 0.940211442 0.916071854

0.075624191 0.927039837 0.927398461 ### 0.926790851 0.926543183 0.910074414
0.075472672 0.934924644 0.939565994 ### 0.934701024 0.934476011 0.922698941

Bigote sup
0.011467225
0.030407192
0.026231911
 Q3 Cur CF CP CB s v

0.960817697 -1.455422872 -0.276530904 ### -0.931167232 0.023764579 0.000564755

0.940340641 -0.333069655 0.4043485166 ### -0.914734287 0.022132643 0.000489854
0.945420453 -0.211515835 -0.431726646 ### -0.934347296 0.020943265 0.00043862
 DM EE ER %ER EA ªL Prob t K

0.020431223 0.005451968 0.025260401 2.526040108 0.059216087 18 0.005 0.996065592 1.96

0.017604683 0.005077576 0.023874533 2.387453263 0.072960163 18 0.005 0.996065592 1.96
0.016087516 0.004804715 0.02240102 2.240101978 0.065075356 18 0.005 0.996065592 1.96
 Uins UB UV UVR Us Uc UEXP

0.003674235 0.004898979 0.004898979 0.001732051 0.005451968 0.009706903 0.019025529

0.003674235 0.004898979 0.004898979 0.001732051 0.005077576 0.009501673 0.018623278
0.003674235 0.004898979 0.004898979 0.001732051 0.004804715 0.009358701 0.018343054
 Intervalo de Intervalo de Intervalo de
LOD LOQ
cobertura confianza k confianza t
0.071293737 0.005647552 0,9408±0,0097 0,9408±0,0190 0,9408±0,996
0.066397928 0.004898539 0,927±0,0095 0,927±0,01862 0,927±0,996
0,9349±0,0183
0.062829796 0.004386204 0,9349±0,0093 0,9349±0,996
4
Media Desviacion
0.9408 0.01192459

LecturaCHgPat01 P-3S P-2S P-S P P+S P+2S

001 0.96661999 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
002 0.92148016 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
003 0.97228492 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
004 0.95038399 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
005 0.94569673 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
006 0.9584451 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
007 0.90868836 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
008 0.93804233 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
009 0.95022246 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
010 0.90958766 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
011 0.93569064 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
012 0.97052673 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
013 0.96672835 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
014 0.90647579 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
015 0.91066355 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
016 0.9631903 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
017 0.90748366 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
018 0.93484645 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
019 0.95783719 0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
0.90501014 0.916934732 0.92885932 0.94078391 0.9527085 0.96463309
 Media Desviacion
0.927039837 0.01110572

P+3S Lectura CHgPat02 P-3S P-2S P-S P

0.97655768 001 0.94092626 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 002 0.94522242 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 003 0.89512364 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 004 0.93975502 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 005 0.89556932 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 006 0.92269061 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 007 0.92739846 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 008 0.92200064 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 009 0.90905318 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 010 0.93463168 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 011 0.91524512 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 012 0.93329424 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 013 0.96890355 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 014 0.92995334 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 015 0.94681005 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 016 0.91109565 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 017 0.90539613 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 018 0.89993974 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 019 0.97074783 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984
0.97655768 0.89372268 0.9048284 0.91593412 0.92703984

P+S P+2S P+3S
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
0.93814555 0.94925127 0.96035699
Media Desviacion
0.934924644 0.02094327
Lectura CHgPat03 P-3S P-2S
001 0.93927054 0.87209485 0.89303811
002 0.94109431 0.87209485 0.89303811
003 0.91555691 0.87209485 0.89303811
004 0.90087085 0.87209485 0.89303811
005 0.95414502 0.87209485 0.89303811
006 0.94555543 0.87209485 0.89303811
007 0.94476597 0.87209485 0.89303811
008 0.94644699 0.87209485 0.89303811
009 0.89922577 0.87209485 0.89303811
010 0.89617969 0.87209485 0.89303811
011 0.93441001 0.87209485 0.89303811
012 0.93956599 0.87209485 0.89303811
013 0.91886846 0.87209485 0.89303811
014 0.93533837 0.87209485 0.89303811
015 0.97165236 0.87209485 0.89303811
016 0.96559354 0.87209485 0.89303811
017 0.92652942 0.87209485 0.89303811
018 0.94528548 0.87209485 0.89303811
019 0.94321311 0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.87209485 0.89303811
0.93814555 0.94925127 0.96035699
P-S P P+S P+2S P+3S
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
0.91398138 0.93492464 0.95586791 0.97681117 0.99775444
 Carta de control para Concentracion de mercurio pat01
0.98 Límite de control superior

0.975

0.97 Límite critico superior

0.965

0.96
Advertencia superior
0.955

0.95

0.945 Promedio

0.94

0.935
Advertencia inferior
0.93

0.925

0.92 Límite critico inferior

0.915

0.91
Límite de control inferior
0.905

0.9
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
 Carta de control para Concentracion de mercurio pat01
0.98
0.975
0.97
Límite de control superior
0.965
0.96
0.955
0.95 Límite critico superior
0.945
0.94
0.935 Advertencia superior
0.93
0.925
0.92 Promedio
0.915
0.91
0.905
Advertencia inferior
0.9
0.895
0.89
0.885 Límite critico inferior
0.88
0.875
0.87 Límite de control inferior
0.865
0.86
0.855
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
 Carta de control para Concentracion de mercurio pat01
1.01
Límite de control superior
1
0.99
0.98
Límite critico superior
0.97
0.96
0.95
Advertencia superior
0.94
0.93
0.92
Promedio
0.91
0.9
0.89
0.88 Advertencia inferior
0.87
0.86
0.85 Límite critico inferior
0.84
0.83
0.82 Límite de control inferior
0.81
0.8
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
 β0 β1 β2 β3 β4 β5 r
INTERCAMBIO IÓNICO 15.01248 -7.40493 3.64423 1.24673 7.93461 -0.59892 0.99614
OXIDACIÓN QUÍMICA 23.32104 15.40747 -27.38366 -1.95176 -1.97588 0.36174 0.99609
BIORREMEDIACIÓN 63.19641 10.63066 12.65232 -2.59607 -0.24837 -0.27849 0.99206
REMOCIÓN
-53.20574 -5.90667 -15.33384 8.48821 -6.34949 0.25861 0.98029
CATALÍTICA
R2 Error β0 Error β1 Error β2 Error β3 Error β4 Error β5 μί
0.99230 62.79568 8.52057 11.46732 1.59689 1.75686 0.39543 2.29164 Remocion
0.99220 67.00932 6.82725 5.23051 0.86312 2.14132 0.14581 1.62022 =15,01248-
0.98418 108.73111 10.13415 9.88734 0.83389 4.09686 0.08504 2.50305 7,40493*pH
+3,64423*C
0.96096 194.09470 19.18431 13.43437 3.80258 3.57892 0.29422 3.23567 Hg+1,24673
*OD+7,934
61*SO4=-
0.59892*µ
 β0 β1 r r2 Error β0 Error β1
AHg01 0.110101241 0.501784738 0.998319556 0.996641935 0.007442681 0.00706428
AHg06 0.098606753 0.505762367 0.998283999 0.996570942 0.007580831 0.007195406
AHg02 0.118512564 0.492407786 0.998149905 0.996303233 0.007664383 0.007274711
AHg04 0.103594329 0.508486514 0.997743768 0.995492627 0.008742974 0.008298463
AHg05 0.102869203 0.505420248 0.997630566 0.995266746 0.008906351 0.008453534
AHg07 0.120046816 0.48817386 0.997538946 0.995083948 0.008767786 0.008322014
AHg03 0.112455328 0.504403565 0.99717456 0.994357103 0.009709459 0.009215811
µ
0.016865738 AHg=0.11010124+0.501178474*CHg+0.01686574
0.017178797
0.017368134 CHg=A-0.11010124/0.501178474
0.01981231
0.020182536
0.019868536
0.022002447
 ELIMINACION DE MERCURIO
0.95

0.945

0.94
% REMOSION

0.935

0.93

0.925

0.92

0.915
AHgPat01 AHgPat02 AHgPat03

LECTRURA
 ELIMINACION DE MERCURIO
0.025

0.02

0.015
% REMOSION

0.01

0.005

0
AHgPat01 AHgPat02 AHgPat03

LECTRURA
 ELIMINACION DE MERCURIO
0.03

0.025

0.02
% REMOSION

0.015

0.01

0.005

0
AHgPat01 AHgPat02 AHgPat03

LECTRURA
 Eliminacion de mercurio
1.2

0.8

0.6

0.4

0.2

0
AHgPat01 AHgPat02 AHgPat03
 ELIMINACION DE MERCURIO
0.02

0.018

0.016

0.014

0.012
% REMOSION

0.01

0.008

0.006

0.004

0.002

0
AHgPat01 AHgPat02 AHgPat03

LECTRURA