Normalidad de Disolucion Patron Primario Molaridad de disolucion Patron Pr

Sustancia Hidroxido de Sodio Hidroxido de sodio

PM 40 g de soluto 0.4 PM 40
Volumen(L) 0.1 Volumen(L) 0.1
Normalidad 0.1 Normalidad 0.1
#Cargas 1

Normalidad de Disolucion Patron Secundario Molaridad de disolucion Patron Sec

Sustancia CH3COOH Glacial Sustancia CH3COOH Glac
PM 60.1 g de soluto Teorico 0.601 PM 60
Volumen(L) 0.1 Densidad 1.055 Volumen(L) 0.1
Normalidad 0.1 Pureza 99.7 Normalidad 0.1
#Cargas 1 mL de soluto REAL 0.57138239
olaridad de disolucion Patron Primario
Hidroxido de sodio
g de soluto 0.4

laridad de disolucion Patron Secundario

CH3COOH Glacial
g de soluto Teorico 0.6
Densidad 1.055
Pureza 99.7
mL de soluto REAL 0.57043167
 Acidos
pKa 4.75 Concentracion 0.1
Ka 1.77827941E-05 a 1
b 1.77827941E-04 c -1.77827941E-04
Los acidos y bases de fuerza media
Grado de Tipo de Acido distaran de resultados exactos por el
Disociacion(α) 0.013157682799 Acido Debil redondeo de decimales al momento de
hacer operaciones en exel y el pKa de
%α 1.315768279905 a 1 acidos fuertes es igual a 2 y el pKb de
b 1.77827941E-05 c -1.77827941E-06 bases fuertes es igual a 2
pH 2.875 Acido Acetico
 Bases
pKb 0 Concentracio 0.1
Kb 1.00000000E+00 a 1
b 1.00000000E+01 c -1.00000000E+01
ases de fuerza media
ultados exactos por el Grado de Tipo de
cimales al momento de Hidrolisis(α) -4.0839202169004 Acido Base Fuerte
nes en exel y el pKa de
es igual a 2 y el pKb de %α -408.39202169004 a 1
ertes es igual a 2 b 1.00000000E+00 c 1.00000000E-01
Hidroxido de
pH 13 Base
Sodio
 Acido debil-Base Fuerte
Molaridad de Acido 0.1 Volumen Inicial (ml) 15
Molaridad de Base 0.1 Volumen Agregado (mL) 0.2
Particiones 75 #Cargas o Equivalencia 1
ka (Acido) 1.8E-05 pka (Acido) 4.74472749489669
Moles B 0.0015 Concentracion Rx 0.1
pKa (Base) 1E-14 pka(Base) 14
Volumen agregado
Acido Moles de A pH
Constante de
0 0 2.87236374744835 equilibrio de Reaccion
0.2 2E-05 2.87549577516572 1800000000
0.4 4E-05 3.18243463044022
0.6
0.8
6E-05
8E-05
3.36451625318509
3.49552913750558 ε
1 0.0001 3.59859945921846 7.453559924999E-05
1.2 0.00012 3.68402965454308
1.4 0.00014 3.75731662220471 %P(Cuantitividad)
1.6 0.00016 3.82174267918781
1.8 0.00018 3.87942606879415 99.992546440075
2 0.0002 3.93181413825384
2.2 0.00022 3.97994020607103
2.4 0.00024 4.02456819149074
2.6 0.00026 4.06627915770528
2.8 0.00028 4.10552569556416
3 0.0003 4.14266750356873
3.2 0.00032 4.17799546591047
3.4 0.00034 4.21174842271203
3.6 0.00036 4.24412514432751
3.8 0.00038 4.27529306884332
4 0.0004 4.30539480106643
4.2 0.00042 4.33455302980765
4.4 0.00044 4.36287430611811
4.6 0.00046 4.39045198727949
4.8 0.00048 4.41736856051036
5 0.0005 4.44369749923271
5.2 0.00052 4.469504762839
5.4 0.00054 4.49485002168009
5.6 0.00056 4.5197876683032
5.8 0.00058 4.54436766111408
6 0.0006 4.56863623584101
6.2 0.00062 4.59263651224478
6.4 0.00064 4.61640901763701
6.6 0.00066 4.63999214437668
6.8 0.00068 4.66342255521921
7 0.0007 4.68673554791901
 7.2 0.00072 4.70996538863748
7.4 0.00074 4.73314562234688
7.6 0.00076 4.75630936744651
7.8 0.00078 4.77948960115591
8 0.0008 4.80271944187438
8.2 0.00082 4.82603243457417
8.4 0.00084 4.84946284541671
8.6 0.00086 4.87304597215637
8.8 0.00088 4.89681847754861
9 0.0009 4.92081875395238
9.2 0.00092 4.94508732867931
9.4 0.00094 4.96966732149019
9.6 0.00096 4.99460496811329
9.8 0.00098 5.01995022695439
10 0.001 5.04575749056068
10.2 0.00102 5.07208642928302
10.4 0.00104 5.0990030025139
10.6 0.00106 5.12658068367528
10.8 0.00108 5.15490195998574
11 0.0011 5.18406018872695
11.2 0.00112 5.21416192095006
11.4 0.00114 5.24532984546588
11.6 0.00116 5.27770656708136
11.8 0.00118 5.31145952388291
12 0.0012 5.34678748622465
12.2 0.00122 5.38392929422922
12.4 0.00124 5.42317583208811
12.6 0.00126 5.46488679830265
12.8 0.00128 5.50951478372235
13 0.0013 5.55764085153955
13.2 0.00132 5.61002892099923
13.4 0.00134 5.66771231060557
13.6 0.00136 5.73213836758867
13.8 0.00138 5.8054253352503
14 0.0014 5.89085553057492
14.2 0.00142 5.9939258522878
14.4 0.00144 6.12493873660829
14.6 0.00146 6.30702035935315
14.8 0.00148 6.61395921462763
15 0.0015 7.96040937697619
15.2 0.00152 11.1818435879448
15.4 0.00154 11.1875207208365
15.6 0.00156 11.1931245983545
15.8 0.00158 11.1986570869544
16 0.0016 11.2041199826559
 16.2 0.00162 11.2095150145426
16.4 0.00164 11.2148438480477
16.6 0.00166 11.2201080880401
16.8 0.00168 11.2253092817259
17 0.0017 11.2304489213783
17.2 0.00172 11.2355284469075
17.4 0.00174 11.2405492482826
17.6 0.00176 11.2455126678141
17.8 0.00178 11.2504200023089
18 0.0018 11.2552725051033
18.2 0.00182 11.2600713879851
18.4 0.00184 11.2648178230095
18.6 0.00186 11.2695129442179
18.8 0.00188 11.2741578492637
19 0.0019 11.2787536009528
19.2 0.00192 11.2833012287035
19.4 0.00194 11.2878017299302
19.6 0.00196 11.2922560713565
19.8 0.00198 11.2966651902615
20 0.002 11.301029995664
20.2 0.00202 11.3053513694466
20.4 0.00204 11.3096301674259
20.6 0.00206 11.3138672203692
20.8 0.00208 11.3180633349628
21 0.0021 11.3222192947339
21.2 0.00212 11.3263358609288
21.4 0.00214 11.3304137733492
21.6 0.00216 11.3344537511509
21.8 0.00218 11.3384564936046
22 0.0022 11.3424226808222
22.2 0.00222 11.3463529744506
22.4 0.00224 11.3502480183342
22.6 0.00226 11.3541084391474
22.7999999999999 0.00228 11.3579348470005
22.9999999999999 0.0023 11.3617278360176
23.1999999999999 0.00232 11.3654879848909
23.3999999999999 0.00234 11.3692158574101
23.5999999999999 0.00236 11.3729120029701
23.7999999999999 0.00238 11.3765769570565
23.9999999999999 0.0024 11.3802112417116
24.1999999999999 0.00242 11.3838153659804
24.3999999999999 0.00244 11.3873898263387
24.5999999999999 0.00246 11.3909351071034
24.7999999999999 0.00248 11.3944516808262
24.9999999999999 0.0025 11.397940008672
25.1999999999999 0.00252 11.4014005407815
25.3999999999999 0.00254 11.4048337166199
25.5999999999999 0.00256 11.4082399653118
25.7999999999999 0.00258 11.4116197059632
25.9999999999999 0.0026 11.4149733479708
26.1999999999999 0.00262 11.4183012913197
26.3999999999999 0.00264 11.4216039268698
26.5999999999999 0.00266 11.4248816366311
26.7999999999999 0.00268 11.4281347940288
26.9999999999999 0.0027 11.431363764159
27.1999999999999 0.00272 11.4345689040342
27.3999999999999 0.00274 11.4377505628204
27.5999999999999 0.00276 11.4409090820652
27.7999999999999 0.00278 11.4440447959181
27.9999999999999 0.0028 11.4471580313422
28.1999999999999 0.00282 11.4502491083194
28.3999999999999 0.00284 11.453318340047
28.5999999999999 0.00286 11.456366033129
28.7999999999999 0.00288 11.4593924877592
28.9999999999999 0.0029 11.462397997899
 Acido debil-Base Fuerte
14

12

10

0
0 5 10 15 20 25 30 35
 C
mL Adicionados pH x ΔpH/Δv 14
0 3.36 0.5 0.8
1 4.16 1.5 0.1 12

2 4.26 2.5 0.14 10

3 4.4 3.5 0.11
4 4.51 4.5 0.13 8

5 4.64 5.5 0.1 6

6 4.74 6.5 0.09
7 4.83 7.5 0.09 4

8 4.92 8.5 0.09 2

9 5.01 9.5 0.11
10 5.12 10.5 0.1 0
0 5
11 5.22 11.5 0.1
12 5.32 12.5 0.08
13 5.4 13.5 0.12
14 5.52 14.5 0.13 12

15 5.65 15.5 0.18

16 5.83 16.5 0.23 10
17 6.06 17.5 0.32
18 6.38 18.1 0.55 8
18.2 6.49 18.3 0.65
18.4 6.62 18.5 2.14999999999997 6
18.6 6.82 18.7 7.20000000000003
18.8 7.05 18.9 10.35 4
19 8.49 19.1 2.60000000000001
19.2 10.56 19.3 0.85
2
19.4 11.08 19.5 0.6
19.6 11.25 19.7 0.65000000000001
0
19.8 11.37 19.9 0.4 0
20 11.5 20.1 0.55
20.2 11.58
20.4 11.69

mL Adicionados pH x ΔpH/Δv
0 3.96 0.5 0.14
1 4.1 1.5 0.14
2 4.24 2.5 0.15
3 4.39 3.5 0.13
4 4.52 4.5 0.11
5 4.63 5.5 0.11
6 4.74 6.5 0.08
7 4.82 7.5 0.11
 8 4.93 8.5 0.08
9 5.01 9.5 0.1
10 5.11 10.5 0.09
11 5.2 11.5 0.11
12 5.31 12.5 0.11
13 5.42 13.5 0.12
14 5.54 14.5 0.14
15 5.68 15.5 0.18
16 5.86 16.5 0.21
17 6.07 17.5 0.33
18 6.4 18.1 0.75
18.2 6.55 18.3 0.70000000000001
18.4 6.69 18.5 1.74999999999997
18.6 6.82 18.7 6.00000000000002
18.8 7.04 18.9 8.60000000000003
19 8.24 19.1 1.85
19.2 9.96 19.3 3.05000000000001
19.4 10.33 19.5 0.85
19.6 10.94 19.7 0.85
19.8 11.11 19.9 0.70000000000001
20 11.28 20.1 0.6
20.2 11.42
20.4 11.54

mL Adicionados pH x ΔpH/Δv

0 3.96 0.5 0.15

1 4.11 1.5 0.13
2 4.24 2.5 0.1
3 4.34 3.5 0.19
4 4.53 4.5 0.1
5 4.63 5.5 0.1
6 4.73 6.5 0.12
7 4.85 7.5 0.09
8 4.94 8.5 0.08
9 5.02 9.5 0.11
10 5.13 10.5 0.1
11 5.23 11.5 0.09
12 5.32 12.5 0.11
13 5.43 13.5 0.11
14 5.54 14.5 0.15
15 5.69 15.5 0.15
16 5.84 16.5 0.19
17 6.03 17.5 0.37
18 6.4 18.1 0.55
18.2 6.51 18.3 0.85
18.4 6.68 18.5 0.99999999999999
18.6 6.88 18.7 0.9
18.8 7.06 18.9 4.15000000000002
19 7.89 19.1 11.25
19.2 10.14 19.3 2.75
19.4 10.69 19.5 1.70000000000001
19.6 11.03 19.7 1.00000000000001
19.8 11.23 19.9 0.85
20 11.4 20.1 0.55
20.2 11.51
20.4 11.6
 Curva de ti tulacion

0 5 10 15 20 25

Derivada de titulacion
12

10

0
0 5 10 15 20 25
mL Adicionados pH x ΔpH/Δv
0 3.36 0.5 0.8
1 4.16 1.5 0.1
2 4.26 2.5 0.14
3 4.4 3.5 0.11
4 4.51 4.5 0.13
5 4.64 5.5 0.1
6 4.74 6.5 0.09
7 4.83 7.5 0.09
8 4.92 8.5 0.09
9 5.01 9.5 0.11
10 5.12 10.5 0.1
11 5.22 11.5 0.1
12 5.32 12.5 0.08
13 5.4 13.5 0.12
14 5.52 14.5 0.13
15 5.65 7.5 -0.012
5.83 8.5 0.01352941
17 6.06 17.5 0.32
18 6.38 18.1 0.55
18.2 6.49 18.3 0.65
18.4 6.62 18.5 2.15
18.6 6.82 18.7 7.2
18.8 7.05 18.9 10.35
19 8.49 19.1 2.6
19.2 10.56 19.3 0.85
19.4 11.08 19.5 0.6
19.6 11.25 19.7 0.65
19.8 11.37 19.9 0.4
20 11.5 20.1 0.55
20.2 11.58
20.4 11.69
 Normalidad por peadas
Patron Primario Biftalato de Sodio PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Teorica 0.1
Muestra Peso de Patron Primario(g) Volumen Ocupado(L) Concentracion
1 0.4083 1.89E-02 1.05779E-01
2 0.4081 1.89E-02 1.05727E-01
3 0.4084 1.91E-02 1.04697E-01
4
5
Promedio %E S CV
1.05401E-01 5.40071838719 0.000863069427 0.81884586726

Normalidad por alicuota CH3COOH

Patron Primario NaOH PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Patron Primario 0.1054 Normalidad Teorica 0.1
Muestra Volumen de Patron Priario(g) Volumen Ocupado(L) Concentracion
1 1.46E-01 1.50E-02 1.02589E+00
2 1.46E-01 1.50E-02 1.02589E+00
3 1.46E-01 1.50E-02 1.02589E+00
4
5
Promedio %E S CV
1.02589E+00 925.893333333 0 0

Normalidad por alicuota HCL

Patron Primario NaOH PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Patron Primario 0.1054 Normalidad Teorica 0.1
Muestra Volumen de Patron Priario(g) Volumen Ocupado(L) Concentracion
1 9.00E-02 1.00E-02 9.48600E-01
2 9.10E-02 1.00E-02 9.59140E-01
3 9.00E-02 1.00E-02 9.48600E-01
4
5
Promedio %E S CV
0.952113 852.113333333 0.008605873963 0.90387075379
Molaridad por alicuotas
 Acido debil-Base Fuerte
Molaridad de Acido 0.1 Volumen Inicial (ml) 15
Molaridad de Base 0.1 Volumen Agregado (mL) 0.2
Particiones 75 #Cargas o Equivalencia 1
Kb (Base) 6.025596E-05 pkb (Base) 4.22
Moles B 0.0015 Concentracion Rx 0.1
Ka (Acido) 1 pka(Acido) 0
Volumen agregado
Acido Moles de A pH
Constante de
0 0 9.61 equilibrio de Reaccion
0.2 2E-05 9.58923171973098 16595.8690743756
0.4 4E-05 9.28229286445648
0.6
0.8
6E-05
8E-05
9.10021124171161
8.96919835739111 ε
1 0.0001 8.86612803567824 0.02454708915685
1.2 0.00012 8.78069784035361
1.4 0.00014 8.70741087269198 %P(Cuantitividad)
1.6 0.00016 8.64298481570888
1.8 0.00018 8.58530142610254 97.545291084315
2 0.0002 8.53291335664286
2.2 0.00022 8.48478728882566
2.4 0.00024 8.44015930340596
2.6 0.00026 8.39844833719142
2.8 0.00028 8.35920179933253
3 0.0003 8.32205999132796
3.2 0.00032 8.28673202898622
3.4 0.00034 8.25297907218466
3.6 0.00036 8.22060235056919
3.8 0.00038 8.18943442605337
4 0.0004 8.15933269383026
4.2 0.00042 8.13017446508905
4.4 0.00044 8.10185318877858
4.6 0.00046 8.07427550761721
4.8 0.00048 8.04735893438633
5 0.0005 8.02102999566398
5.2 0.00052 7.9952227320577
5.4 0.00054 7.9698774732166
5.6 0.00056 7.9449398265935
5.8 0.00058 7.92035983378262
6 0.0006 7.89609125905568
6.2 0.00062 7.87209098265192
6.4 0.00064 7.84831847725968
6.6 0.00066 7.82473535052001
6.8 0.00068 7.80130493967748
7 0.0007 7.77799194697769
 7.2 0.00072 7.75476210625921
7.4 0.00074 7.73158187254982
7.6 0.00076 7.70841812745018
7.8 0.00078 7.68523789374079
8 0.0008 7.66200805302231
8.2 0.00082 7.63869506032252
8.4 0.00084 7.61526464947999
8.6 0.00086 7.59168152274032
8.8 0.00088 7.56790901734809
9 0.0009 7.54390874094432
9.2 0.00092 7.51964016621738
9.4 0.00094 7.4950601734065
9.6 0.00096 7.4701225267834
9.8 0.00098 7.44477726794231
10 0.001 7.41897000433602
10.2 0.00102 7.39264106561367
10.4 0.00104 7.3657244923828
10.6 0.00106 7.33814681122142
10.8 0.00108 7.30982553491095
11 0.0011 7.28066730616974
11.2 0.00112 7.25056557394663
11.4 0.00114 7.21939764943082
11.6 0.00116 7.18702092781534
11.8 0.00118 7.15326797101378
12 0.0012 7.11794000867204
12.2 0.00122 7.08079820066747
12.4 0.00124 7.04155166280859
12.6 0.00126 6.99984069659405
12.8 0.00128 6.95521271117434
13 0.0013 6.90708664335715
13.2 0.00132 6.85469857389746
13.4 0.00134 6.79701518429112
13.6 0.00136 6.73258912730803
13.8 0.00138 6.6593021596464
14 0.0014 6.57387196432177
14.2 0.00142 6.4708016426089
14.4 0.00144 6.33978875828841
14.6 0.00146 6.15770713554355
14.8 0.00148 5.85076828026907
15 0.0015 3.52195437047216
15.2 0.00152 2.81815641205523
15.4 0.00154 2.81247927916354
15.6 0.00156 2.80687540164554
15.8 0.00158 2.80134291304558
16 0.0016 2.79588001734408
 16.2 0.00162 2.79048498545737
16.4 0.00164 2.7851561519523
16.6 0.00166 2.77989191195995
16.8 0.00168 2.77469071827414
17 0.0017 2.76955107862173
17.2 0.00172 2.76447155309245
17.4 0.00174 2.7594507517174
17.6 0.00176 2.75448733218585
17.8 0.00178 2.74957999769111
18 0.0018 2.74472749489669
18.2 0.00182 2.73992861201493
18.4 0.00184 2.73518217699046
18.6 0.00186 2.73048705578208
18.8 0.00188 2.72584215073632
19 0.0019 2.72124639904717
19.2 0.00192 2.71669877129645
19.4 0.00194 2.71219827006977
19.6 0.00196 2.70774392864352
19.8 0.00198 2.70333480973847
20 0.002 2.69897000433602
20.2 0.00202 2.69464863055338
20.4 0.00204 2.6903698325741
20.6 0.00206 2.68613277963085
20.8 0.00208 2.68193666503724
21 0.0021 2.67778070526608
21.2 0.00212 2.67366413907125
21.4 0.00214 2.66958622665081
21.6 0.00216 2.66554624884907
21.8 0.00218 2.6615435063954
22 0.0022 2.65757731917779
22.2 0.00222 2.65364702554936
22.4 0.00224 2.64975198166584
22.6 0.00226 2.6458915608526
22.7999999999999 0.00228 2.64206515299955
22.9999999999999 0.0023 2.63827216398241
23.1999999999999 0.00232 2.6345120151091
23.3999999999999 0.00234 2.63078414258986
23.5999999999999 0.00236 2.62708799702989
23.7999999999999 0.00238 2.62342304294349
23.9999999999999 0.0024 2.61978875828839
24.1999999999999 0.00242 2.61618463401957
24.3999999999999 0.00244 2.61261017366127
24.5999999999999 0.00246 2.60906489289662
24.7999999999999 0.00248 2.60554831917378
24.9999999999999 0.0025 2.60205999132796
25.1999999999999 0.00252 2.59859945921846
25.3999999999999 0.00254 2.59516628338006
25.5999999999999 0.00256 2.59176003468815
25.7999999999999 0.00258 2.58838029403677
25.9999999999999 0.0026 2.58502665202918
26.1999999999999 0.00262 2.58169870868026
26.3999999999999 0.00264 2.57839607313017
26.5999999999999 0.00266 2.57511836336893
26.7999999999999 0.00268 2.57186520597121
26.9999999999999 0.0027 2.56863623584101
27.1999999999999 0.00272 2.5654310959658
27.3999999999999 0.00274 2.56224943717961
27.5999999999999 0.00276 2.55909091793478
27.7999999999999 0.00278 2.55595520408192
27.9999999999999 0.0028 2.55284196865778
28.1999999999999 0.00282 2.54975089168064
28.3999999999999 0.00284 2.54668165995296
28.5999999999999 0.00286 2.54363396687096
28.7999999999999 0.00288 2.54060751224077
28.9999999999999 0.0029 2.53760200210104
 Acido debil-Base Fuerte
12

10

0
0 5 10 15 20 25 30 35