Tiempo Temperatura 1 Temperatura 2 Temperatura 3

(min) (75C) (80°C) (85°C)

0 50 50 50
2 97.6 90 91.03
4 93.9 75 79.36
6 80 65.16 53.18
8 75 48.51 35.51
10 71 41.13 31.68
12 65 30 29
14 60 29 25.1
16 55 25 21.3

Tiempo Temperatura 1 Temperatura 2 Temperatura 3

(días) (75°C) (80°C) (85°C)
A= 82.584 76.891 75.227
B= 1.33 3.3086 3.6234
R= 0.1952 0.6568 0.6485

Tiempo Temperatura 1 Temperatura 2 Temperatura 3

(días) (10°C) (15°C) (20°C)
A= 79.957 81.177 79.053
B= 0.016 0.071 0.082
R= 0.1483 0.7459 0.78
 Chart Title
120
100
80
f(x) = − 1.33 x + 82.5844444444444
f(x)
R² ==0.195194150751387
− 3.30858333333333
3.62341666666667 x + 76.8908888888889
75.2273333333333
60 R² = 0.656784019746483
0.648536222613233
40
20
0
0 2 4 6 8 10 12 14 16 18

Temperatura 1 (75C) Linear (Temperatura 1 (75C))

Temperatura 2 (80°C) Linear (Temperatura 2 (80°C))
Temperatura 3 (85°C) Linear (Temperatura 3 (85°C))

Chart Title
120

100

80
f(x)
f(x) == 81.1774291283302
79.9572154837685 exp(−−0.08174684704032
79.052701390901 exp( 0.070523497570925
x )x )
0.016111592205361
60 R²
R² == 0.74593502665366
0.148324292864893
0.78004515962305

40

20

0
0 2 4 6 8 10 12 14 16 18

Temperatura 1 (75C) Exponential (Temperatura 1 (75C))

Temperatura 2 (80°C) Exponential (Temperatura 2 (80°C))
Temperatura 3 (85°C) Exponential (Temperatura 3 (85°C))
Exponential (Temperatura 3 (85°C))
20

0
0 2 4 6 8 10 12 14 16 18

Temperatura 1 (75C) Exponential (Temperatura 1 (75C))

Temperatura 2 (80°C) Exponential (Temperatura 2 (80°C))
Temperatura 3 (85°C) Exponential (Temperatura 3 (85°C))
Exponential (Temperatura 3 (85°C))
 Tiempo

(min)
0
2
4
6
8
10
12
14
16
A=
𝐶_𝑖=𝐴_𝑖+𝐵(𝑡) B=
R=
A=
𝐶_𝑖=𝐴_𝑖 . B=
𝑒^(−𝐵(𝑡)) R=

Ai =

Ecuación de Arrhenius
𝐿𝑜𝑔(𝑘_𝑖 )=𝐿𝑜𝑔(𝑘_0 )−𝐸_𝑎
𝑅).1/𝑇_𝑎

B=Ki =
 Ki
T (°C)
(1/min)
75 0.016
80 0.071
85 0.082
 Temperatura 1 Temperatura 2 Temperatura 3

(75C) (80°C) (85°C)

50 50 50
97.6 90 91.03
93.9 75 79.36
80 65.16 53.18
75 48.51 35.51
71 41.13 31.68
65 30 29
60 29 25.1
55 25 21.3
82.584 76.891 75.227
1.33 3.3086 3.6234
0.1952 0.6568 0.6485
79.957 81.177 79.053
0.016 0.071 0.082
0.1483 0.7459 0.78

79.957 81.177 79.053

Ai 80.0623333333333

𝑔(𝑘_𝑖 )=𝐿𝑜𝑔(𝑘_0 )−𝐸_𝑎/(2.3

1/𝑇_𝑎

0.016 0.071 0.082

Log Ki
0
0.00278 0.00279 0.0028 0.00281 0.00282 0.00283 0.00284 0.00285 0.00286 0.0028
-0.2
-0.4
-0.6
 Log Ki
1/T Log Ki 0
0.00278 0.00279 0.0028 0.00281 0.00282 0.00283 0.00284 0.00285 0.00286 0.0028
-0.2

0.00287356 -1.79588002 -0.4

-0.6
0.00283286 -1.14874165 -0.8

0.0027933 -1.08618615 -1
f(x) = − 8875.44265293165 x + 23.8026580080003
-1.2 R² = 0.821850629510266
-1.4
-1.6
-1.8
-2
Ki
3 0.00284 0.00285 0.00286 0.00287 0.00288
Ki
3 0.00284 0.00285 0.00286 0.00287 0.00288

3.8026580080003
 Calculando para una temperatura de 72°C
Ta = 72 + 273.15 =345.15
𝐿𝑜𝑔(𝑘𝑖)=10.954−3571.6 .
(1/𝑇_𝑎 )
Remplazando:
Log Ki = 0.59703535
Ki = 3.953988028
Remplazando el valor de Ci:

𝐶_𝑖=𝐴_𝑖 . Ci=10mg/mL
𝑒^(−𝑘_𝑖 (𝑡))
Ai=80.06233333 Ki = 3.953988028 e=2.7182

Obtenemos: t=0.526123 min

2 + 273.15 =345.15 K

e=2.7182
 Calculando para una temperatura de 88°C
Ta = 88 + 273.15 =361.15
𝐿𝑜𝑔(𝑘𝑖)=10.954−3571.6 .
(1/𝑇_𝑎 )
Remplazando:
Log Ki = 1.05548041
Ki = 11.362670422
Remplazando el valor de Ci:

𝐶_𝑖=𝐴_𝑖 . Ci=10mg/mL
𝑒^(−𝑘_𝑖 (𝑡))
Ai=80.06233333 Ki = 11.362670422 e=2.7182

Obtenemos: t=0.1831 min

8 + 273.15 =361.15 K

e=2.7182