COEFICIENTES DE ACTIVIDAD A DISOLUCION INFINITA

Componente No. Asig. ginf

Etanol 50 1 4.82611552
Benceno 113 2 1.37633294

ESTIMACION DE LOS COEFICIENTES BINARIOS A DILUCION INFINITA

A12 1.5740419
A21 0.31942267
 A12 1.574
A21 0.319

x x
1 2 Exp Exp CALC CALC
No. Etanol Benceno g-Etanol-exp g-Benceno-exp g-Etanol-Calc g-Benceno-calc
1 0.0374 0.9626 8.11488476 1.0222437845 3.0307557516 1.0006158681
2 0.0972 0.9028 5.0293965161 1.0532704102 1.9580064154 1.0039613714
3 0.3141 0.6859 2.031958284 1.2968004001 1.1599963184 1.0353238799
4 0.5199 0.4801 1.3683422901 1.7146346057 1.0399842237 1.0851568114
5 0.7087 0.2913 1.1139363462 2.3738188798 1.0093737148 1.1426936169
6 0.9193 0.0807 1.00020002 3.7348214019 1.000482298 1.2165584362
7 0.9591 0.0409 0.9923295691 4.0547944671 1.000115871 1.2314408669

7
COEFICEINTE DE ACTIVIDAD

6
5
g-Etanol -Ca lc
4 g-Benceno-cal c
3 g-Etanol -exp
g-Benceno-exp
2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xETANOL
 Fobj Fobj
1 2
lng-Etanol lng-Benceno Etanol Benceno
1.10881201 0.000615679 25.84836777 0.000467767
0.67192682 0.003953546 9.433437151 0.002431381
0.14841683 0.034714305 0.760317669 0.068369971
0.03920554 0.081724503 0.10781902 0.396242294
0.00933005 0.133388297 0.010933344 1.515669413
0.00048218 0.196025918 7.968086E-08 6.341648364
0.00011586 0.20818492 6.06265E-05 7.971325552
36.16093566 16.29615474 52.4570904
COEFICIENTES DE ACTIVIDAD A DISOLUCION INFINITA
Componente No. Asig. ginf

Etanol 50 1 8.15730491
Benceno 113 2 4.12174812

ESTIMACION DE LOS COEFICIENTES BINARIOS A DILUCION INFINITA

A12 0.19351991
A21 0.54346102

FUNCION OBJETIVO
LADO1 LADO2 FOBJ
2.0989138334 2.09891383 3.1161E-22
1.4162773754 1.41627738 2.8796E-22
5.9957E-22
A12 0.120
A21 0.523

x x
1 2 Exp Exp CALC CALC
No. Etanol Benceno g-Etanol-exp g-Benceno-exp g-Etanol-Calc g-Benceno-calc
1 0.0374 0.9626 8.11488476 1.0222437845 8.1573049068 1.0086029624
2 0.0972 0.9028 5.0293965161 1.0532704102 4.8819122864 1.0450147552
3 0.3141 0.6859 2.031958284 1.2968004001 1.9992620564 1.2974949743
4 0.5199 0.4801 1.3683422901 1.7146346057 1.3566790754 1.7134058008
5 0.7087 0.2913 1.1139363462 2.3738188798 1.1142112433 2.3583542006
6 0.9193 0.0807 1.00020002 3.7348214019 1.0078384163 3.7219924619
7 0.9591 0.0409 0.9923295691 4.0547944671 1.0017746174 4.1217481242

7
COEFICIENTE DE ACTIVIDAD

6
5
g-Eta nol -Ca lc
4 g-Benceno-ca l c
3 g-Eta nol -exp
g-Benceno-exp
2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xETANOL
 Fobj Fobj
1 2
lng-Etanol lng-Benceno Etanol Benceno
2.09891383 0.008566168 0.001799469 0.000186072
1.58553701 0.044031005 0.021751598 6.815584E-05
0.69277814 0.260435463 0.001069043 4.824333E-07
0.30503986 0.538483086 0.000136031 0.00000151
0.10814675 0.857964003 7.556845E-08 0.000239156
0.00780786 1.314259133 5.83451E-05 0.000164582
0.00177304 1.416277375 8.920894E-05 0.004482792
0.02490377 0.00514275 0.03004652
 t12 0.8227217
t21 1.93728473
a12 0.520
G12 0.6517267
G21 0.3649010

x x
1 2 Exp Exp CALC CALC
No. Etanol Benceno g-Etanol-exp g-Benceno-exp g-Etanol-Calc g-Benceno-calc
1 0.0374 0.9626 8.11488476 1.0222437845 8.1044140872 1.0070728292
2 0.0972 0.9028 5.0293965161 1.0532704102 5.0696861032 1.0410509912
3 0.3141 0.6859 2.031958284 1.2968004001 2.011778945 1.3000719221
4 0.5199 0.4801 1.3683422901 1.7146346057 1.3598109826 1.7097086125
5 0.7087 0.2913 1.1139363462 2.3738188798 1.1198108626 2.3255063727
6 0.9193 0.0807 1.00020002 3.7348214019 1.009466336 3.6792404228
7 0.9591 0.0409 0.9923295691 4.0547944671 1.0024802431 4.0967381337

7
COEFICIENTE DE ACTIVIDAD

5
g-Eta nol -Ca l c
4 g-Benceno-ca l c
3 g-Eta nol -exp
g-Benceno-exp
2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xETANOL
 Fobj Fobj
1 2
lng-Etanol lng-Benceno Etanol Benceno
2.09240886 0.007047934 0.000109635 0.000230158
1.6232789 0.040230771 0.001623251 0.000149314
0.69901938 0.262419588 0.000407206 1.070286E-05
0.30734571 0.536322954 7.278321E-05 2.426541E-05
0.1131598 0.84393781 3.450994E-05 0.002334098
0.00942181 1.302706324 8.586461E-05 0.003089245
0.00247717 1.41019108 0.000103036 0.001759271
0.002436285 0.007597055 0.01003334
COEFICIENTES DE ACTIVIDAD A DISOLUCION INFINITA
Componente No. Asig. ginf

Etanol 50 1 8.06373711
Benceno 113 2 4.05402248

Estimacion de los coeficientes binarios a dilucion infinita

t12 0.64410544
t21 1.6115127
a12 0.47

FUNCION OBJETIVO
LADO1 LADO2 FOBJ
2.0873771108 2.08737707 1.4614E-15
1.3997095929 1.39970958 1.4266E-16
1.6041E-15
t12 0.64410544
t21 1.6115127
a12 0.470
G12 0.7387989
G21 0.4688788

x x
1 2 Exp Exp CALC CALC
No. Etanol Benceno g-Etanol-exp g-Benceno-exp g-Etanol-Calc g-Benceno-calc
1 0.0374 0.9626 8.11488476 1.0222437845 6.1965476494 1.0049382928
2 0.0972 0.9028 5.0293965161 1.0532704102 4.3673582201 1.0302966533
3 0.3141 0.6859 2.031958284 1.2968004001 1.9701832106 1.2531120875
4 0.5199 0.4801 1.3683422901 1.7146346057 1.3417738453 1.640838931
5 0.7087 0.2913 1.1139363462 2.3738188798 1.1083637586 2.2190043337
6 0.9193 0.0807 1.00020002 3.7348214019 1.0079168724 3.3588645037
7 0.9591 0.0409 0.9923295691 4.0547944671 1.0020384641 3.6766239273

7
COEFICIENTE DE ACTIVIDAD

5
g-Etanol -Ca l c
4 g-Benceno-ca l c
3 g-Etanol -exp
g-Benceno-exp
2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
xETANOL
 Fobj Fobj
1 2
lng-Etanol lng-Benceno Etanol Benceno
1.82399231 0.004926139 3.68001727 0.00029948
1.4741583 0.029846774 0.438294705 0.000527794
0.67812654 0.225630127 0.00381616 0.001908669
0.2939925 0.495207654 0.000705882 0.005445802
0.10288484 0.797058597 3.105373E-05 0.023967544
0.0078857 1.211602972 5.954981E-05 0.141343589
0.00203639 1.30199492 9.426264E-05 0.143012957
4.123018883 0.316505834 4.43952472
 x x
1 2 Exp Exp
No. Etanol Benceno g-Etanol-exp g-Benceno-exp
1 0.0374 0.9626 8.11488476 1.0222437845
2 0.0972 0.9028 5.0293965161 1.0532704102
3 0.3141 0.6859 2.031958284 1.2968004001
4 0.5199 0.4801 1.3683422901 1.7146346057
5 0.7087 0.2913 1.1139363462 2.3738188798
6 0.9193 0.0807 1.00020002 3.7348214019
7 0.9591 0.0409 0.9923295691 4.0547944671

8.3

7.3

6.3

5.3

4.3

3.3

2.3

1.3

0.3
0 0.1 0.2 0.3 0.4 0.5
 VAN LAAR VAN LAAR WILSON
g-Etanol-VAN LAAR g-Benceno-VAN LAAR g-Etanol-Wilson
3.0307557516 1.0006158681 8.1573049068
1.9580064154 1.0039613714 4.8819122864
1.1599963184 1.0353238799 1.9992620564
1.0399842237 1.0851568114 1.3566790754
1.0093737148 1.1426936169 1.1142112433
1.000482298 1.2165584362 1.0078384163
1.000115871 1.2314408669 1.0017746174

g-Etanol -VA

g-Benceno

g-Etanol -W

g-Benceno

g-Etanol -N

g-Benceno

g-Etanol -ex

g-Benceno

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

 WILSON NRTL NRTL
g-Benceno-Wilson g-Etanol-NRTL g-Benceno-NRTL
1.0086029624 6.1965476494 1.0049382928
1.0450147552 4.3673582201 1.0302966533
1.2974949743 1.9701832106 1.2531120875
1.7134058008 1.3417738453 1.640838931
2.3583542006 1.1083637586 2.2190043337
3.7219924619 1.0079168724 3.3588645037
4.1217481242 1.0020384641 3.6766239273

g-Etanol -VAN LAAR

g-Benceno-VAN LAAR

g-Etanol -Wi l s on

g-Benceno-Wi l s on

g-Etanol -NRTL

g-Benceno-NRTL

g-Etanol -exp

g-Benceno-exp

0.8 0.9 1