EJERCICIOS DE ANALISIS DE VITAMINA C POR VOLTAMETRIA LINEAL

ECU 002

MUESTRA ECU 002

VOL. SOL.
PATRON INTENSIDAD
5 74,351
12 144,335
17 190,280
25 265,423
35 363,631

ECU 002 y = 9.5903x + 27.307

R² = 0.9998
400
350
300
250
200
150
100
50
0
0 5 10 15 20 25 30 35 40
 PIMIENTO ECU002

(𝒃)(𝑪𝒔𝒊)
𝑪𝑴 =
(𝒎)(𝑽𝒎)
0,25𝑔
(32,97𝑢𝐴)( )
𝑪𝑴 = 50𝑚𝑙
𝑢𝐴
(10,126 )(5𝑚𝑙)
𝑚𝑙
𝑔
(32,97𝑢𝐴)(0,005 )
𝑪𝑴 = 𝑚𝑙
(50,63𝑢𝐴)
𝑔
(0,16485)
𝑪𝑴 = 𝑚𝑙
(50,63𝑢𝐴)
𝑔
𝑪𝑴 = 0,00325597
𝑚𝑙
𝑔 1000000 𝑢𝑔 𝑢𝑔
𝑪𝑴 = (𝟎, 𝟎𝟎𝟑𝟐𝟓𝟓𝟗𝟕 )( ) = 3255,97
𝑚𝑙 1𝑔 𝑚𝑙

𝑢𝑔
𝑪𝑴 = 3255,97 = 𝑝𝑝𝑚
𝑚𝑙
𝑚𝑔 𝑚𝑙
𝑝𝑝𝑚 = 𝑜
𝑘𝑔 𝐿

𝑚𝑔 0,1 𝐾𝑔 𝑚𝑔
𝑪𝑴 = (𝟑𝟐𝟓𝟓, 𝟗𝟕 )( ) = 325,597
𝐾𝑔 100 𝑔 100𝑔

𝑢𝑔 1𝑔 1000𝑚𝑔 1000𝑚𝐿 𝑚𝑔
𝑪𝑴 = (𝟑𝟐𝟓𝟓, 𝟗𝟕 )( 6 )( )( ) = 3255,97
𝑚𝑙 10 𝑢𝑔 1𝑔 1𝐿 𝐿
𝑚𝑔 1𝐿 𝑚𝑔
𝑪𝑴 = (𝟑𝟐𝟓𝟓, 𝟗𝟕 )( ) = 3,25597
𝐿 1000𝑔 𝑔
𝑚𝑔 100000 𝑔 1𝑔 𝑚𝑔
𝑪𝑴 = (3,25597 )( )( ) = 325,597
𝑔 100𝑔 1000𝑚𝑔 100𝑔
 G0 AMARILLO

MUESTRA G0 AMARILLO
VOLUMENES INTENSIDAD
5 91,686
12 149,096
17 197,089
25 288,733
35 390,130

G0 AMARILLO y = 10.126x + 32.97

450 R² = 0.9969

400
350
300
250
200
150
100
50
0
0 5 10 15 20 25 30 35 40
 (𝒃)(𝑪𝒔𝒊)
𝑪𝑴 =
(𝒎)(𝑽𝒎)
𝟎, 𝟐𝟓𝒈
(𝟑𝟐, 𝟗𝟕𝒖𝑨) ( )
𝟓𝟎𝒎𝒍
𝑪𝑴 =
𝒖𝑨
(𝟏𝟎, 𝟏𝟐𝟔 ) (𝟓 𝒎𝒍)
𝒎𝒍

𝒈
(𝟑𝟐, 𝟗𝟕𝒖𝑨) (𝟎, 𝟎𝟎𝟓 )
𝑪𝑴 = 𝒎𝒍
(𝟓𝟎, 𝟔𝟑 𝒖𝑨)
𝒈
𝟎, 𝟏𝟔𝟒𝟖𝟓
𝑪𝑴 = 𝒎𝒍
𝟓𝟎, 𝟔𝟑
𝒈
𝑪𝑴 = 𝟎, 𝟎𝟎𝟑𝟐𝟓𝟔
𝒎𝒍
𝒈 𝒖𝒈 𝒖𝒈
𝑪𝑴 = (𝟎, 𝟎𝟎𝟑𝟐𝟓𝟔 ) (𝟏𝟎𝟎𝟎𝟎𝟎𝟎 ) = 𝟑, 𝟐𝟓𝟔
𝒎𝒍 𝟏𝒈 𝒎𝒍
𝒖𝒈
𝑪𝑴 = 𝟑, 𝟐𝟓𝟔 = 𝒑𝒑𝒎
𝒎𝒍
𝒎𝒈 𝒎𝒍
𝒑𝒑𝒎 = 𝒐
𝑲𝒈 𝑳
𝒎𝒈 𝟎, 𝟏𝑲𝒈 𝒎𝒈
𝑪𝑴 = (𝟑, 𝟐𝟓𝟔 )( ) = 𝟎, 𝟑𝟐𝟓𝟔
𝑲𝒈 𝟏𝟎𝟎𝒈 𝟏𝟎𝟎𝒈

𝟑, 𝟐𝟓𝟔 𝒖𝒈 𝟏𝒈 𝟏𝟎𝟎𝟎 𝒎𝒈 𝟏𝟎𝟎𝟎 𝒎𝒍 𝒎𝒈

𝑪𝑴 = ( )( 𝟔 )( )( ) = 𝟑, 𝟐𝟓𝟔
𝒎𝒍 𝟏𝟎 𝒖𝒈 𝟏𝒈 𝟏𝑳 𝑳
𝒎𝒈 𝟏𝑳 𝒎𝒈
𝑪𝑴 = (𝟑, 𝟐𝟓𝟔 )( ) = 𝟎, 𝟎𝟎𝟑𝟐𝟓𝟔
𝑳 𝟏𝟎𝟎𝟎𝒈 𝒈
𝟎, 𝟎𝟎𝟑𝟐𝟓𝟔 𝒎𝒈 𝒎𝒈 𝟏𝒈 𝒎𝒈
𝑪𝑴 = ( ) (𝟏𝟎𝟎𝟎𝟎𝟎 )( ) = 𝟎, 𝟑𝟐𝟓𝟔
𝒈 𝟏𝟎𝟎 𝒈 𝟏𝟎𝟎𝟎𝒎𝒈 𝟏𝟎𝟎 𝒈.
 G0 VERDE

VOLUMENES INTENSIDAD
5 66,500
12 134,374
17 174,896
25 255,241
35 352,835

y = 9.5269x + 17.663
G0 VERDE R² = 0.9993
400.000
350.000
300.000
250.000
200.000
150.000
100.000
50.000
0.000
0 5 10 15 20 25 30 35 40
 (𝒃)(𝑪𝒔𝒊)
𝑪𝑴 =
(𝒎)(𝑽𝒎)
𝟎, 𝟐𝟓𝒈
(𝟏𝟕, 𝟔𝟔𝟑𝒖𝑨) ( )
𝟓𝟎𝒎𝒍
𝑪𝑴 =
𝒖𝑨
(𝟗, 𝟓𝟐𝟔𝟗 ) (𝟓 𝒎𝒍)
𝒎𝒍

𝒈
(𝟏𝟕, 𝟔𝟔𝟑𝒖𝑨) (𝟎, 𝟎𝟎𝟓 )
𝑪𝑴 = 𝒎𝒍
(𝟒𝟕, 𝟔𝟑𝟒𝟓 𝒖𝑨)
𝒈
𝟎, 𝟎𝟖𝟖𝟑𝟏𝟓
𝑪𝑴 = 𝒎𝒍
𝟒𝟕, 𝟔𝟑𝟒𝟓
𝒈
𝑪𝑴 = 𝟎, 𝟎𝟎𝟏𝟖𝟓𝟒
𝒎𝒍
𝒈 𝒖𝒈 𝒖𝒈
𝑪𝑴 = (𝟎, 𝟎𝟎𝟏𝟖𝟓𝟒 ) (𝟏𝟎𝟎𝟎𝟎𝟎𝟎 ) = 𝟏𝟖𝟓𝟒
𝒎𝒍 𝟏𝒈 𝒎𝒍
𝒖𝒈
𝑪𝑴 = 𝟏𝟖𝟓𝟒 = 𝒑𝒑𝒎
𝒎𝒍
𝒎𝒈 𝒎𝒍
𝒑𝒑𝒎 = 𝒐
𝑲𝒈 𝑳
𝒎𝒈 𝟎, 𝟏𝑲𝒈 𝒎𝒈
𝑪𝑴 = (𝟏𝟖𝟓𝟒 )( ) = 𝟏𝟖𝟓, 𝟒
𝑲𝒈 𝟏𝟎𝟎𝒈 𝟏𝟎𝟎𝒈

𝟏𝟖𝟓𝟒 𝒖𝒈 𝟏𝒈 𝟏𝟎𝟎𝟎 𝒎𝒈 𝟏𝟎𝟎𝟎 𝒎𝒍 𝒎𝒈

𝑪𝑴 = ( )( 𝟔 )( )( ) = 𝟏𝟖𝟓𝟒
𝒎𝒍 𝟏𝟎 𝒖𝒈 𝟏𝒈 𝟏𝑳 𝑳
𝒎𝒈 𝟏𝑳 𝒎𝒈
𝑪𝑴 = (𝟏𝟖𝟓𝟒 )( ) = 𝟏, 𝟖𝟓𝟒
𝑳 𝟏𝟎𝟎𝟎𝒈 𝒈
𝟏, 𝟖𝟓𝟒 𝒎𝒈 𝒎𝒈 𝟏𝒈 𝒎𝒈
𝑪𝑴 = ( ) (𝟏𝟎𝟎𝟎𝟎𝟎 )( ) = 𝟏𝟖𝟓, 𝟒
𝒈 𝟏𝟎𝟎 𝒈 𝟏𝟎𝟎𝟎𝒎𝒈 𝟏𝟎𝟎 𝒈.
 G1 ROJO

VOLUMENES INTENSIDAD
5 84,577
12 157,861
17 211,014
25 297,075
35 407,060

G1 ROJO y = 10.754x + 29.341

R² = 0.9999
450
400
350
300
250
200
150
100
50
0
0 5 10 15 20 25 30 35 40
 (𝒃)(𝑪𝒔𝒊)
𝑪𝑴 =
(𝒎)(𝑽𝒎)
0,25𝑔
(29,341𝑢𝐴) ( )
𝐶𝑀 = 50𝑚𝑙
𝑢𝐴
(10,754 ) (5𝑚𝑙)
𝑚𝑙
𝑔
(29,341𝑢𝐴) (0.005 )
𝐶𝑀 = 𝑚𝑙
53.77𝑢𝐴
𝑔
146.705
𝐶𝑀 = 𝑚𝑙
53.77
𝒈
𝑪𝑴 = 𝟐, 𝟕𝟐𝟖𝟑
𝒎𝒍
𝑔 1000000𝑢𝑔 𝑢𝑔
𝐶𝑀 = (2,7283 )( ) = 2728300
𝑚𝑙 1𝑔 𝑚𝑙
𝒖𝒈
𝑪𝑴 = 𝟐𝟕𝟐𝟖𝟑𝟎𝟎 = 𝒑𝒑𝒎
𝒎𝒍
𝒎𝒈 𝒎𝒍
𝒑𝒑𝒎 = 𝒐
𝑲𝒈 𝑳
𝑚𝑔 0,1 𝐾𝑔 𝑚𝑔
𝐶𝑀 = (2728300 )( ) = 272830
𝐾𝑔 100𝑔 100𝑔
𝑢𝑔 1𝑔 1000𝑚𝑔 1000𝑚𝑙 𝑚𝑔
𝐶𝑀 = (2728300 )( )( )( ) = 2728300
𝑚𝑙 1000000𝑢𝑔 1𝑔 1𝐿 𝐿
𝑚𝑔 1𝐿 𝑚𝑔
𝐶𝑀 = (2728300 )( ) = 2728.3
𝐿 1000𝑔 𝑔
𝑚𝑔 100000𝑔 1𝑔 𝑚𝑔
𝐶𝑀 = (2728.3 )( )( ) = 272830
𝑔 100𝑔 1000𝑚𝑔 100𝑔
 PIMIENTO 5

VOLUMENES INTESIDAD
5 66,033
12 141,379
17 194,329
25 263,644
35 370,378

PIMIENTO 5 y = 10.008x + 19.003

R² = 0.9986
400
350
300
250
200
150
100
50
0
0 5 10 15 20 25 30 35 40
 (𝒃)(𝑪𝒔𝒊)
𝑪𝑴 =
(𝒎)(𝑽𝒎)
0,25𝑔
(19,003𝑢𝐴) ( )
𝐶𝑀 = 50𝑚𝑙
𝑢𝐴
(10,008 ) (5𝑚𝑙)
𝑚𝑙
𝑔
(19,003𝑢𝐴) (0.005 )
𝐶𝑀 = 𝑚𝑙
50,04 𝑢𝐴
𝑔
0.095015
𝐶𝑀 = 𝑚𝑙
50.04𝑢𝐴
𝒈
𝑪𝑴 = 𝟏, 𝟖𝟗𝟖𝟕
𝒎𝒍

𝑔 1000000𝑢𝑔 𝑢𝑔
𝐶𝑀 = (1.8987 )( ) = 1898700
𝑚𝑙 1𝑔 𝑚𝑙
𝒖𝒈
𝑪𝑴 = 𝟏𝟖𝟗𝟖𝟕𝟎𝟎 = 𝒑𝒑𝒎
𝒎𝒍
𝒎𝒈 𝒎𝒍
𝒑𝒑𝒎 = 𝒐
𝑲𝒈 𝑳
𝑚𝑔 0,1 𝐾𝑔 𝑚𝑔
𝐶𝑀 = (1898700 )( ) = 1898.7
𝐾𝑔 100𝑔 100𝑔
𝑢𝑔 1𝑔 1000𝑚𝑔 1000𝑚𝑙 𝑚𝑔
𝐶𝑀 = (1898.7 )( )( )( ) = 18987
𝑚𝑙 1000000𝑢𝑔 1𝑔 1𝐿 𝐿
𝑚𝑔 1𝐿 𝑚𝑔
𝐶𝑀 = (18987 )( ) = 18987
𝐿 1000𝑔 𝑔

𝑚𝑔 100000𝑔 1𝑔 𝑚𝑔
𝐶𝑀 = (18987 )( )( ) = 18987
𝑔 100𝑔 1000𝑚𝑔 100𝑔