TERMODINAMICA II

DOCENTE: Ing. Fidel

CARRERA: Ing. Química
NOMBRE: Abel Martínez Ramos
Código: 141567
SEMESTRE: 2018 -I

Evaporación instantánea del sistema cloroformo(1)/etanol(2) a T= 55°C, Z1= 0.5

Burbuja P: X1= Z1 = 0.5

𝑌𝑖 ∗ 𝛾1 ∗ 𝑃
∑ 𝑌1 = 1 = ∑
𝜑𝑖

𝑌𝑖 ∗ 𝜑𝑖 ∗ 𝑃 = 𝑋𝑖 ∗ 𝛾𝑖 𝑃𝑖𝑠𝑎𝑡

𝐵11 ∗ (𝑃 − 𝑃1𝑠𝑎𝑡 ) + 𝑃 ∗ 𝑌22 ∗ 𝛿12

𝜑1 = 𝑒𝑥𝑝
𝑅∗𝑇
𝐵22 ∗ (𝑃 − 𝑃2𝑠𝑎𝑡 ) + 𝑃 ∗ 𝑌12 ∗ 𝛿12
𝜑2 = 𝑒𝑥𝑝
𝑅∗𝑇
𝛾1 = exp(𝑋22 (𝐴12 + 2 ∗ (𝐴21 − 𝐴12 ) ∗ 𝑋1 ))

𝛾1 = exp(𝑋12 (𝐴21 + 2 ∗ (𝐴12 − 𝐴21 ) ∗ 𝑋2 ))

R(cm3*Kpa/mol*K 8314 T (°C)

T (°K) 328.15 55
P1sat(Kpa) 82.37
P2sat(Kpa) 37.31
B11(cm3/mol) -963
B22 -1523
B12 52
X1 0.5
X2 0.5
A21 1.42
A12 0.59
ϒ1 1.4262
ϒ2 1.1589
δ12 2590
 =∅ =1 y1 y2 _1 _2 _ = _ X1 = 0.5
80.3572 0.7310 0.2690 1.0063 1.0169 79.6336 0.49859546
79.6336 0.7330 0.2670 1.0064 1.0171 79.6208 0.49998097
79.6208 0.7330 0.2670 1.0064 1.0171 79.6206 0.49999984
79.6206 0.7330 0.2670 1.0064 1.0171 79.6206 0.5
79.6206 0.7330 0.2670 1.0064 1.0171 79.6206 0.5

Roció p: Y1= Z1 =0.5, T = 55°C

𝑌𝑖 ∗ 𝜑1 ∗ 𝑃
∑ 𝑋1 = 1 = ∑
𝛾𝑖 ∗ 𝑃𝑖𝑠𝑎𝑡
1
𝑃=
𝑌 ∗ 𝜑1
∑ 𝑖 𝑠𝑎𝑡
𝛾𝑖 ∗ 𝑃𝑖

𝑌𝑖 ∗ 𝜑𝑖 ∗ 𝑃 = 𝑋𝑖 ∗ 𝛾𝑖 𝑃𝑖𝑠𝑎𝑡

𝐵11 ∗ (𝑃 − 𝑃1𝑠𝑎𝑡 ) + 𝑃 ∗ 𝑌22 ∗ 𝛿12

𝜑1 = 𝑒𝑥𝑝
𝑅∗𝑇
𝐵22 ∗ (𝑃 − 𝑃2𝑠𝑎𝑡 ) + 𝑃 ∗ 𝑌12 ∗ 𝛿12
𝜑2 = 𝑒𝑥𝑝
𝑅∗𝑇
𝛾1 = exp(𝑋22 (𝐴12 + 2 ∗ (𝐴21 − 𝐴12 ) ∗ 𝑋1 ))

𝛾1 = exp(𝑋12 (𝐴21 + 2 ∗ (𝐴12 − 𝐴21 ) ∗ 𝑋2 ))

 Para el primer cálculo se considera ϒi = 1 para todas las i.

R(cm3*Kpa/mol*K 8314 B12 52

T 328.15 y1 0.5
P1sat 82.37 y2 0.5
P2sat 37.31 A21 1.42
B11 -963 A12 0.59
B22 -1523 delta 12 2590

fugacidad fugacidad
p x1 x2 ϒ1 ϒ2 1 2 P Y1
51.3574 0.3190 0.6810 1.0000 1.0000 1.0234 1.0044 50.8340 0.5051
50.8340 0.1879 0.8121 1.6806 1.0299 1.0235 1.0045 59.6394 0.4262
59.6394 0.2042 0.7958 1.8127 1.0025 1.0224 1.0017 59.4755 0.5014
59.4755 0.2050 0.7950 1.8010 1.0041 1.0224 1.0017 59.4690 0.5001
59.4690 0.2050 0.7950 1.8004 1.0042 1.0224 1.0017 59.4688 0.5000
59.4688 0.2050 0.7950 1.8003 1.0042 1.0224 1.0017 59.4688 0.5000

P= ½(Pburbuja+Procio)=70 KPa