SIMULACION DEL REACTOR DE LECHO FIJO POR EL

MODELO DE DOS DIMENSIONES PARA LA OXIDACION DEL

ANHIDRIDO SULFUROSO
Índice

Presentación

CASO I: REACTOR HOMOGENEO

CASO II: CONSIDERANDO DIFUSION RADIAL

CASO III: CON DIFUSION AXIAL Y RADIAL

COMPARACION DEL CASO I, II YIII

PUNTOS CALIENTES

Conclusiones
 PRESENTACION

Los reactores de lecho fijo consisten en uno o más tubos empacados con partículas
de catalizador, que operan en posición vertical. Las partículas catalíticas pueden
variar de tamaño y forma: granulares, cilíndricas, esféricas, etc. En algunos casos,
especialmente con catalizadores metálicos como el platino, no se emplean partículas
de metal, sino que éste se presenta en forma de mallas de alambre. El lecho
vatalizador está constituído por un conjunto de capas de este material. Estas mallas
catalíticas se emplean en procesos comerciales para la oxidación de amoniaco y para
la oxidación del acetaldehídico a ácido acético.

Debido a la necesidad de eliminar o añadir calor, no es posible usar un solo tubo

de gran diámetro empacado con el catalizador. En su lugar, el reactor deberá
construirse con cierto número de tubos engarzados en un solo cuerpo. El intercambio
energético con los alrededores se obtiene circulando, algunas veces hirviendo un
fluido en el espacio que hay entre los tubos. Si el efecto calorífico es considerable, los
tubos de catalizador deben de ser pequeños (de hasta 1 plg de diámetro) para evitar
temperaturas excesivas en la mezcla reaccionante. El problema de la decisión del
diámetro del tubo y, por tanto, cuántos tubos son necesarios para una producción
dada, constituye un obstáculo importante en el diseño de estos reactores.
 ECUACIÓN GENERAL DE BALANCE DE MATERIA Y ENERGÍA

Conservación de materia
𝜕 2 𝐶𝐴 1 𝜕𝐶𝐴 𝜕𝐶𝐴
𝜀𝐷𝑒𝑟 ( 2 + ) − 𝜐𝑠 − 𝜌 𝑏 𝜈𝐴 𝑟 = 0 … … . (1)
𝜕𝑟 𝑟 𝜕𝑟 𝜕𝑧

Conservación de energía
𝜕 2 𝑇 1 𝜕𝑇 𝜕𝑇
𝐾𝑒𝑟 ( + ) − 𝜐𝑠 𝜌𝑔 𝐶𝑝𝑔 + 𝜌 𝑏 𝑟 (−𝛥𝐻𝑟 ) = 0 … … . . (2)
𝜕𝑟 2 𝑟 𝜕𝑟 𝜕𝑧

Donde:

ε: Porosidad del lecho

Ker: Conductividad efectiva radial
Der: Difusividad efectiva radial
CA: Concentración en cada r, z
T: Temperatura en cada r, z
𝜐S: Velocidad superficial
𝜌b: Densidad del catalizador
𝝂A: Coeficiente estequiometrico
𝜌g: Densidad del fluido
Cpg: Calor especifico del fluido
 CASO I

REACTOR HOMOGENEO

CASO I: REACTOR HOMOGENEO

No se considera difusión radial ni axial:

Esto quiere decir que tanto la concentración como la temperatura se mantienen
constantes en el eje “r” (eje radial)

De la figura se cumple lo siguiente:

En el eje radial: 𝐶𝐴𝑛 = 𝐶𝐴𝑚 ⟹ 𝐶𝐴𝑛 − 𝐶𝐴𝑚 = 0

𝑇𝑛 = 𝑇𝑚 ⟹ 𝑇𝑛 − 𝑇𝑚 = 0

Sabemos que la derivada se define coma la pendiente de la función:

𝜕𝐶𝐴 𝐶𝐴𝑚 − 𝐶𝐴𝑛 𝐶𝐴𝑚 − 𝐶𝐴𝑚 0

= = = =0
𝜕𝑟 𝑟2 − 𝑟1 𝑟2 − 𝑟1 𝑟2 − 𝑟1

𝜕𝐶𝐴
=0
𝜕𝑟

De la misma manera se tiene lo siguiente:

𝜕2 𝐶𝐴 𝜕𝐶𝐴
=0 = 0 …………(α)
𝜕𝑟 2 𝜕𝑟

𝜕2 𝑇 𝜕𝑇
=0 = 0 …………(β)
𝜕𝑟 2 𝜕𝑟
Reemplazando la condición (α) en la ecuación (1) y la condición (β) ecuación 2 se tiene
lo siguiente:
𝜕𝐶𝐴
−𝜕𝑠 − 𝜌 𝑏 𝜈𝐴 𝑟 = 0 … … … (3)
𝜕𝑧

𝜕𝑇
-𝜕𝑠 𝜌𝑔 𝐶𝑝𝑔 𝜕𝑧 + 𝜌 𝑏 𝑟 (– 𝛥𝐻𝑟 ) = 0 … … … (4)

Despejando el término diferencial

𝜕𝐶𝐴 −𝜌 𝑏 𝜈𝐴 𝑟
= ……(5)
𝜕𝑧 𝜕𝑠

𝜕𝑇 𝜌 𝑏 𝑟 (−𝛥𝐻𝑟 )
= … … . . (6)
𝜕𝑧 𝜕𝑠 𝜌𝑔 𝐶𝑝𝑔

La ecuación (5) lo ponemos en función de la conversión

Se sabe que:
𝐶𝐴 = 𝐶𝐴0 − 𝐶𝐴0 𝑋
Derivando
𝜕𝐶𝐴 = −𝐶𝐴0 𝜕𝑋

Reemplazando en la ecuación (5) y que 𝜐𝐴 = −1 , se tiene:

𝜕𝑋 −𝜌 𝑏 𝑟
= ……. (7)
𝜕𝑧 𝜕𝑠 𝐶𝐴0

La ecuación de velocidad para la oxidación del anhídrido sulfuroso:

1
𝑆𝑂2 + 𝑂2 ⇄ 𝑆𝑂3
2
 𝑃𝑆𝑂3
𝐾1 𝑃𝑂2 𝑃𝑆𝑂2 (1 − 1⁄ )
𝑃𝑆𝑂2 𝑃𝑂2 2 𝐾𝑃 𝐾𝑔𝑚𝑜𝑙 𝑆𝑂2
𝑟= ( )
22,414(1 + 𝐾2 𝑃𝑆𝑂2 + 𝐾3 𝑃𝑆𝑂3 )2 𝐾𝑔 𝑐𝑎𝑡 ∗ ℎ

Donde:
5473
𝐾1 = 𝑒𝑥𝑝(12,160 − )
𝑇
8619
𝐾2 = 𝑒𝑥𝑝(−9,953 + )
𝑇
52596
𝐾3 = 𝑒𝑥𝑝(−71,745 + )
𝑇
11300
𝐾𝑃 = 𝑒𝑥𝑝( − 10,68)
𝑇

Datos del Reactor y de la operación:

Oxidación del Anhídrido Sulfuroso

Composición del 6,5% mol de SO2

alimento 93,5% mol de aire seco

Pt/Al2O3(esferas)
Catalizador del
dp= 0,3175cm 𝜌b =
lecho
1025Kg cat/m3 εL = 0,5

𝐾𝐽
𝐶𝑃𝑔 = 1,09
𝐾𝑔 º𝐶
Propiedades del 𝑘𝑔
Flujo y fase fluida 𝜌𝑔 = 0,5864𝑚3

𝑘𝑔
𝐺 = 1709
𝑚3 ℎ

Temperatura de
alimentación, To 400ºC
 Temperatura de la
197ºC
pared, Tw

Diámetro del tubo,

Dt 5,23cm

Longitud del tubo 9,14cm

Numero de Peclet de
transferencia de 4,4
calor radial, PeHr

Numero de Peclet de
transferencia de 9,6
masa radial, PeHr

Numero de Biot en la 6,67

pared Biw
 SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH

# Distancia de reactor
z(0) = 0
z(f) = 0.1524

# Balance de Materia y Energia

d(X)/d(z) = db * Rx / (Cao * Us)
d(T)/d(z) = db * (-dH) * Rx / (Us * df * Cpf) # Temperatura obtenida en C

# Condiciones Iniciales
X(0) = 0 # Conversion a la entrada del reactor
T(0) = 400 # Temperatura a la entrada del reactor

# Velocidad de la reaccion en funcion de la Conversion y Presion R = funcion(x,T), donde T debe

ser usada en Kelvin

Rx = (K1 * Po2 * Pso2 * (1 - Pso3 / (Pso2 * Kp * (Po2) ^ 0.5))) / (22.414 * (1 + K2 * Pso2 + K3 *

Pso3) ^ 2)
Trx = T + 273.15
K1 = exp(12.160 - 5473 / (Trx))
K2 = exp(-9.953 + 8619 / (Trx))
K3 = exp(-71.745 + 52596 / (Trx))
Kp = exp(11300 / (Trx) - 10.68)

# Calculo de las Presiones

Pso2 = Pao * (1 - X)
Po2 = Pbo - 0.5 * Pao * X
Pso3 = Pao * X

# Propiedades del Fluido

P = 1.6 # Presion del sistema

R = 0.082 # Constante universal de los gases
db = 1025 # Densidad del Lecho catalitico
Cpf = 1.09 # Capacidad Calorifica del Fluido
Us = 2914.393 # Velocidad del Fluido G/df
G = 1709 # Flujo masico
df = 0.5864 # Densidad del Fluido
dH = -94886 # Entalpia de la Reaccion

# Calculo de la Concetracion Inicial

Cao = Pao / (R * Tin)
Tin = (400 + 273.15)

# Calculo de la Presion inicial

ya = 0.065
Pao = ya * P
Pbo = (1 - ya) * P * 0.21

Con las tablas obtenidas por polymath, procedemos a graficar

Z X T
0.000 0.0000 400.00
0.015 0.0245257 406.8598
0.030 0.0505842 414.1483
0.046 0.0886139 424.7851
0.061 0.1599124 444.7272
0.076 0.3207904 489.7244
0.091 0.624388 574.6401
0.107 0.7754533 616.8927
0.122 0.7878356 620.356
0.137 0.788415 620.5181
0.152 0.788441 620.5253

CONVERSION vs. LONGITUD DEL REACTOR

 X vs Z
0.8

0.7

0.6

0.5
Conversion

0.4

0.3 P=1.6

0.2

0.1

0.0
0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Z en metros

TEMPERATURA vs. LONGITUD DEL REACTOR

T vs Z
640
620
600
580
560
Temperatura

540
520
500 P= 1.6 atm
480
460
440
420
400
0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Z en metros
 CASO II
CON DIFUSION RADIAL

CASO II: CON DIFUSION RADIAL

Balance de materia:
   2C 1 C  C …………………………………(1)
Der  2    Us  b A ( X ,T )  0
 r r r  z

Se sabe que: C = CA0 - CAoX

Derivando tenemos:
C  C AoX

Lo reemplazamos en la ecuación (1):

  C Ao 2 X 1 (C Ao )X  (C Ao )X

Der     Us  b A ( X ,T )  0
 r r z
2
r 

Dividiendo entre (-CAo)

  2 X 1 X  X b A ( X ,T )
Der     Us  0
 r r r  z
2
C Ao

Despejando tenemos:

X  .d P   2 X 1 X   b . A .rA ( X , T )
    
z PEMr .  r 2 r r  C A0 .U S

b Der
Luego:  A  1 ;  C1 ;  C2
C AoUs Us

Reemplazando:

X   2 X 1 X 
 C 2 2    C1 ( X ,T )  0
z  r r r 

Balance de energía:

  2T 1 T  T
Ker  2    Us f C pf  b (Hr ) ( X ,T )  0
 r r r  z
Despejando:

T Ker   2T 1 T  b . Hr .rA( X ,T )

  2  
z Us f C pf  r r r  U S . f .CPf

b (r ) Ker
Haciendo:   C3 ;  C4
 f C pf Us Us f C pf

Finalmente tenemos:

X   2 X 1 X 
 C 2 2    C1.rA ( X ,T )
z  r r r 
T   2T 1 T 
 C 4 2    C 3.rA ( X ,T )
z  r r r 

Condiciones iníciales:
X(o) = 0
T(o) = 400oC
El radio del reactor se divide en cinco partes iguales:
Radio del reactor:
ri  r i ; i  0,1,2,3,4,5
r  es la fraccion del radio

Los puntos máximos y mínimos:

Xo To
 0; 0
z z
Para r = 0

 1 X    X 
2

lim    
 r 2 
r  0  r r   
 1 T    T 
2

lim    
 r 2 
r  0  r r   

Reemplazando en estas ecuaciones:

X   2 X 1 X 
 C 2 2    C1.rA ( X ,T )
z  r r r 
T   2T 1 T 
 C 4 2    C 3.rA ( X ,T )
z   r r r 

Tenemos:

X  2 X 
 2C 2 2   C1.rA ( X ,T )
z  r 
T   2T 
 2C 4 2   C 3.rA ( X ,T )
z  r 
X i  X  2 X i  X i 1 
 2C 2. i 1   C1.rA X i ,Ti 
z  r 2 
Ti  T  2Ti  Ti 1 
 2C 4. i 1   C 3.rA X i ,Ti 
z  r 2 

i=0
X 0  X  2 X 0  X 1 
 2C 2. 1   C1.rA X i ,Ti 
z  r 2 
T0  T  2T0  T1 
 2C 4. 1   C 3.rA X i ,Ti 
z  r 2 

Estos puntos no existen: X-1; T-1

Por discretizacion regresiva:
X i X i  X i 1

r r
Cuando i = 0; reemplazando: Xo = X-1, To = T-1

Para r ≠0
X i  X  2 X i  X i 1 1  X i  X i 1  
 C 2. i 1      C1.rA  X i ,Ti 
z  r 2
ir  r 
Ti  T  2Ti  Ti 1 1  Ti  Ti 1  
 C 4. i 1      C 3.rA  X i , Ti 
z  r 2
i r   r 

Cuando i = 1

X 1  X  2X1  X 0 1  X1  X 0 
 C 2. 2      C1.rA  X 1 ,T1 
z  r 2
1r  r 
T1  T  2T1  T0 1  T1  T0 
 C 4. 2      C 3.rA  X 1 ,T1 
z  r 2
1r  r 
Cuando i = 2
X 2  X  2X 2  X1 1  X 2  X1 
 C 2. 3      C1.rA  X 2 ,T2 
z  r 2
2r  r  
T2  T  2T2  T1 1  T2  T1  
 C 4. 3      C 3.rA  X 2 ,T2 
z  r 2
2r  r  

Cuando i = 3
X 3  X  2X 3  X 2 1  X 3  X 2 
 C 2. 4      C1.rA  X 3 ,T3 
z  r 2
3 r   r 
T3  T  2T3  T2 1  T3  T2  
 C 4. 4      C 3.rA  X 3 ,T3 
z  r 2
3r  r  

Cuando i = 4
X 4  X  2X 4  X 3 1  X 4  X 3 
 C 2. 5      C1.rA  X 4 ,T4 
z  r 2
4r  r  
T4  T  2T4  T3 1  T4  T3  
 C 4. 5      C 3.rA  X 4 ,T4 
z  r 2
4r  r  

Cuando i = 5
X 5  X  2X 5  X 4 1  X5  X4 
 C 2. 6      C1.rA  X 5 ,T5 
z  r 2
5r  r 
T5  T  2T5  T4 1  T5  T4 
 C 4. 6      C 3.rA  X 5 ,T5 
z  r 2
5r  r 

Condiciones de Frontera:

Para el balance de materia:

Para r = R = ri  ir

C A X
0 ó 0
r r
X i1  X i  0 ; i  5  X6  X5
C A x
r  R;  0 ó 0
r r

Reemplazando:

X 5  X  2X 5  X 4 1  X 5  X 4 
 C 2. 5      C1.rA  X 5 ,T5 
z  r 2
5r  r  

Para el Balance de Energía:

Para: r = R;
Transferencia de calor:
T T
 hTi  Tw     Ti  Tw 
h
k
r r k

Ti 1  Ti h h
  Ti  Tw
r k k

Entonces:
Para i = 5
hr hr
T6  T5  T5  Tw
k k
 hr  hr
T6  1  T5  Tw
 k  k

Además se sabe que:

ri  ir

rh
Bi w 
K
irh
Bi w 
K

Reemplazando:

X 5   X5  X4 1  X 5  X 4 
 C 2.      C1.rA  X 5 ,T5 
z  r
2
5r  r  
  Bi w  Bi 
 1  T5  w Tw  2T5  T4 
T5   5  5 1  T5  T4  
 C 4.     C 3.rA  X 5 ,T5 
z  r 2 5r  r  
 
 

Condiciones iníciales:
Cuando Z = 0
conversión temperatura
Xo(0) = 0 T0(0) = 0
X1 (0) = 0 T1(0) = 0
X2 (0) = 0 T2(0) = 0
X3 (0) = 0 T3(0) = 0
X4 (0) = 0 T4(0) = 0
X5 (0) = 0 T5(0) = 0

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH

# Distancia del Reactor

z(0) = 0
z(f) = 0.1524

# Propiedades del Fluido

P = 1.60 # Presion del sistema

R = 0.082 # Constante Universl de los gases
df = 0.5864 # Densidad del fluido
Tw = 197 # Temperatura de la pared
Phr = 4.4 # Peclet Calor Radial
Pmr = 9.6 # Peclet Masa Radial
Bi = 6.67 # Numero de Biot de la pared
dp = 0.003175 # Densidad del Catalizador
E = 0.5 # Porosidad del Lecho catalitico
db = 1025 # Densidad del lecho
G = 1709 # Flujo masico
Us = 2914.393 # Velocidad
dH = -94886 # Entalpia
Cpf = 1.09 # Capacidad Calorifica del Fluido
dr = (0.02615) / 5 # Espaciamiento Radial 5*dr=Radio

# Calculo de la Concetracion Inicial

Cao = Pao / (R * (Tin))
Tin = 400 + 273.15

# Calculo de la Presion inicial

ya = 0.065
Pao = P * ya
Pbo = (1 - ya) * P * 0.21

# Definicion de Parametros de las Ecuaciones Diferenciales de Materia y Energia

# Para EDB Materia
pi1 = E * Us * dp / (Us * Pmr)
pi2 = db / (Us * Cao)
# Para EDB Energia
pi3 = dp / Phr
pi4 = -dH * db / (Us * df * Cpf)

# Balance de Materia para 5 divisiones del Radio

d(x0)/d(z) = 2 * pi1 * (x1 - 2 * x0 + x0) / dr ^ 2 + pi2 * R0

d(x1)/d(z) = pi1 * ((x2 - 2 * x1 + x0) + (x1 - x0) / 1) / dr ^ 2 + pi2 * R1
d(x2)/d(z) = pi1 * ((x3 - 2 * x2 + x1) + (x2 - x1) / 2) / dr ^ 2 + pi2 * R2
d(x3)/d(z) = pi1 * ((x4 - 2 * x3 + x2) + (x3 - x2) / 3) / dr ^ 2 + pi2 * R3
d(x4)/d(z) = pi1 * ((x5 - 2 * x4 + x3) + (x4 - x3) / 4) / dr ^ 2 + pi2 * R4
d(x5)/d(z) = pi1 * ((x6 - 2 * x5 + x4) + (x5 - x4) / 5) / dr ^ 2 + pi2 * R5

# Valores iniciales de conversion y Temperatura

x0(0) = 0
x1(0) = 0
x2(0) = 0
x3(0) = 0
x4(0) = 0
x5(0) = 0

# Balance de Energia para 5 divisiones del Radio

d(T0)/d(z) = 2 * pi3 * (T1 - 2 * T0 + T0) / dr ^ 2 + pi4 * R0

d(T1)/d(z) = pi3 * ((T2 - 2 * T1 + T0) + (T1 - T0) / 1) / dr ^ 2 + pi4 * R1
d(T2)/d(z) = pi3 * ((T3 - 2 * T2 + T1) + (T2 - T1) / 2) / dr ^ 2 + pi4 * R2
d(T3)/d(z) = pi3 * ((T4 - 2 * T3 + T2) + (T3 - T2) / 3) / dr ^ 2 + pi4 * R3
d(T4)/d(z) = pi3 * ((T5 - 2 * T4 + T3) + (T4 - T3) / 4) / dr ^ 2 + pi4 * R4
d(T5)/d(z) = pi3 * ((T6 - 2 * T5 + T4) + (T5 - T4) / 5) / dr ^ 2 + pi4 * R5

# Valores iniciales de conversion y Temperatura

T0(0) = 400
T1(0) = 400
T2(0) = 400
T3(0) = 400
T4(0) = 400
T5(0) = 400

# Para i = 0
K10 = exp(12.160 - 5473 / (T0 + 273.15))
K20 = exp(-9.953 + 8619 / (T0 + 273.15))
K30 = exp(-71.745 + 52596 / (T0 + 273.15))
Kp0 = exp(11300 / (T0 + 273.15) - 10.68)
Pa0 = Pao * (1 - x0)
Pb0 = Pbo - 0.5 * Pao * x0
Pc0 = Pao * x0
R0 = (K10 * Pb0 * Pa0 * (1 - Pc0 / (Pa0 * Kp0 * (Pb0) ^ 0.5))) / (22.414 * (1 + K20 * Pa0 + K30 *
Pc0) ^ 2)
# Para i = 1
K11 = exp(12.160 - 5473 / (T1 + 273.15))
K21 = exp(-9.953 + 8619 / (T1 + 273.15))
K31 = exp(-71.745 + 52596 / (T1 + 273.15))
Kp1 = exp(11300 / (T1 + 273.15) - 10.68)
Pa1 = Pao * (1 - x1)
Pb1 = Pbo - 0.5 * Pao * x1
Pc1 = Pao * x1
R1 = (K11 * Pb1 * Pa1 * (1 - Pc1 / (Pa1 * Kp1 * (Pb1) ^ 0.5))) / (22.414 * (1 + K21 * Pa1 + K31 *
Pc1) ^ 2)

# Para i = 2
K12 = exp(12.160 - 5473 / (T2 + 273.15))
K22 = exp(-9.953 + 8619 / (T2 + 273.15))
K32 = exp(-71.745 + 52596 / (T2 + 273.15))
Kp2 = exp(11300 / (T2 + 273.15) - 10.68)
Pa2 = Pao * (1 - x2)
Pb2 = Pbo - 0.5 * Pao * x2
Pc2 = Pao * x2
R2 = (K12 * Pb2 * Pa2 * (1 - Pc2 / (Pa2 * Kp2 * (Pb2) ^ 0.5))) / (22.414 * (1 + K22 * Pa2 + K32 *
Pc2) ^ 2)

# Para i = 3
K13 = exp(12.160 - 5473 / (T3 + 273.15))
K23 = exp(-9.953 + 8619 / (T3 + 273.15))
K33 = exp(-71.745 + 52596 / (T3 + 273.15))
Kp3 = exp(11300 / (T3 + 273.15) - 10.68)
Pa3 = Pao * (1 - x3)
Pb3 = Pbo - 0.5 * Pao * x3
Pc3 = Pao * x3
R3 = (K13 * Pb3 * Pa3 * (1 - Pc3 / (Pa3 * Kp3 * (Pb3) ^ 0.5))) / (22.414 * (1 + K23 * Pa3 + K33 *
Pc3) ^ 2)

# Para i = 4
K14 = exp(12.160 - 5473 / (T4 + 273.15))
K24 = exp(-9.953 + 8619 / (T4 + 273.15))
K34 = exp(-71.745 + 52596 / (T4 + 273.15))
Kp4 = exp(11300 / (T4 + 273.15) - 10.68)
Pa4 = Pao * (1 - x4)
Pb4 = Pbo - 0.5 * Pao * x4
Pc4 = Pao * x4
R4 = (K14 * Pb4 * Pa4 * (1 - Pc4 / (Pa4 * Kp4 * (Pb4) ^ 0.5))) / (22.414 * (1 + K24 * Pa4 + K34 *
Pc4) ^ 2)

# Para i = 5
K15 = exp(12.160 - 5473 / (T5 + 273.15))
K25 = exp(-9.953 + 8619 / (T5 + 273.15))
K35 = exp(-71.745 + 52596 / (T5 + 273.15))
Kp5 = exp(11300 / (T5 + 273.15) - 10.68)
Pa5 = Pao * (1 - x5)
Pb5 = Pbo - 0.5 * Pao * x5
Pc5 = Pao * x5
R5 = (K15 * Pb5 * Pa5 * (1 - Pc5 / (Pa5 * Kp5 * (Pb5) ^ 0.5))) / (22.414 * (1 + K25 * Pa5 + K35 *
Pc5) ^ 2)

# en i= 5 hay intercambio de calor con el exterior

T6 = T5 - Bi * (T5 - Tw) / 5

# para x valor minimo dx/dr = 0 en i =5

x6 = x5

Con las tablas obtenidas por polymath, procedemos a graficar

DATOS OBTENIDOS EN POLYMATH

ro r1 r2 r3 r4 r5
Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615
z x0 x1 x2 x3 x4 x5 xprom
0.0000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
0.0152 0.025 0.0245188 0.0244299 0.023 0.017 0.004 0.020
0.0305 0.0504852 0.0501527 0.0478677 0.0377272 0.0177939 0.0051528 0.035
0.0457 0.0868168 0.0835159 0.0701128 0.0420615 0.0182194 0.0060648 0.051
0.0610 0.1446385 0.1283229 0.0864383 0.0428475 0.0187751 0.0069482 0.071
0.0762 0.2391598 0.1861042 0.0951262 0.0436372 0.0193669 0.0078096 0.099
0.0914 0.3793842 0.2557484 0.0996847 0.0446674 0.0200022 0.0086534 0.135
0.1067 0.5419311 0.3333168 0.1044463 0.0458546 0.020685 0.0094841 0.176
0.1219 0.6736494 0.4116675 0.1113297 0.0472624 0.0214188 0.0103061 0.213
0.1372 0.7541042 0.4808613 0.1204608 0.0489946 0.022213 0.0111239 0.240
0.1524 0.7980479 0.5299375 0.1310985 0.0511199 0.0230818 0.0119426 0.258

ro r1 r2 r3 r4 r5
Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615
z T0 T1 T2 T3 T4 T5 Tprom
0.0000 400.000 400.000 400.000 400.000 400.000 400.000 400.000
0.0152 406.8572 406.8403 406.6297 404.6377 390.7559 326.7332 390.409
0.0305 414.0097 413.615 411.223 400.9677 368.9261 291.1729 383.319
0.0457 423.3305 421.0735 412.5478 391.4339 348.9197 271.5301 378.139
0.0610 436.3372 428.8973 410.0592 380.2471 332.3455 259.3035 374.532
0.0762 454.6058 436.5931 404.7496 369.2411 318.8762 250.9334 372.500
0.0914 477.6067 443.7096 398.4598 358.8974 307.8717 244.791 371.889
0.1067 498.1099 449.692 392.4978 349.4955 298.764 240.0527 371.435
0.1219 505.9351 453.4905 387.151 341.1703 291.1446 236.2663 369.193
0.1372 501.659 453.5445 382.1258 333.8768 284.7215 233.1675 364.849
0.1524 491.3662 448.2249 376.8912 327.4304 279.2634 230.5893 358.961
 X vs Z
0.8

0.7

0.6

0.5 T0
Conversion

T1
0.4
T2
0.3 T3
0.2 T4
T5
0.1

0.0
0.0000 0.0152 0.0305 0.0457 0.0610 0.0762 0.0914 0.1067 0.1219 0.1372 0.1524
Z en metros

T vs Z
520.0

470.0

420.0 T0
Temperatura

T1
370.0
T2
T3
320.0
T4

270.0 T5

220.0
0.0000 0.0152 0.0305 0.0457 0.0610 0.0762 0.0914 0.1067 0.1219 0.1372 0.1524
Z en metros
 Perfil de conversion
0.8
0.0000
0.7
0.0152
0.6
0.0305
0.5 0.0457
Conversion

0.4 0.0610

0.3 0.0762
0.0914
0.2
0.1067
0.1
0.1219
0.0 0.1372
0 0.00523 0.01046 0.01569 0.02092 0.02615
0.1524
Radio en Metros

Perfil de Temperatura
510.0

470.0 0.0000
0.0152
430.0
0.0305
Temperatura

390.0 0.0457
0.0610
350.0 0.0762
0.0914
310.0
0.1067

270.0 0.1219
0.1372
230.0 0.1524
0 0.00523 0.01046 0.01569 0.02092 0.02615
Radio en Metros
 X promedio
0.300

0.250
Conversion Promedio

0.200

0.150

0.100

0.050

0.000
0.0000 0.0200 0.0400 0.0600 0.0800 0.1000 0.1200 0.1400 0.1600 0.1800
Z en metros

T promedio
405.000

400.000

395.000
Tmeperatura Promedio

390.000

385.000

380.000

375.000

370.000

365.000

360.000

355.000
0.0000 0.0200 0.0400 0.0600 0.0800 0.1000 0.1200 0.1400 0.1600 0.1800
Z en metros
 CASO III
CON DIFUSION AXIAL Y
RADIAL

CASO III: CON DIFUSION AXIAL Y RADIAL

1. BALANCE DE MATERIA:
 Ecuación de conservación de cantidad de materia
   2 C A 1 C A   2C A C A  b . A .rA ( X , T )

EDer   
  EDeZ US   0 ………….(1)
 r
2
r r  z 2
z

Donde:
CA= CA0- CA0X ,dCA = –CAo.dx
U S . dp
Pemr 
Der
U dp
Pehz  S .
Dez

Reemplazand
 2 X 1 X PeMr  2 X PeMr X  b . A PeMr .rA ( X , T ) o en (1) se
     0............(2)
r 2
r r Pemz z 2
 .d P z  .C A0 .U S .d P obtiene:

Donde:

1 
PeMr PeMr  b . A PeMr
2   3 
Pemz  .d P  .C A0 .U S .d P

Se obtiene:

 2 X 1 X 2 X X
  1 2   2  3 rA ( X , T )  0.............(3)
r 2
r r z z

Luego discretizando
Si: i = 0
𝑑2 𝑥
1 𝑑𝑥
𝑙𝑖𝑚 (𝑟 𝑑𝑟 ) = 𝑑𝑟 2  2 X 1  2 X  2 X 3
𝑖→0    rA ( X , T )  0
r 2 2 z 2 2 z 2

X i 1, j  2 X i , j  X i 1, j 1 ( X i , j 1  2 X i , j  X i , j 1 )  2 ( X i , j  X i , j 1 ) 3
   rA ( X i , j 1 , Ti , j 1 )  0......(4)
r 2
2 z 2
2 z 2
Si : i≠0
X i 1, j  2 X i, j  X i 1,, j 1 X i, j  X i 1, j  ( X i, j 1  2 X i, j  X i, j 1 ) ( X i, j  X i, j 1 )
  1  2  3rA ( X i, j 1,Ti, j 1 )  0............(5)
r 2 ir r z 2 z

Entonces:
 Para los valores:
i=0, j=1,…,6 ; se aplicara la fórmula (4)
 Para los valores:
i=1,…,5 y j=1,…,6; se aplicara la fórmula (5)
 Para los valores:
i=0,….,5 y j=0 son valores iniciales de x = 0
 Para los valores:
i= 5 y j=0,….,6 por ser valor mínimo : dx/dr = 0 𝑥6,𝑗 = 𝑥5,𝑗
 Para los valores:
j = 6 , i = 0,…..,5 por ser valor máximo: dx/dz = 0 𝑥𝑖,7 = 𝑥𝑖,6

2. BALANCE ENERGIA:

 Ecuación de conservación de Energía

  2 T 1 T 
  K ez  T  U S  b C P T   b .(Hr )rA ( X , T )  0 ………..( 6 )
2
K er  2 
 r r r  z 2 z


Donde:
GdpC Pg
Ker 
PeHr
GdpC Pg
Kez 
PeHZ

Reemplazando en (5) se obtiene:

 2T 1 T PEHr  2T U s PEHr . g T  b .PEHr  HR .rA ( X , T )
     0.............(7)
r 2 r r PEHa z 2 G.d P z d P .G.C Pg

Donde:
PeHr U s PEHr . g  b .PEHr (Hr )
4  5   6 
PeHZ G.d P d P .G.C Pg

Se obtiene:

 2T 1 T  2T T
    5  6 rA ( X , T )  0.
r r r z z
2 4 2

Luego discretizando

Si: i = 0
1 T  2T
lim r 0 ( . )  2
r r r

 2T 4  2T 5 T 6
   rA ( X , T )  0
r 2 2 z 2 2 z 2

Ti 1, j 1  2Ti , j 1  Ti 1, j 1  4 (Ti , j 1  2Ti , j  Ti , j 1 ) 5 (Ti , j 1  Ti , j ) 6

   rA ( X i , j 1 , Ti , j 1 )  0....(8)
r 2
2 z 2 2 z 2

Si : i≠1
Ti 1, j  2Ti , j  Ti 1,, j 1 Ti , j  Ti 1, j  (Ti , j 1  2Ti , j  Ti , j 1 ) (Ti , j  Ti , j 1 )
  4     6 rA ( X i , j 1 , Ti , j 1 )  0....(9)
r 2 ir r z 2 z
5

Entonces:

 Para los valores:

i=0 j=1,…,6 ; se aplicara la fórmula (8)
 Para los valores:
 i=1,…,5 y j=1,…,6; se aplicara la fórmula (9)

 Para los valores:

i=0,….,5 y j=0 su temperatura inicial es: 400ªC
 Para los valores:
i= 5 y j=0,….,6 existe intercambio de calor en sector externo
Se utiliza:
𝐵𝑖
𝑇6,𝑗 = 𝑇5,𝑗 − (𝑇 − 𝑇𝑤 )
5 5,𝑗
 Para los valores:
j = 6 , i = 0,…..,5 por ser valor máximo: dT/dz = 0 𝑇𝑖,7 = 𝑇𝑖,6

Para la Ecuación de velocidad:

Para valores de i=0,..,5 y j=0,..,6

38834 2
27 (− )×𝑃𝐴𝑜 (1−𝑥𝑖 ,𝑗)2
𝑇𝑖,𝑗+273
𝑟𝑖,𝑗 = 8.314 × 10 𝑒 ⁄ 21046
(− )
1 + 3.41 × 1015 𝑒 𝑇𝑖,𝑗+273 × 𝑃𝐴𝑜 (1 − 𝑥𝑖,𝑗 )

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH

# Constantes de las Ecuaciones de Balance Materia

pi1 = ( Us * dp / Pmz) / (Us * dp / Pmr)

pi2 = -Us/(E * (Us * dp / Pmr))
pi3 = db / (Cao * E * (Us * dp / Pmr))

# Constantes de las Ecuaciones de Balance de Energia

pi4 = (dp * G * Cpf / Phz) / (dp * G * Cpf / Phr)

pi5 = -Us * df * Cpf / (dp * G * Cpf / Phr)
pi6 = db * (-dH) / (dp * G * Cpf / Phr)
# Datos del problema

db = 1025 # Densidad del lecho

G = 1709 # Flujo masico
Us = 2914.393 # Velocidad
dH = -94886 # Entalpia
Cpf = 1.09 # Capacidad Calorifica del Fluido
df = 0.5864 # Densidad del Fluido
Tw = 197 # Temperatura de la pared
Phr = 4.4 # Peclet de calor en direccion radial
Pmr = 9.6 # Peclet de masa en direccion radial
Phz = 4.4 # Peclet de Calor en Direccion Axial
Pmz = 9.6 # Peclet de Masa en Direccion Axial
Bi = 6.67 # Numero de Biot
dp = 0.003175
E = 0.5 # Porosidad del lecho

dz = (0.1524)/6
dr = 0.02615 / 5

# Calculo de la Concetracion inicial

Tin = 400 +273

Cao = Pao / (R * Tin )
R = 0.082

# Calculo de la Presiones iniciales

P = 1.6
ya = 0.065
Pao = 1.7 * 0.065
Pbo = (1 - ya) * P * 0.21

K101 = exp(12.16 - 5473 / (T01 + 273))

K102 = exp(12.16 - 5473 / (T02 + 273))
K103 = exp(12.16 - 5473 / (T03 + 273))
K104 = exp(12.16 - 5473 / (T04 + 273))
K105 = exp(12.16 - 5473 / (T05 + 273))
K106 = exp(12.16 - 5473 / (T06 + 273))

K111 = exp(12.16 - 5473 / (T11 + 273))

K112 = exp(12.16 - 5473 / (T12 + 273))
K113 = exp(12.16 - 5473 / (T13 + 273))
K114 = exp(12.16 - 5473 / (T14 + 273))
K115 = exp(12.16 - 5473 / (T15 + 273))
K116 = exp(12.16 - 5473 / (T16 + 273))

K121 = exp(12.16 - 5473 / (T21 + 273))

K122 = exp(12.16 - 5473 / (T22 + 273))
K123 = exp(12.16 - 5473 / (T23 + 273))
K124 = exp(12.16 - 5473 / (T24 + 273))
K125 = exp(12.16 - 5473 / (T25 + 273))
K126 = exp(12.16 - 5473 / (T26 + 273))

K131 = exp(12.16 - 5473 / (T31 + 273))

K132 = exp(12.16 - 5473 / (T32 + 273))
K133 = exp(12.16 - 5473 / (T33 + 273))
K134 = exp(12.16 - 5473 / (T34 + 273))
K135 = exp(12.16 - 5473 / (T35 + 273))
K136 = exp(12.16 - 5473 / (T36 + 273))

K141 = exp(12.16 - 5473 / (T41 + 273))

K142 = exp(12.16 - 5473 / (T42 + 273))
K143 = exp(12.16 - 5473 / (T43 + 273))
K144 = exp(12.16 - 5473 / (T44 + 273))
K145 = exp(12.16 - 5473 / (T45 + 273))
K146 = exp(12.16 - 5473 / (T46 + 273))

K151 = exp(12.16 - 5473 / (T51 + 273))

K152 = exp(12.16 - 5473 / (T52 + 273))
K153 = exp(12.16 - 5473 / (T53 + 273))
K154 = exp(12.16 - 5473 / (T54 + 273))
K155 = exp(12.16 - 5473 / (T55 + 273))
K156 = exp(12.16 - 5473 / (T56 + 273))

K201 = exp(-9.953 + 8619 / (T01 + 273))

K202 = exp(-9.953 + 8619 / (T02 + 273))
K203 = exp(-9.953 + 8619 / (T03 + 273))
K204 = exp(-9.953 + 8619 / (T04 + 273))
K205 = exp(-9.953 + 8619 / (T05 + 273))
K206 = exp(-9.953 + 8619 / (T06 + 273))

K211 = exp(-9.953 + 8619 / (T11 + 273))

K212 = exp(-9.953 + 8619 / (T12 + 273))
K213 = exp(-9.953 + 8619 / (T13 + 273))
K214 = exp(-9.953 + 8619 / (T14 + 273))
K215 = exp(-9.953 + 8619 / (T15 + 273))
K216 = exp(-9.953 + 8619 / (T16 + 273))

K221 = exp(-9.953 + 8619 / (T21 + 273))

K222 = exp(-9.953 + 8619 / (T22 + 273))
K223 = exp(-9.953 + 8619 / (T23 + 273))
K224 = exp(-9.953 + 8619 / (T24 + 273))
K225 = exp(-9.953 + 8619 / (T25 + 273))
K226 = exp(-9.953 + 8619 / (T26 + 273))

K231 = exp(-9.953 + 8619 / (T31 + 273))

K232 = exp(-9.953 + 8619 / (T32 + 273))
K233 = exp(-9.953 + 8619 / (T33 + 273))
K234 = exp(-9.953 + 8619 / (T34 + 273))
K235 = exp(-9.953 + 8619 / (T35 + 273))
K236 = exp(-9.953 + 8619 / (T36 + 273))

K241 = exp(-9.953 + 8619 / (T41 + 273))

K242 = exp(-9.953 + 8619 / (T42 + 273))
K243 = exp(-9.953 + 8619 / (T43 + 273))
K244 = exp(-9.953 + 8619 / (T44 + 273))
K245 = exp(-9.953 + 8619 / (T45 + 273))
K246 = exp(-9.953 + 8619 / (T46 + 273))
K251 = exp(-9.953 + 8619 / (T51 + 273))
K252 = exp(-9.953 + 8619 / (T52 + 273))
K253 = exp(-9.953 + 8619 / (T53 + 273))
K254 = exp(-9.953 + 8619 / (T54 + 273))
K255 = exp(-9.953 + 8619 / (T55 + 273))
K256 = exp(-9.953 + 8619 / (T56 + 273))

K301 = exp(-71.745 + 52596 / (T01 + 273))

K302 = exp(-71.745 + 52596 / (T02 + 273))
K303 = exp(-71.745 + 52596 / (T03 + 273))
K304 = exp(-71.745 + 52596 / (T04 + 273))
K305 = exp(-71.745 + 52596 / (T05 + 273))
K306 = exp(-71.745 + 52596 / (T06 + 273))

K311 = exp(-71.745 + 52596 / (T11 + 273))

K312 = exp(-71.745 + 52596 / (T12 + 273))
K313 = exp(-71.745 + 52596 / (T13 + 273))
K314 = exp(-71.745 + 52596 / (T14 + 273))
K315 = exp(-71.745 + 52596 / (T15 + 273))
K316 = exp(-71.745 + 52596 / (T16 + 273))

K321 = exp(-71.745 + 52596 / (T21 + 273))

K322 = exp(-71.745 + 52596 / (T22 + 273))
K323 = exp(-71.745 + 52596 / (T23 + 273))
K324 = exp(-71.745 + 52596 / (T24 + 273))
K325 = exp(-71.745 + 52596 / (T25 + 273))
K326 = exp(-71.745 + 52596 / (T26 + 273))

K331 = exp(-71.745 + 52596 / (T31 + 273))

K332 = exp(-71.745 + 52596 / (T32 + 273))
K333 = exp(-71.745 + 52596 / (T33 + 273))
K334 = exp(-71.745 + 52596 / (T34 + 273))
K335 = exp(-71.745 + 52596 / (T35 + 273))
K336 = exp(-71.745 + 52596 / (T36 + 273))

K341 = exp(-71.745 + 52596 / (T41 + 273))

K342 = exp(-71.745 + 52596 / (T42 + 273))
K343 = exp(-71.745 + 52596 / (T43 + 273))
K344 = exp(-71.745 + 52596 / (T44 + 273))
K345 = exp(-71.745 + 52596 / (T45 + 273))
K346 = exp(-71.745 + 52596 / (T46 + 273))

K351 = exp(-71.745 + 52596 / (T51 + 273))

K352 = exp(-71.745 + 52596 / (T52 + 273))
K353 = exp(-71.745 + 52596 / (T53 + 273))
K354 = exp(-71.745 + 52596 / (T54 + 273))
K355 = exp(-71.745 + 52596 / (T55 + 273))
K356 = exp(-71.745 + 52596 / (T56 + 273))

Kp01 = exp(11300 / (T01 + 273) - 10.68)

Kp02 = exp(11300 / (T02 + 273) - 10.68)
Kp03 = exp(11300 / (T03 + 273) - 10.68)
Kp04 = exp(11300 / (T04 + 273) - 10.68)
Kp05 = exp(11300 / (T05 + 273) - 10.68)
Kp06 = exp(11300 / (T06 + 273) - 10.68)

Kp11 = exp(11300 / (T11 + 273) - 10.68)

Kp12 = exp(11300 / (T12 + 273) - 10.68)
Kp13 = exp(11300 / (T13 + 273) - 10.68)
Kp14 = exp(11300 / (T14 + 273) - 10.68)
Kp15 = exp(11300 / (T15 + 273) - 10.68)
Kp16 = exp(11300 / (T16 + 273) - 10.68)

Kp21 = exp(11300 / (T21 + 273) - 10.68)

Kp22 = exp(11300 / (T22 + 273) - 10.68)
Kp23 = exp(11300 / (T23 + 273) - 10.68)
Kp24 = exp(11300 / (T24 + 273) - 10.68)
Kp25 = exp(11300 / (T25 + 273) - 10.68)
Kp26 = exp(11300 / (T26 + 273) - 10.68)

Kp31 = exp(11300 / (T31 + 273) - 10.68)

Kp32 = exp(11300 / (T32 + 273) - 10.68)
Kp33 = exp(11300 / (T33 + 273) - 10.68)
Kp34 = exp(11300 / (T34 + 273) - 10.68)
Kp35 = exp(11300 / (T35 + 273) - 10.68)
Kp36 = exp(11300 / (T36 + 273) - 10.68)

Kp41 = exp(11300 / (T41 + 273) - 10.68)

Kp42 = exp(11300 / (T42 + 273) - 10.68)
Kp43 = exp(11300 / (T43 + 273) - 10.68)
Kp44 = exp(11300 / (T44 + 273) - 10.68)
Kp45 = exp(11300 / (T45 + 273) - 10.68)
Kp46 = exp(11300 / (T46 + 273) - 10.68)

Kp51 = exp(11300 / (T51 + 273) - 10.68)

Kp52 = exp(11300 / (T52 + 273) - 10.68)
Kp53 = exp(11300 / (T53 + 273) - 10.68)
Kp54 = exp(11300 / (T54 + 273) - 10.68)
Kp55 = exp(11300 / (T55 + 273) - 10.68)
Kp56 = exp(11300 / (T56 + 273) - 10.68)

Pa01 = Pao * (1 - x01)

Pa02 = Pao * (1 - x02)
Pa03 = Pao * (1 - x03)
Pa04 = Pao * (1 - x04)
Pa05 = Pao * (1 - x05)
Pa06 = Pao * (1 - x06)

Pa11 = Pao * (1 - x11)

Pa12 = Pao * (1 - x12)
Pa13 = Pao * (1 - x13)
Pa14 = Pao * (1 - x14)
Pa15 = Pao * (1 - x15)
Pa16 = Pao * (1 - x16)

Pa21 = Pao * (1 - x21)

Pa22 = Pao * (1 - x22)
Pa23 = Pao * (1 - x23)
Pa24 = Pao * (1 - x24)
Pa25 = Pao * (1 - x25)
Pa26 = Pao * (1 - x26)

Pa31 = Pao * (1 - x31)

Pa32 = Pao * (1 - x32)
Pa33 = Pao * (1 - x33)
Pa34 = Pao * (1 - x34)
Pa35 = Pao * (1 - x35)
Pa36 = Pao * (1 - x36)

Pa41 = Pao * (1 - x41)

Pa42 = Pao * (1 - x42)
Pa43 = Pao * (1 - x43)
Pa44 = Pao * (1 - x44)
Pa45 = Pao * (1 - x45)
Pa46 = Pao * (1 - x46)

Pa51 = Pao * (1 - x51)

Pa52 = Pao * (1 - x52)
Pa53 = Pao * (1 - x53)
Pa54 = Pao * (1 - x54)
Pa55 = Pao * (1 - x55)
Pa56 = Pao * (1 - x56)

Pb01 = Pbo - 0.5 * Pao * x01

Pb02 = Pbo - 0.5 * Pao * x02
Pb03 = Pbo - 0.5 * Pao * x03
Pb04 = Pbo - 0.5 * Pao * x04
Pb05 = Pbo - 0.5 * Pao * x05
Pb06 = Pbo - 0.5 * Pao * x06

Pb11 = Pbo - 0.5 * Pao * x11

Pb12 = Pbo - 0.5 * Pao * x12
Pb13 = Pbo - 0.5 * Pao * x13
Pb14 = Pbo - 0.5 * Pao * x14
Pb15 = Pbo - 0.5 * Pao * x15
Pb16 = Pbo - 0.5 * Pao * x16

Pb21 = Pbo - 0.5 * Pao * x21

Pb22 = Pbo - 0.5 * Pao * x22
Pb23 = Pbo - 0.5 * Pao * x23
Pb24 = Pbo - 0.5 * Pao * x24
Pb25 = Pbo - 0.5 * Pao * x25
Pb26 = Pbo - 0.5 * Pao * x26

Pb31 = Pbo - 0.5 * Pao * x31

Pb32 = Pbo - 0.5 * Pao * x32
Pb33 = Pbo - 0.5 * Pao * x33
Pb34 = Pbo - 0.5 * Pao * x34
Pb35 = Pbo - 0.5 * Pao * x35
Pb36 = Pbo - 0.5 * Pao * x36

Pb41 = Pbo - 0.5 * Pao * x41

Pb42 = Pbo - 0.5 * Pao * x42
Pb43 = Pbo - 0.5 * Pao * x43
Pb44 = Pbo - 0.5 * Pao * x44
Pb45 = Pbo - 0.5 * Pao * x45
Pb46 = Pbo - 0.5 * Pao * x46

Pb51 = Pbo - 0.5 * Pao * x51

Pb52 = Pbo - 0.5 * Pao * x52
Pb53 = Pbo - 0.5 * Pao * x53
Pb54 = Pbo - 0.5 * Pao * x54
Pb55 = Pbo - 0.5 * Pao * x55
Pb56 = Pbo - 0.5 * Pao * x56

Pr01 = Pao * x01

Pr02 = Pao * x02
Pr03 = Pao * x03
Pr04 = Pao * x04
Pr05 = Pao * x05
Pr06 = Pao * x06

Pr11 = Pao * x11

Pr12 = Pao * x12
Pr13 = Pao * x13
Pr14 = Pao * x14
Pr15 = Pao * x15
Pr16 = Pao * x16

Pr21 = Pao * x21

Pr22 = Pao * x22
Pr23 = Pao * x23
Pr24 = Pao * x24
Pr25 = Pao * x25
Pr26 = Pao * x26

Pr31 = Pao * x31

Pr32 = Pao * x32
Pr33 = Pao * x33
Pr34 = Pao * x34
Pr35 = Pao * x35
Pr36 = Pao * x36

Pr41 = Pao * x41

Pr42 = Pao * x42
Pr43 = Pao * x43
Pr44 = Pao * x44
Pr45 = Pao * x45
Pr46 = Pao * x46

Pr51 = Pao * x51

Pr52 = Pao * x52
Pr53 = Pao * x53
Pr54 = Pao * x54
Pr55 = Pao * x55
Pr56 = Pao * x56

f(x01) = 2 * (x11 - 2 * x01 + x01) / dr ^ 2 + pi1 * (x02 - 2 * x01 + x00) / dz ^ 2 + pi2 * (x01 - x00) / dz
+ pi3 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414 * (1 + K201 * Pa01
+ K301 * Pr01) ^ 2)
f(x02) = 2 * (x12 - 2 * x02 + x02) / dr ^ 2 + pi1 * (x03 - 2 * x02 + x01) / dz ^ 2 + pi2 * (x02 - x01) / dz
+ pi3 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414 * (1 + K202 * Pa02
+ K302 * Pr02) ^ 2)
f(x03) = 2 * (x13 - 2 * x03 + x03) / dr ^ 2 + pi1 * (x04 - 2 * x03 + x02) / dz ^ 2 + pi2 * (x03 - x02) / dz
+ pi3 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414 * (1 + K203 * Pa03
+ K303 * Pr03) ^ 2)
f(x04) = 2 * (x14 - 2 * x04 + x04) / dr ^ 2 + pi1 * (x05 - 2 * x04 + x03) / dz ^ 2 + pi2 * (x04 - x03) / dz
+ pi3 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414 * (1 + K204 * Pa04
+ K304 * Pr04) ^ 2)
f(x05) = 2 * (x15 - 2 * x05 + x05) / dr ^ 2 + pi1 * (x06 - 2 * x05 + x04) / dz ^ 2 + pi2 * (x05 - x04) / dz
+ pi3 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414 * (1 + K205 * Pa05
+ K305 * Pr05) ^ 2)
f(x06) = 2 * (x16 - 2 * x06 + x06) / dr ^ 2 + pi1 * (x06 - 2 * x06 + x05) / dz ^ 2 + pi2 * (x06 - x05) / dz
+ pi3 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414 * (1 + K206 * Pa06
+ K306 * Pr06) ^ 2)
f(T01) = 2 * (T11 - 2 * T01 + T01) / dr ^ 2 + pi4 * (T02 - 2 * T01 + T00) / dz ^ 2 + pi5 * (T01 - T00) /
dz + pi6 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414 * (1 + K201 *
Pa01 + K301 * Pr01) ^ 2)
f(T02) = 2 * (T12 - 2 * T02 + T02) / dr ^ 2 + pi4 * (T03 - 2 * T02 + T01) / dz ^ 2 + pi5 * (T02 - T01) /
dz + pi6 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414 * (1 + K202 *
Pa02 + K302 * Pr02) ^ 2)
f(T03) = 2 * (T13 - 2 * T03 + T03) / dr ^ 2 + pi4 * (T04 - 2 * T03 + T02) / dz ^ 2 + pi5 * (T03 - T02) /
dz + pi6 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414 * (1 + K203 *
Pa03 + K303 * Pr03) ^ 2)
f(T04) = 2 * (T14 - 2 * T04 + T04) / dr ^ 2 + pi4 * (T05 - 2 * T04 + T03) / dz ^ 2 + pi5 * (T04 - T03) /
dz + pi6 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414 * (1 + K204 *
Pa04 + K304 * Pr04) ^ 2)
f(T05) = 2 * (T15 - 2 * T05 + T05) / dr ^ 2 + pi4 * (T06 - 2 * T05 + T04) / dz ^ 2 + pi5 * (T05 - T04) /
dz + pi6 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414 * (1 + K205 *
Pa05 + K305 * Pr05) ^ 2)
f(T06) = 2 * (T16 - 2 * T06 + T06) / dr ^ 2 + pi4 * (T06 - 2 * T06 + T05) / dz ^ 2 + pi5 * (T06 - T05) /
dz + pi6 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414 * (1 + K206 *
Pa06 + K306 * Pr06) ^ 2)

f(x11) = (x21 - 2 * x11 + x01) / dr ^ 2 + (x11 - x01) / (1 * dr ^ 2) + pi1 * (x12 - 2 * x11 + x10) / dz ^ 2
+ pi2 * (x11 - x10) / dz + pi3 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11 ^ 0.5) * Kp11))) /
(22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2)
f(x12) = (x22 - 2 * x12 + x02) / dr ^ 2 + (x12 - x02) / (1 * dr ^ 2) + pi1 * (x13 - 2 * x12 + x11) / dz ^ 2
+ pi2 * (x12 - x11) / dz + pi3 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12 ^ 0.5) * Kp12))) /
(22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2)
f(x13) = (x23 - 2 * x13 + x03) / dr ^ 2 + (x13 - x03) / (1 * dr ^ 2) + pi1 * (x14 - 2 * x13 + x12) / dz ^ 2
+ pi2 * (x13 - x12) / dz + pi3 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13 ^ 0.5) * Kp13))) /
(22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2)
f(x14) = (x24 - 2 * x14 + x04) / dr ^ 2 + (x14 - x04) / (1 * dr ^ 2) + pi1 * (x15 - 2 * x14 + x13) / dz ^ 2
+ pi2 * (x14 - x13) / dz + pi3 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14 ^ 0.5) * Kp14))) /
(22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2)
f(x15) = (x25 - 2 * x15 + x05) / dr ^ 2 + (x15 - x05) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x15 + x14) / dz ^ 2
+ pi2 * (x15 - x14) / dz + pi3 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15 ^ 0.5) * Kp15))) /
(22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2)
f(x16) = (x26 - 2 * x16 + x06) / dr ^ 2 + (x16 - x06) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x16 + x15) / dz ^ 2
+ pi2 * (x16 - x15) / dz + pi3 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16 ^ 0.5) * Kp16))) /
(22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2)
f(T11) = (T21 - 2 * T11 + T01) / dr ^ 2 + (T11 - T01) / (1 * dr ^ 2) + pi4 * (T12 - 2 * T11 + T10) / dz ^
2 + pi5 * (T11 - T10) / dz + pi6 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11 ^ 0.5) * Kp11))) /
(22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2)
f(T12) = (T22 - 2 * T12 + T02) / dr ^ 2 + (T12 - T02) / (1 * dr ^ 2) + pi4 * (T13 - 2 * T12 + T11) / dz ^
2 + pi5 * (T12 - T11) / dz + pi6 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12 ^ 0.5) * Kp12))) /
(22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2)
f(T13) = (T23 - 2 * T13 + T03) / dr ^ 2 + (T13 - T03) / (1 * dr ^ 2) + pi4 * (T14 - 2 * T13 + T12) / dz ^
2 + pi5 * (T13 - T12) / dz + pi6 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13 ^ 0.5) * Kp13))) /
(22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2)
f(T14) = (T24 - 2 * T14 + T04) / dr ^ 2 + (T14 - T04) / (1 * dr ^ 2) + pi4 * (T15 - 2 * T14 + T13) / dz ^
2 + pi5 * (T14 - T13) / dz + pi6 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14 ^ 0.5) * Kp14))) /
(22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2)
f(T15) = (T25 - 2 * T15 + T05) / dr ^ 2 + (T15 - T05) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T15 + T14) / dz ^
2 + pi5 * (T15 - T14) / dz + pi6 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15 ^ 0.5) * Kp15))) /
(22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2)
f(T16) = (T26 - 2 * T16 + T06) / dr ^ 2 + (T16 - T06) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T16 + T15) / dz ^
2 + pi5 * (T16 - T15) / dz + pi6 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16 ^ 0.5) * Kp16))) /
(22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2)

f(x21) = (x31 - 2 * x21 + x11) / dr ^ 2 + (x21 - x11) / (2 * dr ^ 2) + pi1 * (x22 - 2 * x21 + x20) / dz ^ 2
+ pi2 * (x21 - x20) / dz + pi3 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21 ^ 0.5) * Kp21))) /
(22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2)
f(x22) = (x32 - 2 * x22 + x12) / dr ^ 2 + (x22 - x12) / (2 * dr ^ 2) + pi1 * (x23 - 2 * x22 + x21) / dz ^ 2
+ pi2 * (x22 - x21) / dz + pi3 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22 ^ 0.5) * Kp22))) /
(22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2)
f(x23) = (x33 - 2 * x23 + x13) / dr ^ 2 + (x23 - x13) / (2 * dr ^ 2) + pi1 * (x24 - 2 * x23 + x22) / dz ^ 2
+ pi2 * (x23 - x22) / dz + pi3 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23 ^ 0.5) * Kp23))) /
(22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2)
f(x24) = (x34 - 2 * x24 + x14) / dr ^ 2 + (x24 - x14) / (2 * dr ^ 2) + pi1 * (x25 - 2 * x24 + x23) / dz ^ 2
+ pi2 * (x24 - x23) / dz + pi3 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24 ^ 0.5) * Kp24))) /
(22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2)
f(x25) = (x35 - 2 * x25 + x15) / dr ^ 2 + (x25 - x15) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x25 + x24) / dz ^ 2
+ pi2 * (x25 - x24) / dz + pi3 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25 ^ 0.5) * Kp25))) /
(22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2)
f(x26) = (x36 - 2 * x26 + x16) / dr ^ 2 + (x26 - x16) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x26 + x25) / dz ^ 2
+ pi2 * (x26 - x25) / dz + pi3 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26 ^ 0.5) * Kp26))) /
(22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2)
f(T21) = (T31 - 2 * T21 + T11) / dr ^ 2 + (T21 - T11) / (2 * dr ^ 2) + pi4 * (T22 - 2 * T21 + T20) / dz ^
2 + pi5 * (T21 - T20) / dz + pi6 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21 ^ 0.5) * Kp21))) /
(22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2)
f(T22) = (T32 - 2 * T22 + T12) / dr ^ 2 + (T22 - T12) / (2 * dr ^ 2) + pi4 * (T23 - 2 * T22 + T21) / dz ^
2 + pi5 * (T22 - T21) / dz + pi6 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22 ^ 0.5) * Kp22))) /
(22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2)
f(T23) = (T33 - 2 * T23 + T13) / dr ^ 2 + (T23 - T13) / (2 * dr ^ 2) + pi4 * (T24 - 2 * T23 + T22) / dz ^
2 + pi5 * (T23 - T22) / dz + pi6 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23 ^ 0.5) * Kp23))) /
(22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2)
f(T24) = (T34 - 2 * T24 + T14) / dr ^ 2 + (T24 - T14) / (2 * dr ^ 2) + pi4 * (T25 - 2 * T24 + T23) / dz ^
2 + pi5 * (T24 - T23) / dz + pi6 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24 ^ 0.5) * Kp24))) /
(22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2)
f(T25) = (T35 - 2 * T25 + T15) / dr ^ 2 + (T25 - T15) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T25 + T24) / dz ^
2 + pi5 * (T25 - T24) / dz + pi6 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25 ^ 0.5) * Kp25))) /
(22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2)
f(T26) = (T36 - 2 * T26 + T16) / dr ^ 2 + (T26 - T16) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T26 + T25) / dz ^
2 + pi5 * (T26 - T25) / dz + pi6 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26 ^ 0.5) * Kp26))) /
(22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2)

f(x31) = (x41 - 2 * x31 + x21) / dr ^ 2 + (x31 - x21) / (3 * dr ^ 2) + pi1 * (x32 - 2 * x31 + x30) / dz ^ 2
+ pi2 * (x31 - x30) / dz + pi3 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31 ^ 0.5) * Kp31))) /
(22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2)
f(x32) = (x42 - 2 * x32 + x22) / dr ^ 2 + (x32 - x22) / (3 * dr ^ 2) + pi1 * (x33 - 2 * x32 + x31) / dz ^ 2
+ pi2 * (x32 - x31) / dz + pi3 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32 ^ 0.5) * Kp32))) /
(22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2)
f(x33) = (x43 - 2 * x33 + x23) / dr ^ 2 + (x33 - x23) / (3 * dr ^ 2) + pi1 * (x34 - 2 * x33 + x32) / dz ^ 2
+ pi2 * (x33 - x32) / dz + pi3 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33 ^ 0.5) * Kp33))) /
(22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2)
f(x34) = (x44 - 2 * x34 + x24) / dr ^ 2 + (x34 - x24) / (3 * dr ^ 2) + pi1 * (x35 - 2 * x34 + x33) / dz ^ 2
+ pi2 * (x34 - x33) / dz + pi3 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34 ^ 0.5) * Kp34))) /
(22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2)
f(x35) = (x45 - 2 * x35 + x25) / dr ^ 2 + (x35 - x25) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x35 + x34) / dz ^ 2
+ pi2 * (x35 - x34) / dz + pi3 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35 ^ 0.5) * Kp35))) /
(22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2)
f(x36) = (x46 - 2 * x36 + x26) / dr ^ 2 + (x36 - x26) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x36 + x35) / dz ^ 2
+ pi2 * (x36 - x35) / dz + pi3 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36 ^ 0.5) * Kp36))) /
(22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2)
f(T31) = (T41 - 2 * T31 + T21) / dr ^ 2 + (T31 - T21) / (3 * dr ^ 2) + pi4 * (T32 - 2 * T31 + T30) / dz ^
2 + pi5 * (T31 - T30) / dz + pi6 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31 ^ 0.5) * Kp31))) /
(22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2)
f(T32) = (T42 - 2 * T32 + T22) / dr ^ 2 + (T32 - T22) / (3 * dr ^ 2) + pi4 * (T33 - 2 * T32 + T31) / dz ^
2 + pi5 * (T32 - T31) / dz + pi6 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32 ^ 0.5) * Kp32))) /
(22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2)
f(T33) = (T43 - 2 * T33 + T23) / dr ^ 2 + (T33 - T23) / (3 * dr ^ 2) + pi4 * (T34 - 2 * T33 + T32) / dz ^
2 + pi5 * (T33 - T32) / dz + pi6 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33 ^ 0.5) * Kp33))) /
(22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2)
f(T34) = (T44 - 2 * T34 + T24) / dr ^ 2 + (T34 - T24) / (3 * dr ^ 2) + pi4 * (T35 - 2 * T34 + T33) / dz ^
2 + pi5 * (T34 - T33) / dz + pi6 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34 ^ 0.5) * Kp34))) /
(22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2)
f(T35) = (T45 - 2 * T35 + T25) / dr ^ 2 + (T35 - T25) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T35 + T34) / dz ^
2 + pi5 * (T35 - T34) / dz + pi6 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35 ^ 0.5) * Kp35))) /
(22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2)
f(T36) = (T46 - 2 * T36 + T26) / dr ^ 2 + (T36 - T26) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T36 + T35) / dz ^
2 + pi5 * (T36 - T35) / dz + pi6 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36 ^ 0.5) * Kp36))) /
(22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2)

f(x41) = (x51 - 2 * x41 + x31) / dr ^ 2 + (x41 - x31) / (4 * dr ^ 2) + pi1 * (x42 - 2 * x41 + x40) / dz ^ 2
+ pi2 * (x41 - x40) / dz + pi3 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41 ^ 0.5) * Kp41))) /
(22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2)
f(x42) = (x52 - 2 * x42 + x32) / dr ^ 2 + (x42 - x32) / (4 * dr ^ 2) + pi1 * (x43 - 2 * x42 + x41) / dz ^ 2
+ pi2 * (x42 - x41) / dz + pi3 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42 ^ 0.5) * Kp42))) /
(22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2)
f(x43) = (x53 - 2 * x43 + x33) / dr ^ 2 + (x43 - x33) / (4 * dr ^ 2) + pi1 * (x44 - 2 * x43 + x42) / dz ^ 2
+ pi2 * (x43 - x42) / dz + pi3 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43 ^ 0.5) * Kp43))) /
(22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2)
f(x44) = (x54 - 2 * x44 + x34) / dr ^ 2 + (x44 - x34) / (4 * dr ^ 2) + pi1 * (x45 - 2 * x44 + x43) / dz ^ 2
+ pi2 * (x44 - x43) / dz + pi3 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44 ^ 0.5) * Kp44))) /
(22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2)
f(x45) = (x55 - 2 * x45 + x35) / dr ^ 2 + (x45 - x35) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x45 + x44) / dz ^ 2
+ pi2 * (x45 - x44) / dz + pi3 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45 ^ 0.5) * Kp45))) /
(22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2)
f(x46) = (x56 - 2 * x46 + x36) / dr ^ 2 + (x46 - x36) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x46 + x45) / dz ^ 2
+ pi2 * (x46 - x45) / dz + pi3 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46 ^ 0.5) * Kp46))) /
(22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2)
f(T41) = (T51 - 2 * T41 + T31) / dr ^ 2 + (T41 - T31) / (4 * dr ^ 2) + pi4 * (T42 - 2 * T41 + T40) / dz ^
2 + pi5 * (T41 - T40) / dz + pi6 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41 ^ 0.5) * Kp41))) /
(22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2)
f(T42) = (T52 - 2 * T42 + T32) / dr ^ 2 + (T42 - T32) / (4 * dr ^ 2) + pi4 * (T43 - 2 * T42 + T41) / dz ^
2 + pi5 * (T42 - T41) / dz + pi6 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42 ^ 0.5) * Kp42))) /
(22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2)
f(T43) = (T53 - 2 * T43 + T33) / dr ^ 2 + (T43 - T33) / (4 * dr ^ 2) + pi4 * (T44 - 2 * T43 + T42) / dz ^
2 + pi5 * (T43 - T42) / dz + pi6 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43 ^ 0.5) * Kp43))) /
(22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2)
f(T44) = (T54 - 2 * T44 + T34) / dr ^ 2 + (T44 - T34) / (4 * dr ^ 2) + pi4 * (T45 - 2 * T44 + T43) / dz ^
2 + pi5 * (T44 - T43) / dz + pi6 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44 ^ 0.5) * Kp44))) /
(22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2)
f(T45) = (T55 - 2 * T45 + T35) / dr ^ 2 + (T45 - T35) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T45 + T44) / dz ^
2 + pi5 * (T45 - T44) / dz + pi6 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45 ^ 0.5) * Kp45))) /
(22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2)
f(T46) = (T56 - 2 * T46 + T36) / dr ^ 2 + (T46 - T36) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T46 + T45) / dz ^
2 + pi5 * (T46 - T45) / dz + pi6 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46 ^ 0.5) * Kp46))) /
(22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2)

f(x51) = (x51 - 2 * x51 + x41) / dr ^ 2 + (x51 - x41) / (5 * dr ^ 2) + pi1 * (x52 - 2 * x51 + x50) / dz ^ 2
+ pi2 * (x51 - x50) / dz + pi3 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51 ^ 0.5) * Kp51))) /
(22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2)
f(x52) = (x52 - 2 * x52 + x42) / dr ^ 2 + (x52 - x42) / (5 * dr ^ 2) + pi1 * (x53 - 2 * x52 + x51) / dz ^ 2
+ pi2 * (x52 - x51) / dz + pi3 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52 ^ 0.5) * Kp52))) /
(22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2)
f(x53) = (x53 - 2 * x53 + x43) / dr ^ 2 + (x53 - x43) / (5 * dr ^ 2) + pi1 * (x54 - 2 * x53 + x52) / dz ^ 2
+ pi2 * (x53 - x52) / dz + pi3 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53 ^ 0.5) * Kp53))) /
(22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2)
f(x54) = (x54 - 2 * x54 + x44) / dr ^ 2 + (x54 - x44) / (5 * dr ^ 2) + pi1 * (x55 - 2 * x54 + x53) / dz ^ 2
+ pi2 * (x54 - x53) / dz + pi3 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54 ^ 0.5) * Kp54))) /
(22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2)
f(x55) = (x55 - 2 * x55 + x45) / dr ^ 2 + (x55 - x45) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x55 + x54) / dz ^ 2
+ pi2 * (x55 - x54) / dz + pi3 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55 ^ 0.5) * Kp55))) /
(22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2)
f(x56) = (x56 - 2 * x56 + x46) / dr ^ 2 + (x56 - x46) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x56 + x55) / dz ^ 2
+ pi2 * (x56 - x55) / dz + pi3 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56 ^ 0.5) * Kp56))) /
(22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2)
f(T51) = (T61 - 2 * T51 + T41) / dr ^ 2 + (T51 - T41) / (5 * dr ^ 2) + pi4 * (T52 - 2 * T51 + T50) / dz ^
2 + pi5 * (T51 - T50) / dz + pi6 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51 ^ 0.5) * Kp51))) /
(22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2)
f(T52) = (T62 - 2 * T52 + T42) / dr ^ 2 + (T52 - T42) / (5 * dr ^ 2) + pi4 * (T53 - 2 * T52 + T51) / dz ^
2 + pi5 * (T52 - T51) / dz + pi6 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52 ^ 0.5) * Kp52))) /
(22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2)
f(T53) = (T63 - 2 * T53 + T43) / dr ^ 2 + (T53 - T43) / (5 * dr ^ 2) + pi4 * (T54 - 2 * T53 + T52) / dz ^
2 + pi5 * (T53 - T52) / dz + pi6 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53 ^ 0.5) * Kp53))) /
(22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2)
f(T54) = (T64 - 2 * T54 + T44) / dr ^ 2 + (T54 - T44) / (5 * dr ^ 2) + pi4 * (T55 - 2 * T54 + T53) / dz ^
2 + pi5 * (T54 - T53) / dz + pi6 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54 ^ 0.5) * Kp54))) /
(22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2)
f(T55) = (T65 - 2 * T55 + T45) / dr ^ 2 + (T55 - T45) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T55 + T54) / dz ^
2 + pi5 * (T55 - T54) / dz + pi6 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55 ^ 0.5) * Kp55))) /
(22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2)
f(T56) = (T66 - 2 * T56 + T46) / dr ^ 2 + (T56 - T46) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T56 + T55) / dz ^
2 + pi5 * (T56 - T55) / dz + pi6 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56 ^ 0.5) * Kp56))) /
(22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2)
T61 = T51 - Bi*(T51 - Tw)/5
T62 = T52 - Bi*(T52 - Tw)/5
T63 = T53 - Bi*(T53 - Tw)/5
T64 = T54 - Bi*(T54 - Tw)/5
T65 = T55 - Bi*(T55 - Tw)/5
T66 = T56 - Bi*(T56 - Tw)/5

x00 = 0
x10 = 0
x20 = 0
x30 = 0
x40 = 0
x50 = 0
x01(0) = 0
x02(0) = 0
x03(0) = 0
x04(0) = 0
x05(0) = 0
x06(0) = 0
x11(0) = 0
x12(0) = 0
x13(0) = 0
x14(0) = 0
x15(0) = 0
x16(0) = 0
x21(0) = 0
x22(0) = 0
x23(0) = 0
x24(0) = 0
x25(0) = 0
x26(0) = 0
x31(0) = 0
x32(0) = 0
x33(0) = 0
x34(0) = 0
x35(0) = 0
x36(0) = 0
x41(0) = 0
x42(0) = 0
x43(0) = 0
x44(0) = 0
x45(0) = 0
x46(0) = 0
x51(0) = 0
x52(0) = 0
x53(0) = 0
x54(0) = 0
x55(0) = 0
x56(0) = 0

T00 = 400
T10 = 400
T20 = 400
T30 = 400
T40 = 400
T50 = 400
T01(0) = 400
T02(0) = 400
T03(0) = 400
T04(0) = 400
T05(0) = 400
T06(0) = 400
T11(0) = 400
T12(0) = 400
T13(0) = 400
T14(0) = 400
T15(0) = 400
T16(0) = 400
T21(0) = 400
T22(0) = 400
T23(0) = 400
T24(0) = 400
T25(0) = 400
T26(0) = 400
T31(0) = 400
T32(0) = 400
T33(0) = 400
T34(0) = 400
T35(0) = 400
T36(0) = 400
T41(0) = 400
T42(0) = 400
T43(0) = 400
T44(0) = 400
T45(0) = 400
T46(0) = 400
T51(0) = 400
T52(0) = 400
T53(0) = 400
T54(0) = 400
T55(0) = 400
T56(0) = 400

Con las tablas obtenidas por polymath, procedemos a graficar

DATOS OBTENIDOS EN POLYMATH

ro r1 r2 r3 r4 r5

Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615

Z x0 x1 x2 x3 x4 x5 xprom

0 0 0 0 0 0 0 0

0.0254 0.033205 0.0304528 0.0241723 0.0141693 0.0037283 0.0004082 0.01768932

0.0508 0.0621238 0.0510427 0.0331441 0.0156018 0.0044601 0.0008516 0.02787068

0.0762 0.0743783 0.0565632 0.0337676 0.0158213 0.0051107 0.0013177 0.0311598

 0.1016 0.0730974 0.0547159 0.0329347 0.0159783 0.0056959 0.0017967 0.03070315

0.127 0.0684806 0.0517973 0.0320125 0.0160927 0.0062261 0.0022813 0.02948175

0.1524 0.0639686 0.0490635 0.031104 0.0161683 0.006707 0.0027627 0.02829568

ro r1 r2 r3 r4 r5

Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615

z T0 T1 T2 T3 T4 T5 Tprom

0 400 400 400 400 400 400 400

0.0254 408.0895 406.6659 402.9154 394.5097 374.5033 320.175 384.476467

0.0508 411.5191 407.0443 397.5037 380.2837 347.0625 281.0043 370.736267

0.0762 407.4392 400.5537 387.003 363.9168 324.0797 259.7039 357.11605

0.1016 398.1714 390.3222 374.4462 347.7533 305.7875 246.8546 343.8892

0.127 387.0574 378.6604 361.2166 332.7341 291.2583 238.3402 331.5445

0.1524 375.5467 366.7055 348.3545 319.4386 279.7556 232.3394 320.356717

X vs Z
0.08

0.07

0.06

0.05 T0
Conversion

T1
0.04
T2
0.03 T3

0.02 T4
T5
0.01

0.00
0 0.015240.030480.045720.06096 0.0762 0.091440.106680.121920.13716 0.1524
Z en metros
 T vs Z
420.0
400.0
380.0
360.0
T0
Temperatura

340.0
T1
320.0
T2
300.0
T3
280.0
T4
260.0
T5
240.0
220.0
0 0.015240.030480.045720.060960.07620.091440.106680.121920.137160.1524
Z en metros

Perfil de conversion
0.08

0.07

0.06
0
0.05
0.0254
Conversion

0.04 0.0508
0.0762
0.03
0.1016
0.02
0.127
0.01 0.1524

0.00
0 0.00523 0.01046 0.01569 0.02092 0.02615
Radio en Metros
 Perfil de Temperatura
430.0
410.0
390.0
370.0 0
Temperatura

350.0 0.0254
330.0 0.0508
310.0 0.0762

290.0 0.1016

270.0 0.127
0.1524
250.0
230.0
0 0.00523 0.01046 0.01569 0.02092 0.02615
Radio en Metros

X promedio
0.035

0.03

0.025
Conversion Promedio

0.02

0.015

0.01

0.005

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18
Z en metros
 T promedio
400
390
380
Tmeperatura Promedio

370
360
350
340
330
320
310
300
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18
Z en metros

COMPARACION DEL
CASO I, II YIII
COMPARACION DEL CASO I, II YIII

Se obtuvo las siguientes tablas

CASO I CASO II CASO III

Z Xprom z xprom z xprom

0.000 0.0000 0.0000 0.000 0 0
0.015 0.0245257 0.0152 0.000 0.0254 0
0.030 0.0505842 0.0305 0.000 0.0508 0
0.046 0.0886139 0.0457 0.000 0.0762 0
0.061 0.1599124 0.0610 0.000 0.1016 0
0.076 0.3207904 0.0762 0.000 0.127 0
0.091 0.624388 0.0914 0.000 0.1524 0
0.107 0.7754533 0.1067 0.000
0.122 0.7878356 0.1219 0.000
0.137 0.788415 0.1372 0.000
0.152 0.788441 0.1524 0.000
 X vs Z
0.8

0.7

0.6

0.5
Conversion

0.4 Caso 1
Caso 2
0.3
Caso 3

0.2

0.1

0.0
-0.015 0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Longitud del reactor metros

Se obtuvo las siguientes tablas

CASO I CASO II CASO III

Z Tprom z Tprom z Tprom

0.000 400.00 0.0000 0 0 0
0.015 406.8598 0.0152 0 0.0254 0
0.030 414.1483 0.0305 0 0.0508 0
0.046 424.7851 0.0457 0 0.0762 0
0.061 444.7272 0.0610 0 0.1016 0
0.076 489.7244 0.0762 0 0.127 0
0.091 574.6401 0.0914 0 0.1524 0
0.107 616.8927 0.1067 0
0.122 620.356 0.1219 0
0.137 620.5181 0.1372 0
0.152 620.5253 0.1524 0
 X vs Z
0.8

0.7

0.6

0.5
Conversion

0.4 Caso 1
Caso 2
0.3 Caso 3

0.2

0.1

0.0
-0.015 0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Longitud del reactor metros

PUNTOS CALIENTES
PUNTOS CALIENTES

TABLAS OBTENIDAS EN POLYMATH

390ºC 400ºC 410ºC

r z r z r z
10 0.002 0 0 0 0.023
9 0.008 1 0 1 0.023
8 0.02 2 0 2 0.023
7 0.035 3 0 3 0.023
6 0.055 4 0 4 0.025
5 0.08 5 0 4 0.05
4 0.12 6 0 3 0.088
3 0.135 7 0 2 0.116
2 0.151 8 0 1 0.129
9 0 0 0.134
420ºC 10 0
r z 10 0
0 0.041 9 0
1 0.042 8 0.005
2 0.045 7 0.015
 2 0.101 6 0.029
1 0.12 5 0.047
0 0.126 4 0.074
3 0.105
430ºC 2 0.126 440ºC
r z 1 0.138 r z
0 0.056 0 0.143 0 0.068
1 0.058 1 0.079
1 0.11 1 0.096
0 0.119 0 0.11

GRAFICA DE PUNTOS CALIENTES

CONCLUSIONES
 La presión que utilizamos para el trabajo fue de 1.6 atm. Estuvimos probando con
varias presiones, y esta fue la que mejor se adecuo a las graficas dadas por el
profesor.
 Comparando los tres casos, concluimos que el caso que mejor se ajusta al trabajo es
el caso II. Del cual se obtiene una conversión de 0.798 a la presión de 1.6 atm.
 En el caso III se observo una conversión mínima (muy baja) esto se debía al igualar
el peclet axial con el peclet radial, (no teníamos datos del peclet radial de masa y
calor).
 Los valores mas altos en el caso III son los valores centrales, tal como se observa en
la grafica.

FIN…
 CASO III
MODIFICADO
CON DIFUSION AXIAL Y
RADIAL

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH

Calculated values of NLE variables

Variable Value f(x) Initial Guess
1 x01 0.0736259 6.149E-07 0
2 x02 0.1577011 6.391E-07 0
3 x03 0.2533425 -3.403E-08 0
4 x04 0.3513065 -5.805E-08 0
5 x05 0.4294447 -3.635E-06 0
6 x06 0.4663684 -4.697E-06 0
7 T01 408.209 4.188E-05 400.
8 T02 419.8046 4.35E-05 400.
9 T03 441.2436 -2.367E-06 400.
10 T04 475.2143 -4.003E-06 400.
11 T05 506.0725 -0.0002476 400.
12 T06 499.5153 -0.0003198 400.
13 x11 0.0362447 1.555E-08 0
14 x12 0.0727259 8.195E-09 0
15 x13 0.1066693 3.7E-09 0
16 x14 0.1333403 1.401E-09 0
17 x15 0.1471837 3.765E-09 0
18 x16 0.1474863 -2.762E-08 0
19 T11 409.9081 1.057E-06 400.
20 T12 419.9525 5.617E-07 400.
21 T13 429.1264 2.454E-07 400.
22 T14 436.5353 1.001E-07 400.
23 T15 435.7941 2.489E-07 400.
24 T16 413.4572 -1.906E-06 400.
25 x21 0.0150895 9.863E-09 0
26 x22 0.0253191 1.312E-08 0
27 x23 0.0306477 2.094E-08 0
28 x24 0.0331322 1.616E-08 0
29 x25 0.0344738 3.405E-09 0
30 x26 0.0351303 1.471E-10 0
31 T21 407.8283 6.716E-07 400.
32 T22 408.5118 8.976E-07 400.
33 T23 402.4555 1.428E-06 400.
34 T24 393.5392 1.103E-06 400.
35 T25 383.775 2.274E-07 400.
36 T26 371.0321 1.168E-08 400.
37 x31 0.0060563 3.242E-08 0
38 x32 0.0079257 7.98E-08 0
39 x33 0.0086074 1.466E-08 0
40 x34 0.0091252 4.258E-10 0
41 x35 0.0095016 9.255E-12 0
42 x36 0.0097058 2.187E-13 0
43 T31 398.5568 2.209E-06 400.
44 T32 386.2546 5.432E-06 400.
45 T33 370.9801 9.97E-07 400.
46 T34 356.2591 2.592E-08 400.
47 T35 342.8984 4.634E-09 400.
48 T36 330.5216 -1.519E-09 400.
49 x41 0.0014707 2.232E-06 0
50 x42 0.0017463 6.058E-08 0
51 x43 0.0019836 6.279E-11 0
52 x44 0.0021775 -1.435E-13 0
53 x45 0.0023179 1.022E-12 0
54 x46 0.0023939 -6.128E-13 0
55 T41 376.2505 0.0001521 400.
56 T42 349.3648 4.13E-06 400.
57 T43 326.983 8.268E-09 400.
58 T44 309.4037 1.234E-09 400.
59 T45 295.6876 -9.838E-10 400.
60 T46 284.7872 1.332E-09 400.
61 x51 0.000118 4.238E-08 0
62 x52 0.0002281 -4.72E-14 0
63 x53 0.000326 9.864E-14 0
64 x54 0.0004069 -1.167E-13 0
65 x55 0.0004659 4.008E-14 0
66 x56 0.0004981 3.054E-14 0
67 T51 320.3186 2.889E-06 400.
68 T52 281.4645 -5.52E-09 400.
69 T53 260.4833 -4.2E-09 400.
70 T54 247.9473 2.224E-09 400.
71 T55 239.7515 5.852E-11 400.
72 T56 233.993 1.339E-09 400.

Variable Value
1 Pmz 0.01
2 E 0.5
3 R 0.082
4 Phz 9.
5 Phr 4.4
6 dp 0.003175
7 db 1025.
8 G 1709.
9 Us 2914.393
10 dH -9.489E+04
11 Cpf 1.09
12 df 0.5864
13 Tw 197.
14 pi5 -1385.827
15 Pmr 9.6
16 pi4 0.4888889
17 pi1 960.
18 Bi 6.67
19 pi6 7.235E+07
20 pi2 -6047.244
21 dz 0.0254
22 dr 0.00523
23 Tin 673.
24 Pao 0.1105
25 Cao 0.0020023
26 P 1.6
27 ya 0.065
28 pi3 1.062E+06
29 Pbo 0.31416
30 K101 61.91454
31 K102 70.826
32 K103 89.77875
33 K104 127.1352
34 K105 169.8609
35 K106 160.0284
36 K111 63.16464
37 K112 70.94545
38 K113 78.65786
39 K114 85.32788
40 K115 84.64238
41 K116 65.8368
42 K121 61.63703
43 K122 62.13592
44 K123 57.81914
45 K124 51.87981
46 K125 45.91801
47 K126 38.9382
48 K131 55.16234
49 K132 47.37996
50 K133 38.91154
51 K134 31.89568
52 K135 26.41136
53 K136 22.01137
54 K141 41.69075
55 K142 28.966
56 K143 20.86502
57 K144 15.84317
58 K145 12.63015
59 K146 10.46477
60 K151 18.83306
61 K152 9.867191
62 K153 6.692647
63 K154 5.228571
64 K155 4.420328
65 K156 3.915641
66 K201 14.87236
67 K202 12.03401
68 K203 8.283879
69 K204 4.789504
70 K205 3.034829
71 K206 3.333624
72 K211 14.41147
73 K212 12.00211
74 K213 10.20183
75 K214 8.974493
76 K215 9.089221
77 K216 13.50112
78 K221 14.97795
79 K222 14.789
80 K223 16.56477
81 K224 19.64795
82 K225 23.81261
83 K226 30.87275
84 K231 17.83845
85 K232 22.6658
86 K233 30.90608
87 K234 42.26924
88 K235 56.89405
89 K236 75.80611
90 K241 27.72428
91 K242 49.1949
92 K243 82.4678
93 K244 127.232
94 K245 181.8075
95 K246 244.4789
96 K251 96.90825
97 K252 268.1985
98 K253 494.2702
99 K254 729.1366
100 K255 949.8571
101 K256 1149.675
102 K301 236.225
103 K302 64.87775
104 K303 6.644177
105 K304 0.2346565
106 K305 0.014495
107 K306 0.025709
108 K311 194.9381
109 K312 63.83557
110 K313 23.67893
111 K314 10.83071
112 K315 11.70366
113 K316 130.9079
114 K321 246.6463
115 K322 228.2596
116 K323 455.9817
117 K324 1292.186
118 K325 4176.448
119 K326 2.037E+04
120 K331 716.5909
121 K332 3090.28
122 K333 2.05E+04
123 K334 1.386E+05
124 K335 8.493E+05
125 K336 4.894E+06
126 K341 1.057E+04
127 K342 3.497E+05
128 K343 8.182E+06
129 K344 1.154E+08
130 K345 1.019E+09
131 K346 6.207E+09
132 K351 2.19E+07
133 K352 1.092E+10
134 K353 4.556E+11
135 K354 4.885E+12
136 K355 2.453E+13
137 K356 7.865E+13
138 Kp01 368.0263
139 Kp02 278.8054
140 Kp03 170.8751
141 Kp04 83.31468
142 Kp05 45.80652
143 Kp06 51.80783
144 Kp11 353.1462
145 Kp12 277.8371
146 Kp13 224.5206
147 Kp14 189.7895
148 Kp15 192.9767
149 Kp16 324.1911
150 Kp21 371.4556
151 Kp22 365.3241
152 Kp23 423.8803
153 Kp24 530.1936
154 Kp25 682.1725
155 Kp26 958.8266
156 Kp31 467.1136
157 Kp32 639.4263
158 Kp33 960.1839
159 Kp34 1447.547
160 Kp35 2137.049
161 Kp36 3113.302
162 Kp41 832.7102
163 Kp42 1766.141
164 Kp43 3476.802
165 Kp44 6138.577
166 Kp45 9801.704
167 Kp46 1.445E+04
168 Kp51 4295.899
169 Kp52 1.632E+04
170 Kp53 3.637E+04
171 Kp54 6.055E+04
172 Kp55 8.564E+04
173 Kp56 1.1E+05
174 Pa01 0.1023643
175 Pa02 0.093074
176 Pa03 0.0825057
177 Pa04 0.0716806
178 Pa05 0.0630464
179 Pa06 0.0589663
180 Pa11 0.106495
181 Pa12 0.1024638
182 Pa13 0.098713
183 Pa14 0.0957659
184 Pa15 0.0942362
185 Pa16 0.0942028
186 Pa21 0.1088326
187 Pa22 0.1077022
188 Pa23 0.1071134
189 Pa24 0.1068389
190 Pa25 0.1066906
191 Pa26 0.1066181
192 Pa31 0.1098308
193 Pa32 0.1096242
194 Pa33 0.1095489
195 Pa34 0.1094917
196 Pa35 0.1094501
197 Pa36 0.1094275
198 Pa41 0.1103375
199 Pa42 0.110307
200 Pa43 0.1102808
201 Pa44 0.1102594
202 Pa45 0.1102439
203 Pa46 0.1102355
204 Pa51 0.110487
205 Pa52 0.1104748
206 Pa53 0.110464
207 Pa54 0.110455
208 Pa55 0.1104485
209 Pa56 0.110445
210 Pb01 0.3100922
211 Pb02 0.305447
212 Pb03 0.3001628
213 Pb04 0.2947503
214 Pb05 0.2904332
215 Pb06 0.2883931
216 Pb11 0.3121575
217 Pb12 0.3101419
218 Pb13 0.3082665
219 Pb14 0.306793
220 Pb15 0.3060281
221 Pb16 0.3060114
222 Pb21 0.3133263
223 Pb22 0.3127611
224 Pb23 0.3124667
225 Pb24 0.3123294
226 Pb25 0.3122553
227 Pb26 0.3122191
228 Pb31 0.3138254
229 Pb32 0.3137221
230 Pb33 0.3136844
231 Pb34 0.3136558
232 Pb35 0.313635
233 Pb36 0.3136238
234 Pb41 0.3140787
235 Pb42 0.3140635
236 Pb43 0.3140504
237 Pb44 0.3140397
238 Pb45 0.3140319
239 Pb46 0.3140277
240 Pb51 0.3141535
241 Pb52 0.3141474
242 Pb53 0.314142
243 Pb54 0.3141375
244 Pb55 0.3141343
245 Pb56 0.3141325
246 Pr01 0.0081357
247 Pr02 0.017426
248 Pr03 0.0279943
249 Pr04 0.0388194
250 Pr05 0.0474536
251 Pr06 0.0515337
252 Pr11 0.004005
253 Pr12 0.0080362
254 Pr13 0.011787
255 Pr14 0.0147341
256 Pr15 0.0162638
257 Pr16 0.0162972
258 Pr21 0.0016674
259 Pr22 0.0027978
260 Pr23 0.0033866
261 Pr24 0.0036611
262 Pr25 0.0038094
263 Pr26 0.0038819
264 Pr31 0.0006692
265 Pr32 0.0008758
266 Pr33 0.0009511
267 Pr34 0.0010083
268 Pr35 0.0010499
269 Pr36 0.0010725
270 Pr41 0.0001625
271 Pr42 0.000193
272 Pr43 0.0002192
273 Pr44 0.0002406
274 Pr45 0.0002561
275 Pr46 0.0002645
276 Pr51 1.304E-05
277 Pr52 2.52E-05
278 Pr53 3.602E-05
279 Pr54 4.496E-05
280 Pr55 5.149E-05
281 Pr56 5.504E-05
282 T61 155.8116
283 T62 168.7888
284 T63 175.7966
285 T64 179.9836
286 T65 182.721
287 T66 184.6443
288 x00 0
289 x10 0
290 x20 0
291 x30 0
292 x40 0
293 x50 0
294 T00 400.
295 T10 400.
296 T20 400.
297 T30 400.
298 T40 400.
299 T50 400.

Nonlinear equations
f(x01) = 2 * (x11 - 2 * x01 + x01) / dr ^ 2 + pi1 * (x02 - 2 * x01 + x00) / dz ^ 2 + pi2 * (x01
1 - x00) / dz + pi3 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414
* (1 + K201 * Pa01 + K301 * Pr01) ^ 2) = 0
f(x02) = 2 * (x12 - 2 * x02 + x02) / dr ^ 2 + pi1 * (x03 - 2 * x02 + x01) / dz ^ 2 + pi2 * (x02
2 - x01) / dz + pi3 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414
* (1 + K202 * Pa02 + K302 * Pr02) ^ 2) = 0
f(x03) = 2 * (x13 - 2 * x03 + x03) / dr ^ 2 + pi1 * (x04 - 2 * x03 + x02) / dz ^ 2 + pi2 * (x03
3 - x02) / dz + pi3 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414
* (1 + K203 * Pa03 + K303 * Pr03) ^ 2) = 0
f(x04) = 2 * (x14 - 2 * x04 + x04) / dr ^ 2 + pi1 * (x05 - 2 * x04 + x03) / dz ^ 2 + pi2 * (x04
4 - x03) / dz + pi3 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414
* (1 + K204 * Pa04 + K304 * Pr04) ^ 2) = 0
f(x05) = 2 * (x15 - 2 * x05 + x05) / dr ^ 2 + pi1 * (x06 - 2 * x05 + x04) / dz ^ 2 + pi2 * (x05
5 - x04) / dz + pi3 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414
* (1 + K205 * Pa05 + K305 * Pr05) ^ 2) = 0
f(x06) = 2 * (x16 - 2 * x06 + x06) / dr ^ 2 + pi1 * (x06 - 2 * x06 + x05) / dz ^ 2 + pi2 * (x06
6 - x05) / dz + pi3 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414
* (1 + K206 * Pa06 + K306 * Pr06) ^ 2) = 0
f(T01) = 2 * (T11 - 2 * T01 + T01) / dr ^ 2 + pi4 * (T02 - 2 * T01 + T00) / dz ^ 2 + pi5 *
7 (T01 - T00) / dz + pi6 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) /
(22.414 * (1 + K201 * Pa01 + K301 * Pr01) ^ 2) = 0
 f(T02) = 2 * (T12 - 2 * T02 + T02) / dr ^ 2 + pi4 * (T03 - 2 * T02 + T01) / dz ^ 2 + pi5 *
8 (T02 - T01) / dz + pi6 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) /
(22.414 * (1 + K202 * Pa02 + K302 * Pr02) ^ 2) = 0
f(T03) = 2 * (T13 - 2 * T03 + T03) / dr ^ 2 + pi4 * (T04 - 2 * T03 + T02) / dz ^ 2 + pi5 *
9 (T03 - T02) / dz + pi6 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) /
(22.414 * (1 + K203 * Pa03 + K303 * Pr03) ^ 2) = 0
f(T04) = 2 * (T14 - 2 * T04 + T04) / dr ^ 2 + pi4 * (T05 - 2 * T04 + T03) / dz ^ 2 + pi5 *
10 (T04 - T03) / dz + pi6 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) /
(22.414 * (1 + K204 * Pa04 + K304 * Pr04) ^ 2) = 0
f(T05) = 2 * (T15 - 2 * T05 + T05) / dr ^ 2 + pi4 * (T06 - 2 * T05 + T04) / dz ^ 2 + pi5 *
11 (T05 - T04) / dz + pi6 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) /
(22.414 * (1 + K205 * Pa05 + K305 * Pr05) ^ 2) = 0
f(T06) = 2 * (T16 - 2 * T06 + T06) / dr ^ 2 + pi4 * (T06 - 2 * T06 + T05) / dz ^ 2 + pi5 *
12 (T06 - T05) / dz + pi6 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) /
(22.414 * (1 + K206 * Pa06 + K306 * Pr06) ^ 2) = 0
f(x11) = (x21 - 2 * x11 + x01) / dr ^ 2 + (x11 - x01) / (1 * dr ^ 2) + pi1 * (x12 - 2 * x11 +
13 x10) / dz ^ 2 + pi2 * (x11 - x10) / dz + pi3 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11
^ 0.5) * Kp11))) / (22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2) = 0
f(x12) = (x22 - 2 * x12 + x02) / dr ^ 2 + (x12 - x02) / (1 * dr ^ 2) + pi1 * (x13 - 2 * x12 +
14 x11) / dz ^ 2 + pi2 * (x12 - x11) / dz + pi3 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12
^ 0.5) * Kp12))) / (22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2) = 0
f(x13) = (x23 - 2 * x13 + x03) / dr ^ 2 + (x13 - x03) / (1 * dr ^ 2) + pi1 * (x14 - 2 * x13 +
15 x12) / dz ^ 2 + pi2 * (x13 - x12) / dz + pi3 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13
^ 0.5) * Kp13))) / (22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2) = 0
f(x14) = (x24 - 2 * x14 + x04) / dr ^ 2 + (x14 - x04) / (1 * dr ^ 2) + pi1 * (x15 - 2 * x14 +
16 x13) / dz ^ 2 + pi2 * (x14 - x13) / dz + pi3 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14
^ 0.5) * Kp14))) / (22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2) = 0
f(x15) = (x25 - 2 * x15 + x05) / dr ^ 2 + (x15 - x05) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x15 +
17 x14) / dz ^ 2 + pi2 * (x15 - x14) / dz + pi3 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15
^ 0.5) * Kp15))) / (22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2) = 0
f(x16) = (x26 - 2 * x16 + x06) / dr ^ 2 + (x16 - x06) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x16 +
18 x15) / dz ^ 2 + pi2 * (x16 - x15) / dz + pi3 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16
^ 0.5) * Kp16))) / (22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2) = 0
f(T11) = (T21 - 2 * T11 + T01) / dr ^ 2 + (T11 - T01) / (1 * dr ^ 2) + pi4 * (T12 - 2 * T11 +
19 T10) / dz ^ 2 + pi5 * (T11 - T10) / dz + pi6 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11
^ 0.5) * Kp11))) / (22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2) = 0
f(T12) = (T22 - 2 * T12 + T02) / dr ^ 2 + (T12 - T02) / (1 * dr ^ 2) + pi4 * (T13 - 2 * T12 +
20 T11) / dz ^ 2 + pi5 * (T12 - T11) / dz + pi6 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12
^ 0.5) * Kp12))) / (22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2) = 0
f(T13) = (T23 - 2 * T13 + T03) / dr ^ 2 + (T13 - T03) / (1 * dr ^ 2) + pi4 * (T14 - 2 * T13 +
21 T12) / dz ^ 2 + pi5 * (T13 - T12) / dz + pi6 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13
^ 0.5) * Kp13))) / (22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2) = 0
f(T14) = (T24 - 2 * T14 + T04) / dr ^ 2 + (T14 - T04) / (1 * dr ^ 2) + pi4 * (T15 - 2 * T14 +
22 T13) / dz ^ 2 + pi5 * (T14 - T13) / dz + pi6 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14
^ 0.5) * Kp14))) / (22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2) = 0
f(T15) = (T25 - 2 * T15 + T05) / dr ^ 2 + (T15 - T05) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T15 +
23 T14) / dz ^ 2 + pi5 * (T15 - T14) / dz + pi6 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15
^ 0.5) * Kp15))) / (22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2) = 0
 f(T16) = (T26 - 2 * T16 + T06) / dr ^ 2 + (T16 - T06) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T16 +
24 T15) / dz ^ 2 + pi5 * (T16 - T15) / dz + pi6 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16
^ 0.5) * Kp16))) / (22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2) = 0
f(x21) = (x31 - 2 * x21 + x11) / dr ^ 2 + (x21 - x11) / (2 * dr ^ 2) + pi1 * (x22 - 2 * x21 +
25 x20) / dz ^ 2 + pi2 * (x21 - x20) / dz + pi3 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21
^ 0.5) * Kp21))) / (22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2) = 0
f(x22) = (x32 - 2 * x22 + x12) / dr ^ 2 + (x22 - x12) / (2 * dr ^ 2) + pi1 * (x23 - 2 * x22 +
26 x21) / dz ^ 2 + pi2 * (x22 - x21) / dz + pi3 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22
^ 0.5) * Kp22))) / (22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2) = 0
f(x23) = (x33 - 2 * x23 + x13) / dr ^ 2 + (x23 - x13) / (2 * dr ^ 2) + pi1 * (x24 - 2 * x23 +
27 x22) / dz ^ 2 + pi2 * (x23 - x22) / dz + pi3 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23
^ 0.5) * Kp23))) / (22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2) = 0
f(x24) = (x34 - 2 * x24 + x14) / dr ^ 2 + (x24 - x14) / (2 * dr ^ 2) + pi1 * (x25 - 2 * x24 +
28 x23) / dz ^ 2 + pi2 * (x24 - x23) / dz + pi3 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24
^ 0.5) * Kp24))) / (22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2) = 0
f(x25) = (x35 - 2 * x25 + x15) / dr ^ 2 + (x25 - x15) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x25 +
29 x24) / dz ^ 2 + pi2 * (x25 - x24) / dz + pi3 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25
^ 0.5) * Kp25))) / (22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2) = 0
f(x26) = (x36 - 2 * x26 + x16) / dr ^ 2 + (x26 - x16) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x26 +
30 x25) / dz ^ 2 + pi2 * (x26 - x25) / dz + pi3 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26
^ 0.5) * Kp26))) / (22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2) = 0
f(T21) = (T31 - 2 * T21 + T11) / dr ^ 2 + (T21 - T11) / (2 * dr ^ 2) + pi4 * (T22 - 2 * T21 +
31 T20) / dz ^ 2 + pi5 * (T21 - T20) / dz + pi6 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21
^ 0.5) * Kp21))) / (22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2) = 0
f(T22) = (T32 - 2 * T22 + T12) / dr ^ 2 + (T22 - T12) / (2 * dr ^ 2) + pi4 * (T23 - 2 * T22 +
32 T21) / dz ^ 2 + pi5 * (T22 - T21) / dz + pi6 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22
^ 0.5) * Kp22))) / (22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2) = 0
f(T23) = (T33 - 2 * T23 + T13) / dr ^ 2 + (T23 - T13) / (2 * dr ^ 2) + pi4 * (T24 - 2 * T23 +
33 T22) / dz ^ 2 + pi5 * (T23 - T22) / dz + pi6 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23
^ 0.5) * Kp23))) / (22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2) = 0
f(T24) = (T34 - 2 * T24 + T14) / dr ^ 2 + (T24 - T14) / (2 * dr ^ 2) + pi4 * (T25 - 2 * T24 +
34 T23) / dz ^ 2 + pi5 * (T24 - T23) / dz + pi6 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24
^ 0.5) * Kp24))) / (22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2) = 0
f(T25) = (T35 - 2 * T25 + T15) / dr ^ 2 + (T25 - T15) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T25 +
35 T24) / dz ^ 2 + pi5 * (T25 - T24) / dz + pi6 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25
^ 0.5) * Kp25))) / (22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2) = 0
f(T26) = (T36 - 2 * T26 + T16) / dr ^ 2 + (T26 - T16) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T26 +
36 T25) / dz ^ 2 + pi5 * (T26 - T25) / dz + pi6 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26
^ 0.5) * Kp26))) / (22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2) = 0
f(x31) = (x41 - 2 * x31 + x21) / dr ^ 2 + (x31 - x21) / (3 * dr ^ 2) + pi1 * (x32 - 2 * x31 +
37 x30) / dz ^ 2 + pi2 * (x31 - x30) / dz + pi3 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31
^ 0.5) * Kp31))) / (22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2) = 0
f(x32) = (x42 - 2 * x32 + x22) / dr ^ 2 + (x32 - x22) / (3 * dr ^ 2) + pi1 * (x33 - 2 * x32 +
38 x31) / dz ^ 2 + pi2 * (x32 - x31) / dz + pi3 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32
^ 0.5) * Kp32))) / (22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2) = 0
f(x33) = (x43 - 2 * x33 + x23) / dr ^ 2 + (x33 - x23) / (3 * dr ^ 2) + pi1 * (x34 - 2 * x33 +
39 x32) / dz ^ 2 + pi2 * (x33 - x32) / dz + pi3 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33
^ 0.5) * Kp33))) / (22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2) = 0
 f(x34) = (x44 - 2 * x34 + x24) / dr ^ 2 + (x34 - x24) / (3 * dr ^ 2) + pi1 * (x35 - 2 * x34 +
40 x33) / dz ^ 2 + pi2 * (x34 - x33) / dz + pi3 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34
^ 0.5) * Kp34))) / (22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2) = 0
f(x35) = (x45 - 2 * x35 + x25) / dr ^ 2 + (x35 - x25) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x35 +
41 x34) / dz ^ 2 + pi2 * (x35 - x34) / dz + pi3 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35
^ 0.5) * Kp35))) / (22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2) = 0
f(x36) = (x46 - 2 * x36 + x26) / dr ^ 2 + (x36 - x26) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x36 +
42 x35) / dz ^ 2 + pi2 * (x36 - x35) / dz + pi3 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36
^ 0.5) * Kp36))) / (22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2) = 0
f(T31) = (T41 - 2 * T31 + T21) / dr ^ 2 + (T31 - T21) / (3 * dr ^ 2) + pi4 * (T32 - 2 * T31 +
43 T30) / dz ^ 2 + pi5 * (T31 - T30) / dz + pi6 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31
^ 0.5) * Kp31))) / (22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2) = 0
f(T32) = (T42 - 2 * T32 + T22) / dr ^ 2 + (T32 - T22) / (3 * dr ^ 2) + pi4 * (T33 - 2 * T32 +
44 T31) / dz ^ 2 + pi5 * (T32 - T31) / dz + pi6 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32
^ 0.5) * Kp32))) / (22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2) = 0
f(T33) = (T43 - 2 * T33 + T23) / dr ^ 2 + (T33 - T23) / (3 * dr ^ 2) + pi4 * (T34 - 2 * T33 +
45 T32) / dz ^ 2 + pi5 * (T33 - T32) / dz + pi6 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33
^ 0.5) * Kp33))) / (22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2) = 0
f(T34) = (T44 - 2 * T34 + T24) / dr ^ 2 + (T34 - T24) / (3 * dr ^ 2) + pi4 * (T35 - 2 * T34 +
46 T33) / dz ^ 2 + pi5 * (T34 - T33) / dz + pi6 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34
^ 0.5) * Kp34))) / (22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2) = 0
f(T35) = (T45 - 2 * T35 + T25) / dr ^ 2 + (T35 - T25) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T35 +
47 T34) / dz ^ 2 + pi5 * (T35 - T34) / dz + pi6 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35
^ 0.5) * Kp35))) / (22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2) = 0
f(T36) = (T46 - 2 * T36 + T26) / dr ^ 2 + (T36 - T26) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T36 +
48 T35) / dz ^ 2 + pi5 * (T36 - T35) / dz + pi6 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36
^ 0.5) * Kp36))) / (22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2) = 0
f(x41) = (x51 - 2 * x41 + x31) / dr ^ 2 + (x41 - x31) / (4 * dr ^ 2) + pi1 * (x42 - 2 * x41 +
49 x40) / dz ^ 2 + pi2 * (x41 - x40) / dz + pi3 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41
^ 0.5) * Kp41))) / (22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2) = 0
f(x42) = (x52 - 2 * x42 + x32) / dr ^ 2 + (x42 - x32) / (4 * dr ^ 2) + pi1 * (x43 - 2 * x42 +
50 x41) / dz ^ 2 + pi2 * (x42 - x41) / dz + pi3 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42
^ 0.5) * Kp42))) / (22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2) = 0
f(x43) = (x53 - 2 * x43 + x33) / dr ^ 2 + (x43 - x33) / (4 * dr ^ 2) + pi1 * (x44 - 2 * x43 +
51 x42) / dz ^ 2 + pi2 * (x43 - x42) / dz + pi3 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43
^ 0.5) * Kp43))) / (22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2) = 0
f(x44) = (x54 - 2 * x44 + x34) / dr ^ 2 + (x44 - x34) / (4 * dr ^ 2) + pi1 * (x45 - 2 * x44 +
52 x43) / dz ^ 2 + pi2 * (x44 - x43) / dz + pi3 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44
^ 0.5) * Kp44))) / (22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2) = 0
f(x45) = (x55 - 2 * x45 + x35) / dr ^ 2 + (x45 - x35) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x45 +
53 x44) / dz ^ 2 + pi2 * (x45 - x44) / dz + pi3 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45
^ 0.5) * Kp45))) / (22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2) = 0
f(x46) = (x56 - 2 * x46 + x36) / dr ^ 2 + (x46 - x36) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x46 +
54 x45) / dz ^ 2 + pi2 * (x46 - x45) / dz + pi3 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46
^ 0.5) * Kp46))) / (22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2) = 0
f(T41) = (T51 - 2 * T41 + T31) / dr ^ 2 + (T41 - T31) / (4 * dr ^ 2) + pi4 * (T42 - 2 * T41 +
55 T40) / dz ^ 2 + pi5 * (T41 - T40) / dz + pi6 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41
^ 0.5) * Kp41))) / (22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2) = 0
 f(T42) = (T52 - 2 * T42 + T32) / dr ^ 2 + (T42 - T32) / (4 * dr ^ 2) + pi4 * (T43 - 2 * T42 +
56 T41) / dz ^ 2 + pi5 * (T42 - T41) / dz + pi6 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42
^ 0.5) * Kp42))) / (22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2) = 0
f(T43) = (T53 - 2 * T43 + T33) / dr ^ 2 + (T43 - T33) / (4 * dr ^ 2) + pi4 * (T44 - 2 * T43 +
57 T42) / dz ^ 2 + pi5 * (T43 - T42) / dz + pi6 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43
^ 0.5) * Kp43))) / (22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2) = 0
f(T44) = (T54 - 2 * T44 + T34) / dr ^ 2 + (T44 - T34) / (4 * dr ^ 2) + pi4 * (T45 - 2 * T44 +
58 T43) / dz ^ 2 + pi5 * (T44 - T43) / dz + pi6 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44
^ 0.5) * Kp44))) / (22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2) = 0
f(T45) = (T55 - 2 * T45 + T35) / dr ^ 2 + (T45 - T35) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T45 +
59 T44) / dz ^ 2 + pi5 * (T45 - T44) / dz + pi6 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45
^ 0.5) * Kp45))) / (22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2) = 0
f(T46) = (T56 - 2 * T46 + T36) / dr ^ 2 + (T46 - T36) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T46 +
60 T45) / dz ^ 2 + pi5 * (T46 - T45) / dz + pi6 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46
^ 0.5) * Kp46))) / (22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2) = 0
f(x51) = (x51 - 2 * x51 + x41) / dr ^ 2 + (x51 - x41) / (5 * dr ^ 2) + pi1 * (x52 - 2 * x51 +
61 x50) / dz ^ 2 + pi2 * (x51 - x50) / dz + pi3 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51
^ 0.5) * Kp51))) / (22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2) = 0
f(x52) = (x52 - 2 * x52 + x42) / dr ^ 2 + (x52 - x42) / (5 * dr ^ 2) + pi1 * (x53 - 2 * x52 +
62 x51) / dz ^ 2 + pi2 * (x52 - x51) / dz + pi3 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52
^ 0.5) * Kp52))) / (22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2) = 0
f(x53) = (x53 - 2 * x53 + x43) / dr ^ 2 + (x53 - x43) / (5 * dr ^ 2) + pi1 * (x54 - 2 * x53 +
63 x52) / dz ^ 2 + pi2 * (x53 - x52) / dz + pi3 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53
^ 0.5) * Kp53))) / (22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2) = 0
f(x54) = (x54 - 2 * x54 + x44) / dr ^ 2 + (x54 - x44) / (5 * dr ^ 2) + pi1 * (x55 - 2 * x54 +
64 x53) / dz ^ 2 + pi2 * (x54 - x53) / dz + pi3 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54
^ 0.5) * Kp54))) / (22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2) = 0
f(x55) = (x55 - 2 * x55 + x45) / dr ^ 2 + (x55 - x45) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x55 +
65 x54) / dz ^ 2 + pi2 * (x55 - x54) / dz + pi3 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55
^ 0.5) * Kp55))) / (22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2) = 0
f(x56) = (x56 - 2 * x56 + x46) / dr ^ 2 + (x56 - x46) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x56 +
66 x55) / dz ^ 2 + pi2 * (x56 - x55) / dz + pi3 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56
^ 0.5) * Kp56))) / (22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2) = 0
f(T51) = (T61 - 2 * T51 + T41) / dr ^ 2 + (T51 - T41) / (5 * dr ^ 2) + pi4 * (T52 - 2 * T51 +
67 T50) / dz ^ 2 + pi5 * (T51 - T50) / dz + pi6 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51
^ 0.5) * Kp51))) / (22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2) = 0
f(T52) = (T62 - 2 * T52 + T42) / dr ^ 2 + (T52 - T42) / (5 * dr ^ 2) + pi4 * (T53 - 2 * T52 +
68 T51) / dz ^ 2 + pi5 * (T52 - T51) / dz + pi6 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52
^ 0.5) * Kp52))) / (22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2) = 0
f(T53) = (T63 - 2 * T53 + T43) / dr ^ 2 + (T53 - T43) / (5 * dr ^ 2) + pi4 * (T54 - 2 * T53 +
69 T52) / dz ^ 2 + pi5 * (T53 - T52) / dz + pi6 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53
^ 0.5) * Kp53))) / (22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2) = 0
f(T54) = (T64 - 2 * T54 + T44) / dr ^ 2 + (T54 - T44) / (5 * dr ^ 2) + pi4 * (T55 - 2 * T54 +
70 T53) / dz ^ 2 + pi5 * (T54 - T53) / dz + pi6 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54
^ 0.5) * Kp54))) / (22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2) = 0
f(T55) = (T65 - 2 * T55 + T45) / dr ^ 2 + (T55 - T45) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T55 +
71 T54) / dz ^ 2 + pi5 * (T55 - T54) / dz + pi6 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55
^ 0.5) * Kp55))) / (22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2) = 0
 f(T56) = (T66 - 2 * T56 + T46) / dr ^ 2 + (T56 - T46) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T56 +
72 T55) / dz ^ 2 + pi5 * (T56 - T55) / dz + pi6 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56
^ 0.5) * Kp56))) / (22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2) = 0

Explicit equations
1 Pmz = 0.01
Peclet de Masa en Direccion Axial

2 E = 0.5
Porosidad del lecho

3 R = 0.082
4 Phz = 9
Peclet de Calor en Direccion Axial

5 Phr = 4.4
Peclet de calor en direccion radial

6 dp = 0.003175
7 db = 1025
Densidad del lecho

8 G = 1709
Flujo masico

9 Us = 2914.393
Velocidad

10 dH = -94886
Entalpia

11 Cpf = 1.09
Capacidad Calorifica del Fluido

12 df = 0.5864
Densidad del Fluido

13 Tw = 197
Temperatura de la pared

14 pi5 = -Us * df * Cpf / (dp * G * Cpf / Phr)

15 Pmr = 9.6
Peclet de masa en direccion radial

16 pi4 = (dp * G * Cpf / Phz) / (dp * G * Cpf / Phr)

17 pi1 = ( Us * dp / Pmz) / (Us * dp / Pmr)
18 Bi = 6.67
Numero de Biot

19 pi6 = db * (-dH) / (dp * G * Cpf / Phr)

20 pi2 = -Us/(E * (Us * dp / Pmr))
21 dz = (0.1524)/6
22 dr = 0.02615 / 5
23 Tin = 400 +273
24 Pao = 1.7 * 0.065
25 Cao = Pao / (R * Tin )
26 P = 1.6
27 ya = 0.065
28 pi3 = db / (Cao * E * (Us * dp / Pmr))
29 Pbo = (1 - ya) * P * 0.21
30 K101 = exp(12.16 - 5473 / (T01 + 273))
31 K102 = exp(12.16 - 5473 / (T02 + 273))
32 K103 = exp(12.16 - 5473 / (T03 + 273))
33 K104 = exp(12.16 - 5473 / (T04 + 273))
34 K105 = exp(12.16 - 5473 / (T05 + 273))
35 K106 = exp(12.16 - 5473 / (T06 + 273))
36 K111 = exp(12.16 - 5473 / (T11 + 273))
37 K112 = exp(12.16 - 5473 / (T12 + 273))
38 K113 = exp(12.16 - 5473 / (T13 + 273))
39 K114 = exp(12.16 - 5473 / (T14 + 273))
40 K115 = exp(12.16 - 5473 / (T15 + 273))
41 K116 = exp(12.16 - 5473 / (T16 + 273))
42 K121 = exp(12.16 - 5473 / (T21 + 273))
43 K122 = exp(12.16 - 5473 / (T22 + 273))
44 K123 = exp(12.16 - 5473 / (T23 + 273))
45 K124 = exp(12.16 - 5473 / (T24 + 273))
46 K125 = exp(12.16 - 5473 / (T25 + 273))
47 K126 = exp(12.16 - 5473 / (T26 + 273))
48 K131 = exp(12.16 - 5473 / (T31 + 273))
49 K132 = exp(12.16 - 5473 / (T32 + 273))
50 K133 = exp(12.16 - 5473 / (T33 + 273))
51 K134 = exp(12.16 - 5473 / (T34 + 273))
52 K135 = exp(12.16 - 5473 / (T35 + 273))
53 K136 = exp(12.16 - 5473 / (T36 + 273))
54 K141 = exp(12.16 - 5473 / (T41 + 273))
55 K142 = exp(12.16 - 5473 / (T42 + 273))
56 K143 = exp(12.16 - 5473 / (T43 + 273))
57 K144 = exp(12.16 - 5473 / (T44 + 273))
58 K145 = exp(12.16 - 5473 / (T45 + 273))
59 K146 = exp(12.16 - 5473 / (T46 + 273))
60 K151 = exp(12.16 - 5473 / (T51 + 273))
61 K152 = exp(12.16 - 5473 / (T52 + 273))
62 K153 = exp(12.16 - 5473 / (T53 + 273))
63 K154 = exp(12.16 - 5473 / (T54 + 273))
64 K155 = exp(12.16 - 5473 / (T55 + 273))
65 K156 = exp(12.16 - 5473 / (T56 + 273))
66 K201 = exp(-9.953 + 8619 / (T01 + 273))
67 K202 = exp(-9.953 + 8619 / (T02 + 273))
68 K203 = exp(-9.953 + 8619 / (T03 + 273))
69 K204 = exp(-9.953 + 8619 / (T04 + 273))
70 K205 = exp(-9.953 + 8619 / (T05 + 273))
71 K206 = exp(-9.953 + 8619 / (T06 + 273))
72 K211 = exp(-9.953 + 8619 / (T11 + 273))
73 K212 = exp(-9.953 + 8619 / (T12 + 273))
74 K213 = exp(-9.953 + 8619 / (T13 + 273))
75 K214 = exp(-9.953 + 8619 / (T14 + 273))
76 K215 = exp(-9.953 + 8619 / (T15 + 273))
77 K216 = exp(-9.953 + 8619 / (T16 + 273))
78 K221 = exp(-9.953 + 8619 / (T21 + 273))
79 K222 = exp(-9.953 + 8619 / (T22 + 273))
80 K223 = exp(-9.953 + 8619 / (T23 + 273))
81 K224 = exp(-9.953 + 8619 / (T24 + 273))
82 K225 = exp(-9.953 + 8619 / (T25 + 273))
83 K226 = exp(-9.953 + 8619 / (T26 + 273))
84 K231 = exp(-9.953 + 8619 / (T31 + 273))
85 K232 = exp(-9.953 + 8619 / (T32 + 273))
86 K233 = exp(-9.953 + 8619 / (T33 + 273))
87 K234 = exp(-9.953 + 8619 / (T34 + 273))
88 K235 = exp(-9.953 + 8619 / (T35 + 273))
89 K236 = exp(-9.953 + 8619 / (T36 + 273))
90 K241 = exp(-9.953 + 8619 / (T41 + 273))
91 K242 = exp(-9.953 + 8619 / (T42 + 273))
92 K243 = exp(-9.953 + 8619 / (T43 + 273))
93 K244 = exp(-9.953 + 8619 / (T44 + 273))
94 K245 = exp(-9.953 + 8619 / (T45 + 273))
95 K246 = exp(-9.953 + 8619 / (T46 + 273))
96 K251 = exp(-9.953 + 8619 / (T51 + 273))
97 K252 = exp(-9.953 + 8619 / (T52 + 273))
98 K253 = exp(-9.953 + 8619 / (T53 + 273))
99 K254 = exp(-9.953 + 8619 / (T54 + 273))
100 K255 = exp(-9.953 + 8619 / (T55 + 273))
101 K256 = exp(-9.953 + 8619 / (T56 + 273))
102 K301 = exp(-71.745 + 52596 / (T01 + 273))
103 K302 = exp(-71.745 + 52596 / (T02 + 273))
104 K303 = exp(-71.745 + 52596 / (T03 + 273))
105 K304 = exp(-71.745 + 52596 / (T04 + 273))
106 K305 = exp(-71.745 + 52596 / (T05 + 273))
107 K306 = exp(-71.745 + 52596 / (T06 + 273))
108 K311 = exp(-71.745 + 52596 / (T11 + 273))
109 K312 = exp(-71.745 + 52596 / (T12 + 273))
110 K313 = exp(-71.745 + 52596 / (T13 + 273))
111 K314 = exp(-71.745 + 52596 / (T14 + 273))
112 K315 = exp(-71.745 + 52596 / (T15 + 273))
113 K316 = exp(-71.745 + 52596 / (T16 + 273))
114 K321 = exp(-71.745 + 52596 / (T21 + 273))
115 K322 = exp(-71.745 + 52596 / (T22 + 273))
116 K323 = exp(-71.745 + 52596 / (T23 + 273))
117 K324 = exp(-71.745 + 52596 / (T24 + 273))
118 K325 = exp(-71.745 + 52596 / (T25 + 273))
119 K326 = exp(-71.745 + 52596 / (T26 + 273))
120 K331 = exp(-71.745 + 52596 / (T31 + 273))
121 K332 = exp(-71.745 + 52596 / (T32 + 273))
122 K333 = exp(-71.745 + 52596 / (T33 + 273))
123 K334 = exp(-71.745 + 52596 / (T34 + 273))
124 K335 = exp(-71.745 + 52596 / (T35 + 273))
125 K336 = exp(-71.745 + 52596 / (T36 + 273))
126 K341 = exp(-71.745 + 52596 / (T41 + 273))
127 K342 = exp(-71.745 + 52596 / (T42 + 273))
128 K343 = exp(-71.745 + 52596 / (T43 + 273))
129 K344 = exp(-71.745 + 52596 / (T44 + 273))
130 K345 = exp(-71.745 + 52596 / (T45 + 273))
131 K346 = exp(-71.745 + 52596 / (T46 + 273))
132 K351 = exp(-71.745 + 52596 / (T51 + 273))
133 K352 = exp(-71.745 + 52596 / (T52 + 273))
134 K353 = exp(-71.745 + 52596 / (T53 + 273))
135 K354 = exp(-71.745 + 52596 / (T54 + 273))
136 K355 = exp(-71.745 + 52596 / (T55 + 273))
137 K356 = exp(-71.745 + 52596 / (T56 + 273))
138 Kp01 = exp(11300 / (T01 + 273) - 10.68)
139 Kp02 = exp(11300 / (T02 + 273) - 10.68)
140 Kp03 = exp(11300 / (T03 + 273) - 10.68)
141 Kp04 = exp(11300 / (T04 + 273) - 10.68)
142 Kp05 = exp(11300 / (T05 + 273) - 10.68)
143 Kp06 = exp(11300 / (T06 + 273) - 10.68)
144 Kp11 = exp(11300 / (T11 + 273) - 10.68)
145 Kp12 = exp(11300 / (T12 + 273) - 10.68)
146 Kp13 = exp(11300 / (T13 + 273) - 10.68)
147 Kp14 = exp(11300 / (T14 + 273) - 10.68)
148 Kp15 = exp(11300 / (T15 + 273) - 10.68)
149 Kp16 = exp(11300 / (T16 + 273) - 10.68)
150 Kp21 = exp(11300 / (T21 + 273) - 10.68)
151 Kp22 = exp(11300 / (T22 + 273) - 10.68)
152 Kp23 = exp(11300 / (T23 + 273) - 10.68)
153 Kp24 = exp(11300 / (T24 + 273) - 10.68)
154 Kp25 = exp(11300 / (T25 + 273) - 10.68)
155 Kp26 = exp(11300 / (T26 + 273) - 10.68)
156 Kp31 = exp(11300 / (T31 + 273) - 10.68)
157 Kp32 = exp(11300 / (T32 + 273) - 10.68)
158 Kp33 = exp(11300 / (T33 + 273) - 10.68)
159 Kp34 = exp(11300 / (T34 + 273) - 10.68)
160 Kp35 = exp(11300 / (T35 + 273) - 10.68)
161 Kp36 = exp(11300 / (T36 + 273) - 10.68)
162 Kp41 = exp(11300 / (T41 + 273) - 10.68)
163 Kp42 = exp(11300 / (T42 + 273) - 10.68)
164 Kp43 = exp(11300 / (T43 + 273) - 10.68)
165 Kp44 = exp(11300 / (T44 + 273) - 10.68)
166 Kp45 = exp(11300 / (T45 + 273) - 10.68)
167 Kp46 = exp(11300 / (T46 + 273) - 10.68)
168 Kp51 = exp(11300 / (T51 + 273) - 10.68)
169 Kp52 = exp(11300 / (T52 + 273) - 10.68)
170 Kp53 = exp(11300 / (T53 + 273) - 10.68)
171 Kp54 = exp(11300 / (T54 + 273) - 10.68)
172 Kp55 = exp(11300 / (T55 + 273) - 10.68)
173 Kp56 = exp(11300 / (T56 + 273) - 10.68)
174 Pa01 = Pao * (1 - x01)
175 Pa02 = Pao * (1 - x02)
176 Pa03 = Pao * (1 - x03)
177 Pa04 = Pao * (1 - x04)
178 Pa05 = Pao * (1 - x05)
179 Pa06 = Pao * (1 - x06)
180 Pa11 = Pao * (1 - x11)
181 Pa12 = Pao * (1 - x12)
182 Pa13 = Pao * (1 - x13)
183 Pa14 = Pao * (1 - x14)
184 Pa15 = Pao * (1 - x15)
185 Pa16 = Pao * (1 - x16)
186 Pa21 = Pao * (1 - x21)
187 Pa22 = Pao * (1 - x22)
188 Pa23 = Pao * (1 - x23)
189 Pa24 = Pao * (1 - x24)
190 Pa25 = Pao * (1 - x25)
191 Pa26 = Pao * (1 - x26)
192 Pa31 = Pao * (1 - x31)
193 Pa32 = Pao * (1 - x32)
194 Pa33 = Pao * (1 - x33)
195 Pa34 = Pao * (1 - x34)
196 Pa35 = Pao * (1 - x35)
197 Pa36 = Pao * (1 - x36)
198 Pa41 = Pao * (1 - x41)
199 Pa42 = Pao * (1 - x42)
200 Pa43 = Pao * (1 - x43)
201 Pa44 = Pao * (1 - x44)
202 Pa45 = Pao * (1 - x45)
203 Pa46 = Pao * (1 - x46)
204 Pa51 = Pao * (1 - x51)
205 Pa52 = Pao * (1 - x52)
206 Pa53 = Pao * (1 - x53)
207 Pa54 = Pao * (1 - x54)
208 Pa55 = Pao * (1 - x55)
209 Pa56 = Pao * (1 - x56)
210 Pb01 = Pbo - 0.5 * Pao * x01
211 Pb02 = Pbo - 0.5 * Pao * x02
212 Pb03 = Pbo - 0.5 * Pao * x03
213 Pb04 = Pbo - 0.5 * Pao * x04
214 Pb05 = Pbo - 0.5 * Pao * x05
215 Pb06 = Pbo - 0.5 * Pao * x06
216 Pb11 = Pbo - 0.5 * Pao * x11
217 Pb12 = Pbo - 0.5 * Pao * x12
218 Pb13 = Pbo - 0.5 * Pao * x13
219 Pb14 = Pbo - 0.5 * Pao * x14
220 Pb15 = Pbo - 0.5 * Pao * x15
221 Pb16 = Pbo - 0.5 * Pao * x16
222 Pb21 = Pbo - 0.5 * Pao * x21
223 Pb22 = Pbo - 0.5 * Pao * x22
224 Pb23 = Pbo - 0.5 * Pao * x23
225 Pb24 = Pbo - 0.5 * Pao * x24
226 Pb25 = Pbo - 0.5 * Pao * x25
227 Pb26 = Pbo - 0.5 * Pao * x26
228 Pb31 = Pbo - 0.5 * Pao * x31
229 Pb32 = Pbo - 0.5 * Pao * x32
230 Pb33 = Pbo - 0.5 * Pao * x33
231 Pb34 = Pbo - 0.5 * Pao * x34
232 Pb35 = Pbo - 0.5 * Pao * x35
233 Pb36 = Pbo - 0.5 * Pao * x36
234 Pb41 = Pbo - 0.5 * Pao * x41
235 Pb42 = Pbo - 0.5 * Pao * x42
236 Pb43 = Pbo - 0.5 * Pao * x43
237 Pb44 = Pbo - 0.5 * Pao * x44
238 Pb45 = Pbo - 0.5 * Pao * x45
239 Pb46 = Pbo - 0.5 * Pao * x46
240 Pb51 = Pbo - 0.5 * Pao * x51
241 Pb52 = Pbo - 0.5 * Pao * x52
242 Pb53 = Pbo - 0.5 * Pao * x53
243 Pb54 = Pbo - 0.5 * Pao * x54
244 Pb55 = Pbo - 0.5 * Pao * x55
245 Pb56 = Pbo - 0.5 * Pao * x56
246 Pr01 = Pao * x01
247 Pr02 = Pao * x02
248 Pr03 = Pao * x03
249 Pr04 = Pao * x04
250 Pr05 = Pao * x05
251 Pr06 = Pao * x06
252 Pr11 = Pao * x11
253 Pr12 = Pao * x12
254 Pr13 = Pao * x13
255 Pr14 = Pao * x14
256 Pr15 = Pao * x15
257 Pr16 = Pao * x16
258 Pr21 = Pao * x21
259 Pr22 = Pao * x22
260 Pr23 = Pao * x23
261 Pr24 = Pao * x24
262 Pr25 = Pao * x25
263 Pr26 = Pao * x26
264 Pr31 = Pao * x31
265 Pr32 = Pao * x32
266 Pr33 = Pao * x33
267 Pr34 = Pao * x34
268 Pr35 = Pao * x35
269 Pr36 = Pao * x36
270 Pr41 = Pao * x41
271 Pr42 = Pao * x42
272 Pr43 = Pao * x43
273 Pr44 = Pao * x44
274 Pr45 = Pao * x45
275 Pr46 = Pao * x46
276 Pr51 = Pao * x51
277 Pr52 = Pao * x52
278 Pr53 = Pao * x53
279 Pr54 = Pao * x54
280 Pr55 = Pao * x55
281 Pr56 = Pao * x56
282 T61 = T51 - Bi*(T51 - Tw)/5
283 T62 = T52 - Bi*(T52 - Tw)/5
284 T63 = T53 - Bi*(T53 - Tw)/5
285 T64 = T54 - Bi*(T54 - Tw)/5
286 T65 = T55 - Bi*(T55 - Tw)/5
287 T66 = T56 - Bi*(T56 - Tw)/5
288 x00 = 0
289 x10 = 0
290 x20 = 0
291 x30 = 0
292 x40 = 0
293 x50 = 0
294 T00 = 400
295 T10 = 400
296 T20 = 400
297 T30 = 400
298 T40 = 400
299 T50 = 400

Con las tablas obtenidas por polymath procedemos a graficar

DATOS OBTENIDOS EN POLYMATH

ro r1 r2 r3 r4 r5
Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615
z x0 x1 x2 x3 x4 x5 xprom
0 0 0 0 0 0 0 0
0.0254 0.0736259 0.0362447 0.0150895 0.0060563 0.0014707 0.000118 0.02210085
0.0508 0.1577011 0.0727259 0.0253191 0.0079257 0.0017463 0.0002281 0.04427437
0.0762 0.2533425 0.1066693 0.0306477 0.0086074 0.0019836 0.000326 0.06692942
0.1016 0.3513065 0.1333403 0.0331322 0.0091252 0.0021775 0.0004069 0.0882481
0.127 0.4294447 0.1471837 0.0344738 0.0095016 0.0023179 0.0004659 0.10389793
0.1524 0.4663684 0.1474863 0.0351303 0.0097058 0.0023939 0.0004981 0.1102638

ro r1 r2 r3 r4 r5
Radio 0 0.00523 0.01046 0.01569 0.02092 0.02615
z T0 T1 T2 T3 T4 T5 Tprom
0 400 400 400 400 400 400 400
0.0254 408.209 409.9081 407.8283 398.5568 376.2505 320.3186 386.845217

0.0508 419.8046 419.9525 408.5118 386.2546 349.3648 281.4645 377.5588

0.0762 441.2436 429.1264 402.4555 370.9801 326.983 260.4833 371.87865

0.1016 475.2143 436.5353 393.5392 356.2591 309.4037 247.9473 369.816483

0.127 506.0725 435.7941 383.775 342.8984 295.6876 239.7515 367.32985

0.1524 499.5153 413.4572 371.0321 330.5216 284.7872 233.993 355.551067

 0.50
X vs Z
0.45
0.40
0.35 T0
Conversion

0.30
T1
0.25
T2
0.20
T3
0.15
0.10 T4

0.05 T5
0.00
0 0.015240.030480.045720.060960.07620.091440.106680.121920.137160.1524
Z en metros

T vs Z
570.0

520.0

470.0
T0
Temperatura

420.0
T1
T2
370.0
T3
320.0 T4
T5
270.0

220.0
0 0.015240.030480.045720.06096 0.0762 0.091440.106680.121920.13716 0.1524
Z en metros
 Perfil de conversion
0.50
0.45
0.40
0.35 0
0.0254
Conversion

0.30
0.25 0.0508
0.20 0.0762
0.15 0.1016
0.10 0.127
0.05 0.1524
0.00
0 0.00523 0.01046 0.01569 0.02092 0.02615
Radio en Metros

Perfil de Temperatura
530.0
510.0
490.0
470.0
450.0
430.0 0
Temperatura

410.0 0.0254
390.0
0.0508
370.0
350.0 0.0762
330.0 0.1016
310.0
0.127
290.0
270.0 0.1524
250.0
230.0
0 0.00523 0.01046 0.01569 0.02092 0.02615
Radio en Metros
 X promedio
0.12

0.1
Conversion Promedio

0.08

0.06

0.04

0.02

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18
Z en metros

T promedio
400

390

380

370
Tmeperatura Promedio

360

350

340

330

320

310

300
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18
Z en metros

HALLANDO EL PESO DEL CATALIZADOR

W  V    D..........(1)
 
V Z d2
4

Donde:

 = 0.5 (porosidad)
D = 800Kg/m3 (densidad del catalizador)
Z= 0.1524m (longitud del catalizador)
d = 0.0523m (diámetro del catalizador)
Reemplazando datos en (1)

W  0.1524  0.0523 2 * 0.5 * 800
4

W  0.1309 Kg