Documentos de Académico
Documentos de Profesional
Documentos de Cultura
Ecuaciones:1
Lee-Kesler:
Ec.1
Donde:
Y: Propiedad requerida.
: Factor acéntrico.
Propiedades Reducidas-Critícas
Ec.2
Donde:
Y: Propiedad requerida.
: Propiedad reducida.
: Propiedad Crítica.
1
Smith Van Ness. Capítulo 11
Corrección virial para gases reales
Ec.3
Donde:
P: presión
T: Temperatura
Ec.5
Donde:
: Fracción molar de i
Volumen molar de i
Entalpía de un componente a partir del estado de referencia
Ec.5
Donde:
Entalpía de referencia
Temperatura de referencia
T: Temperatura
Ec.5
Donde:
: Fracción molar de i
Entalpía molar de i
Entalpía de una solución ideal
Ec.5
Donde:
: Fracción molar de i
T: Temperatura
1.1. Vm =f(Xa,T)
50
40
Vm (L/mol)
30
20
10
0 T: 450K
0 0.1
0.2 0.3 T: 300K
0.4 0.5
0.6 0.7 T: 160K
0.8 0.9
1
Xa
50
45
40
T: 160K
35
T: 200K
30 T: 250K
Vm (L/mol)
25 T: 300K
T: 350K
20
T: 400K
15
T: 450K
10 T: 500K
5 T: 550K
0
0 0.2 0.4 0.6 0.8 1 1.2
Xa
1.2. Vm, =f(Xa)
30
25
20
Vm (L/mol)
15
Va
10 Vb
Vm
5
0
0 0.2 0.4 0.6 0.8 1 1.2
Xa
1.3. Hm =f(Xa,T)
25000000
20000000
15000000
Hm (J/mol)
10000000
5000000 T: 550K
T: 450K
0 T: 350K
0 0.1 0.2 T: 250K
-5000000 0.3 0.4 0.5 0.6 0.7 0.8 T: 160K
0.9 1
Xa
30000000
25000000 T: 160K
T: 200K
20000000
T: 250K
Hm (J/mol)
15000000 T: 300K
T: 350K
10000000
T: 400K
5000000 T: 450K
T: 500K
0
0 0.2 0.4 0.6 0.8 1 1.2 T: 550K
-5000000
Xa
1.4. Hm, =f(Xa)
250
200
Hm (KJ/mol)
150
Ha
100 Hb
Hm
50
0
0 0.2 0.4 0.6 0.8 1 1.2
Xa
1.5. Gm =f(Xa,T)
250000
200000
Gm (J,mol)
150000
100000
50000
0
0 0.1 T: 400 K
0.2 0.3 0.4
0.5 0.6 T: 298.15 K
0.7 0.8
0.9 1
Xa
250000
200000
150000
Gm (J,mol)
T: 298.15 K
T: 350 K
100000
T: 400 K
T: 500 K
50000
0
0 0.2 0.4 0.6 0.8 1 1.2
Xa
ANEXOS
1.6. Vm =f(Xa,T)
T: 298.15 K P: 1atm
Xa Xb Va Vb Vm
0 1 0 24.3005285 24.3005285
0.1 0.9 2.40675759 21.8704757 24.2772332
0.2 0.8 4.81351518 19.4404228 24.253938
0.3 0.7 7.22027277 17.01037 24.2306427
0.4 0.6 9.62703036 14.5803171 24.2073475
0.5 0.5 12.033788 12.1502643 24.1840522
0.6 0.4 14.4405455 9.7202114 24.1607569
0.7 0.3 16.8473031 7.29015855 24.1374617
0.8 0.2 19.2540607 4.8601057 24.1141664
0.9 0.1 21.6608183 2.43005285 24.0908712
1 0 24.0675759 0 24.0675759
1.8. Hm =f(Xa,T)
T: 160K P: 1atm
Xa Xb Hm mezcla Ha Hb
0 1 2922404.205 7419069.13 2922404.2
0.1 0.9 3372070.697 7419069.13 2922404.2
0.2 0.8 3821737.189 7419069.13 2922404.2
0.3 0.7 4271403.682 7419069.13 2922404.2
0.4 0.6 4721070.174 7419069.13 2922404.2
0.5 0.5 5170736.666 7419069.13 2922404.2
0.6 0.4 5620403.159 7419069.13 2922404.2
0.7 0.3 6070069.651 7419069.13 2922404.2
0.8 0.2 6519736.143 7419069.13 2922404.2
0.9 0.1 6969402.636 7419069.13 2922404.2
1 0 7419069.128 7419069.13 2922404.2
T: 500K P: 1atm
Xa Xb Hm mezcla Ha Hb
0 1 15419068.6 14948741.1 15419068.6
0.1 0.9 15372035.8 14948741.1 15419068.6
0.2 0.8 15325003.1 14948741.1 15419068.6
0.3 0.7 15277970.3 14948741.1 15419068.6
0.4 0.6 15230937.6 14948741.1 15419068.6
0.5 0.5 15183904.8 14948741.1 15419068.6
0.6 0.4 15136872.1 14948741.1 15419068.6
0.7 0.3 15089839.3 14948741.1 15419068.6
0.8 0.2 15042806.6 14948741.1 15419068.6
0.9 0.1 14995773.8 14948741.1 15419068.6
1 0 14948741.1 14948741.1 15419068.6
1.9. Hm, =f(Xa)
T: 298.15 K P: 1atm
Xa Xb Ha Hb Hm
0 1 190.5 52.5 52.5
0.1 0.9 190.5 52.5 66.3
0.2 0.8 190.5 52.5 80.1
0.3 0.7 190.5 52.5 93.9
0.4 0.6 190.5 52.5 107.7
0.5 0.5 190.5 52.5 121.5
0.6 0.4 190.5 52.5 135.3
0.7 0.3 190.5 52.5 149.1
0.8 0.2 190.5 52.5 162.9
0.9 0.1 190.5 52.5 176.7
1 0 190.5 52.5 190.5
1.10. Gm =f(Xa,T)
T: 298.15 K P: 1atm
Gm mez
Xa Xb (J/mol) pa pb
0 1 68400 68400
0.1 0.9 80188.3562 196692.308 68138.8303
0.2 0.8 92719.1858 198410.495 67846.8675
0.3 0.7 105571.556 199415.569 67515.8673
0.4 0.6 118663.452 200128.681 67133.7557
0.5 0.5 131963.627 200681.814 66681.8135
0.6 0.4 145463.452 201133.756 66128.681
0.7 0.3 159171.556 201515.867 65415.5692
0.8 0.2 173119.186 201846.868 64410.4946
0.9 0.1 187388.356 202138.83 62692.3081
1 0 202400 202400
T: 500 K P: 1atm
Gm mez
Xa Xb (J/mol) pa pb
0 1 68400 68400
0.1 0.9 79097.2602 192828.154 67962.0163
0.2 0.8 91039.6543 195709.567 67472.3923
0.3 0.7 103521.274 197395.085 66917.3023
0.4 0.6 116404.581 198590.979 66276.4979
0.5 0.5 129637.174 199518.587 65518.5872
0.6 0.4 143204.581 200276.498 64590.9794
0.7 0.3 157121.274 200917.302 63395.0851
0.8 0.2 171439.654 201472.392 61709.5666
0.9 0.1 186297.26 201962.016 58828.1538
1 0 202400 202400