ESPECIE

CH4
H20
CO
H2
SUMAS

To
H
LnKeo
J

vi
-1
-1
1
3
2

Ho,fi
-74520
-241818
-110525
0
205813

Go,fi
-50460
-228572
-137169
0
141863

Ai
1.702
3.47
3.376
3.249
7.951

10 Bi
9.081
1.45
0.557
0.422
-0.008708

10 Ci
-2.164
0
0
0
0.000002164

10 Di
0
0.121
-0.031
0.083
9700

298
189440
-57.259
-24.884

Ho,Rx,T

LnKe

Ke

1000
1100
1200
500
600
700
800
900

225262
226263
226935
214031
217232
219918
222126
223896

3.2658545197
5.7345919748
7.7995225169
-23.11001617
-14.4667961
-8.208063198
-3.461098597
0.264398774

26.202491974
309.38670744
2439.4369095
9.19279E-011
5.21375E-007
0.0002724479
0.0313952523
1.3026475547

PARA DOS COMPONENTES:

K =
0.74089
PARA TRES COMPONENTES:
K =
0.60488
PARA CUATRO COMPONENTES:
K =
#DIV/0!

i,j
1,1
1,2
1,3
1,4
2,2
2,3
2,4
3,3
3,4
4,4

ESPECIE
ALCANOS
CH4
CH3-CH3
CH3CH2CH3
n-C4H10
iso-C4H10
n-C5H12
n-C6H14

vi

Ho,fi

Go,fi

Ai

10 Bi

10 Ci

10 Di

-74520
-83820
-104680
-125790

-50460
-31855
-24290
-16570

-146760
-166920

-8650
150

1.702
1.131
1.213
1.935
1.677
2.464
3.025

9.081
19.225
28.785
36.915
37.853
45.351
53.722

-2.164
-5.561
-8.824
-11.402
-11.945
-14.111
-16.791

0
0
0
0
0
0
0

n-C7H16
-187780
n-C8H18
-208750
ALQUENOS
CH2=CH2
52510
CH2=CH-CH3
19710
1-C4H8
-540
1-C5H10
-21280
1-C6H12
-41950
1-C7H14
-62760
1-C8H16
ORGANICOS GASEOSOS
CH3CH=O
-166190
C2H2
227480
C6H6
82930
1,3-butadieno
109240
ciclohexano
-123140
CH3CH2OH
-235100
C2H5-C6H5
29920
(CH2)-O
-52630
CH2=O
-108570
CH3OH
-200660
estireno
147360
CH3-C6H5
50170
INORGNICOS GASEOSOS
aire
NH3
-46110
Br2
0
CO
-110525
CO2
-393509
CS2
Cl2
0
H2
0
H2S
-20630
HCl
-92307
HCN
135100
N2
0
N2O
82050
NO
90250
NO2
33180
N2O4
9160
O2
0
SO2
-296830
SO3
-395720
H20
-241818
LIQUIDOS
NH3 ac
NH2-C6H5
C6H6
49080

8260
16260

3.57
4.108

62.127
70.567

-19.486
-22.208

0
0

68460
62205
70340
78410
86830

1.424
1.637
1.967
2.691
3.221
3.768
4.324

14.394
22.706
31.63
39.753
48.189
56.588
64.96

-4.392
-6.915
-9.873
-12.447
-15.157
-17.847
-20.521

0
0
0
0
0
0
0

-128860
209970
129665
149795
31920
-168490
130890
-13010
-102530
-161960
213900
122050

1.693
6.132
-0.206
2.734
-3.876
3.518
1.124
-0.385
2.264
2.211
2.05
0.29

17.978
1.952
39.064
26.786
63.249
20.001
55.38
23.463
7.022
12.216
50.192
47.052

-6.158
0
-13.301
-8.882
-20.882
-6.002
-18.476
-9.296
-1.877
-3.45
-16.662
-15.716

0
-1.299
0
0
0
0
0
0
0
0
0
0

3.355
3.578
4.493
3.376
5.457
6.311
4.442
3.249
3.931
3.156
4.736
3.28
5.328
3.387
4.982
11.66
3.639
5.699
8.06
3.47

0.575
3.02
0.056
0.557
1.045
0.805
0.089
0.422
1.49
0.623
1.359
0.593
1.214
0.629
1.195
2.257
0.506
0.801
1.056
1.45

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

-0.016
-0.186
-0.154
-0.031
-1.157
-0.906
-0.344
0.083
-0.232
0.151
-0.725
0.04
-0.928
0.014
-0.792
-2.787
-0.227
-1.015
-2.028
0.121

22.626
15.819
-0.747

-100.75
29.03
67.96

192.71
-15.8
-37.78

0
0
0

-16450
0
-137169
-394359
0
0
-33560
-95299
124700
0
104200
86550
51310
97540
0
-300194
-371060
-228572
-26500
124520

1,3butadieno
CCl4
Cl-C6H5
CHCl3
ciclohexano
CH3CH2OH
(CH2)-O
CH3OH
n-C3H7OH
SO3
CH3-C6H5
H2O
SOLIDOS
CaO
CaCO3
Ca(OH)2
CaC2
CaCl2
C (grafito)
Cu
CuO
Fe ()
Fe2O3
Fe3O4
FeS2
I2
LiCl
NH4Cl
Na
NaCl
NaOH
NaHCO3
S (rmbico)
SiO2 (cuarzo)

-156230
-277690

26850
-174780

-238660

-166270

-441040
12180
-285830

113630
-237129

-635090
-1206920
-986090
-59800
-795800
0
0

-604030
-1128790
-898490
-64900
-748100
0
0

0
-824200
-1118400
-178200
0
-408610

0
-742200
-1015400
-166900
0

-411153
-425609

-384138
-379494

22.711
21.155
11.278
19.215
-9.048
33.866
21.039
13.431
41.653
-2.93
15.133
8.712

-87.96
-48.28
32.86
-42.89
141.38
-172.6
-86.41
-51.28
-210.32
137.08
6.79
1.25

205.79
101.14
-31.9
83.01
-161.62
349.17
172.28
131.13
427.2
-84.73
16.35
-0.18

0
0
0
0
0
0
0
0
0
0
0
0

6.1040
12.5720
9.5970
8.2540
8.6460
1.7710
2.6770
5.7800
-0.1110
11.8120
9.5940
2.6120
6.4810
5.2570
5.9390
1.9880
5.5260
0.1210
5.1280
4.1140
4.8710

0.4430
2.6370
5.4350
1.4290
1.5300
0.7710
0.8150
0.9730
6.1110
9.6970
27.1120
13.2860
1.5020
2.4760
16.1050
4.6880
1.9630
16.3160
18.1480
-1.7280
5.3650

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

-1.0470
-3.1200
0.0000
-1.0420
-0.3020
-0.8670
0.0350
-0.8740
1.1500
-1.9760
0.4090
0.0000
0.0000
-0.1930
0.0000
0.0000
0.0000
1.9480
0.0000
-0.7830
-1.0010

Tci (K)
126.2
33.19
405.7

Pci (bar)
34
13.13
112.8

wi
0.038
-0.216
0.253

Zci
0.289
0.305
0.242

Vci
89.2
64.1
72.5

Tri
5.72900
21.78367
1.78211
#DIV/0!

Pri
17.64706
45.69688
5.31915
#DIV/0!

Boi
0.05715
0.07995
-0.08442
#DIV/0!

PARA CALCULAR i PARA UNA MEZCLA IDEAL DE GASES NO IDEALES:

T (K) = 723
PARA DOS COMPONENTES:
P (bar) = 600
K = 0.74301
1 =
1.212046 PARA TRES COMPONENTES:
2 =
1.110414
K = 0.63411
3 =
0.853428 PARA CUATRO COMPONENTES:
4 =
#DIV/0!
K = #DIV/0!

MPONENTES:

OMPONENTES:

O COMPONENTES:

Tci,j
126.2000
64.7192
226.2727
0.0000
33.1900
116.0396
0.0000
405.7000
0.0000
0.0000

PARA CALCULAR i PARA UNA MEZCLA NO IDEAL DE GASES NO IDEALES:

T(K) = 723
y1 = 0.1248
PARA DOS COMPONENTES:
P (bar) = 600
y2 = 0.3736
1 = 1.21517
y3 = 0.5018
PARA TRES COMPONENTES:
y4 = 0
1 = 1.23834
PARA CUATRO COMPONENTES:
1 = #DIV/0!
3 = #DIV/0!
Pci,j
34.0000

0.0000

wi,j
0.0380
-0.0890
0.1455
0.019
-0.2160
0.0185
-0.108
0.2530
0.1265
0.0000

Zci,j
0.2890
0.297
0.2655
0.1445
0.305
0.2735
0.1525
0.242
0.121
0

Vci,j
89.2000
75.9602
80.5617
11.1500
64.1000
68.2138
8.0125
72.5000
9.0625
0.0000

Tci (K)

Pci (bar)

wi

Zci

Vci

190.6
305.3
369.8
425.1
408.1
469.7
507.6

45.99
48.72
42.48
37.96
36.48
33.7
30.25

13.1300

112.8000

0.012
0.1
0.152
0.2
0.181
0.252
0.301

0.286
0.279
0.276
0.274
0.282
0.27
0.266

98.6
145.5
200
255
262.7
313
371

Pci,j
33.9940
21.0384
61.9980
0.0000
13.1298
38.6813
0.0000
112.5881
0.0000
#DIV/0!

Tri,j
5.7290
11.1713
3.1953
#DIV/0!
21.7837
6.2306
#DIV/0!
1.7821
#DIV/0!
#DIV/0!

2 =
2 =
2 =
4 =

Pri,j
17.6502
28.5192
9.6777
#DIV/0!
45.6975
15.5114
#DIV/0!
5.3292
#DIV/0!
#DIV/0!

540.2
568.7

27.4
24.9

0.35
0.4

0.261
0.256

428
486

282.3
365.6
420

50.4
46.65
40.43

0.087
0.14
0.191

0.281
0.289
0.277

131
188.4
239.3

504

31.4

0.28

0.265

354

466
308.3
562.2
425.2
553.6
513.9
617.2

55.5
61.39
48.98
42.77
40.73
61.48
36.06

0.291
0.187
0.21
0.19
0.21
0.645
0.303

0.221
0.271
0.271
0.267
0.273
0.24
0.263

154
113
259
220.4
308
167
374

408
512.6
636
591.8

65.9
80.97
38.4
41.06

0.282
0.564
0.297
0.262

0.223
0.224
0.256
0.264

115
118
352
316

132.2
405.7

37.45
112.8

0.035
0.253

0.289
0.242

84.8
72.5

132.9
304.2
552
417.2
33.19
373.5
324.7
456.7
126.2
309.6
180.2

34.99
73.83
79
77.1
13.13
89.63
83.1
53.9
34
72.45
64.8

0.048
0.224
0.111
0.069
-0.216
0.094
0.132
0.41
0.038
0.141
0.583

0.299
0.274
0.275
0.265
0.305
0.284
0.249
0.197
0.289
0.274
0.251

93.4
94
160
124
64.1
98.5
81
139
89.2
97.4
58

154.6
430.8
490.9
647.1

50.43
78.84
82.1
220.55

0.022
0.245
0.424
0.345

0.288
0.269
0.255
0.229

73.4
122
127
55.9

405.7

112.8

0.253

0.242

72.5

562.2

48.98

0.21

0.271

259

425.2
556.4
632.4
536.4
553.6
513.9

42.77
45.6
45.2
54.72
40.73
61.48

0.19
0.193
0.25
0.222
0.21
0.645

0.267
0.272
0.265
0.293
0.273
0.24

220.4
276
308
239
308
167

512.6
536.8
490.9
591.8
647.1

80.97
51.75
82.1
41.06
220.55

0.564
0.622
0.424
0.262
0.345

0.224
0.254
0.255
0.264
0.229

118
219
127
316
55.9

B1i
0.13889
0.13900
0.12381
#DIV/0!

1.11073
1.23332

3 = 0.92381

#DIV/0!
#DIV/0!
Boi,j
0.0572
0.0741
0.0172
#DIV/0!
0.0799
0.0604
#DIV/0!
-0.0844
#DIV/0!
#DIV/0!

B1i,j
0.1389
0.1390
0.1377
#DIV/0!
0.1390
0.1389
#DIV/0!
0.1238
#DIV/0!
#DIV/0!

Bi,j
19.2697
15.7933
11.3038
#DIV/0!
10.4927
15.7060
#DIV/0!
-15.9084
#DIV/0!
#DIV/0!

i,j
0.0000
1.8243
19.2462
#DIV/0!
0.0000
36.8278
#DIV/0!
0.0000
#DIV/0!
#DIV/0!

ESPECIE
CO
H2
CH4
H2O
To
H
LnKeo
J
T
Ho,Rx,T
LnKe
Ke

vi
1
3
-1
-1

Ho,fi
-110525
0
-74520
-241818
205813

Go,fi
-137169
0
-50460
-228572
141863

Ai
3.376
3.249
1.702
3.47
7.951

Bi
5.57E-01
0.422
9.08E+00
1.45E+00
-8.708

Ci
0
0
-2.16E+00
0
2.164

298
186394.703
-57.2588809
-26.1128126
973
600
650
700
750
800
3401.25839 214186.754 215591.46 216872.166 218033.665 219080.676
1.66175796 -15.0855416 -11.7719941 -8.91403014 -6.42311643 -4.23248163
5.26856463 2.808E-007 7.718E-006 0.00013449 0.00162359 0.01451632

Di
-0.031
0.083
0
1.21E-01
0.097

Tci
345
120
32
550

850
900
220017.867 220849.867
-2.29078196 -0.55786344
0.10118731 0.57243079

Pci
45
12
345
34

wi
0.045
0.23
-0.0023

Boi

B1i

fi

ESPECIE
pentano
isopentano

vi
-1
1

Ho,fi
-146538
-154577
-8039

Go,fi
-8206
-14653
-6447

Ai
2.447
2.875
0.428

Bi
450
150
-300

Ci
-28
-20
8

To
H
LnKeo
J
T
Ho,Rx,T
LnKe
Ke

298
-8392.15198
2.60214436
41.290007
550
600
650
700
750
800
-380177.05 -450591.918 -527045.096 -609519.452 -697997.991 -792463.806
-36.2507419 -43.7929682 -51.3072728 -58.7984503 -66.2699794 -73.7244427
1.805E-016 9.571E-020 5.218E-023 2.912E-026 1.657E-029 9.591E-033

ESPECIE

vi

Dho,fi

Di
0
0.121
0.121

Tci
345
120

850
900
-892900.06 -999289.96
-81.1637954 -88.5895433
5.637E-036 3.358E-039

Pci
45
12

wi
0.045
0.23

Boi

B1i

fi