THERMODYNAMIC DATA

TABLE 13-1

13-11

Constant-Pressure Liquid-Vapor Equilibrium Data for Selected Binary Systems

Component

Mole fraction A in

Temperature,
C

Liquid

Vapor

Total pressure,
kPa

Reference

Acetone

Chloroform

62.50
62.82
63.83
64.30
64.37
64.35
64.02
63.33
62.23
60.72
58.71
57.48

0.0817
0.1390
0.2338
0.3162
0.3535
0.3888
0.4582
0.5299
0.6106
0.7078
0.8302
0.9075

0.0500
0.1000
0.2000
0.3000
0.3500
0.4000
0.5000
0.6000
0.7000
0.8000
0.9000
0.9500

101.3

Acetone

Methanol

64.65
61.78
59.60
58.14
56.96
56.22
55.78
55.41
55.29
55.37
55.54
55.92
56.21

0.0
0.091
0.190
0.288
0.401
0.501
0.579
0.687
0.756
0.840
0.895
0.954
1.000

0.0
0.177
0.312
0.412
0.505
0.578
0.631
0.707
0.760
0.829
0.880
0.946
1.000

101.3

Acetone

Water

74.80
68.53
65.26
63.59
61.87
60.75
59.95
59.12
58.29
57.49
56.68
56.30

0.0500
0.1000
0.1500
0.2000
0.3000
0.4000
0.5000
0.6000
0.7000
0.8000
0.9000
0.9500

0.6381
0.7301
0.7716
0.7916
0.8124
0.8269
0.8387
0.8532
0.8712
0.8950
0.9335
0.9627

101.3

Carbon tetrachloride

Benzene

80.0
79.3
78.8
78.6
78.5
78.2
78.0
77.6
77.4
77.1

0.0
0.1364
0.2157
0.2573
0.2944
0.3634
0.4057
0.5269
0.6202
0.7223

0.0
0.1582
0.2415
0.2880
0.3215
0.3915
0.4350
0.5480
0.6380
0.7330

101.3

Chloroform

Methanol

63.0
60.9
59.3
57.8
55.9
54.7
54.0
53.7
53.5
53.5
53.7
54.4
55.2
56.3
57.9

0.040
0.095
0.146
0.196
0.287
0.383
0.459
0.557
0.636
0.667
0.753
0.855
0.904
0.937
0.970

0.102
0.215
0.304
0.378
0.472
0.540
0.580
0.619
0.646
0.655
0.684
0.730
0.768
0.812
0.875

101.3

Ethanol

Benzene

76.1
72.7
70.8
69.2
68.4
68.0
67.9
68.0
68.7
69.5

0.027
0.063
0.100
0.167
0.245
0.341
0.450
0.578
0.680
0.766

0.137
0.248
0.307
0.360
0.390
0.422
0.447
0.478
0.528
0.566

101.3

13-12

DISTILLATION

TABLE 13-1

Constant-Pressure Liquid-Vapor Equilibrium Data for Selected Binary Systems (Continued )

Component

Mole fraction A in

Temperature,
C

Liquid

Vapor

70.4
72.7
76.9

0.820
0.905
0.984

0.615
0.725
0.937

Total pressure,
kPa

Reference

Ethanol

Water

95.5
89.0
86.7
85.3
84.1
82.7
82.3
81.5
80.7
79.8
79.7
79.3
78.74
78.41
78.15

0.0190
0.0721
0.0966
0.1238
0.1661
0.2337
0.2608
0.3273
0.3965
0.5079
0.5198
0.5732
0.6763
0.7472
0.8943

0.1700
0.3891
0.4375
0.4704
0.5089
0.5445
0.5580
0.5826
0.6122
0.6564
0.6599
0.6841
0.7385
0.7815
0.8943

101.3

Ethyl acetate

Ethanol

78.3
76.6
75.5
73.9
72.8
72.1
71.8
71.8
71.9
72.2
73.0
74.7
76.0
77.1

0.0
0.050
0.100
0.200
0.300
0.400
0.500
0.540
0.600
0.700
0.800
0.900
0.950
1.000

0.0
0.102
0.187
0.305
0.389
0.457
0.516
0.540
0.576
0.644
0.726
0.837
0.914
1.000

101.3

Ethylene glycol

Water

69.5
76.1
78.9
83.1
89.6
103.1
118.4
128.0
134.7
145.0
160.7

0.0
0.23
0.31
0.40
0.54
0.73
0.85
0.90
0.93
0.97
1.00

0.0
0.002
0.003
0.010
0.020
0.06
0.13
0.22
0.30
0.47
1.00

30.4

n-Hexane

Ethanol

78.30
76.00
73.20
67.40
65.90
61.80
59.40
58.70
58.35
58.10
58.00
58.25
58.45
59.15
60.20
63.50
66.70
68.70

0.0
0.0100
0.0200
0.0600
0.0800
0.1520
0.2450
0.3330
0.4520
0.5880
0.6700
0.7250
0.7650
0.8980
0.9550
0.9900
0.9940
1.0000

0.0
0.0950
0.1930
0.3650
0.4200
0.5320
0.6050
0.6300
0.6400
0.6500
0.6600
0.6700
0.6750
0.7100
0.7450
0.8400
0.9350
1.0000

101.3

10

Methanol

Benzene

70.67
66.44
62.87
60.20
58.64
58.02
58.10
58.47
59.90
62.71

0.026
0.050
0.088
0.164
0.333
0.549
0.699
0.782
0.898
0.973

0.267
0.371
0.457
0.526
0.559
0.595
0.633
0.665
0.760
0.907

101.3

11

THERMODYNAMIC DATA
TABLE 13-1

13-13

Constant-Pressure Liquid-Vapor Equilibrium Data for Selected Binary Systems (Continued )

Component

Mole fraction A in

Temperature,
C

Liquid

Vapor

Total pressure,
kPa

76.10
74.15
71.24
67.75
65.60
64.10
64.00
63.25
62.97
62.50
62.65
62.50
62.35
62.60
62.80
63.21
63.90

0.0125
0.0320
0.0800
0.1550
0.2510
0.3465
0.4020
0.4975
0.5610
0.5890
0.6220
0.6960
0.7650
0.8250
0.8550
0.9160
0.9550

Reference

0.0475
0.1330
0.2475
0.3650
0.4550
0.5205
0.5560
0.5970
0.6380
0.6560
0.6670
0.7000
0.7420
0.7890
0.8070
0.8600
0.9290

101.3

12

0.0
0.020
0.040
0.060
0.080
0.100
0.150
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
0.950
1.000

0.0
0.134
0.230
0.304
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.870
0.915
0.958
0.979
1.000

101.3

13

57.80
55.50
55.04
53.88
53.82
53.90
54.50
56.86

0.173
0.321
0.380
0.595
0.643
0.710
0.849
1.000

0.342
0.477
0.516
0.629
0.657
0.691
0.783
1.000

101.3

14

Methanol

Ethyl acetate

Methanol

Water

Methyl acetate

Methanol

1-Propanol

Water

100.00
98.59
95.09
91.05
88.96
88.26
87.96
87.79
87.66
87.83
89.34
92.30
97.18

0.0
0.0030
0.0123
0.0322
0.0697
0.1390
0.2310
0.3110
0.4120
0.5450
0.7300
0.8780
1.0000

0.0
0.0544
0.1790
0.3040
0.3650
0.3840
0.3970
0.4060
0.4280
0.4650
0.5670
0.7210
1.0000

101.3

15

2-Propanol

Water

100.00
97.57
96.20
93.66
87.84
84.28
82.84
82.52
81.52
81.45
81.19
80.77
80.73
80.58
80.52
80.46
80.55

0.0
0.0045
0.0069
0.0127
0.0357
0.0678
0.1330
0.1651
0.3204
0.3336
0.3752
0.4720
0.4756
0.5197
0.5945
0.7880
0.8020

0.0
0.0815
0.1405
0.2185
0.3692
0.4647
0.5036
0.5153
0.5456
0.5489
0.5615
0.5860
0.5886
0.6033
0.6330
0.7546
0.7680

101.3

16

100.0
96.4
93.5
91.2
89.3
87.7
84.4
81.7
78.0
75.3
73.1
71.2
69.3
67.5
66.0
65.0
64.5

13-14

DISTILLATION

TABLE 13-1

Constant-Pressure Liquid-Vapor Equilibrium Data for Selected Binary Systems (Continued )

Component

Tetrahydrofuran

Water

Mole fraction A in

Temperature,
C

Liquid

Vapor

Total pressure,
kPa

81.32
81.85
82.39

0.9303
0.9660
1.0000

0.9010
0.9525
1.0000

Reference

73.00
66.50
65.58
64.94
64.32
64.27
64.23
64.16
63.94
63.70
63.54
63.53
63.57
63.64
63.87
64.29
65.07
65.39

0.0200
0.0400
0.0600
0.1000
0.2000
0.3000
0.4000
0.5000
0.6000
0.7000
0.8000
0.8200
0.8400
0.8600
0.9000
0.9400
0.9800
0.9900

0.6523
0.7381
0.7516
0.7587
0.7625
0.7635
0.7643
0.7658
0.7720
0.7831
0.8085
0.8180
0.8260
0.8368
0.8660
0.9070
0.9625
0.9805

101.3

17

Water

Acetic acid

118.3
110.6
107.8
105.2
104.3
103.5
102.8
102.1
101.5
100.8
100.8
100.5
100.2
100.0

0.0
0.1881
0.3084
0.4498
0.5195
0.5824
0.6750
0.7261
0.7951
0.8556
0.8787
0.9134
0.9578
1.0000

0.0
0.3063
0.4467
0.5973
0.6580
0.7112
0.7797
0.8239
0.8671
0.9042
0.9186
0.9409
0.9708
1.0000

101.3

18

Water

1-Butanol

117.6
111.4
106.7
102.0
101.0
98.5
96.7
95.2
93.6
93.1
93.0
92.9
92.9
93.2
95.2
96.8
100.0

0.0
0.049
0.100
0.161
0.173
0.232
0.288
0.358
0.487
0.551
0.580
0.628
0.927
0.986
0.993
0.996
1.000

0.0
0.245
0.397
0.520
0.534
0.605
0.654
0.693
0.739
0.751
0.752
0.758
0.758
0.760
0.832
0.883
1.000

101.3

19

Water

Formic acid

102.30
104.60
105.90
107.10
107.60
107.60
107.60
107.10
106.00
104.20
102.90
101.80
100.00

0.0405
0.1550
0.2180
0.3210
0.4090
0.4110
0.4640
0.5220
0.6320
0.7400
0.8290
0.9000
1.0000

0.0245
0.1020
0.1620
0.2790
0.4020
0.4050
0.4820
0.5670
0.7180
0.8360
0.9070
0.9510
1.0000

101.3

20

Water

Glycerol

278.8
247.0
224.0
219.2
210.0
202.5
196.5

0.0275
0.0467
0.0690
0.0767
0.0901
0.1031
0.1159

0.9315
0.9473
0.9563
0.9743
0.9783
0.9724
0.9839

101.3

21

THERMODYNAMIC DATA
TABLE 13-1

Constant-Pressure Liquid-Vapor Equilibrium Data for Selected Binary Systems (Concluded )

Component

13-15

Temperature,
C
175.2
149.3
137.2
136.8
131.8
121.5
112.8
111.3
106.3
100.0

Mole fraction A in
Liquid

Vapor

0.1756
0.3004
0.3847
0.3895
0.4358
0.5633
0.7068
0.7386
0.8442
1.0000

0.9899
0.9964
0.9976
0.9878
0.9976
0.9984
0.9993
0.9994
0.9996
1.0000

Total pressure,
kPa

Reference

To convert degrees Celsius to degrees Fahrenheit, C = (F 32)/1.8. To convert kilopascals to pounds-force per square inch, multiply by 0.145.
Kojima, Kato, Sunaga, and Hashimoto, Kagaku Kogaku, 32, 337 (1968).
Marinichev and Susarev, Zh. Prtkl. Khtm., 38, 378 (1965).
3
Kojima, Tochigi, Seki, and Watase, Kagaku Kogaku, 32, 149 (1968).
4
International Critical Tables, McGraw-Hill, New York, 1928.
5
Nagata, J. Chem. Eng. Data, 7, 367 (1962).
6
Ellis and Clark, Chem. Age India, 12, 377 (1961).
7
Carey and Lewis, Ind. Eng. Chem., 24, 882 (1932).
8
Chu, Getty, Brennecke, and Paul, Distillation Equilibrium Data, New York, 1950.
9
Trimble and Potts, Ind. Eng. Chem., 27, 66 (1935).
10
Sinor and Weber, J. Chem. Eng. Data, 5, 243 (1960).
11
Hudson and Van Winkle, J. Chem. Eng. Data, 14, 310 (1969).
12
Murti and Van Winkle, Chem. Eng. Data Ser., 3, 72 (1958).
13
Dunlop, M.S. thesis, Brooklyn Polytechnic Institute, 1948.
14
Dobroserdov and Bagrov, Zh. Prtkl. Kthm. (Leningrad), 40, 875 (1967).
15
Smirnova, Vestn. Leningr. Univ. Fiz. Khim., 81 (1959).
16
Kojima, Ochi, and Nakazawa, Int. Chem. Eng., 9, 342 (1964).
17
Shnitko and Kogan, J. Appl. Chem., 41, 1236 (1968).
18
Brusset, Kaiser, and Hoequel, Chim. Ind., Gente Chim. 99, 207 (1968).
19
Boublik, Collect. Czech. Chem. Commun., 25, 285 (1960).
20
Ito and Yoshida, J. Chem. Eng. Data, 8, 315 (1963).
21
Chen and Thompson, J. Chem. Eng. Data, 15, 471 (1970).
NOTE:
1
2

Isobaric vapor-liquid equilibrium data for benzene-toluence.

(Brian, Staged Cascades in Chemical Processing, Prentice-Hall, Englewood
Cliffs, NJ, 1972.)

FIG. 13-9

Isobaric y-x curves for benzene-toluene. (Brian, Staged Cascades

in Chemical Processing, Prentice-Hall, Englewood Cliffs, NJ, 1972.)

FIG. 13-8