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cho khi chuyn

K thi hc sinh gii thnh ph lp 11 thpt

Nm hc 2001-2002
*****
mn thi :ha hc

Ngy thi :23-3-2002

Thi gian lm bi:120 pht

Cu I: (5 im )
1.Cho dung dch Ba(NO3)2 vo ng nghim cha bt Cu v dung dch H2SO4 long
.Nhng phn ng no c th xy ra .Vit phng trnh ca nhng phn ng
.Cho bit vai tr ca ion NO3- trong th nghim trn.
2.C 6 ng nghim cha rieng r 6 dung dch sau :Pb(NO3)2,NH4Cl,NH4NO3,Na2SO4,
KI,Ba(NO3)2 .Khng dng thm ho cht no khc .lm th no nhn ra cc
dung dch trn,bit rng PbI2 l cht c mu vng.
Cu II :(4 im )
Cho 1,1 -ibrmpropan phn ng trong KOH c ,ru vi lng d thu c cht A
.un nng cht A n 6000C c mt C hot tnh c 2 sn phm B v D .Cht B
khi tham gia phn ng brm ho c nh sng hoc c mt bt Fe ,trong mi trng
hp cho ta 1 sn phm monobrom.Cht D cng tham gia phn ng brm ho trong
cc iu kin tng t nhng mi trng hp cho 3 sn phm brom ho .Vit cc phng trnh phn ng .
Cu III: (3 im)
Mt xicloankan no c th b phn tch thnh hn hp 2 hircacbon theo
phng trnh phn ng :
n1C2x+2H5x n2C3xH2x+2 + n3C4x-2H 6x
Xc nh cng thc ca cc cht trn.Bit n1 ,n2 ,n3 l h s ca phng trnh
Cu IV: (5 im)
4,95 gam hn hp 2 mui nitrat kim loi khan (trong c 1 mui ca kim loi
kim) c nung nng .Sn phm to ra gm 1,38 gam cht rn A v hn hp kh
v hi .Nu em hn hp ny nung n 10000C (p=1 atm) th c th tch l
6,26 lit khi kh NO2 b phn tch thnh NO v O2 .Tm cng thc ca 2
mui .
Cu V: (3 im )
t chy han ton 3,36 lit (dktc ) hn hp gm 2 hircacbon .Khi cho ton b
sn phm chy vo bnh ng dung dch Ca(OH)2 thu c 15 gam kt ta v
1000 ml dung dch mui c nng 0,05 M ,dung dch ny c khi lng ln hn
khi lng ca nc vi trong dng l 3,2 gam .
Xc nh cng thc phn t ca cc cht trn ,bit rng s mol ca cc
hircacbon c phn t khi nh bng mt na s mol ca hircacbon c
phn t khi ln.
Cho H=1,C=12,N=14,O=16,Ca=40.
Ghi ch:Th sinh c s dng h thng tun hon cc nguyn t ho hc.

S gio dc-o to
H ni
*****

K thi hc sinh gii thnh ph lp 11 thpt

Nm hc 2000-2001
*****
mn thi :ha hc

Ngy thi :17-3-2001

Thi gian lm bi:120 pht

Cu I: (6 im )
1.Hon thnh cc phng trnh ion theo s sau:
As2S3 + Fe2+ + NO3- + H+
AsO42- + Fe3+ + SO2 + NO + H2O
+
2FeS2 + H + SO4
Fe3+ + SO2 + H2O.
2.Trnh by cc phng php ho hc phn bit cc dung dch khng mu
sau m ch cn dng mt kim loi lm thuc th (khng dng thm ho cht no
khc ):NaOH ,HCl ,Na2SO4 ,H2SO4 ,NaCl,BaCl2 ,dung dch NH3.
Cu II: (4 im)
B tr 4 b dng c th nghim nh hnh v ri ln lt
vo mi bnh 100 ml dung dch khc nhau :

Bnh 1:l dung dch Ba(OH)2 0,001 M

K
Bnh 2: l dung dch CH3COOH 0,001 M
Bnh 3 :l dung dch KOH 0,001 M
Bnh 4:ch cho 100 ml H2O
Hy so snh sng ca n mi bnh trong cc
th nghim sau (sng ,sng m,hay khng sng) v gii thch cc hin tng xy ra
:
Th nghim 1:ng kho X
Th nghim 2 : tip vo mi bnh 100 ml dung dch MgSO4 0.001 M ri
ng kho K
Cu III :(6 im)Dung dch A cha KOH 0.2M v Ba(NO3)2 0.1M ,dung dch B
cha CuSO4 ,H2SO4,RSO4 (R l kim loi ho tr II ,c hirxit khng tan v khng lng tnh )
. 1 lng d dung dch A vo 80 ml dung dch B ,phn ng xong lc tch kt
ta ,cho tc dng vi lng d dung dch NH3 ;sau khi phn ng hon ton ,tch
phn cht rn khng tan trong NH3 em nung thu c 1 lng cht rn ng
bng 11,052 gam .Mt khc nu 20 ml dung dch A vo 20 ml dung dch B
nhn thy trong dung dch C to thnh va ht axit ,thm tip lng d dung dch A
vo hn hp phn ng lc tch c 3,245 gam kt ta.Nung kt ta ny ti khi lng khng i c cht rn K .Cho K tc dng vi lng d dung dch HCl ,nhn
thy sau phn ng lng cht rn cn li khng tan trong axit vt qu 2,54
gam.Hy xc nh nng mol/l ca cc cht c trong dung dch B v R l kim
loi no trong s nhng kim loi cho di y (b qua hin tng thu phn ca
cc mui khi tan trong dung dch H2O )
Cu IV : (4 im )Trong thnh phn 1 hp cht hu c ,hiro chim 16,13%
khi lng .t chy hon ton 1 hp cht ny thu c hn hp kh A ch gm

CO2,H2O v N2 c t khi so vi H2l 12,875.Dn A qua bnh ng H2SO4 c ,d

thy khi lng bnh ny tng 8,1 gam v hn hp kh B i ra khi bnh c t khi
so vi Oxi l dB /oxi =3,625/3.Hy xc nh cng thc phn t ca hp cht hu c
ny.
Cho:H=1,O=16,C=12,NaOH=23,N=14,Be=19,Mg=24,S=32,Cl=35,5,K=39,
Ca=40,
Cu=64,Zn=65
Ghi ch :-th sinh ch c s dng my tnh c nhn ,nhng khng c s dng
h thng tun hon hay bt c ti liu no khc.

S gio dc-o to
H ni
*****
cho khi chuyn

K thi hc sinh gii thnh ph lp 11 thpt

Nm hc 2000-2001
*****
mn thi :ha hc

Ngy thi :17-3-2001

Thi gian lm bi:120 pht
Cu I: (6 im )1.Hon thnh cc phng trnh ion theo s sau:
As2S3 + Fe2+ + NO3- + H+
AsO42- + Fe3+ + SO2 + NO + H2O
FeS2 + H+ + SO42Fe3+ + SO2 + H2O.
2.hp cht C3H8 mch h phn ng cng vi Brm theo t l mol 1:1 to thnh hp
cht A Hy vit cc cng thc cu to c th c ca A.
3.Trnh by phng php ho hc phn bit cc dung dch khng mu sau
m ch cn dng mt kim loi lm thuc th (khng dng thm ho cht no
khc ):NaOH ,HCl ,Na2SO4 ,H2SO4 ,NaCl,BaCl2 ,dung dch NH3.
Cu II: (4 im)
B tr 4 b dng c th nghim nh hnh v ri ln lt
vo mi bnh 100 ml dung dch khc nhau :

Bnh 1:l dung dch Ba(OH)2 0,001 M

K
Bnh 2: l dung dch CH3COOH 0,001 M
Bnh 3 :l dung dch KOH 0,001 M
Bnh 4:ch cho 100 ml H2O
Hy so snh sng ca n mi bnh trong cc
th nghim sau (sng ,sng m,hay khng sng) v gii thch cc hin tng xy ra
:
Th nghim 1:ng kho X
Th nghim 2 : tip vo mi bnh 100 ml dung dch MgSO4 0.001 M ri
ng kho K
Cu III: (6 im)Dung dch A cha KOH 0.2M v Ba(NO3)2 0.1M ,dung dch B
cha CuSO4 ,H2SO4,RSO4 (R l kim loi ho tr II ,c hirxit khng tan v khng lng tnh )
. 1 lng d dung dch A vo 80 ml dung dch B ,phn ng xong lc tch kt
ta ,cho tc dng vi lng d dung dch NH3 ;sau khi phn ng hon ton ,tch

phn cht rn khng tan trong NH3 em nung thu c 1 lng cht rn ng
bng 11,052 gam .Mt khc nu 20 ml dung dch A vo 20 ml dung dch B
nhn thy trong dung dch C to thnh va ht axit ,thm tip lng d dung dch A
vo hn hp phn ng lc tch c 3,245 gam kt ta.Nung kt ta ny ti khi lng khng i c cht rn K .Cho K tc dng vi lng d dung dch HCl ,nhn
thy sau phn ng lng cht rn cn li khng tan trong axit vt qu 2,54
gam.Hy xc nh nng mol/l ca cc cht c trong dung dch B v R l kim
loi no trong s nhng kim loi cho di y (b qua hin tng thu phn ca
cc mui khi tan trong dung dch H2O )
Cu IV : (4 im )Trong thnh phn 1 hp cht hu c ,hiro chim 16,13%
khi lng .t chy hon ton 1 hp cht ny thu c hn hp kh A ch gm
CO2,H2O v N2 c t khi so vi H2l 12,875.Dn A qua bnh ng H2SO4 c ,d
thy khi lng bnh ny tng 8,1 gam v hn hp kh B i ra khi bnh c t khi
so vi Oxi l dB /oxi =3,625/3.Hy xc nh cng thc phn t ca hp cht hu c
ny.
Cho:H=1,O=16,C=12,NaOH=23,N=14,Be=19,Mg=24,S=32,Cl=35,5,K=39,
Ca=40,
Cu=64,Zn=65
Ghi ch :-th sinh ch c s dng my tnh c nhn ,nhng khng c s dng
h thng tun hon hay bt c ti liu no khc.