CINÉTICA DE LA

Camila Gil Santana

Nicolás Noreña Toro
REACCIÓN DE UN
Brayan A. Jiménez Duque ESTER CON EL ION
HIDROXILO
ABSTRACT
In this experiment a reaction between Ethyl
Acetate and NaOH was measured using a
conductometer with the purpose of determine
the rate constant and the reaction order. The
reaction was made varying the concentrations
of the Ethyl Acetate and NaOH. In addition, to
determine the activation energy was necessary
to use Arrhenius equation, which requires
determining the rate constant at two different
temperatures, so the reaction was made at 21
°C and 33 °C.
 Tabla 1. Resultados para la reacción entre el ion hidroxilo y el acetato de etilo a 21°C
[NaOH]=[CH₃COOC₂H₅] 21° C
Cꝏ 84 µS
Conductividad (mS) Tiempo (s) (k0-kt)/(kt-kf)
5.580 0
5.426 30 0.0289
5.122 60 0.0910
4.856 90 0.1518
4.621 120 0.2115
4.428 150 0.2653
4.226 180 0.3270
4.118 210 0.3625
RESULTADOS 3.999 240 0.4039
3.89 270 0.4441
3.794 300 0.4815
3.712 330 0.5150
3.636 360 0.5474
3.568 390 0.5776
3.508 420 0.6052
3.446 450 0.6348
3.393 480 0.6610
3.353 510 0.6814
3.306 540 0.7059
3.27 570 0.7252
3.23 600 0.7471
 Gráfica [NaOH]=[CH₃COOC₂H₅] a 21°C
[NaOH]=[CH₃COOC₂H₅] a 21°C

0.7000

0.6000
(k0-kt)/(kt-kf)

0.5000

0.4000

0.3000

0.2000

0.1000
y = 0.0016x + 0.0136
R² = 0.9861
0.0000
0 50 100 150 200 250 300 350 400
Tiempo (s)
 Tabla 2. Resultados para la reacción entre el ion hidroxilo y el acetato de etilo a 21°C con la
doble concentración de éster.
[NaOH]=2[CH₃COOC₂H₅] 21° C
Cꝏ 350 µS
Conductividad (mS) Tiempo (s) (k0-kt)/(kt-kf)
5.656 0
5.091 30 0.1192
4.545 60 0.2649
4.14 90 0.4000
3.808 120 0.5344
3.559 150 0.6535
3.372 180 0.7558
3.211 210 0.8546
RESULTADOS 3.078 240 0.9451
2.972 270 1.0237
2.885 300 1.0931
2.81 330 1.1570
2.748 360 1.2127
2.685 390 1.2724
2.64 420 1.3171
2.606 450 1.3520
2.564 480 1.3966
2.539 510 1.4240
2.508 540 1.4588
2.485 570 1.4853
2.47 600 1.5029
 Gráfica [NaOH]=2[CH₃COOC₂H₅] a 21°C

[NaOH]=2[CH₃COOC₂H₅] a 21°C
1.4000

1.2000

1.0000
(k0-kt)/(kt-kf)

0.8000

0.6000
y = 0.0033x + 0.1073
0.4000
R² = 0.9791
0.2000

0.0000
0 50 100 150 200 250 300 350 400
Tiempo (s)
 Tabla 3. Resultados para la reacción entre el ion hidroxilo y el acetato de etilo a 21°C con la
doble concentración de base.
2[NaOH]=[CH₃COOC₂H₅] 21° C
Cꝏ 5,998 mS
Conductividad (mS) Tiempo (s) (k0-kt)/(kt-kf)
9.345 0
8.916 30 0.1473
8.478 60 0.3499
8.144 90 0.5600
7.885 120 0.7741
7.675 150 0.9963
7.527 180 1.1895
7.383 210 1.4172
RESULTADOS 7.278 240 1.6155
7.19 270 1.8086
7.134 300 1.9470
7.077 330 2.1027
7.031 360 2.2408
6.985 390 2.3919
6.958 420 2.4873
6.935 450 2.5729
6.903 480 2.6992
6.879 510 2.8000
6.866 540 2.8569
6.845 570 2.9525
6.836 600 2.9950
 Gráfica 2[NaOH]=[CH₃COOC₂H₅] a 21°C

2[NaOH]=[CH₃COOC₂H₅] a 21°C
2.5000

2.0000
(k0-kt)/(kt-kf)

1.5000

1.0000

y = 0.0065x - 0.0051
0.5000 R² = 0.9954

0.0000
0 50 100 150 200 250 300 350 400
Tiempo (s)
 Tabla 4. Resultados para la reacción entre el ion hidroxilo y el acetato de etilo a 33°C
[NaOH]=2[CH₃COOC₂H₅] 33° C
Cꝏ 450 µS
Conductividad (mS) Tiempo (s) (k0-kt)/(kt-kf)
5.277 0
4.941 30 0.0748
4.569 60 0.1719
4.303 90 0.2528
4.087 120 0.3272
RESULTADOS 3.912 150 0.3943
3.789 180 0.4457
3.679 210 0.4949
3.59 240 0.5373
3.514 270 0.5754
3.448 300 0.6101
3.392 330 0.6407
3.332 360 0.6749
3.293 390 0.6979
3.261 420 0.7172
 Gráfica [NaOH]=[CH₃COOC₂H₅] a 33°C

[NaOH]=[CH₃COOC₂H₅] a 33°C
0.8000

0.7000

0.6000
(k0-kt)/(kt-kf)

0.5000

0.4000

0.3000

0.2000 y = 0.0018x + 0.0915

R² = 0.9651
0.1000

0.0000
0 50 100 150 200 250 300 350 400
Tiempo (s)
Energía de activación
LN (K) VS (1/T)
-4
0.00322 0.00324 0.00326 0.00328 0.0033 0.00332 0.00334 0.00336
-4.02
k’ k= k’/a
-4.04
a=b a 21°C 0,0016 0,016
-4.06
a=b a 33°C 0,0018 0,018

LN (K)
-4.08

b=2 a 21°C 0,0033 0,0165 -4.1

a=2 b 21°C 0,0065 0,065 -4.12

y = -1082.1x - 0.5057
-4.14 R² = 1

-4.16
(1/T)
LN(K) 1/T
-4,13516656 0,00335402
-4,01738352 0,00324517 𝐸𝑎
1082,1 =
𝑅

1082,1 8,314 = 𝐸𝑎

𝐽
𝐸𝑎 = 8996,5794 𝑚𝑜𝑙
Mecanismo
O –
O
–
O
H3C
O CH3
+ HO
+ –
O
H3C O CH3
H3C OH OH
H3C