Para la reacción: A + B -----> Prod.

Determine los órdenes de reacción y la constante de velocidad k

CB0 = 0.5150 M
CV 7.5*10^-5 CV 5.625*10^-5 CV 3.75*10^-5
Tiempo (s) Absorbancia Tiempo (s) Absorbancia Tiempo (s) Absorbancia
0 1.3928 0 1.0683 0 0.557
2 1.3075 2 1.016 2 0.5209
4 1.2402 4 0.9685 4 0.4951
6 1.1858 6 0.9226 6 0.4696
8 1.134 8 0.8818 8 0.4453
10 1.0799 10 0.8418 10 0.4253

CA0 = 7.5*10^-5
NAOH 0.5150 NAOH 0.3862 NAOH 0.2575
Tiempo (s) Absorbancia Tiempo (s) Absorbancia Tiempo (s) Absorbancia
0 1.3506 0 1.3644 0 1.4579
2 1.2955 2 1.3121 2 1.4177
4 1.2259 4 1.2707 4 1.3786
6 1.1665 6 1.2260 6 1.3453
8 1.1070 8 1.1862 8 1.3167
10 1.0509 10 1.1466 10 1.2868

*
1.4200

1.4100 f(x) = − 0.00371142857142857 x + 1.41605714

R² = 0.953247729018844
1.4000

1.3900

1.3800

1.3700

1.3600

1.3500
0 2 4 6
 B,E,H,K,N
B0 = 0.5150 M m
CV 2.8125*10^-5 CV 1.875*10^-5 -5.59415E-07
Tiempo (s) Absorbancia Tiempo (s) Absorbancia -4.131627E-07
0 0.4931 0 0.3216 -2.3766E-07
2 0.4668 2 0.3038 -1.919561E-07
4 0.4448 4 0.2891 -1.297989E-07
6 0.4244 6 0.2751
8 0.4047 8 0.2620 Alfa
10 0.3868 10 0.2494 1
B,E,H,K,N
A0 = 7.5*10^-5 m
NAOH 0.1975 NAOH 0.1375 -5.539305E-07
Tiempo (s) Absorbancia Tiempo (s) Absorbancia -3.948812E-07
0 1.456 0 1.4131 -3.107861E-07
2 1.4343 2 1.4076 -8.775137E-08
4 1.4258 4 1.4060 -6.76417E-08
6 1.4188 6 1.3962
8 1.4112 8 1.3861
10 1.4044 10 1.3760

*
Alfa.
− 0.00371142857142857 x + 1.41605714285714 -11 -10.8 -10.6 -10.4 -10.2 -10 -9
953247729018844

f(x) = 1.06560949337492 x − 4.29959544782002

R² = 0.991532398897953

2 4 6 8 10 12
 y x mx b
r0 Ca0 ln(r0) ln(Ca0) CB0 va Alfa b
5.59415E-07 0.00007500 -14.3963743 -9.49802244 0.515 -1 1 -4.2996
4.131627E-07 0.00005625 -14.6994244 -9.78570452
2.3766E-07 0.00003750 -15.2524249 -10.1911696 54700
1.919561E-07 0.00002813 -15.465999 -10.4788517
1.297989E-07 0.00001875 -15.8572795 -10.8843168

Beta k= 0.03867672 seg ^-1 M^ -2

2 r= 0.03867672 seg ^-1 M^ -2 Ca^

r0 Ca0 ln(r0) ln(Ca0) CA0 vb Beta b

5.539305E-07 0.5150 -14.4062266 -0.66358838 0.000075 -1 2 -13.141
3.948812E-07 0.3862 -14.744681 -0.95139991 mx b
3.107861E-07 0.2575 -14.9841609 -1.35673556
8.775137E-08 0.1975 -16.2487583 -1.62201669
6.76417E-08 0.1375 -16.5090414 -1.98413136
y x

Alfa. Beta.
-13.5 -16.1
-10.2 -10 -9.8 -9.6 -9.4 -2.05 -2 -1.95 -1.9 -1.85 -1.8 -1.75 -1.7 -1.65 -1
-16.15
-14 -16.2
-16.25
f(x) = 0.718786400593586 x − 15.0828748078347
959544782002 -14.5 R² = 1 -16.3
-16.35
-15
-16.4
-16.45
-15.5
-16.5

-16 -16.55
 k' k
0.01357399 0.05117914

1 Cb^ 2

k´´ k
1.9631E-06 0.02617429

-16.1
-1.75 -1.7 -1.65 -1.6
-16.15
-16.2
-16.25
748078347
-16.3
-16.35
-16.4
-16.45
-16.5
-16.55
 CB0 = 0.5150 M
CV 7.5*10^-5 CV 5.625*10^-5 CV 3.75*10^-5
Tiempo (s) Absorbancia Tiempo (s) Absorbancia Tiempo (s) Absorbancia
0 1.3928 0 1.0683 0 0.557
2 1.3075 2 1.016 2 0.5209
4 1.2402 4 0.9685 4 0.4951
6 1.1858 6 0.9226 6 0.4696
8 1.134 8 0.8818 8 0.4453
10 1.0799 10 0.8418 10 0.4253

CA0 = 7.5*10^-5
NAOH 0.5150 NAOH 0.3862 NAOH 0.2575
Tiempo (s) Absorbancia Tiempo (s) Absorbancia Tiempo (s) Absorbancia
0 1.3506 0 1.3644 0 1.4579
2 1.2955 2 1.3121 2 1.4177
4 1.2259 4 1.2707 4 1.3786
6 1.1665 6 1.2260 6 1.3453
8 1.1070 8 1.1862 8 1.3167
10 1.0509 10 1.1466 10 1.2868

Chart Title
1.4200

1.4100 f(x) = − 0.00371142857142857 x + 1.41605714285714

R² = 0.953247729018844
1.4000

1.3900

1.3800

1.3700

1.3600

1.3500
0 2 4 6 8 10 12
= 0.5150 M m
CV 2.8125*10^-5 CV 1.875*10^-5 -5.59415E-07
Tiempo (s) Absorbancia Tiempo (s) Absorbancia -4.131627E-07
0 0.4931 0 0.3216 -2.3766E-07
2 0.4668 2 0.3038 -1.919561E-07
4 0.4448 4 0.2891 -1.297989E-07
6 0.4244 6 0.2751
8 0.4047 8 0.2620 Alfa
10 0.3868 10 0.2494 1
B,E,H,K,N
= 7.5*10^-5 m
NAOH 0.1975 NAOH 0.1375 -5.545574E-07
Tiempo (s) Absorbancia Tiempo (s) Absorbancia -3.947245E-07
0 1.456 0 1.4131 -3.112561E-07
2 1.4343 2 1.4076 -8.730731E-08
4 1.4258 4 1.4060 -6.78506E-08
6 1.4188 6 1.3962
8 1.4112 8 1.3861
10 1.4044 10 1.3760

ALFA
-13.5
-11 -10.8 -10.6 -10.4 -10.2 -10 -9.8 -9.6 -9.4
-2.2 -2 -1.8 -1
-14

f(x) = 1.06560949337492 x − 4.29959544782002 -14.5 f(x) = 1.7005119

R² = 0.991532398897953 R² = 0.89808007

-15

-15.5

-16
 r0 Ca0 ln(r0) ln(Ca0) CB0 va Alfa b
5.59414991E-07 0.00007500 -14.3963743 -9.49802244 0.515 -1 1 -4.2996
4.13162706E-07 0.00005625 -14.6994244 -9.78570452
2.37659963E-07 0.00003750 -15.2524249 -10.1911696 54700
1.91956124E-07 0.00002813 -15.465999 -10.4788517
1.29798903E-07 0.00001875 -15.8572795 -10.8843168

Beta k= 0.03867672 seg ^-1 M^ -2

2 r= 0.03867672 seg ^-1 M^ -2 Ca^

r0 Ca0 ln(r0) ln(Ca0) CA0 vb Beta b

5.54557404E-07 0.5150 -14.4050955 -0.66358838 0.000075 -1 2 -13.141
3.94724497E-07 0.3862 -14.7450778 -0.95139991 mx b
3.11256124E-07 0.2575 -14.9826497 -1.35673556
8.73073126E-08 0.1975 -16.2538316 -1.62201669
6.78506E-08 0.1375 -16.505957 -1.98413136
y x

BETA
-13
-2.2 -2 -1.8 -1.6 -1.4 -1.2 -1 -0.8 -0.6 -0.4
-13.5

-14

f(x) = 1.70051198182118 x − 13.1413723326797 -14.5

R² = 0.89808007136607
-15

-15.5

-16

-16.5

-17
 k' k
0.013573987521 0.05117914

1 Cb^ 2

k´´ k
0.000001963072 0.02617429