100

99
98
97
96
95
94
93
92
91
Temperatura (°C)

90
89
88
87
86
85
84
83
82
81
80
79
78
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X isop, Yisop
sistema isopropanol-agua

T(°C) xisop% yisop% xisop yisop

97.3 0 0 0 0
93 1.18 21.97 0.0118 0.2197
89.75 3.22 32.41 0.0322 0.3241
84.02 8.41 46.2 0.0841 0.462
83.85 9.1 47.06 0.091 0.4706
82.12 19.78 52.42 0.1978 0.5242
81.64 28.68 53.44 0.2868 0.5344
81.25 34.96 55.16 0.3496 0.5516
80.62 45.25 59.26 0.4525 0.5926
80.32 60.3 64.22 0.603 0.6422
80.16 67.94 68.21 0.6794 0.6821
80.21 68.1 68.26 0.681 0.6826
80.28 76.93 74.21 0.7693 0.7421
80.66 85.67 82.7 0.8567 0.827
81.51 94.42 91.6 0.9442 0.916
82.5 100 100 1 1
 66

65

64

63

62

61
Temperatura (°C)

60

59 expy
expx
58 modelx
modely
57

56

55

54

53

52
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X clor, Yclor
datos experimentales 1 atm
sistema cloroformo- metanol
T(°C) Xcloroformo Ycloroformo
64.2 0 0
63 0.04 0.102
60.9 0.095 0.215
57.8 0.196 0.378
55.9 0.287 0.472
54.3 0.425 0.564
53.5 0.65 0.65
53.9 0.797 0.701
55.2 0.904 0.768
57.9 0.97 0.875
60.5 1 1
 1

0.9

0.8

0.7

0.6
Y clor

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X clorof
Ecuacion NRTL
estimacion datos de equilibrio cloroformo (C) metanol (M) Ptotal= 760 mmHg

xC xM T(°C) lngamaC lngamaM gamaC gamaM pvC pvM

0 1 64.56 0.9266523865 0 2.5260388061 1 846.90282471 760.36696359
0.1 0.9 60.6 0.8417527693 0.0046254651 2.320430594 1.004636179 745.14259565 649.31950547
0.2 0.8 57.79 0.7489448051 0.0212188604 2.1147673472 1.0214455812 678.96854286 579.02596831
0.3 0.7 55.85 0.648726575 0.0549277486 1.9131030838 1.0564642809 636.05602559 534.30815013
0.4 0.6 54.61 0.5420828341 0.1127892257 1.7195847446 1.1193959682 609.77105204 507.2704245
0.5 0.5 53.92 0.4307515383 0.2045352079 1.5384132657 1.2269546536 595.52168448 492.72865805
0.6 0.4 53.62 0.3176447324 0.3438098049 1.3738880766 1.4103103759 589.40919316 486.51612096
0.7 0.3 53.61 0.2075261824 0.5500523216 1.2306299373 1.7333437067 589.20630308 486.31017356
0.8 0.2 53.87 0.1081275837 0.8514864648 1.1141898888 2.3431272406 594.4994639 491.6886387
0.9 0.1 54.95 0.0320373683 1.2900084175 1.0325560895 3.632817135 616.89104214 514.56721442
1 0 61.205 0 1.9294577869 1 6.8857756715 760.0323625 665.35038185

alfa= 0.3
tau12 2.1416 Temperatura vs composicion
tau21= -0.1998 66
G12= 0.525986359
64
G21= 1.0617728383
62

Temperatura
60
Constantes de Antoine
58
especie A B C
Clororformo 6.95465 1170.966 226.232 56
Metanol 8.08097 1582.271 239.726 54
52
50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
Composicion

Xc - Yc
1.2

1 1

0.8 0.8

0.6 0.6
Yc

M
 Xc - Yc
1.2

1 1

0.8 0.8

0.6 0.6

Yc

YM
0.4 0.4

0.2 0.2

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2
Xc
 (pvC)(xC)(gamaC) (pvM)(xM)(gamaM) Ptotal yC yM
0 760.366963593625 760.36696359 0 1
172.905167584955 587.096880259563 760.00204784 0.2275061864 0.7724938136
287.172100844189 473.154813375596 760.32691422 0.3776955616 0.6223044384
365.052223210941 395.134232914793 760.18645613 0.4802140584 0.5197859416
419.421199520483 340.701880772316 760.12308029 0.5517806397 0.4482193603
458.079229718396 302.277859984788 760.3570897 0.6024527632 0.3975472368
485.869357633296 274.455493365321 760.324851 0.6390286428 0.3609713572
507.566441066064 252.882803657922 760.44924472 0.6674560394 0.3325439606
529.908233240161 230.417808652118 760.32604189 0.6969486826 0.3030513174
573.277141893522 186.932859368025 760.21000126 0.7541036568 0.2458963432
760.03236250041 0 760.0323625 1 0
Promedio 760.24591392
Referencia
0 0
mposicion 1 1

0.6 0.7 0.8 0.9 1 1.1

on

Xm-Ym
1

0.8

0.6
M
 Xm-Ym
1

0.8

0.6
YM

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
XM
 Sistema metanol-cloroformo (0.5 atm)
T vs xy
50

49

48

47

46

45

44
Temperatura °C

43

42

41

40

39

38

37

36

35
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Xc, Yc
 Cloroformo-metanol 0.5 atm
1

0.9

0.8

0.7

0.6

0.5
Yc

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Xc
Ecuacion NRTL
estimacion datos de equilibrio cloroformo (C) metanol (M) Ptotal= 380 mmHg

xC xM T(°C) lngamaC lngamaM gamaC gamaM

0 1 47.9 0.9266523865 0 2.5260388061 1
0.1 0.9 43.66 0.8417527693 0.0046254651 2.320430594 1.004636179
0.2 0.8 40.68 0.7489448051 0.0212188604 2.1147673472 1.0214455812
0.3 0.7 38.64 0.648726575 0.0549277486 1.9131030838 1.0564642809
0.4 0.6 37.3 0.5420828341 0.1127892257 1.7195847446 1.1193959682
0.5 0.5 36.5 0.4307515383 0.2045352079 1.5384132657 1.2269546536
0.6 0.4 36.11 0.3176447324 0.3438098049 1.3738880766 1.4103103759
0.7 0.3 35.99 0.2075261824 0.5500523216 1.2306299373 1.7333437067
0.8 0.2 36.15 0.1081275837 0.8514864648 1.1141898888 2.3431272406
0.9 0.1 36.88 0.0320373683 1.2900084175 1.0325560895 3.632817135
1 0 41.46 0 1.9294577869 1 6.8857756715

alfa= 0.3
tau12 2.1416
tau21= -0.1998
G12= 0.525986359
G21= 1.0617728383
pvC pvM (pvC)(xC)(gamaC)
482.06908637 380.04028072
413.05076445 314.42855663 95.8455630694881
369.45676184 274.27371075 156.263019226327
341.80232404 249.36249376 196.170924054104
324.5606558 234.06497677 223.243820971032
314.6054047 225.31729071 241.996564032372
309.84217689 221.15438102 255.413083474339
308.38831252 219.88669199 265.658322789246
310.3280232 221.57831981 276.611476520824
319.30303168 229.43721405 296.72846077499
380.49302174 284.33941803 380.493021744198
(pvM)(xM)(gamaM) Ptotal yC
0 380.040280719346 380.04028072 0
284.297673344465 380.14323641 0.2521301286
224.124535905078 380.38755513 0.4107995047
184.409797351421 380.58072141 0.5154515534
157.206834772054 380.45065574 0.5867878465
138.227049193016 380.22361323 0.6364585355
124.758527285451 380.17161076 0.6718362872
114.341764125297 380.00008691 0.6991006895
103.837239414125 380.44871593 0.7270663954
83.3503442614912 380.07880504 0.7807024671
0 380.49302174 1
Referencia
0
1
yM KC KM volat relat
1 #DIV/0! 1 #DIV/0!
0.7478698714 2.5213012856 0.8309665238 3.0341791316
0.5892004953 2.0539975233 0.7365006192 2.7888605519
0.4845484466 1.7181718448 0.6922120665 2.4821466251
0.4132121535 1.4669696162 0.6886869226 2.1300965187
0.3635414645 1.272917071 0.727082929 1.750717862
0.3281637128 1.1197271453 0.820409282 1.3648396842
0.3008993105 0.9987152708 1.0029977015 0.9957303683
0.2729336046 0.9088329942 1.3646680231 0.6659736865
0.2192975329 0.8674471856 2.1929753292 0.3955572022
0 1 #DIV/0! #DIV/0!

0
1